WO2009108167A2 - Blast-resistant barrier - Google Patents

Blast-resistant barrier Download PDF

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Publication number
WO2009108167A2
WO2009108167A2 PCT/US2008/012574 US2008012574W WO2009108167A2 WO 2009108167 A2 WO2009108167 A2 WO 2009108167A2 US 2008012574 W US2008012574 W US 2008012574W WO 2009108167 A2 WO2009108167 A2 WO 2009108167A2
Authority
WO
WIPO (PCT)
Prior art keywords
panel
barrier
blast
polycarbonate
frame
Prior art date
Application number
PCT/US2008/012574
Other languages
English (en)
French (fr)
Other versions
WO2009108167A3 (en
Inventor
Robert A. Pyles
James M. Lorenzo
Raymond L. Goodson
Original Assignee
Bayer Materialscience Llc
3-Form Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Materialscience Llc, 3-Form Inc. filed Critical Bayer Materialscience Llc
Priority to CN200880116446A priority Critical patent/CN101855415A/zh
Priority to EP20080872862 priority patent/EP2209957A4/en
Priority to AU2008351442A priority patent/AU2008351442A1/en
Priority to JP2010534022A priority patent/JP2011508679A/ja
Publication of WO2009108167A2 publication Critical patent/WO2009108167A2/en
Publication of WO2009108167A3 publication Critical patent/WO2009108167A3/en
Priority to IL204939A priority patent/IL204939A/en

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Classifications

    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04HBUILDINGS OR LIKE STRUCTURES FOR PARTICULAR PURPOSES; SWIMMING OR SPLASH BATHS OR POOLS; MASTS; FENCING; TENTS OR CANOPIES, IN GENERAL
    • E04H9/00Buildings, groups of buildings or shelters adapted to withstand or provide protection against abnormal external influences, e.g. war-like action, earthquake or extreme climate
    • E04H9/04Buildings, groups of buildings or shelters adapted to withstand or provide protection against abnormal external influences, e.g. war-like action, earthquake or extreme climate against air-raid or other war-like actions
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04HBUILDINGS OR LIKE STRUCTURES FOR PARTICULAR PURPOSES; SWIMMING OR SPLASH BATHS OR POOLS; MASTS; FENCING; TENTS OR CANOPIES, IN GENERAL
    • E04H9/00Buildings, groups of buildings or shelters adapted to withstand or provide protection against abnormal external influences, e.g. war-like action, earthquake or extreme climate
    • E04H9/04Buildings, groups of buildings or shelters adapted to withstand or provide protection against abnormal external influences, e.g. war-like action, earthquake or extreme climate against air-raid or other war-like actions
    • E04H9/10Independent shelters; Arrangement of independent splinter-proof walls
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/10Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
    • E04C2/20Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/10Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products
    • E04C2/20Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics
    • E04C2/22Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of wood, fibres, chips, vegetable stems, or the like; of plastics; of foamed products of plastics reinforced
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/30Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure
    • E04C2/38Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels
    • E04C2/384Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels with a metal frame
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/013Mounting or securing armour plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0407Transparent bullet-proof laminatesinformative reference: layered products essentially comprising glass in general B32B17/06, e.g. B32B17/10009; manufacture or composition of glass, e.g. joining glass to glass C03; permanent multiple-glazing windows, e.g. with spacing therebetween, E06B3/66
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/24Armour; Armour plates for stationary use, e.g. fortifications ; Shelters; Guard Booths

Definitions

  • the present invention relates to a blast-resistant barrier and in particular to a barrier comprising at least one polycarbonate panel.
  • Government and commercial buildings e.g., hotels, casinos, malls, airports and stadiums have proven attractive targets for bombing attacks throughout the world.
  • the attacker in most cases, is a politically motivated terrorist using, as a weapon, a high explosive device transported and detonated inside a vehicle adjacent to the targeted building.
