WO2010028869A1 - Universelle infrastruktur für chemische prozesse - Google Patents
Universelle infrastruktur für chemische prozesse Download PDFInfo
- Publication number
- WO2010028869A1 WO2010028869A1 PCT/EP2009/055858 EP2009055858W WO2010028869A1 WO 2010028869 A1 WO2010028869 A1 WO 2010028869A1 EP 2009055858 W EP2009055858 W EP 2009055858W WO 2010028869 A1 WO2010028869 A1 WO 2010028869A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- infrastructure
- space
- extinguishing agent
- products
- plant
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00015—Scale-up
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00018—Construction aspects
- B01J2219/00022—Plants mounted on pallets or skids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00225—Control algorithm taking actions stopping the system or generating an alarm
Definitions
- the invention relates to a plant for carrying out chemical processes according to the preamble of claim 1.
- a genus same plant shows EP 0 754 084 B1.
- a modular ethanol production plant which is composed of a plurality of modules of identical size.
- the individual modules are each designed as a sea container.
- US Pat. No. 5,656,491 discloses a modular production plant for the production of biotechnological products.
- the system consists of at least two mobile modules that can be connected together to form a functional unit.
- a portable, modular system for the production and use of biogas is known for example from DE 199 58 142 A1.
- the individual components of this system, such as fermenter and energy part are provided in at least two separate components, each housed in standard transport container frame.
- EP 0 754 084 B1 which is considered to be generic, describes a modular chemical reaction system based on an assembly plate which serves as an infrastructure. All system components are designed as function modules that can be combined with each other; For mass transfer between aggregates, the assembly plate provides integrated flow paths.
- WO 01/89681 A2 likewise describes a modular system for the configuration of microreaction plants.
- the devices connected to the plant are designed as standardized with regard to their dimensions, rastered functional modules, which are used in a mounting frame.
- the mounting frame has no integrated flow paths; Rather, the interfaces of the apparatuses are organized so that the respective inlets and outlets of the modules used adjacently in the mounting frame abut each other, thus allowing a direct mass transfer between the modules.
- the present invention seeks to further develop a plant of the type mentioned so that chemical reactions in a laboratory scale beyond the production quantity in compliance with strict safety precautions are feasible.
- Region of the invention is therefore a plant for carrying out chemical processes, a) with at least one device for receiving and / or providing reactants, b) with at least one device for receiving and / or providing products, c) having at least one reactor for the reaction the educts in products; d) and with at least one device for controlling and / or regulating the implementation, e) the system being based on an infrastructure; (f) where the infrastructure provides integrated conduits by means of which substance and / or energy and / or information between the facilities are interchangeable and / or between the reactor and the facilities, g) the infrastructure is provided with at least one assembly field in which said facilities and / or reactors and / or
- Auxiliary equipment can be fixed, h) wherein the infrastructure is transportable, i) wherein the infrastructure spatially delimits at least one accessible space, k) wherein the assembly field is arranged in said space, I) and wherein the infrastructure has an extinguishing agent distribution.
- a basic idea of the present invention is to design the infrastructure on which the system is based in a spatial manner, in a volume that can be accessed by a human, but nevertheless can be forwarded with minimal logistical effort, and at the same time the necessary safety devices such as an extinguishing agent distribution into the infrastructure to integrate.
- An infrastructure in the sense of the invention is therefore independent of a higher-level security system and therefore does not need to be installed in a laboratory environment.
- the infrastructure can be standardized independently of the processes running on it, the same infrastructure can be used for a wide range of installations. This lowers the investment costs and at the same time increases the quality. Therefore, the infrastructure as such is also the subject of the invention.
- a particular advantage of the system according to the invention is that it can be used over several product development phases thanks to its universal infrastructure.
- a laboratory phase in which process steps and parameters are evaluated in small batch quantities in discontinuous processes.
- the chemistry of the targeted process is at the center of interest.
- a continuous process management using apparatuses which correspond in function to those of a later large-scale plant practiced.
- scale up is carried out, in which the process developed in the pilot plant is transferred to the production scale, whereby similarity problems are regularly resolved.
- the devices for receiving and / or providing educts and products and the reactor are therefore designed on a laboratory scale.
- the measured values from the laboratory reaction are collected in the device for measuring / controlling / regulating.
- the infrastructure serves as a technical center.
- the laboratory equipment is exchanged for small apparatuses that correspond to the functioning of large apparatuses.
- the device for measuring / controlling / regulating is still used, it collects from then on data that correspond to the learning process in the technical center.
- the infrastructure serves as the basis for a large-scale plant.
