WO2010011027A3 - 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법 - Google Patents

올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법 Download PDF

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Publication number
WO2010011027A3
WO2010011027A3 PCT/KR2009/003348 KR2009003348W WO2010011027A3 WO 2010011027 A3 WO2010011027 A3 WO 2010011027A3 KR 2009003348 W KR2009003348 W KR 2009003348W WO 2010011027 A3 WO2010011027 A3 WO 2010011027A3
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WO
WIPO (PCT)
Prior art keywords
olefin polymerization
same
polymerization catalyst
polymerization method
compound represented
Prior art date
Application number
PCT/KR2009/003348
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English (en)
French (fr)
Other versions
WO2010011027A2 (ko
Inventor
홍사문
강성우
전용재
손병길
Original Assignee
대림산업
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 대림산업 filed Critical 대림산업
Priority to JP2011519973A priority Critical patent/JP5560274B2/ja
Priority to RU2011106320/04A priority patent/RU2469046C2/ru
Priority to EP09800508.5A priority patent/EP2305719B1/en
Priority to CN2009801285049A priority patent/CN102099384B/zh
Priority to ES09800508.5T priority patent/ES2674143T3/es
Publication of WO2010011027A2 publication Critical patent/WO2010011027A2/ko
Publication of WO2010011027A3 publication Critical patent/WO2010011027A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Abstract

본 발명은 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법에 관한 것으로, 상기 올레핀 중합 촉매는 R1-H 또는 R1-Q-R1 로 표시되는 유기 화합물; M1R2 mR3 nR4 pR6 q로 표시되는 유기 금속 화합물; M2R7 rXs 로 표시되는 유기 전이금속 화합물 및 알루미녹산을 포함한다. 또한, 본 발명의 올레핀 중합 방법은 상기 올레핀 중합 촉매 존재하에서, 하나 이상의 올레핀을 중합하는 단계를 포함한다.
PCT/KR2009/003348 2008-07-21 2009-06-23 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법 WO2010011027A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2011519973A JP5560274B2 (ja) 2008-07-21 2009-06-23 オレフィン重合触媒及びそれを用いたオレフィンの重合方法
RU2011106320/04A RU2469046C2 (ru) 2008-07-21 2009-06-23 Катализатор полимеризации олефина и способ полимеризации олефина с его использованием
EP09800508.5A EP2305719B1 (en) 2008-07-21 2009-06-23 Method for preparing an olefin polymerization catalyst and olefin polymerization method using the same
CN2009801285049A CN102099384B (zh) 2008-07-21 2009-06-23 烯烃聚合催化剂和使用该烯烃聚合催化剂的烯烃聚合方法
ES09800508.5T ES2674143T3 (es) 2008-07-21 2009-06-23 Procedimiento para la preparación de un catalizador de polimerización de olefina y procedimiento de polimerización de olefina que utiliza el mismo

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2008-0070637 2008-07-21
KR1020080070637A KR100976666B1 (ko) 2008-07-21 2008-07-21 올레핀 중합 촉매 및 이를 이용한 폴리올레핀 중합체의제조방법

Publications (2)

Publication Number Publication Date
WO2010011027A2 WO2010011027A2 (ko) 2010-01-28
WO2010011027A3 true WO2010011027A3 (ko) 2010-03-25

Family

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PCT/KR2009/003348 WO2010011027A2 (ko) 2008-07-21 2009-06-23 올레핀 중합 촉매 및 이를 이용한 올레핀의 중합 방법

Country Status (7)

Country Link
EP (1) EP2305719B1 (ko)
JP (1) JP5560274B2 (ko)
KR (1) KR100976666B1 (ko)
CN (1) CN102099384B (ko)
ES (1) ES2674143T3 (ko)
RU (1) RU2469046C2 (ko)
WO (1) WO2010011027A2 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102453129B (zh) * 2010-10-19 2013-05-01 中国石油化工股份有限公司 一种烯烃聚合催化剂组分浆液的制备方法
KR101212637B1 (ko) 2011-06-09 2012-12-14 에스케이종합화학 주식회사 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR101670072B1 (ko) * 2014-04-14 2016-10-27 주식회사 지앤지테크놀러지 강변 여과수 수평집수용 관정 청소용 고압방사기를 포함하는 청소장비의 이동 장치 및 이를 이용한 관정 청소 방법
KR102114993B1 (ko) * 2015-10-15 2020-05-25 주식회사 파이안에스테틱스 폴리펩타이드 및/또는 세포 배양 여액을 함유하는 수용성 스크럽 입자를 포함하는 화장제 조성물
PL3661982T3 (pl) * 2017-08-02 2022-04-04 Total Research & Technology Feluy Kompozycja podwójnego katalizatora

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US6410659B1 (en) * 1994-04-07 2002-06-25 Bp Chemicals Limited Polymerization process
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US20070142221A1 (en) * 2005-12-16 2007-06-21 Daelim Industrial Co., Ltd. Olefin polymerization catalyst and olefin polymerization process using the same

Also Published As

Publication number Publication date
RU2469046C2 (ru) 2012-12-10
CN102099384B (zh) 2013-03-27
CN102099384A (zh) 2011-06-15
JP2012503678A (ja) 2012-02-09
WO2010011027A2 (ko) 2010-01-28
KR20100009828A (ko) 2010-01-29
JP5560274B2 (ja) 2014-07-23
ES2674143T3 (es) 2018-06-27
EP2305719A2 (en) 2011-04-06
EP2305719B1 (en) 2018-01-24
RU2011106320A (ru) 2012-08-27
KR100976666B1 (ko) 2010-08-18
EP2305719A4 (en) 2015-10-28

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