  • the explosive device carried in such vehicles is typically capable of generating a shock wave of sufficient force as to shear the face off unprotected buildings, leading to tremendous loss of life and property damage.
  • the resulting debris field surrounding the building is often several feet thick blocking entrances.
  • glass remnants dangle precariously, potentially falling from great heights to the ground in the slightest breeze. Consequently, both hazards hinder and threaten the safety of emergency response teams as they attempt to enter the damaged building to render aid to the injured.
  • Patent 3,624,238 concerns a bullet resistant laminated structure that includes outer faces or plies of safety glass with an intermediary ply formed of a polycarbonate resin.
  • U.S. Patent 4,312,903 deals with an impact resistant double glazed structure made of glass and polycarbonate and is concerned in particular with the thickness of the layers of the laminated window panes, and their chemical compositions.
  • U.S. Patent 5,059,467 is concerned with a protective ballistic panel including a first-impact, front layer and a second rear layer, the layers being spaced from one another by a semi-elastic material, defining a sealed space.
  • the panel is used as a personnel protective shield.
  • U.S. Patent 6,266,926 describes a flexible apparatus that is deployed by inflating a protective barrier adjacent to windows to reduce the quantity of debris hazard in the event of an explosion.
  • U.S. Patent 6,349,505 discloses a louver system mounted adjacent to the inside and/or outside of a glass window and reinforced using high elongation cables or straps attached to the floor and ceiling. The louver system would immediately close upon detection of an explosion, reducing the quantity of debris hazard in the building.
  • U.S. Patent 4,625,659 disclosed a bullet and explosion proof window or door system comprising two spaced apart panels, whereby the outer panel is spaced from a support soffit such that a gap is formed for providing a ventilation channel. However, peripheral portions of the panels are fitted with a security layer in order to prevent projectiles from entering through the ventilation gap.
  • U.S. Patents 6,177,368 and 4,642,255 disclosed blast- resistant panels produced from PVC and woven fiberglass, and polyvinyl acetal, glass and a fibrous layer encapsulated in the polyvinyl acetal layer.
  • U.S. Patent 3,191 ,728 disclosed a barrier consisting of welded metal strips, as protection for workers in aircraft parking areas from the exhaust of jet engines.
  • U.S. Patent 5,277,952 disclosed a decorative, cracked mirrored, glass panels created from glass bonded together with a polymeric interlayer.
  • U.S. Patents 5,643,666, 5,894,048, 5,958,539, 5,998,028 and 6,025,069 disclosed panels consisting of laminated copolyester sheets and containing decorative interlayers and high relief surfaces.
  • Retrofits to protect building facades have traditionally involved strengthening of walls.
  • wall-strengthening is often an invasive operation which adversely affects the appearance of the structure and impacts building operations. It is, therefore, desirable to have a structure that is unobtrusive, easy to install, and at the same time protective of the entire building from the devastating effects of a vehicular bombing attack.
  • a blast-resistant barrier comprising a plurality of units each including a panel having a thickness of greater than 20 to less than 40 millimeter.
  • the panel is in the form of a monolithic polycarbonate sheet or a laminate that is positioned vertically between the source of a blast and the blast target, the laminate including at least two polycarbonate sheets and an optional image layer interposed therebetween.
  • the panel is fixedly attached to a frame which is firmly embedded in concrete in a manner calculated to provide stiffness sufficient to absorb and withstand external forces resulting from said blast.
  • the panel includes at least two polycarbonate sheets laminated one to the other, optionally including an image layer interposed therebetween.
  • the frame is anchored securely to the target enabling dissipation of the blast force through the target's structure.
  • the height of the blast-resistant barrier is preferably proportional to the height of the target.
  • the inventive panel comprise at least one monolithic, preferably two or more superposed polycarbonate sheets that are laminated and/or adhesively bonded one to the other to form a laminate.
  • the inventive panel may optionally include at least one image layer in the form of wood, stone, glass, textile, metal, paper, plastic, plants, flowers or vegetation and their products and each of these may be of any color.
