WO2010079541A1 - 半導体レーザ装置 - Google Patents
半導体レーザ装置 Download PDFInfo
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- WO2010079541A1 WO2010079541A1 PCT/JP2009/005403 JP2009005403W WO2010079541A1 WO 2010079541 A1 WO2010079541 A1 WO 2010079541A1 JP 2009005403 W JP2009005403 W JP 2009005403W WO 2010079541 A1 WO2010079541 A1 WO 2010079541A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
- H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/34—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers
- H01S5/343—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
- H01S5/34333—Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser with a well layer based on Ga(In)N or Ga(In)P, e.g. blue laser
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/20—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
- H01S5/22—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
- H01S5/2201—Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure in a specific crystallographic orientation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/30—Structure or shape of the active region; Materials used for the active region
- H01S5/32—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures
- H01S5/3202—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures grown on specifically orientated substrates, or using orientation dependent growth
- H01S5/3203—Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures grown on specifically orientated substrates, or using orientation dependent growth on non-planar substrates to create thickness or compositional variations
Definitions
- the present invention relates to a semiconductor laser device, and more particularly to a semiconductor laser device using a nitride semiconductor.
- GaN gallium nitride
- a GaN-based semiconductor laser device is required to have an output beam shape with a far-field image (Far Field Pattern: FFP) having a single peak.
- the flatness of the optical waveguide is low and there are irregularities with a period that causes scattering in the laser light guided in the optical waveguide, a part of the scattered laser light is absorbed inside the resonator. A part of the scattered laser light is emitted to the substrate side. Since light loss occurs due to scattering, the efficiency of the laser device is reduced. The light emitted to the substrate is guided in a mode called a substrate mode, which is different from the original waveguide mode. When this light is radiated to the outside, it appears as a ripple in the FFP of the outgoing beam and the unimodality is impaired. For this reason, in order to realize a semiconductor laser device in which the FFP is unimodal, it is important to flatten the optical waveguide.
- GaN-based semiconductor lasers are required to have high efficiency (high output) for high-speed writing and multi-layer recording in disk applications. Further, for display and backlight applications, high efficiency (high output) is required for high brightness.
- the effective volume of the active layer that contributes to the generation of laser light decreases.
- the reduction in active layer deposition reduces the efficiency of the laser device to reduce the active layer gain. Therefore, in order to realize a highly efficient semiconductor laser device w, it is necessary to keep the band gap energy (Eg) of the active layer sufficiently uniform in the optical gain region.
- a method for controlling the off-angle of the substrate is known (see, for example, Patent Document 1). For example, when the off angle of the substrate is 0.2 ° to 1.0 °, the semiconductor layer formed over the substrate can be planarized and the optical waveguide can be planarized.
- the inventor of the present application has found that by controlling the off-angle of the substrate, not only can the flatness of the surface of the laminated structure be improved, but also the variation in Eg of the active layer can be reduced.
- the off-angle is provided in the substrate to flatten the optical waveguide and make the active layer Eg uniform, there is a problem that the cost of the substrate increases.
- there is an off-angle distribution in the plane of the substrate only specific portions of the substrate can be used. For this reason, the number of semiconductor laser devices obtained from one wafer is greatly reduced.
- An object of the present disclosure is to solve the above problems and to realize a semiconductor laser device having a planarized optical waveguide and an active layer with uniform band gap energy without controlling the off-angle of the substrate. .
- an exemplary semiconductor laser device has a configuration in which a semiconductor layer is formed on a step and an optical waveguide is formed in a flat region near the step.
- the exemplary semiconductor laser device includes a semiconductor layer stack including an active layer formed on a substrate, and the semiconductor layer stack is in a direction intersecting the front end surface that emits light and the front end surface. Striped optical waveguides formed, a first region extending in a direction intersecting the front end surface, a second region having a height different from that of the first region, and the first region and the second region And a flat region having a smaller periodic unevenness on the surface than the second region, and the optical waveguide is formed in the flat region.
- the optical waveguide is formed in a flat region, the flatness of the optical waveguide can be improved. For this reason, ripples are less likely to occur in the far-field image (FFP) of the laser beam, and an FFP closer to unimodality can be realized. Furthermore, since the variation in band gap energy in the active layer can be reduced, the efficiency of the semiconductor laser device can be improved.
