WO2010009656A1 - Appât artificiel et biodégradable pour la pêche et son procédé de production - Google Patents

Appât artificiel et biodégradable pour la pêche et son procédé de production Download PDF

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Publication number
WO2010009656A1
WO2010009656A1 PCT/CN2009/072739 CN2009072739W WO2010009656A1 WO 2010009656 A1 WO2010009656 A1 WO 2010009656A1 CN 2009072739 W CN2009072739 W CN 2009072739W WO 2010009656 A1 WO2010009656 A1 WO 2010009656A1
Authority
WO
WIPO (PCT)
Prior art keywords
fishing lure
phas
artificial fishing
biodegradable
fish
Prior art date
Application number
PCT/CN2009/072739
Other languages
English (en)
Chinese (zh)
Inventor
王德祥
Original Assignee
集伍国际控股集团有限公司
丁晓冬
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 集伍国际控股集团有限公司, 丁晓冬 filed Critical 集伍国际控股集团有限公司
Publication of WO2010009656A1 publication Critical patent/WO2010009656A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K85/00—Artificial bait for fishing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones

Definitions

  • the invention relates to the technical field of artificial biodegradable fake fishing lures, in particular to the use of a degradable material as a main material of a fishing lure, which can be degraded in the environment, without causing harm to the environment, the present invention It also relates to the method of making artificial fake fishing lures using these materials.
  • PVC must add a large amount (possibly up to 80%) of plasticizer to achieve a suitable degree of softness and softness (plasticization and flexibility) to achieve simulation effects in swimming in the water, the most common of which is Adding dioctyl phthalate (DIOP), this plasticizer is in liquid form, insoluble in water, and will be present in rivers/oceans for a long time after use. And a large number of experiments have shown that this plasticizer is a serious hazard to organisms. Such plasticizers have been banned from being used in food-related fields at home and abroad, and the use of fake fishing lures and the consequent series of safety problems may lead to serious consequences.
  • DIOP dioctyl phthalate
  • PC polycarbonate
  • PE polyethylene resin
  • acrylonitrile-butadiene-styrene resin mixture PC itself is harder in material, in addition to the similar problems with PVC, and because of its addition of peroxide initiator and azo blowing agent (1 ⁇ 4%), it will also have adverse effects on the environment and the animals and plants in the water. .
  • certain fish bait formula compounds are very harmful to fish survival, such as Japanese Patent Application No. 4,360,637 and 4,365,454, using potassium polyphosphate (sodium) as a binder, and sodium chondroitin sulfate as a water retaining agent. , its hazard may even lead to the death of different degrees of fresh fish. Since the bait made of natural organisms (worms or squids, etc.) is difficult to store, it is easy to emit an unpleasant odor. The fake bait is durable and will not lose its integrity due to its long time in the water. It has better strength and can be shaped into any shape that attracts fish. It is easy to hook and is loved by most fishing enthusiasts.
  • US Patent No. 4,385,302 describes a method of making a fishing lure using PVA as a main material.
  • the manufacturing process is very complicated, and the process of making the gel requires 2 to 50 hours of freezing, which is not only time consuming but also uneconomical, and
  • the patented PVA polymerization degree can not exceed 2000, so its strength can not reach the effect of the traditional PVC fishing lure, and its application is also limited.
  • U.S. Patent No. 6,174,525 discloses a molded fishing lure using a water-soluble long chain polyhydroxy polymer, but similar to the above patents, merely increases the degree of polymerization of PVA, PVA in terms of degradability and processability. The defect still exists.
  • European Patent EP0515231 discloses a fake fishing lure using a polyurethane (PU) polymer glue or a foaming material, the polymer structure comprising hydrolytically unstable ester bonds and other additives, according to the patent, the degradation properties of the novel material Depending on the hydrolysis-labile ester bond in the PU foam, this ester bond is obtained by polycondensation of an acid and an alcohol by a polyhydric alcohol with a (hydroxyl acid) to produce a hydrolysis-labile ester bond.
  • isocyanate and the isocyanate gas, steam, dust or aerosol is inhaled into the human body, which will endanger human health and may cause irritation to the skin.