  • the image layer may be laminated to or between any two of the layers.
  • the thickness of the panel is in the range of 20 to 40 millimeters.
  • the panel includes a laminate it is preferred that it includes a first polycarbonate sheet 10 to 20, preferably 12-18 millimeter (mm) in thickness, a second polycarbonate sheet 10 to 20, preferably 12-18 mm in thickness and at least one image layer interposed between the first and second sheets.
  • a first polycarbonate sheet 10 to 20 preferably 12-18 millimeter (mm) in thickness
  • a second polycarbonate sheet 10 to 20 preferably 12-18 mm in thickness
  • at least one image layer interposed between the first and second sheets entail a plurality of polycarbonate sheets, typically three of four sheets of identical thicknesses or differing thicknesses.
  • the several sheets making up the inventive panel may be bonded one to the other by lamination or by the use of an adhesive.
  • a suitable adhesive layer includes 0.025" thick A4700 Dureflex polyurethane film, a product of Deerfield Urethane. It is imperative that the adhesive be sufficiently heat resistant to withstand the thermal conditions encountered in lamination without degradation and distortion. Naturally, in circumstances where transparency of the panel is desired, the adhesive must be transparent.
  • the panel may be prepared by (a) providing a first polycarbonate sheet having a thickness of 10 to 20mm; and (b) providing a second polycarbonate sheet having a thickness of 10 to 20 mm; and (c) placing at least one image layer between the first and second sheets to form a sandwiched structure and (d) pressing the structure at elevated temperature for a time sufficient to form a laminate.
  • Suitable thermal conditions are generally 18 to 249° C, preferably 32 to 227°C under pressure of 69 to 2069, preferably 448 to 662 kPa, for a time at maximum temperature and pressure of 0.1 to 20 preferably 0.1 to 5 most preferably 0.17 to 3 minutes.
  • the sheet layers may squeeze out of the aligned image layer. It is preferred to apply pressure before the application of heat.
  • the laminate thus formed may be cooled at pressure between 7 and 2065 kPa.
  • the inventive laminate further includes a protective hard-coat layer.
  • first and second sheets are not necessarily the outermost sheets of the inventive panel.
  • the panel may contain a plurality of sheets (layers) on each side of the image layer as well as several image layers. It is however required that the total thickness of the panel be greater than 20 and less than 40 mm.
  • the panel is preferably 4 feet wide and 8 feet long but these are not limiting dimensions.
  • the polycarbonate sheets independently may be transparent, translucent, or opaque. Moreover the sheets may differ one from the others in their respective degrees of transparency or translucency and color.
  • Polycarbonate is well known thermoplastic, aromatic polymeric resin (see German Offenlegungsschriften 2,063,050; 1 ,561 ,518; 1 ,570,703; 2,211 ,956; 2,211 ,957 and 2,248,817; French Patent 1 ,561 ,518; and in particular the monograph by H. Schnell, "Chemistry and Physics of Polycarbonates", lnterscience Publishers, New York, N.Y., 1964, which is incorporated herein by reference).
  • the polycarbonate suitable in the context of the invention has weight average molecular weight of 8,000 to 200,000, preferably up to 80,000 and an intrinsic viscosity of 0.40 to 1.5 dl/g as measured in methylene chloride at 25°C.
  • the glass transition temperature of polycarbonates ranges from 145 to 148°C.
  • Polycarbonate sheets suitable in the context of the invention are available in commerce. Preferable for their good mechanical properties and excellent transparency are sheets made of a homopolycarbonate based on bisphenol A. Such suitable sheets are available under the MAKROLON trademark from Sheffield Plastics Inc.; a Bayer MaterialScience company.
  • the image layer(s) preferably includes fabric, metallic wire, rod and/or bar, papers or photographic images, and vegetation, such as grasses, flowers, wheat, and thatch.
  • the image layer may display images or designs or may be of a solid color and should be sufficiently thermally resistant, e.g. of sufficiently high melt temperature to avoid any degradation or distortion of the image during the manufacture or processing of the panel.