- FFP far-field image
- the flat region may be configured such that the change in height is smaller than that of the second region in the direction intersecting the front end surface.
- the semiconductor layer stack may have a stripe-shaped ridge portion formed in a direction intersecting the front end surface, and the ridge portion may be formed in a flat region.
- the substrate has two regions whose top surfaces are different from each other, the first region is formed on one of the two regions, and the second region is the other of the two regions. It is good also as a structure currently formed on the top.
- one of the two regions may be a groove
- the first region may be formed on the groove
- one of the two regions may be a stripe-shaped convex portion
- the first region may be convex. It may be formed on the part.
- the distance between the boundary between the two regions and the ridge portion may be 1 ⁇ m or more and 15 ⁇ m or less.
- the portion formed below the ridge portion in the active layer may have a configuration in which variation in band gap energy is smaller than that in other portions of the active layer.
- the upper surface of the region where the optical waveguide is formed in the semiconductor layer stack may have a root mean square roughness of 20 nm or less.
- the semiconductor layer stack may be made of a nitride semiconductor, and the optical waveguide may be formed in a direction along the m-axis of the nitride semiconductor.
- the active layer may include indium.
- the flat region is preferably formed continuously from the front end surface to the rear end surface opposite to the front end surface.
- the exemplary semiconductor laser device it is possible to realize a semiconductor laser device having a planarized optical waveguide and an active layer with uniform band gap energy without controlling the off-angle of the substrate.
- (A) and (b) are graphs obtained by quantifying the surface shape of the semiconductor layer shown in FIG. 1, (a) is a graph along the IIa-IIa line in FIG. 1, and (b) is a IIb- It is a graph in the IIb line. It is the result of measuring the emission wavelength of cathodoluminescence in the vicinity of the groove in the active layer formed on the substrate having the groove. It is the result of having measured the emission wavelength of the cathode luminescence in the part away from the groove part in the active layer formed on the substrate having the groove part.
- FIG. 1 shows a semiconductor laser device according to an embodiment
- (a) is a plan view
- (b) is a cross-sectional view taken along line Vb-Vb in (a)
- (c) is shown in FIG. It is sectional drawing in a resonator end surface. It is sectional drawing which shows the modification of the semiconductor laser apparatus which concerns on one Embodiment. It is sectional drawing which shows the modification of the semiconductor laser apparatus which concerns on one Embodiment. It is sectional drawing which shows the modification of the semiconductor laser apparatus which concerns on one Embodiment.
- FIG. 1 shows the result of measuring the surface shape of the nitride semiconductor layer 104 grown on the substrate having the groove 102 using a laser interferometer type shape measuring machine (PTI250 manufactured by Zygo).
- the plane orientation of the hexagonal GaN-based crystal is indicated by the symbols c, a, and m.
- c indicates a plane equivalent to the (0001) plane and a c-axis which is a normal vector thereof.
- a indicates a plane equivalent to the (11-20) plane and an a-axis which is a normal vector thereof.
- m indicates a plane equivalent to the (1-100) plane and its normal vector, the m-axis.
- the minus sign “ ⁇ ” attached to the Miller index in the plane orientation represents the inversion of one index following the minus sign for convenience.
- the thickness is 100 mm on the substrate on which the groove 102 having a length in the m-axis direction of 100 ⁇ m, a width in the a-axis direction of 20 ⁇ m, and a depth of 2 ⁇ m in the c-axis direction is formed.
- a 2 ⁇ m nitride semiconductor layer 104 is formed.
- the nitride semiconductor layer 104 has a recess that reflects the shape of the groove 102.
- FIG. 2 shows the result of examining the shape of the recess in more detail.
- FIGS. 2A and 2B show changes in the height of the nitride semiconductor layer 104 along the IIa-IIa line and the IIb-IIb line in FIG. 1, respectively. In FIG. 2, the height of the nitride semiconductor layer 104 is relatively shown with the height of the lowest portion being 0.
- FIG. 2A shows the measurement at a position of 5 ⁇ m from the end of the groove 102.
- the portion formed on the side of the groove 102 of the nitride semiconductor layer 104 has a height of 0.2 ⁇ m higher than the other portions.
- the level is low.
- a periodic change in height was observed in a portion formed in a region other than the side of the groove 102.