  • the synthesis process is complicated. More importantly, the synthesized multilayer PU structure is not fully biodegradable, and it still has adverse effects on the organism. Hydrolysis also needs to be under certain conditions. Patented US 5,266,323 and US 5,270,044 It is similar.
  • biodegradable materials mainly include PHA, PLA (polylactic acid), PBS (polybutylene succinate), PCL (polycaprolactone), APC (carbon dioxide / epoxy compound copolymer), starch-based Materials, modified PVA, etc.
  • PHA polyhydroxyalkanoate PHAs
  • PLA polylactic acid
  • PBS polybutylene succinate
  • PCL polycaprolactone
  • APC carbon dioxide / epoxy compound copolymer
  • starch-based Materials modified PVA, etc.
  • polyhydroxyalkanoate PHAs are derived from natural renewable raw materials and have various compositions, good performance, wide application, good physical, mechanical and processing properties, good biodegradability and biocompatibility. It can be absorbed by living organisms and has a bright future.
  • PHAs copolymers such as PHBV, PHBH, P3HB4HB, etc.
  • PHAs copolymers can be used to achieve elastomeric materials from brittle materials to excellent toughness.
  • the copolymer transitions from a crystalline hard plastic to a resilient rubbery state, and has good thermal stability, becoming an elastomer.
  • the physical and mechanical properties of the polymer are changed by changing the content of the flexible molecules in the polymer to obtain materials having different rigidity, crystallinity, melting point and glass transition temperature suitable for different uses.
  • PHAs are currently the only fully biodegradable materials that can be used as elastomers, and have broad prospects for certain special applications.
  • the object of the present invention is to provide a novel, low-cost bait that has excellent durability, tensile strength, flexibility, elasticity, bond strength, and aesthetic simulation. More importantly, this new type of bait can be degraded without harming the environment and organisms.
  • This bait can be made into any shape that fish likes by injection molding or molding, such as worms, cockroaches, squid, crayfish, squid eggs and the like. This bait has good biocompatibility and is absorbed by the organism without any side effects.
  • a biodegradable artificial fishing lure the main constituent material of the fishing lure being PHAs (polyhydroxyalkanoate), including monomers, copolymers and blends thereof in the PHAs family.
  • PHAs polyhydroxyalkanoate
  • the biodegradable artificial fishing lure whose main constituent material PHAs is a copolymer is P3HB4HB.
  • the biodegradable artificial fishing lure wherein the fishing lure further comprises any one of PCL (polycaprolactone), PBS (polybutylene succinate), PPC (polypropylene carbonate), or any More than one material.
  • PCL polycaprolactone
  • PBS polybutylene succinate
  • PPC polypropylene carbonate
  • the biodegradable artificial fishing lure wherein the fishing lure further comprises a natural or petroleum-based elastic material.
  • the biodegradable artificial fishing lure further comprises one or more of an auxiliary agent, a fish attractant, and a toner in order to improve the attraction and use performance of the fishing lure to the fish.
  • the biodegradable artificial fishing lure wherein the artificial fishing lure is composed of the following weight percentages:
  • the biodegradable artificial fishing lure wherein the artificial fishing lure is composed of the following weight percentages:
  • the biodegradable artificial fishing lure wherein the artificial fishing lure is composed of the following weight percentages:
  • a method for manufacturing a biodegradable artificial fishing lure comprising the following steps:
  • the invention has the advantages that the PHAs copolymer is used as the base material of the degradable fishing lure, and the traditional fishing bait can not be degraded, has no biocompatibility problem, and has good biomimetic performance, and the physical and mechanical properties are close to the traditional bait, and has good performance.
  • the simulated simultaneous processing performance is good, and the fishing lure can be formed by conventional injection molding or molding.
  • the monomers, copolymers and blends thereof in the PHA family are proposed as the matrix material of the degradable fishing lure. Since the PHAs have many different molecular compositions and copolymerized units, the PHAs copolymer referred to in this patent It should include, but is not limited to, a single polymer and copolymer in PHA, such as P3HB4HB, PHBV, PHBH, etc., and mixtures of these copolymers or homopolymers.