  • the image layer(s) are substantially continuous.
  • the thickness of the image layer is advantageously 0.0254 to 1.524 mm, preferably 0.0254 to 0.05 mm, and is most preferably 0.04mm.
  • polymeric films thinner or thicker may be used in the decorative image layer depending on the equipment available, and under such conditions the thickness is limited only by functionality.
  • the panel includes at least one first image layer positioned between the first and the second polycarbonate sheet and at least one second image layer positioned between the second and the third polycarbonate sheet.
  • the image layer comprises a fabric of textile fibers.
  • the fabric may display images or designs produced, e.g., by weaving or knitting techniques, in the fabric.
  • the fabrics may be textile fibers, (i.e., fibers of natural-occurring, semi-synthetic or synthetic polymeric materials).
  • the fabrics may be prepared from cotton, wool, silk, rayon (regenerated cellulose), polyester such as polyethylene terephthalate, synthetic polyamides such as nylon 66 and nylon 6, acrylic, methacrylic, and cellulose acetate fibers.
  • the melting point of the textile fibers should be sufficiently high to avoid any degradation or distortion of the fabric during the manufacture or processing of the laminate of the invention.
  • the fabric may be woven, spun-bonded, knitted, or prepared by other processes well known in the textile trade and may be uncolored, e.g., white, or colored by conventional dyeing and printing techniques.
  • the fabrics may be produced from dyed yarn or from filaments and yarn derived from mass colored polymers.
  • the fabrics present within the decorated laminate structure are substantially continuous and constitute a distinct image layer or laminate.
  • the image layer comprises metallic wire, rod, or bar.
  • the metal wire may be formed by a variety of techniques to produce metal mesh fabric, screens, or open mesh having high transparency.
  • the metal wire, rod or bar may be woven, welded, knitted, or fabricated by means of other processes well known in the metal wire fabrication art.
  • the metallic wire, rod and bar may be of any color.
  • the metallic element of the image layer may be of different metallic materials such copper, aluminum, stainless steel, steel, galvanized steel, titanium, etc. or combinations thereof.
  • the metallic component of the image layer may be prepared from wire filaments, rods and bars having various cross-sectional areas and geometries, e.g., generally circular, oval or relatively flat.
  • the thickness or diameter of the wire, rod and bar is not critical. It is however critical that the metallic surfaces are smooth so as avoid creating of propagating cracks that may weaken the panel.
  • embedding the metallic surfaces in a polymeric material such as polyvinyl chloride, copolyester or polyurethane, may be advantageous.
  • the only requirement relative to this embodiment is that the embedding polymeric materials have sufficient heat resistance so as not to be thermally degraded or distorted by the panel lamination and forming processes.
  • the panel may comprise an image layer of wire, rod, or bar that reinforce the polycarbonate.
  • the image layer comprises a printed or colored image.
  • the printed or colored image layer has opposed surfaces wherein an image is printed on one of the surfaces and/or the decorative image layer contains coloration. More than one printed or colored decorative image layer may be used in the decorated laminate structure of the present invention.
  • the use of multiple decorative image layers may provide a 3-dimensional or "floating" appearance to the decorative images or lettering in the printed or colored image layers.
  • Each of the printed or colored image layers is joined to a first sheet on one of its surfaces such that the image or coloration may be viewed through the first sheet without significant distortion.
  • the printed or colored image layer may comprise any suitable polymeric material which is compatible with the materials used for the first and second sheets, inks, or other materials used in fabricating the laminate.
  • the image layer comprises polyvinylchloride, copolyester, polycarbonate or polyurethane thermoplastic.
  • the image or coloration is printed on the bottom side of the image layer in which case the polymer used to prepare the image layer is transparent.
  • the printed image may be prepared according to conventional photographic printing processes or with a digitized database generated from a photographic image. Digitizing and storing the image may be accomplished through any of a number of processes well known in the computer art such as scanning.