- the magnitude of the change was about 0.02 ⁇ m to 0.04 ⁇ m, and the period of the change was about 20 ⁇ m to 25 ⁇ m.
- the flat region 105 has almost no difference in height in the m-axis direction, and the change in height is small compared to regions other than the flat region 105.
- RMS root mean square roughness
- the height of the nitride semiconductor layer 104 is about 20 ⁇ m and about 0.1 ⁇ m higher at the position about 5 ⁇ m from the end of the groove 102. It has a slope.
- one side of the groove 102 has a steep slope, and the other side has a gentle slope. This is due to the crystal anisotropy of the nitride semiconductor layer 104. That is, on the side of the groove portion 102 in the a-axis direction, a flat region 105 whose height changes in the a-axis direction in parallel with the groove portion 102 but hardly changes in height in the m-axis direction. Is formed.
- a very flat optical waveguide can be realized by forming an optical waveguide along the m-axis direction in a flat region 105 that is formed on the side of the a-axis direction of the groove 102 and hardly changes in height in the m-axis direction. it can. Thereby, a semiconductor laser device having a unimodal FFP shape can be realized.
- the flat region 105 has an inclination in the a-axis direction, but the width of the ridge portion in the a-axis direction is usually about 1 ⁇ m to 2 ⁇ m. Accordingly, the height change in the a-axis direction in the ridge portion is a monotonous change of about 0.01 ⁇ m, and the inclination in the a-axis direction does not cause a problem. Further, the flat region is not formed only in a portion having an inclination in the a-axis direction, and the flat region 105 having almost no inclination in the a-axis direction can be formed depending on the formation conditions of the semiconductor layer.
- the length of the flat region 105 in the m-axis direction is about 40 ⁇ m.
- the length of the flat region 105 is determined by the length of the groove 102. Therefore, if the length of the groove 102 is increased, the length of the flat region 105 can be increased, and a semiconductor laser device having a large resonator length can be easily formed.
- FIG. 3 and 4 show the results of measuring the emission peak wavelength of cathodoluminescence (CathodeathLuminescence: CL), which is an index of the band gap energy of the active layer, using the nitride semiconductor layer 104 as an active layer.
- CL is measured along a line parallel to the m-axis direction.
- FIG. 3 shows the result of measurement along a line passing through a position 5 ⁇ m away from the end of the groove 102 in the a-axis direction. The result of having performed the measurement along the line which passes the position away from the edge part of the groove part 102 at 100 micrometer or more in the a-axis direction is shown.
- the emission peak wavelength of CL periodically changes in a region sufficiently spaced from the groove 102.
- the magnitude of the change is about 10 nm, and the period of the change is about 25 ⁇ m.
- FIG. 3 at a position of about 5 ⁇ m in the a-axis direction from the groove 102, there is a region where the change in the emission peak wavelength of CL is smaller than the other regions.
- FIG. 3 when the distance in the a-axis direction to the groove 102 is 5 ⁇ m, there is a region where the change in the emission peak wavelength of CL is very small.
- the change in the emission peak wavelength of CL in the region of 50 ⁇ m to 130 ⁇ m is 4 nm or less.
- This region substantially coincides with the flat region shown in FIG. 2A where almost no periodic unevenness is observed. Therefore, by forming the optical waveguide in the flat region 105 shown in FIG. 2A, not only an optical waveguide with excellent flatness can be obtained, but also the variation in the band gap energy of the active layer can be suppressed small. .
- FIG. 5A to 5C show a semiconductor laser device according to an embodiment, where FIG. 5A shows a planar configuration, FIG. 5B shows a cross-sectional configuration taken along line Vb-Vb in FIG. ) Shows a cross-sectional configuration at the resonator end face.
- the semiconductor laser device of this embodiment includes a semiconductor layer stack 20 formed on a substrate 11 having a groove 11a extending in the m-axis direction.
- the substrate 11 may be made of n-type hexagonal GaN or the like whose main surface is the (0001) plane.
- the groove 11a may be formed as follows, for example. An SiO 2 film having a thickness of 0.6 ⁇ m is formed on the substrate 11 by a thermal CVD method using SiH 4 or the like, and then the SiO 2 film is selectively removed by photolithography, and the m-axis direction is removed. A stripe-shaped opening is formed.