  • this patent proposes to use PHAs as matrix materials for degradable bait, and can also be blended with other tougher degradable materials, such as polycaprolactone (PCL). , butyl succinate (PBS), aliphatic polycarbonate (APC), etc., to form a new fully biodegradable material to meet different application requirements.
  • PCL polycaprolactone
  • PBS butyl succinate
  • API aliphatic polycarbonate
  • Natural elastic materials and petroleum-based elastic materials may also be added to the fake fishing lure material, including natural and elastic materials including but not limited to PU, EVA (ethylene-vinyl acetate copolymer), SEBS (styrene-ethylene/butene) A styrene copolymer), etc., form a new degradable material to meet different use requirements.
  • natural and elastic materials including but not limited to PU, EVA (ethylene-vinyl acetate copolymer), SEBS (styrene-ethylene/butene) A styrene copolymer), etc.
  • the components involved in this patent mainly include:
  • Natural elastic materials petroleum-based elastic materials, including but not limited to PU, EVA, SEBS, etc.;
  • auxiliaries referred to in the present invention should include, but are not limited to, plasticizers, slip agents, nucleating agents, crosslinking agents, surfactants, colorants, lubricants, heat stabilizers, antioxidants, flame retardants, Waxes, tackifying resins, extenders, anti-fastening agents or other inorganic or organic fillers and mixtures thereof.
  • plasticizers slip agents
  • nucleating agents crosslinking agents
  • surfactants colorants
  • lubricants heat stabilizers
  • antioxidants antioxidants
  • flame retardants Waxes
  • tackifying resins extenders
  • anti-fastening agents or other inorganic or organic fillers and mixtures thereof tackifying resins
  • extenders anti-fastening agents or other inorganic or organic fillers and mixtures thereof.
  • the fish attractant of the present invention includes a flavoring agent, a sweetener, a koji, a fish oil, and the like, and other natural, artificial materials which are attractive to fish.
  • the toner in the present invention may be a natural, artificial pigment material.
  • the PHAs used in the present invention may be modified by changing the composition of the copolymer in the PHA (e.g., the content of 4HB in P3HB4HB), or the composition of the PHA (such as using a PHA blend to change the content of P3HB4HB and PHBH), or PHAs and The composition of other biodegradable materials to change the properties of the blend, and depending on the processing method, a small amount of additives are added to obtain a high-performance composite.
  • the composition of the copolymer in the PHA e.g., the content of 4HB in P3HB4HB
  • the composition of the PHA such as using a PHA blend to change the content of P3HB4HB and PHBH
  • PHAs and The composition of other biodegradable materials to change the properties of the blend, and depending on the processing method, a small amount of additives are added to obtain a high-performance composite.
  • the biodegradable artificial fishing lure proposed by the invention has the following weight percentages:
  • the invention also proposes a biodegradable artificial fishing lure method comprising the following steps:
  • Blending Blend PHAs with petroleum-based elastomers according to the above ratio, and choose to add suitable according to the end use. Additives, stir in a high speed mixer.
  • Plasticization The dried blend was re-plasticized using a twin-screw extruder to complete the blending modification to form a new degradable material.
  • the granulated degradation masterbatch is formed into a suitable shape by injection molding or molding.
  • the blending material is stirred in the mixer for 1 to 30 minutes, preferably 5 to 10 minutes.
  • the temperature of the electric blast drying oven is 40 to 100 ° C, and the drying time is 2 to 48 hours, preferably 50 to 50
  • drying time is 6 to 12 hours
  • the blending materials in the above step 4 are plasticized in a twin-screw extruder.
  • the temperature range of the feeding section, the compression section and the homogenizing section of the entire twin-screw extruder is in the range of 90 to 180°. Between C, maintain the die temperature at 110 ⁇
  • the feed section, the compression section and the homogenization section of the extruder preferably have a temperature ranging from 110 to 165 ° C and a die temperature of between 120 and 155 ° C.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