- the apparatuses can be increased in terms of their capacity, but this leads to similarity problems.
- the system is simply mirrored by subordinating a second infrastructure with identical equipment.
- the learned data are also mirrored, so that there are hardly any similarity problems due to the parallelization.
- the invention therefore also provides a process for the production of products using a plant discussed herein, which comprises the following steps: a) producing a first quantity of products over a first period of time while recording required for the control or regulation of the reaction in the reactor Information in the device for the control or regulation of the implementation; (b) increasing the capacity of the installation while maintaining the infrastructure and the means to control or regulate the implementation; c) preparing a second quantity of products for a second period of time reading information from the means for controlling or regulating the reaction required to control the reaction in the reactor; wherein the second amount is greater than the first amount and the second period is behind the first period.
- the infrastructure is considered as an integrated solution for both the development and the continuous production of chemical products the functionalities supply and disposal of educts, by-products and end products, control / regulation / air conditioning to understand.
- the extinguishing agent distribution allows the distribution of extinguishing agent in said space, which also has the mounting field for the system components. If a fire occurs here, it can be deleted by means of the extinguishing agent distribution.
- the extinguishing agent distribution may comprise a loop circulating on the infrastructure, which has a plurality of spaced-apart nozzles for a liquid coating of the plant. If the fire breaks out of the room, the entire system can be covered with an extinguishing agent to prevent the fire from spreading to the surroundings of the infrastructure.
- the infrastructure preferably has at least one externally accessible extinguishing agent connection for feeding extinguishing agent into the extinguishing agent distribution.
- the approaching fire brigade therefore only needs to feed an extinguishing agent into the burning infrastructure and, moreover, does not need to set up extinguishing instruments. This increases the extinguishing speed.
- the said room should be hermetically shut off.
- the space of the infrastructure may be underpinned by a drip pan.
- the mounting panel has a plurality of receptacles for receiving said devices and / or said reactors and / or
- a higher degree of integration can be achieved in that the infrastructure has two assembly fields in the said space, which extend orthogonally to each other.
- the units can be arranged in three dimensions to each other, which saves space and cable routes.
- the infrastructure has at least one outward-facing interface for the injection or removal of energy and / or an auxiliary medium and / or a by-product.
- the infrastructure should take the format of a standard container, in particular a container in accordance with ISO 668.
- a further variant according to the invention is characterized in that means for carrying out the reaction, means for controlling the reaction and means for receiving and / or providing reactants and / or products are arranged in different rooms of a single transport container, which preferably has standard dimensions ,
- the infrastructure as a transportable functional unit preferably comprises at least one work-up space at least one storage room and at least one control room. Edukt-, product, by-product packages and the like can be stored in the storage room. With a particularly high capacity of
- Plant can be accommodated there the process-related storage containers.
- the actual apparatuses for carrying out the process and the work-up can be provided.
- the plant according to the invention forms a, in particular in the implementation of the implementation to the required interfaces for electrical energy, supply and exhaust air and the like, fully closed functional unit.
- At least one lock space is provided, through which the functional unit or system is accessible.
- the treatment room can be actively ventilated, for example, with air, wherein the atmosphere can be monitored by means of conventional sensors with respect to the maximum workplace concentration of certain substances and explosion protection.
- the control room includes process control and disconnection equipment installed separately there. These include in particular the process control systems and other electrical equipment. These are devices for controlling and / or regulating the reaction in the sense of the invention.
- Switch boxes needed for the EMSR technology can be parqueted in a known manner.
- the arrangement and shape of the switch boxes in the form of a honeycomb is proposed.
- at least the storage space is underpinned by a collecting trough.
- the entire functional unit can be underpinned by a drip pan.
- one or more liquid sensors can be provided which trigger an accumulation of liquids in the drip pan an audible and / or visual alarm or cause a shutdown of the system.
- the storage room is expediently provided with at least one roller door.
- Roller shutters can be provided without special space requirements and allow free access to the storage room in case of need, for example, from the outside.
- roller doors Apart from the fact that the space requirement for roller doors is relatively small, they can also relatively easily, i. in the sense of low operating forces, open and close.
- At least one central extinguishing agent connection and at least one extinguishing agent distribution to individual rooms are provided.
- a pipeline may be provided as a so-called "semi-stationary quenching line".
- extinguishing agents such as, for example, CO2, nitrogen, pulverized aerosils, sipernates or the like, are suitable for this purpose.