  • the image layer comprises vegetation, such as grasses, thatch, flowers, for example rose petals, wheat, grains, natural papers and others, such that the natural color of vegetation is preserved.
  • More than one image layer comprising vegetation may be used in the decorated laminate structure of the present invention.
  • the use of multiple image layers may provide a 3-dimensional or "floating" appearance to the decorative vegetation in the image layers.
  • Each of the image layers is joined to a first sheet on one of its surfaces such that the vegetation can be seen through the first sheet without significant distortion.
  • the laminate structure may optionally comprise a protective hard-coat layer, which is a transparent, hard, scratch-resistant or abrasion resistant coating or layer laminated to the top surface of the first sheet. Such coating may also increase the chemical resistance of the laminate and provide an anti-graffiti surface.
  • the protective layer may be a bi-layer film comprising a protective layer on top of a sheet layer.
  • the protective layer is preferably selected from the UV- cured or electron-beam-cured crosslinked acrylic, vacuum-cured or UV-cured urethane, UV-cured or electron-beam-cured silicon with acrylic or heat cured urethane or plastisol.
  • a layer of polyurethane may be applied over the exterior surface to provide abrasion resistance.
  • a biaxially oriented polyethylene terephthalate such as MYLAR® or a TEFLON® film, such as TEDLAR® both available from DuPont Chemical Company, may be laminated to the top surface of the first sheet as a protective layer.
  • the protective layer comprises a thermal-cured, UV-cured or electron-beam-cured silicon to achieve glass appearance.
  • Lamination of the inventive panel is conventional.
  • a plywood laminating press that features efficient heat transfer and even distribution of heat is preferably used.
  • a vacuum may be applied in order to remove trapped air between the layers.
  • the polycarbonate materials may be bonded or fused together with the use of adhesive.
  • the laminating method comprises hot press bonding or cold press bonding.
  • hot press bonding methods include, but are not limited to, hot steam, electric heat, hot oil heated and other methods known in the art.
  • Cold press bonding methods include, but are not limited to, cold water and glycol cooled method.
  • the lamination may be performed either with or without a vacuum press. Generally, the formation of bubbles in the laminated panel is less likely if the air is evacuated prior to applying heat and pressure. In any event it is critical that sufficient pressure is applied to rid the system of air prior to bonding. Following the hot press bonding, the bonded structure is allowed to cool by being held at 10 to about 148°C.
  • the frame to which the panel is fixedly attached is preferably made of carbon steel, i.e. steels having up to about 2 percent carbon content, stainless steel or aluminum.
  • frames of carbon steel may be treated with corrosion resistant coatings and/or paints.
  • Stainless steels are preferred for outdoor applications because they are more resistant to rusting and staining than carbon and low alloy steels, thus maintaining their aesthetic appeal. It is imperative that in the instances where the image layer is capable of absorbing moisture, the edges of the panel are sealed to prevent wicking. Suitable sealing may be by the application of silicone or by gluing to the edge a thin polymeric film, e.g. polycarbonate film.
  • the steel frame comprise shaped members (e.g., a "C" cross section shaped members) providing sufficient stiffness and strength to absorb the external forces applied by the blast without major distortion.
  • the frame may be extended vertically at its bottom so that the extensions can be embedded in reinforced concrete foundation.
  • the steel frame may be attached to the steel skeleton of the target (e.g. building) in a manner to dissipate the shock wave.
  • the panel may be attached to the frame by either a structural adhesive or by a plurality of bolts.
  • the bolts preferably shoulder bolts, are 0.75 to 1.25 inches, preferably 1.0 inch in diameter, with flat heads so that upon tightening, the bolt head and nut place the area of the panel around the bolt hole in compression without creating cracks or notches.
  • the bolts may be spaced 4 inches to 8 inches, preferably 6 inches, apart and offset approximately 1.0 inch to 1.5 inches from the panel edge.