- the exposed portion of the substrate 11 is etched to a depth of 2 ⁇ m with an inductive coupled plasma (ICP) etching apparatus using carbon tetrafluoride (CF 4 ).
- ICP inductive coupled plasma
- the groove 11a may have a width in the a-axis direction of 20 ⁇ m.
- the length of the groove 11a in the m-axis direction may be formed so as to reach the opposite rear end surface from the front end surface that emits light.
- the front end face is an end face with a large light output of the two resonator end faces, and the rear end face is an end face with a smaller light output than the front end face opposite to the front end face.
- the semiconductor layer stack 20 includes an n-type cladding layer 22, an n-type guide layer 24, an active layer 26, a p-type guide layer 28, an overflow layer 30, a p-type cladding layer 32, and a contact layer, which are sequentially formed from the substrate 11 side. 34.
- the n-type cladding layer 22 may be n-type Al 0.03 Ga 0.97 N having a thickness of 2 ⁇ m.
- the n-type guide layer 24 may be an n-type GaN layer having a thickness of 0.1 ⁇ m.
- the active layer 26 may be a quantum well active layer in which a barrier layer made of In 0.02 Ga 0.98 N and a well layer made of In 0.06 Ga 0.94 N are stacked three periods.
- the p-type guide layer 28 may be a p-type GaN layer having a thickness of 0.1 ⁇ m.
- the overflow layer (OFS layer) 30 may be an Al 0.20 Ga 0.80 N layer having a thickness of 10 nm.
- the p-type cladding layer 32 includes a strained superlattice layer having a thickness of 0.48 ⁇ m, in which a p-type Al 0.16 Ga 0.84 N layer having a thickness of 1.5 nm and a GaN layer having a thickness of 1.5 ⁇ m are stacked 160 times. do it.
- the p-type cladding layer 32 is partially removed to form a striped ridge portion 20a extending in the m-axis direction, and the contact layer 34 is formed on the ridge portion 20a.
- the semiconductor layer stack 20 may be formed by, for example, a metal organic chemical vapor deposition (MOCVD) method.
- MOCVD metal organic chemical vapor deposition
- As raw materials when using the MOCVD method for example, trimethyl gallium (TMG) is used as a Ga raw material, trimethyl indium (TMI) is used as an In raw material, trimethyl aluminum (TMA) is used as an Al raw material, and ammonia (NH 3 ) is used as an N raw material.
- an n-type impurity silane to Si material is (SiH 4) gas, the Mg raw material is a p-type impurity may be used bis (cyclopentadienyl) magnesium (Cp 2 M g).
- a growth method capable of growing a nitride semiconductor such as a molecular beam epitaxy (MBE) method or a chemical beam epitaxy (CBE) method, may be used.
- MBE molecular beam epitaxy
- CBE chemical beam epitaxy
- the semiconductor layer stack 20 has a first region 20A formed on the groove 11a and a second region 20B having a height higher than that of the first region. Between the first region 20A and the second region 20B, there is an inclined portion whose height changes in the a-axis direction, and a flat portion in which the height in the m-axis direction hardly changes in a portion including the inclined portion. A region 20C is formed. In FIG. 5, the boundary between the first region 20A and the inclined portion is clearly shown, but the first region 20A and the inclined portion may be integrated depending on the width of the groove 11a. . In addition, the second region 20B is illustrated as a flat region, but as described above, the second region 20B has periodic unevenness. Further, in FIG.
- flat regions 20C having the same size are formed on both sides of the first region 20A.
- the flat regions 20C on the left and right sides of the first region 20A. May vary in size.
- the flat region 20C may include a portion other than the inclined portion.
- the second region 20B may include a part of the inclined portion.
- the ridge portion 20a is formed in the flat region 20C.
- the position where the ridge portion 20a is formed may be appropriately determined depending on the shape of the groove portion 11a, the direction of the groove portion, and the like. However, if the distance is too close to the groove 11a, the inclination in the a-axis direction becomes large. Therefore, the distance between the end of the groove 11a and the center line of the ridge 20a is preferably about 1 ⁇ m, and more preferably 2 ⁇ m or more. . In addition, if the distance from the end of the groove 11a is too large, flattening is not sufficient, so the distance is preferably 15 ⁇ m or less, and more preferably 10 ⁇ m or less. In this embodiment, the thickness is 5 ⁇ m.