- individual rooms can also be provided with extinguishing line connections separately from the outside. This makes it possible, if necessary, to introduce different extinguishing agents in different rooms. For example, it may be necessary to use water instead of CO2 as the extinguishing agent in one of the rooms. For example, it may be necessary to use powder or foam as the extinguishing agent in the control room, as an alternative to water or foam
- a arranged in the roof area of the transport container ring line can be provided with spaced apart nozzles. In this way, if necessary, a fogging of the entire system can be generated with liquid. A cooling of the system by remplisstechniksbeschletechnik or -befeseling from the outside can be accomplished.
- all rooms of the system or all rooms of the functional unit are individually hermetically shut off.
- self-closing doors with electrical door contacts are provided in case of fire.
- the system is provided with at least one auxiliary media connection.
- Suitable auxiliary media are water, gas, steam, compressed air, nitrogen, electricity or the like.
- At least one externally accessible pipe bundle (utility bus) can be provided. This reduces the number of external interfaces required, increases the degree of integration and improves mobility.
- Figure 1 Floor plan of a system according to the invention.
- Fig. 1 shows the layout of a plant 1 according to the invention, which is completely in an infrastructure in the form of a standard overseas transport container 2 with a length of 40 feet (13 m), a width of about 2.4 meters and a height of about 2.9 meters is integrated. This corresponds to the standard ISO 668.
- the plant 1 is, as can be seen from the floor plan, divided into different rooms and includes in the described embodiment, a storage room 3, a work-4, a control room 5 (EMSR space), and a lock chamber 6.
- the whole system can in operated an explosion protection zone.
- the lock chamber 6 makes it possible to enter the system 1 without having to switch off the process operated in this system. All rooms are hermetically sealed by doors.
- the lock chamber 6 is accessible from the outside, while the doors to the refurbishment space 4 and the control chamber 5 are closed. After closing the outer door, the doors to the work-up room and / or the control room 6 can be opened optionally. All doors are provided with door contacts, so that, for example, at the same time opening doors of the lock chamber 6 and the refurbishment 4 an automatic shutdown of the system can be done.
- educt or by-product packages are arranged in the storage room 3. These are devices for receiving and / or providing starting materials.
- the containers are preferably arranged on carriages to allow control of the filling level or to be able to determine the discharge or filling mass flow in the balance.
- Optical displays of the scales are provided on the walls of the storage room.
- this can be opened from the outside by means of a roller door provided for this purpose also during operation of the system 1.
- the roller shutter can be operated either electrically or pneumatically.
- the walls of the storage room 3 and the other walls of the system 1 are preferably designed as fire protection barriers.
- the floor of the control room is equipped with a bath complying with the requirements of the Water Resources Act, the volume of which is such that it can absorb the liquid volume of the largest container.
- liquid sensors which indicate the leakage of the container or the system, give alarm and if necessary switch off the system.
- gas sensors and a system off and / or emergency stop switch are also provided.
- the air conditioning of the entire system is expediently realized by mounted under the ceiling cooling or heating coils. These are expediently designed as Quergerippte pipes and are connected to a cooling water circuit. Alternatively, one or more air conditioning unit modules may be provided.
- the storage room 3 like all other rooms, is connected to an extinguishing pipe.
- both means for the development of chemical products and means for mass production of such products can be provided.
- reactors for reacting the starting materials in products reactor heating, storage tanks, heat exchangers, evaporators, condensers, quenching stages, thermostats for cooling heating medium supply, apparatus for workup / purification / separation, such as distillation columns, pumps, vacuum pumps, etc.
- work-up room 4 the necessary piping with fittings provided. These include temperature, pressure, liquid level, flow measuring devices, control valves, solenoid valves, drive motors, etc. These are (auxiliary) units within the meaning of the invention.
- control technology is arranged in control cabinets, which are distributed in a preferred variant in the work-4. But they can also be provided in the separate control room 5.
- the control technology is understood as a device for controlling and / or regulating the implementation.
- the process apparatuses provided in the work-up area 4 are connected to the containers and containers of the storage space 3 via pipelines which pass through the walls of the plant 1 and are preferably designed as metal pipes. These are integrated into the infrastructure lines by means which substance and / or energy and / or information is interchangeable between the devices and / or the devices and the reactor.
- All rooms of the system can be traversed with the walls partially skeleton-like bracing scaffolding, where electrical components, containers, process equipment and the like can be attached so that the system is transportable overall.
- the scaffolding components used for this purpose can be embodied, for example, as metal hollow profiles which can serve both for stiffening the installation and for fastening components as well as for guiding and distributing pipes and pipes.
- the hollow sections can be interspersed, for example, with a standardized threaded hole pattern, so that simple attachment of a variety of facilities is possible.