La présente invention concerne un appât artificiel et biodégradable pour la pêche, ainsi que son procédé de production. Cet appât est essentiellement constitué de polyhydroxyalcanoates (PHA), ce qui comprend des homopolymères, des copolymères et des mélanges de ces substances du groupe des PHA. En plus de ce composant principal, on peut ajouter audit appât artificiel pour la pêche, du PCL, du PBS, de l'APC ou, encore, des élastomères naturels et des élastomères à base de pétrole. Des adjuvants, des appâts pour poisson et des colorants peuvent également être ajoutés. Cet appât artificiel et biodégradable pour la pêche peut être fabriqué par moulage par injection ou par moulage par compression.
PCT/CN2009/072739 2008-07-20 2009-07-13 Appât artificiel et biodégradable pour la pêche et son procédé de production WO2010009656A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200810144556.2 2008-07-20
CN2008101445562A CN101525480B (zh) 2008-07-20 2008-07-20 可生物降解人造鱼饵及其制造方法

Publications (1)

Publication Number Publication Date
WO2010009656A1 true WO2010009656A1 (fr) 2010-01-28

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WO (1) WO2010009656A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103535334A (zh) * 2013-09-26 2014-01-29 安徽福斯特渔具有限公司 可降解环保仿生鱼饵
BE1023539B1 (nl) * 2016-02-15 2017-04-27 Niels CIEZKOWSKI Onderdelen voor karpervissen
CN106818667A (zh) * 2017-01-19 2017-06-13 界首市蒙特普休闲用品有限公司 一种环保型高仿真人造鱼饵衣膜及其制备方法
CN113214590A (zh) * 2021-04-21 2021-08-06 界首市猎钓渔具有限公司 一种环境友好型高强度高弹性仿生鱼饵制备方法
CN114479199A (zh) * 2022-01-20 2022-05-13 四川大学 一种全生物降解仿生鱼饵及其制备方法
WO2023245997A1 (fr) * 2022-08-16 2023-12-28 北京蓝晶微生物科技有限公司 Composition de polyhydroxyalcanoate dégradable marine, corps moulé et procédé de préparation associé

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CN103027208A (zh) * 2013-01-08 2013-04-10 严斯文 一种鲫鱼饲料制作方法
CN103431193A (zh) * 2013-08-01 2013-12-11 宁波天安生物材料有限公司 一种新型含聚羟基烷酸酯pha细胞的饲料
CN104109365A (zh) * 2014-08-10 2014-10-22 宁国市宁盛橡塑制品有限公司 一种可降解发泡塑料
CN104285925B (zh) * 2014-09-03 2016-04-13 界首市蒙特普休闲用品有限公司 新型环保降解玉米朊软体仿生仿真鱼诱饵
CN105557654A (zh) * 2014-10-11 2016-05-11 山东大学（威海） 一种金枪鱼延绳钓生态拟饵及其制造方法
CN105623178A (zh) * 2014-11-05 2016-06-01 李斌 一种仿真鱼饵及其制作工艺
CN104497509B (zh) * 2014-11-29 2016-04-27 张旭 一种可以降解的仿生鱼饵
CN104855349A (zh) * 2015-04-24 2015-08-26 界首市超强渔具有限公司 易降解环保软体彩色仿生鱼饵
CN106046722B (zh) * 2016-06-07 2018-02-23 威海两岸环保新材料科技有限公司 全生物降解仿生鱼饵及其制备方法
CN108794772A (zh) * 2018-07-02 2018-11-13 界首市汇珠渔具有限公司 一种用于仿生鱼饵的水凝胶材料制备方法
CN108935356A (zh) * 2018-08-17 2018-12-07 巢湖市翔宇渔具有限公司 一种全降解仿生仿真诱鱼拟饵材料
EP3698644A1 (fr) * 2019-02-20 2020-08-26 Kl-Teho Oy Appât de pêche, composition moulable pour la fabrication de l'appât de pêche, procédé de fabrication de l'appât de pêche et utilisation de la composition moulable
CN111349326A (zh) * 2020-04-30 2020-06-30 安徽宏飞钓具有限公司 一种柔软环保型仿生鱼饵及其制备方法
CN111493034B (zh) * 2020-05-08 2021-12-21 安徽宏飞钓具有限公司 一种耐油污的发光型仿生鱼饵
CN113234310B (zh) * 2021-06-28 2023-07-18 安徽宏飞钓具有限公司 一种高韧性仿生鱼饵及其制备方法

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JP2003009721A (ja) * 2001-07-02 2003-01-14 Canon Inc 生分解性疑似餌およびその製造方法

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103535334A (zh) * 2013-09-26 2014-01-29 安徽福斯特渔具有限公司 可降解环保仿生鱼饵
BE1023539B1 (nl) * 2016-02-15 2017-04-27 Niels CIEZKOWSKI Onderdelen voor karpervissen
CN106818667A (zh) * 2017-01-19 2017-06-13 界首市蒙特普休闲用品有限公司 一种环保型高仿真人造鱼饵衣膜及其制备方法
CN113214590A (zh) * 2021-04-21 2021-08-06 界首市猎钓渔具有限公司 一种环境友好型高强度高弹性仿生鱼饵制备方法
CN114479199A (zh) * 2022-01-20 2022-05-13 四川大学 一种全生物降解仿生鱼饵及其制备方法
CN114479199B (zh) * 2022-01-20 2022-10-14 四川大学 一种全生物降解仿生鱼饵及其制备方法
WO2023245997A1 (fr) * 2022-08-16 2023-12-28 北京蓝晶微生物科技有限公司 Composition de polyhydroxyalcanoate dégradable marine, corps moulé et procédé de préparation associé

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CN101525480B (zh) 2012-05-09

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