JP6239540B2 - ペーパー捺染法に用いる捺染用紙 - Google Patents
ペーパー捺染法に用いる捺染用紙 Download PDFInfo
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- JP6239540B2 JP6239540B2 JP2015021000A JP2015021000A JP6239540B2 JP 6239540 B2 JP6239540 B2 JP 6239540B2 JP 2015021000 A JP2015021000 A JP 2015021000A JP 2015021000 A JP2015021000 A JP 2015021000A JP 6239540 B2 JP6239540 B2 JP 6239540B2
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- 229920001778 nylon Polymers 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- HXHCOXPZCUFAJI-UHFFFAOYSA-N prop-2-enoic acid;styrene Chemical compound OC(=O)C=C.C=CC1=CC=CC=C1 HXHCOXPZCUFAJI-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- KUIXZSYWBHSYCN-UHFFFAOYSA-L remazol brilliant blue r Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=C2C(=O)C3=CC=CC=C3C(=O)C2=C1NC1=CC=CC(S(=O)(=O)CCOS([O-])(=O)=O)=C1 KUIXZSYWBHSYCN-UHFFFAOYSA-L 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/28—Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/72—Coated paper characterised by the paper substrate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
- D21H23/34—Knife or blade type coaters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/002—Tissue paper; Absorbent paper
- D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
- D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
- D06P5/007—Transfer printing using non-subliming dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Paper (AREA)
Description
本発明において、「捺染用紙」とは、ペーパー捺染法に用いられ、転写する画像が印刷される前の白紙状態にある紙をいう。「捺染紙」とは、捺染用紙に対して転写する画像が印刷された状態にある紙をいう。以下、ペーパー捺染法に用いる捺染用紙を「捺染用紙」と記載する。
<糊層塗工液の調製>
水溶性ポリエステル系バインダー(プラスコートRZ−142、ガラス転移温度34℃、互応化学工業社製)300部、ポリビニルアルコール(AP−17、日本酢ビ・ポバール社製)30部、エーテル化澱粉(ソルビトーゼC−5、AVEBE社製)120部、珪酸アルミニウム誘導体(エンバテックスD−23、共栄化学社製)60部、酸化珪素(ミズカシルP−78A、水澤化学工業社製)55部、ジシアンジアミド60部、ソーダ灰210部、尿素90部、チオ尿素60部、界面活性剤(MAC−100S、北広ケミカル社製)15部、水930部を、撹拌機でよく撹拌しながら混合し、糊層塗工液を調製した。
原紙として、坪量77g/m2、JAPAN TAPPI No.1:2000で規定される原紙表面のワックスピック強度がNo.8Aである上質紙を用いた。この原紙の一方の表面へ上記糊層塗工液を、エアーナイフコーターを用いて塗工し乾燥し、捺染用紙を得た。このとき、糊層の塗工量は20g/m2であった。
反応染料インク液(C.I.Reactive Blue 19 15%、ポリエチレングリコール5%、グリセリン5%、ε−カプロラクタム5%、イオン交換水70%)、反応染料インク液(C.I.Reactive Red 226 10%、ポリエチレングリコール5%、グリセリン5%、ε−カプロラクタム5%、イオン交換水75%)、および反応染料インク液(C.I.Reactive Yellow 95 15%、ポリエチレングリコール5%、グリセリン5%、ε−カプロラクタム5%、イオン交換水70%)を用いて、捺染用紙の糊層を設けた側にインクジェットプリンター(ValueJet VJ−1324、武藤工業社製)によって評価画像を印刷し、捺染紙(ロール紙)を得た。
被印刷物として綿布を用いた。得られた捺染紙と綿布とを密着させ、加熱・加圧(190℃、0.5MPa、2.5m/min、ローラー型)して綿布に捺染紙を貼り付けた。捺染紙を綿布に貼り付けたままの状態で、100℃で15分間スチーミングによる固着処理を行い、染料インクを綿布に転写することによって捺染した。その後、捺染紙を剥離した。
実施例1において、原紙として、坪量77g/m2、JAPAN TAPPI No.1:2000で規定される原紙表面のワックスピック強度がNo.13Aである上質紙を用いた以外は実施例1と同様に行い、実施例2とした。