- the hollow profiles represent an assembly field in the context of the invention.
- Windows can be provided in the walls between the spaces of the installation 1, which allow observation of, for example, the work-up space 4 from the control technology room 5.
- Appendix 1 electronic bulbs are preferably provided in the form of high-performance light-emitting diodes. On the one hand, they enable energy-efficient provision of light and, on the other hand, homogeneous illumination of all rooms. In addition, these bulbs allow easy compliance with health and safety regulations. In addition to the normal Lighting is provided an emergency lighting, which is integrated, for example, in the ceiling of the transport container.
- the ventilation of the reprocessing room is designed as forced ventilation from the outside.
- air is supplied from an air supply system.
- the air is drawn in via fans and blown in. It is also possible to connect the work-up room 4 for ventilation purposes, for example with the control room 5.
- the system is supplied with auxiliary media such as electricity, water, nitrogen, compressed air, etc. via a bundled pipe connection, which is provided on the outside of the transport container. It is an outwardly facing interface for feeding energy or an auxiliary medium or a by-product. This can be led from there into the work-up room 4, where the auxiliary media can be removed at a distribution station.
- the pipes required for this purpose can be performed, for example, in an intermediate level above the drip pan.
- the exhaust gas streams from the individual rooms can be combined via a collecting duct and removed together.
- means for exhaust gas purification may be provided, for example an exhaust gas scrubber and / or a fine dust filter.
- the purified exhaust gas can be removed via a provided on the roof of the transport container fireplace.
- the fireplace is an outwardly facing interface for discharging energy and / or an auxiliary medium and / or a by-product in the sense of the invention.
- switch boxes are to be provided in the work-up room, they are superimposed or rinsed with dry compressed air in order to prevent penetration into the switch boxes in the event of the escape of corrosive gases in the work-up room 4. This allows a possible fire development by electrical
- the compressed air for the Switch boxes intended flushing current can be performed, for example, via integrated fire alarm sensors.
- control room 5 may be provided with forced ventilation. Among other things, this may be due to the possibly required cooling of the electrical units. Additionally or alternatively, an integrated into the ceiling room air conditioner can be provided with cooling and / or heating coils.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2736933A CA2736933A1 (en) | 2008-09-10 | 2009-05-14 | Universal infrastructure for chemical processes |
EP09779482A EP2323758A1 (de) | 2008-09-10 | 2009-05-14 | Universelle infrastruktur für chemische prozesse |
JP2011526427A JP2012501770A (ja) | 2008-09-10 | 2009-05-14 | 化学的なプロセスのためのユニバーサルインフラストラクチャ |
RU2011113826/05A RU2502557C2 (ru) | 2008-09-10 | 2009-05-14 | Универсальное инфраструктурное устройство для химических процессов |
AU2009291162A AU2009291162C1 (en) | 2008-09-10 | 2009-05-14 | Universal infrastructure for chemical processes |
BRPI0917157A BRPI0917157A2 (pt) | 2008-09-10 | 2009-05-14 | infraestrutura universal para processos químicos |
KR1020117005580A KR101686684B1 (ko) | 2008-09-10 | 2009-05-14 | 화학 공정을 위한 범용 기반구조 |
DE212009000008U DE212009000008U1 (de) | 2008-09-10 | 2009-05-14 | Universelle Infrastruktur für chemische Prozesse |
US13/063,171 US20110163462A1 (en) | 2008-09-10 | 2009-05-14 | Universal Infrastructure for Chemical Processes |
CN2009801354922A CN102149459A (zh) | 2008-09-10 | 2009-05-14 | 用于化学工艺的通用基础设施 |
IL210670A IL210670A (en) | 2008-09-10 | 2011-01-16 | Universal Infrared Structure for Chemical Processes |
ZA2011/01820A ZA201101820B (en) | 2008-09-10 | 2011-03-09 | Universal infrastructure for chemical processes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008041950.8 | 2008-09-10 | ||