- the ridge portion 20a may be formed as follows. After the growth of the p-type contact layer 34 is completed, a SiO 2 film having a thickness of 0.3 ⁇ m is formed on the p-type contact layer 34. Subsequently, a stripe-shaped opening having a width of 1.5 ⁇ m is formed in the SiO 2 film by lithography and etching. The opening is formed in parallel with the m-axis. Subsequently, the p-type contact layer 34 and a part of the p-type cladding layer 32 are removed using the SiO 2 film as a mask.
- An insulating film (passivation film) 36 made of SiO 2 having a thickness of 200 nm is formed in a portion of the semiconductor layer stack 20 except for the top of the ridge portion 20a.
- the insulating film 36 may be formed as follows. First, after forming the ridge portion 20a, an SiO 2 film is formed on the entire surface of the semiconductor layer stack 20 including the upper surface of the ridge portion 20a by a thermal CVD method or the like. Next, a resist pattern having an opening having a width of 1.3 ⁇ m is formed on the upper surface of the ridge portion 20a. Subsequently, the SiO 2 film is selectively etched by reactive ion etching (RIE) using trifluoromethane (CHF 3 ) gas using the resist pattern as a mask to expose the contact layer 34.
- RIE reactive ion etching
- CHF 3 trifluoromethane
- a p-side electrode 38 made of palladium (Pd) having a thickness of 40 nm and platinum (Pt) having a thickness of 35 nm is formed in contact with the contact layer 34.
- the p-side electrode 38 may be formed by an electron beam (Electron Beam: EB) vapor deposition method and a lift-off method.
- EB electron beam
- a pad electrode 40 in which titanium (Ti), platinum (Pt), and gold (Au) having a thickness of 50 nm, 200 nm, and 10 ⁇ m are stacked is formed on the p-side electrode 38.
- Ti titanium
- Pt platinum
- Au gold
- the pad electrode 40 is preferably formed at a distance from the end face and side face of the resonator.
- the length in the direction parallel to the ridge portion 20a is 500 ⁇ m and the width in the direction intersecting the ridge portion 20a. May be 150 ⁇ m.
- the pad electrode 40 is formed by first forming a laminated film of titanium (Ti), platinum (Pt), and gold (Au) having thicknesses of 50 nm, 200 nm, and 100 nm, respectively, using an EB vapor deposition method and a lift-off method.
- the thickness of the Au layer may be increased to about 10 ⁇ m by electroplating.
- An n-side electrode 42 in which Ti having a thickness of 5 nm, platinum having a thickness of 10 nm, and Au having a thickness of 1000 nm is stacked is formed on the surface (back surface) opposite to the semiconductor layer stack 20 of the substrate 11. ing.
- the n-side electrode 42 may be formed by EB vapor deposition after forming the pad electrode 40, polishing the substrate 11 from the back surface with diamond slurry, and reducing the thickness of the substrate 11 to about 100 ⁇ m.
- primary cleavage was performed along the m-plane so that the length in the m-axis direction was 600 ⁇ m.
- Secondary cleavage was performed along the a-plane so that the length in the a-axis direction was 200 ⁇ m.
- a flat region 20C that hardly changes in height in the direction parallel to the groove 11a is formed on the side of the groove 11a. Formed.
- the flatness of the optical waveguide can be improved.
- the RMS in the flat region 20C is preferably 10 nm or less, but if the RMS is 20 nm or less, a semiconductor laser device having a unimodal FFP shape can be realized.
- An optical waveguide generally refers to the entire region where laser light is distributed.
- the ridge stripe laser device includes not only the ridge portion but also a region where the laser light on the side of the ridge portion is distributed.
- the entire optical waveguide does not necessarily have to be formed in a flat region with high flatness. Therefore, at least in the ridge stripe type semiconductor laser device, the ridge portion only needs to be formed in a flat region.
- the groove 11 a is not necessarily formed in the substrate 11, and it is sufficient that two regions having different heights are formed.
- the flat region 20C can be formed on the side of the convex part 11b.
- substrate 11 which has the convex part 11b as follows.
- 600 nm of SiO 2 is deposited on the n-type hexagonal GaN substrate 11 whose main surface is the (0001) plane by, for example, a thermal CVD method using SiH 4 as a raw material.