実施例1において、原紙として、坪量77g/m2、JAPAN TAPPI No.1:2000で規定される原紙表面のワックスピック強度がNo.18Aである上質紙を用いた以外は実施例1と同様に行い、実施例3とした。
実施例1において、水溶性ポリエステル系バインダー(プラスコートRZ−142、ガラス転移温度34℃、互応化学工業社製)を水溶性ポリエステル系バインダー(ペスレジンA−615GE、ガラス転移温度47℃、高松油脂社製)に変更する以外は実施例1と同様に行い、実施例4とした。
実施例1において、水溶性ポリエステル系バインダー(プラスコートRZ−142、ガラス転移温度34℃、互応化学工業社製)を水溶性ポリエステル系バインダー(ペスレジンA−613D、ガラス転移温度54℃、高松油脂社製)に変更する以外は実施例1と同様に行い、実施例5とした。
実施例1において、水溶性ポリエステル系バインダー(プラスコートRZ−142、ガラス転移温度34℃、互応化学工業社製)を水溶性ポリエステル系バインダー(エマルションエリーテルKA−5071S、ガラス転移温度67℃、ユニチカ社製)に変更する以外は実施例1と同様に行い、実施例6とした。
実施例1において、水溶性ポリエステル系バインダー(プラスコートRZ−142、ガラス転移温度34℃、互応化学工業社製)を水溶性ポリエステル系バインダー(エマルションエリーテルKZA−6034、ガラス転移温度72℃、ユニチカ社製)に変更する以外は実施例1と同様に行い、実施例7とした。
実施例1において、水溶性ポリエステル系バインダー(プラスコートRZ−142、ガラス転移温度34℃、互応化学工業社製)を水溶性ポリエステル系バインダー(エマルションエリーテルKZA−3556、ガラス転移温度80℃、ユニチカ社製)に変更する以外は実施例1と同様に行い、実施例8とした。
実施例1において、水溶性ポリエステル系バインダー(プラスコートRZ−142、ガラス転移温度34℃、互応化学工業社製)を水溶性ポリエステルウレタン系バインダー(ハイドランAP−20、ガラス転移温度27℃、DIC社製)に変更する以外は実施例1と同様に行い、実施例9とした。
実施例1において、原紙として、坪量77g/m2、JAPAN TAPPI No.1:2000で規定される原紙表面のワックスピック強度がNo.20Aである上質紙を用いた以外は実施例1と同様に行い、実施例10とした。
実施例1において、原紙として、坪量77g/m2、JAPAN TAPPI No.1:2000で規定される原紙表面のワックスピック強度がNo.6Aである上質紙を用いた以外は実施例1と同様に行い、比較例1とした。
固着処理後に捺染紙を被印刷物から剥離するときの被印刷物の状態を観察した。被印刷物の表面を目視にて下記の基準により官能評価した。本発明において、評価2であれば、剥離性に優れるものとする。
2:被印刷物より容易に剥離でき、被印刷物へ捺染紙の付着がほとんどない。
1:被印刷物より剥離し難く、被印刷物の表面に捺染紙が破れて一部付着している。
捺染カブリ抑制性は、捺染後の被印刷物の画像に対して、染料インクが転写されないで現れる微小なインク抜け部あるいは画像の境界域の滲みという捺染カブリの存在を目視で確認し、下記の基準によって官能評価した。本発明において、評価2以上であれば、捺染カブリ抑制性を有するものとする。
4:カブリが認められず、極めて良好である。
3:僅かにカブリが認められるが、良好である。
2:カブリが認められるものの、実用上許容できる下限レベルである。
1:カブリが認められ、実用上許容できるレベルにない。
上記のように得られた捺染用紙において、斜光を当てながら糊層塗工液が塗工された表面を観察した。結果を下記の基準により官能評価した。本発明において、評価2または3であれば、塗工ムラが抑制されているものとする。
3:塗工ムラがほとんど認められない。
2:塗工ムラが若干認められる。
1:上記2の評価よりも明らかに塗工ムラが認められる。
また、実施例1〜4、9および10と実施例5〜8との対比から、水溶性合成系バインダーの少なくとも1種が、ガラス転移温度51℃以上の水溶性ポリエステル系バインダーであると、塗工ムラが抑制されて、より好ましいと分かる。
Claims (1)
- 被印刷物に捺染紙を密着させたままで染料の固着処理を行うペーパー捺染法に用いる捺染用紙であって、原紙と、原紙表面に糊層とを有し、原紙のワックスピック強度がNo.8A以上であり、前記糊層が水溶性合成系バインダーと天然系糊剤とを少なくとも含有し、前記水溶性合成系バインダーの少なくとも1種がガラス転移温度51℃以上の水溶性ポリエステル系バインダーであることを特徴とする捺染用紙。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015021000A JP6239540B2 (ja) | 2015-02-05 | 2015-02-05 | ペーパー捺染法に用いる捺染用紙 |
CN201680005751.XA CN107109783B (zh) | 2015-02-05 | 2016-01-27 | 用于纸印花法的印花用纸 |
US15/545,787 US10221526B2 (en) | 2015-02-05 | 2016-01-27 | Textile printing paper for use in paper printing method |
PCT/JP2016/052319 WO2016125652A1 (ja) | 2015-02-05 | 2016-01-27 | ペーパー捺染法に用いる捺染用紙 |
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JP2015021000A JP6239540B2 (ja) | 2015-02-05 | 2015-02-05 | ペーパー捺染法に用いる捺染用紙 |
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JP2016141919A JP2016141919A (ja) | 2016-08-08 |
JP6239540B2 true JP6239540B2 (ja) | 2017-11-29 |