  • the bolt holes in the panel are preferably produced with smooth, elongated edges to allow for thermal expansion and to mitigate stress. Rubber or elastomeric washers or spacers may be used between the panel and frame to further absorb impact energy and dampen forces transmitted to the building.
  • the mechanical properties for the "C" section steel channels preferably exhibit a final yield strength in tension of approximately 300 MPa. Otherwise, for higher or lower modulus materials such as aluminum, equivalent section properties are preferably followed through use of thicker or thinner walls.
  • the inventive panel is preferably placed at a distance of at least 12 inches from the surface of the protected target to avoid the polycarbonate panels striking the building while bending as a result of being hit with the shock wave resulting from a blast. Shorter distances may be used for lower threat levels or smaller panels.
  • a panel in the form of a laminate that includes a colored textile was prepared.
  • a hot press platen was preheated to 475°F.
  • the cold press platen temperature was set at 65° F.
  • steel press plate Nomex pad (Nomex pressure distribution pads), or another suitable medium to attain even distribution of pressure
  • aluminum separation plate Nomex pad (Nomex pressure distribution pads), or another suitable medium to attain even distribution of pressure
  • release paper patina finish Ultra-cast release paper
  • 0.060" polycarbonate sheet image layer in the form of textile (sheer nylon textile), 0.060" polycarbonate sheet, release paper, aluminum separation plate, Nomex pad, steel press plate.
  • thermocouple was inserted in-between the first sheet of polycarbonate and the textile.
  • the assembly was then inserted in the hot press, the press was closed and the pressure was increased to 94 psi.
  • the temperature was closely monitored until the thermocouple read 42O 0 F. Once the temperature was reached, the pressure was released and the press opened.
  • the assembly was then transferred to the cold press set to cold press platen temperature of 65° F. Next, the pressure in the cold press was increased to 94 psi. This transfer and re- pressurizing was completed in less than 3 minutes. The temperature was closely monitored until the thermocouple read 90 0 F at which point the decorated laminate structure was removed from the press.
  • An additional panel in the form of a laminate was prepared.
  • a hot press platen was preheated to 475°F.
  • the cold press platen temperature was set at 65° F.
  • the following were assembled in the following order (top to bottom): steel press plate, Nomex pad (Nomex pressure distribution pads), aluminum separation plate, release paper (patina finish Ultra-cast release paper), hard coated polycarbonate film (0.005" thick film), oriented with the hard-coat against the release paper, 0.118" polycarbonate sheet, image layer in the form of textile, 0.118" polycarbonate sheet, release paper, aluminum separation plate, Nomex pad, and steel press plate.
  • the "hard coat” used was a flexible aliphatic polyurethane coating.
  • thermocouple was inserted in-between the first sheet of polycarbonate and the textile.
  • the assembly was then inserted in the hot press, the press was closed and the pressure was increased to 94 psi.
  • the temperature was closely monitored until the thermocouple read 420°F. At that temperature the pressure was released and the press opened.
  • the assembly was then split between the first release paper and hard-coated polycarbonate film and then transferred to the cold press (press platen temperature of 65° F) and the pressure in the cold press was increased to 94 psi. This transfer and re-pressurizing was completed in less than 3 minutes.
  • the temperature was closely monitored until the thermocouple read 90 0 F at which point the laminate was removed from the press. Surface finishes on the bottom of the product were uniform and even.
  • An additional panel in the form of a laminate that including botanical matter with clear resin, flat texture, thatch reeds embedded on multiple layers, and patina finish on both sides, was prepared as follows: A hot press platen was preheated to 475°F. The cold press platen temperature was set at 65° F. Next the following were assembled in the following order (top to bottom): steel press plate, Nomex pad (Nomex pressure distribution pads), aluminum separation plate, release paper , 0.118" polycarbonate sheet, thatch (thatch reeds), 0.236" polycarbonate sheet, thatch, 0.118" polycarbonate sheet, release paper, aluminum separation plate, Nomex pad, and steel press plate.