DE102008041950A DE102008041950A1 (de) | 2008-09-10 | 2008-09-10 | System zur Bereitstellung einer universellen Infrastruktur für chemische Prozesse |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010028869A1 true WO2010028869A1 (de) | 2010-03-18 |
Family
ID=40972956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2009/055858 WO2010028869A1 (de) | 2008-09-10 | 2009-05-14 | Universelle infrastruktur für chemische prozesse |
Country Status (14)
Country | Link |
---|---|
US (1) | US20110163462A1 (de) |
EP (1) | EP2323758A1 (de) |
JP (2) | JP2012501770A (de) |
KR (1) | KR101686684B1 (de) |
CN (2) | CN102149459A (de) |
AU (1) | AU2009291162C1 (de) |
BR (1) | BRPI0917157A2 (de) |
CA (1) | CA2736933A1 (de) |
DE (2) | DE102008041950A1 (de) |
IL (1) | IL210670A (de) |
MY (1) | MY158254A (de) |
RU (1) | RU2502557C2 (de) |
WO (1) | WO2010028869A1 (de) |
ZA (1) | ZA201101820B (de) |
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DE102011077788A1 (de) | 2011-06-20 | 2012-12-20 | Evonik Degussa Gmbh | Verfahren zur Modifizierung eines methanhaltigen Gasvolumenstroms |
DE102013201171A1 (de) | 2013-01-24 | 2014-07-24 | Infracor Gmbh | Verfahren und System zur Nutzung eines Industriegrundstücks |
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AU2019325589B2 (en) | 2018-08-23 | 2023-08-31 | Transform Materials Llc | Systems and methods for processing gases |
US11633710B2 (en) | 2018-08-23 | 2023-04-25 | Transform Materials Llc | Systems and methods for processing gases |
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2008
- 2008-09-10 DE DE102008041950A patent/DE102008041950A1/de not_active Withdrawn
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2009
- 2009-05-14 BR BRPI0917157A patent/BRPI0917157A2/pt not_active Application Discontinuation
- 2009-05-14 CN CN2009801354922A patent/CN102149459A/zh active Pending
- 2009-05-14 KR KR1020117005580A patent/KR101686684B1/ko active IP Right Grant
- 2009-05-14 CN CN201310647810.1A patent/CN103752242A/zh active Pending
- 2009-05-14 RU RU2011113826/05A patent/RU2502557C2/ru active
- 2009-05-14 CA CA2736933A patent/CA2736933A1/en active Pending
- 2009-05-14 DE DE212009000008U patent/DE212009000008U1/de not_active Expired - Lifetime
- 2009-05-14 MY MYPI2011000919A patent/MY158254A/en unknown
- 2009-05-14 JP JP2011526427A patent/JP2012501770A/ja active Pending
- 2009-05-14 AU AU2009291162A patent/AU2009291162C1/en active Active
- 2009-05-14 EP EP09779482A patent/EP2323758A1/de not_active Ceased
- 2009-05-14 WO PCT/EP2009/055858 patent/WO2010028869A1/de active Application Filing
- 2009-05-14 US US13/063,171 patent/US20110163462A1/en not_active Abandoned
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2011
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011077788A1 (de) | 2011-06-20 | 2012-12-20 | Evonik Degussa Gmbh | Verfahren zur Modifizierung eines methanhaltigen Gasvolumenstroms |
WO2012175279A1 (de) | 2011-06-20 | 2012-12-27 | Evonik Degussa Gmbh | Verfahren zur modifizierung eines methanhaltigen gasvolumenstroms |
US9051526B2 (en) | 2011-06-20 | 2015-06-09 | Evonik Degussa Gmbh | Method for modification of a methane-containing gas stream |
DE102013201171A1 (de) | 2013-01-24 | 2014-07-24 | Infracor Gmbh | Verfahren und System zur Nutzung eines Industriegrundstücks |
Also Published As
Publication number | Publication date |
---|---|
BRPI0917157A2 (pt) | 2015-11-17 |
IL210670A0 (en) | 2011-03-31 |
KR20110053352A (ko) | 2011-05-20 |
CN103752242A (zh) | 2014-04-30 |
US20110163462A1 (en) | 2011-07-07 |
ZA201101820B (en) | 2011-11-30 |
MY158254A (en) | 2016-09-30 |
RU2502557C2 (ru) | 2013-12-27 |
AU2009291162A1 (en) | 2010-03-18 |
RU2011113826A (ru) | 2012-10-20 |
AU2009291162B2 (en) | 2015-08-06 |
CN102149459A (zh) | 2011-08-10 |
IL210670A (en) | 2016-05-31 |
JP5931135B2 (ja) | 2016-06-08 |
AU2009291162C1 (en) | 2015-12-10 |
JP2014217782A (ja) | 2014-11-20 |
KR101686684B1 (ko) | 2016-12-14 |
DE212009000008U1 (de) | 2010-09-02 |
EP2323758A1 (de) | 2011-05-25 |
JP2012501770A (ja) | 2012-01-26 |
CA2736933A1 (en) | 2010-03-18 |
DE102008041950A1 (de) | 2010-03-11 |
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