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US (1) | US10221526B2 (ja) |
JP (1) | JP6239540B2 (ja) |
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WO (1) | WO2016125652A1 (ja) |
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CN110168162A (zh) * | 2017-01-25 | 2019-08-23 | 三菱制纸株式会社 | 纸印染法中使用的印染用纸 |
JP2022026570A (ja) * | 2020-07-31 | 2022-02-10 | セイコーエプソン株式会社 | インクジェット顔料捺染用処理液組成物、インクセット、及び記録方法 |
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JPS5227891A (en) * | 1975-08-22 | 1977-03-02 | Nippon Kankoushi Kougiyou Kk | Stencil material for printing |
US6811840B1 (en) * | 1996-02-23 | 2004-11-02 | Stahls' Inc. | Decorative transfer process |
NZ508191A (en) * | 1999-11-23 | 2002-03-28 | Nat Starch Chem Invest | A method of modulating surface sizing properties such as porosity reduction, resistance to liquid penetration and surface strength when used as surface size on paper |
US6521088B1 (en) * | 1999-11-23 | 2003-02-18 | National Starch And Chemical Investment Holding Corporation | Degraded hydrophobic, particulate starches and their use in paper sizing |
DE60227459D1 (ja) * | 2001-03-09 | 2008-08-21 | Dainippon Printing Co Ltd | |
JP2003073985A (ja) * | 2001-08-31 | 2003-03-12 | Dainichi Shigyo Kk | 転写捺染印刷用紙 |
EP2500464A4 (en) | 2009-11-09 | 2015-01-14 | Yamamoto Genshi | METHOD OF PRINTING FIBROUS MATERIALS AND LEATHER BY PAPER TRANSFER |
CN102828439B (zh) * | 2011-06-13 | 2015-02-18 | 金东纸业(江苏)股份有限公司 | 转移印花纸及其生产方法 |
JP6075945B2 (ja) * | 2011-11-02 | 2017-02-08 | 株式会社 Smi | 繊維材料又は皮革材料のペーパー捺染法及び捺染紙 |
JP6161871B2 (ja) * | 2012-03-30 | 2017-07-12 | 日本製紙株式会社 | 捺染印刷用転写紙および捺染方法 |
WO2015093276A1 (ja) * | 2013-12-18 | 2015-06-25 | 三菱製紙株式会社 | ペーパー捺染法に用いる捺染用紙 |
WO2015093277A1 (ja) * | 2013-12-18 | 2015-06-25 | 三菱製紙株式会社 | ペーパー捺染法に用いる捺染用紙 |
JP5778366B1 (ja) * | 2015-02-27 | 2015-09-16 | 大王製紙株式会社 | 昇華型インクジェット捺染転写紙 |
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2015
- 2015-02-05 JP JP2015021000A patent/JP6239540B2/ja active Active
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2016
- 2016-01-27 WO PCT/JP2016/052319 patent/WO2016125652A1/ja active Application Filing
- 2016-01-27 CN CN201680005751.XA patent/CN107109783B/zh not_active Expired - Fee Related
- 2016-01-27 US US15/545,787 patent/US10221526B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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JP2016141919A (ja) | 2016-08-08 |
CN107109783B (zh) | 2020-06-05 |
WO2016125652A1 (ja) | 2016-08-11 |
US10221526B2 (en) | 2019-03-05 |
CN107109783A (zh) | 2017-08-29 |
US20180016747A1 (en) | 2018-01-18 |
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