  • thermocouple was inserted in-between the first thatch and 0.236" polycarbonate sheet.
  • the assembly was then inserted in the hot press, the press was closed and the pressure was increased to 10 psi.
  • the temperature was closely monitored until the thermocouple read 410°F. At that temperature the pressure was increased to 30 psi.
  • the temperature was closely monitored until the thermocouple read 420 0 F. At that temperature the pressure was increased to 94 psi.
  • the temperature was closely monitored until the thermocouple read 435°F.
  • the pressure was released and the press opened.
  • the assembly was then transferred to the cold press (press platen temperature of 65° F) and the pressure in the cold press was increased to 94 psi.
  • a yet additional panel in the form of a laminate that includes textile as the image layer was prepared.
  • the sheet was unmasked, cleaned with 50/50% (by volume) water/isopropyl solution, air dried and the static electricity was removed from the sheet using deionized air.
  • the following were assembled on a table in order (top to bottom): 0.5" X 4' X 8' polycarbonate sheet, image layer (sheer nylon textile), 0.025" aliphatic TPU film (Deerfield A 4700), 0.5" X 4' X 8'polycarbonate sheet.
  • the assembly was then inserted into a vacuum bag which was subsequently evacuated to 29 "of mercury. This vacuum was maintained 1 hr prior to, and subsequently throughout, the autoclaving cycle.
  • the vacuum bag with its contents was then placed in an autoclave and heated 2.5°F/min for 96 min to 240 °F. At the same time the pressure was increased 3.8 psi/min to 171 psi over 45 minutes. The 240 0 F temperature was then held for 90 min at 171 psi.
  • the vacuum bag was gradually cooled at 2.0 0 F/ min to 105 0 F, and the pressure was then reduced at 3.8 psi/min to ambient. The assembly was allowed to sit undisturbed for another hour. Finally the assembly was removed from the vacuum bag.
  • a virtual barrier structure produced in accordance with the invention was tested in a ABAQUS computer model simulating vehicular bomb blasts.
  • the model simulated a blast using the equivalent of 2000 pounds of trinitrotoluene (TNT) against a panel wherein the panel was a 4' by 8' sheet of polycarbonate 25 to 35 mm thick at distances of 100 feet, 80 feet and 50 feet, and against 2' by 8' sheets of polycarbonate 25 mm thick at 80 feet, 50 feet and 40 feet from the blast resistant barrier.
  • TNT trinitrotoluene

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Environmental & Geological Engineering (AREA)
  • Laminated Bodies (AREA)
  • Buildings Adapted To Withstand Abnormal External Influences (AREA)
PCT/US2008/012574 2007-11-13 2008-11-07 Blast-resistant barrier WO2009108167A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN200880116446A CN101855415A (zh) 2007-11-13 2008-11-07 防爆阻挡物
EP20080872862 EP2209957A4 (en) 2007-11-13 2008-11-07 RADIATION-RESISTANT BARRIER
AU2008351442A AU2008351442A1 (en) 2007-11-13 2008-11-07 Blast-resistant barrier
JP2010534022A JP2011508679A (ja) 2007-11-13 2008-11-07 耐ブラスト性バリア
IL204939A IL204939A (en) 2007-11-13 2010-04-08 Explosion-resistant barrier

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/983,980 2007-11-13
US11/983,980 US20110048219A1 (en) 2007-11-13 2007-11-13 Blast-resistant barrier

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WO2009108167A2 true WO2009108167A2 (en) 2009-09-03