- the mask film is removed in stripes in the m-axis direction by a lithography method and an etching method so that the length in the a-axis direction is 20 ⁇ m.
- the upper part of the substrate 11 on which the mask film is formed is etched by an ICP etching apparatus using CF 4 as an etching gas. Thereby, the convex part 11b whose height is 2 ⁇ m can be formed on the substrate 11.
- the width in the a-axis direction of the groove portion 11a and the convex portion 11b is about 20 ⁇ m, but may be 2 ⁇ m or more. If the width is increased, the formation becomes difficult, so it may be 200 ⁇ m or less, and preferably 100 ⁇ m or less. However, since the effect of facilitating the formation of the flat region 20C is obtained when the volume of the groove 11a and the protrusion 11b is larger, the width of the groove 11a and the protrusion 11b may be further increased. Finally, as shown in FIG. 7 or 8, the semiconductor layer stack is formed on the substrate 11 having the first region 11 ⁇ / b> A and the second region 11 ⁇ / b> B having different heights by extending the groove or the protrusion. 20 may be formed.
- the groove portion 11a and the convex portion 11b may be formed from the front end surface to the rear end surface. However, there is no problem even if there is a portion where the groove 11a or the convex portion 11b is not formed in the vicinity of the front end surface and the rear end surface.
- the depth of the groove portion 11a and the height of the convex portion 11b are about 0.1 ⁇ m or more. Since formation will become difficult if the depth of the groove part 11a and the height of the convex part 11b are made high, it is preferable to set it as 10 micrometers or less.
- the groove or protrusion on the semiconductor layer stack After forming a part of the semiconductor layer stack on a flat substrate, the groove or protrusion on the semiconductor layer stack Followed by re-growth of the semiconductor layer stack.
- a groove or a protrusion is formed by etching or the like, and a semiconductor layer including an active layer is formed by regrowth.
- the depth of the groove or the height of the protrusion is sufficient if it is 0.01 ⁇ m or more.
- it is preferable that the depth of the groove or the height of the convex is 5 ⁇ m or less.
- the main surface of the substrate is the c-plane and the optical waveguide is formed in the m-axis direction.
- the semiconductor layer stack may be formed on a substrate having another plane orientation.
- the direction of the optical waveguide may be other directions.
- GaN-based substrate such as a GaN substrate or an AlGaN substrate belonging to a hexagonal system was used as the substrate, but other substrates capable of growing GaN-based materials, such as silicon carbide (SiC), silicon (Si), and sapphire (Single crystal Al 2 O 3 ) or zinc oxide (ZnO) may be used.
- SiC silicon carbide
- Si silicon
- Si silicon
- sapphire Single crystal Al 2 O 3
- ZnO zinc oxide
- a ridge stripe type semiconductor laser device having a ridge portion has been described.
- the same effect can be obtained also in an embedded semiconductor laser device.
- the opening of the current blocking layer may be positioned in a flat region. In this way, the optical waveguide can be formed in a flat region.
- the exemplary semiconductor laser device can realize a semiconductor laser device having a planarized optical waveguide and an active layer with uniform bandgap energy without controlling the off-angle of the substrate, and a nitride semiconductor laser device, particularly a laser display and It is useful as a nitride semiconductor laser device used for a liquid crystal backlight or the like.
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Abstract
Description
図5(a)~(c)は一実施形態に係る半導体レーザ装置であり、(a)は平面構成を示し、(b)は(a)のVb-Vb線における断面構成を示し、(c)は共振器端面における断面構成を示している。
11A 第1の領域
11B 第2の領域
11a 溝部
11b 凸部
20 半導体層積層体
20A 第1の領域
20B 第2の領域
20C 平坦領域
20a リッジ部
22 n型クラッド層
24 n型ガイド層
26 活性層
28 p型ガイド層
30 オーバーフロー層
32 p型クラッド層
34 p型コンタクト層
34 コンタクト層
36 絶縁膜
38 p側電極
40 パッド電極
42 n側電極
102 溝部
104 窒化物半導体層
105 平坦領域
Claims (12)
- 半導体レーザ装置は、
基板の上に形成された活性層を含む半導体層積層体を備え、
前記半導体層積層体は、
光を出射する前方端面と、
前記前方端面と交差する方向に形成されたストライプ状の光導波路と、
前記前方端面と交差する方向に延びる第1の領域と、
前記第1の領域と上面の高さが異なる第2の領域と、
前記第1の領域と前記第2の領域との間に形成され、前記第2の領域と比べて表面における周期的な凹凸の変化が小さい平坦領域とを有し、
前記光導波路は、前記平坦領域に形成されている。 - 請求項1に記載の半導体レーザ装置において、
前記平坦領域は、前記光導波路に沿った方向において、高さの変化が前記第2の領域と比べて小さい。 - 請求項1に記載の半導体レーザ装置において、
前記半導体層積層体は、前記前方端面と交差する方向に形成されたストライプ状のリッジ部を有し、
前記リッジ部は、前記平坦領域に形成されている。 - 請求項3に記載の半導体レーザ装置において、
前記基板は、上面の高さが互いに異なる2つの領域を有し、
前記第1の領域は前記2つの領域の一方の上に形成され、前記第2の領域は前記2つの領域の他方の上に形成されている。 - 請求項4に記載の半導体レーザ装置において、
前記2つの領域の一方は、溝部であり、
前記第1の領域は、前記溝部の上に形成されている。 - 請求項4に記載の半導体レーザ装置において、
前記2つの領域の一方は、ストライプ状の凸部であり、
前記第1の領域は、前記凸部の上に形成されている。 - 請求項4に記載の半導体レーザ装置において、
前記リッジ部の中央から前記2つの領域の境界までの距離は1μm以上且つ15μm以下である。 - 請求項3に記載の半導体レーザ装置において、
前記活性層における前記リッジ部の下に形成された部分は、前記活性層の他の部分と比べてバンドギャップエネルギーのばらつきが小さい。 - 請求項1に記載の半導体レーザ装置において、
前記半導体層積層体における、前記光導波路が形成された領域の上面は、二乗平均粗さが20nm以下である。 - 請求項1に記載の半導体レーザ装置において、
前記半導体層積層体は、窒化物半導体からなり、
前記光導波路は、前記窒化物半導体のm軸に沿った方向に形成されている。 - 請求項1に記載の半導体レーザ装置において、
前記活性層は、インジウムを含む。 - 請求項1に記載の半導体レーザ装置において、
前記平坦領域は、前記前方端面から、該前方端面と反対側の後方端面まで連続して形成されている。
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US12/742,573 US8472491B2 (en) | 2009-01-06 | 2009-10-16 | Semiconductor laser device |
CN2009801041970A CN101939883A (zh) | 2009-01-06 | 2009-10-16 | 半导体激光器装置 |
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JP2003234544A (ja) * | 2002-02-06 | 2003-08-22 | Sharp Corp | 窒化物系半導体レーザ素子とその製造方法 |
JP2008198743A (ja) * | 2007-02-09 | 2008-08-28 | Furukawa Electric Co Ltd:The | 半導体レーザダイオード |
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JP2003179331A (ja) * | 2001-12-12 | 2003-06-27 | Matsushita Electric Ind Co Ltd | 部品接合方法及び装置 |
US7462882B2 (en) * | 2003-04-24 | 2008-12-09 | Sharp Kabushiki Kaisha | Nitride semiconductor light-emitting device, method of fabricating it, and semiconductor optical apparatus |
JP2004327655A (ja) | 2003-04-24 | 2004-11-18 | Sharp Corp | 窒化物半導体レーザ素子、その製造方法および半導体光学装置 |
JP2006128661A (ja) * | 2004-09-29 | 2006-05-18 | Matsushita Electric Ind Co Ltd | 窒化物系半導体レーザ |
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US7863623B2 (en) * | 2005-09-15 | 2011-01-04 | Panasonic Corporation | Semiconductor light emitting device |
JP2007081182A (ja) * | 2005-09-15 | 2007-03-29 | Matsushita Electric Ind Co Ltd | 半導体発光素子 |
JP2007119325A (ja) * | 2005-10-31 | 2007-05-17 | Sumitomo Electric Ind Ltd | Iii族窒化物結晶およびその成長方法 |
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JP2008285364A (ja) * | 2007-05-17 | 2008-11-27 | Sumitomo Electric Ind Ltd | GaN基板、それを用いたエピタキシャル基板及び半導体発光素子 |
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US8472491B2 (en) | 2013-06-25 |
CN101939883A (zh) | 2011-01-05 |
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