WO2009108167A3 WO2009108167A3 (en) 2009-10-22

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US (1) US20110048219A1 (zh)
EP (1) EP2209957A4 (zh)
JP (1) JP2011508679A (zh)
KR (1) KR20100090771A (zh)
CN (2) CN101855415A (zh)
AU (1) AU2008351442A1 (zh)
IL (1) IL204939A (zh)
WO (1) WO2009108167A2 (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013050783A1 (en) * 2011-10-05 2013-04-11 University Of Ulster Protective panels
RU2592291C1 (ru) * 2015-07-31 2016-07-20 Олег Савельевич Кочетов Взрывозащитная разрушающаяся конструкция кочетова ограждения зданий
RU2599811C1 (ru) * 2015-10-09 2016-10-20 Олег Савельевич Кочетов Взрывозащитная разрушающаяся конструкция кочетова для ограждения зданий
RU2638374C1 (ru) * 2017-01-13 2017-12-13 Олег Савельевич Кочетов Взрывозащитная разрушающаяся конструкция для взрывоопасных зданий

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10408576B2 (en) 2008-10-27 2019-09-10 Plaskolite Massachusetts, Llc High-energy impact absorbing polycarbonate mounting method
KR101250903B1 (ko) * 2011-01-11 2013-04-04 박종영 알루미늄 폼 패널과 콘크리트판의 합성 방폭벽체, 그 시공방법 및 이를 이용한 방폭구조물
WO2014035482A2 (en) 2012-08-29 2014-03-06 Bayer Materialscience Llc Energy absorber for high-performance blast barrier system
US20150090411A1 (en) * 2013-09-30 2015-04-02 Bayer Materialscience Llc Polycarbonate laminate window covers for rapid deployment providing protection from forced-entry and ballistics
CN103628583B (zh) * 2013-11-12 2016-04-20 中国人民解放军空军工程大学 一种组装式移动防爆墙
US9879474B2 (en) 2014-05-06 2018-01-30 Covestro Llc Polycarbonate based rapid deployment cover system
WO2016123632A1 (en) * 2015-02-01 2016-08-04 Raymond Lynn Goodson Ballistic resistant laminate material and method of making
US10260842B2 (en) * 2015-02-09 2019-04-16 Plaskolite Massachusetts, Llc Lightweight blast-mitigating polycarbonate-based laminate system
CN104845291B (zh) * 2015-05-04 2016-09-21 常州伊柯瑞斯装饰材料有限公司 一种petg生态树脂板及其制备方法
EP3208123A1 (en) * 2016-02-16 2017-08-23 Hammerglass AB Protective windscreen arrangement
CN107165298B (zh) * 2017-04-06 2019-03-19 武汉大学 高波阻抗双重反射爆炸冲击防护装置
NO345273B1 (en) * 2017-10-30 2020-11-23 Aquafence As Flood barrier ground sealing arrangement
CN108442573B (zh) * 2018-03-27 2019-12-17 北京建筑大学 一种装配式抗爆减爆墙及其施工方法
US10765045B1 (en) * 2019-06-19 2020-09-01 Go Team Ccr, Llc Electromagnetic pulse (EMP) protective composite enclosure panel system and EMP protective building structures and systems

Family Cites Families (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1283981A (fr) * 1960-12-29 1962-02-09 Panneau métallique et son application à une barrière anti-souffle, notamment pouraéroports
US3520768A (en) * 1966-12-12 1970-07-14 Bayer Ag Laminated safety panes of glass and polycarbonate using acrylic ester adhesives
US3624238A (en) * 1969-03-24 1971-11-30 Binswanger Glass Co Laminated transparent bullet resisting structure
US3666614A (en) * 1969-06-24 1972-05-30 Union Carbide Corp Glass-polycarbonate resin laminates
CA1042334A (en) * 1973-06-13 1978-11-14 Richard E. Molari (Jr.) Laminates bonded with siloxane-carbonate block copolymers
US3917891A (en) * 1974-04-11 1975-11-04 Asg Ind Inc Fragmentation shield for impact resisting optical medium
US4070805A (en) * 1976-08-16 1978-01-31 Sid Kastner Displaceable building unit for off-the-wall games
DE2962408D1 (en) * 1978-01-30 1982-05-19 Cin Ind Investments Limited Synthetic resin/glass laminates and process for producing these laminates
US4312903A (en) * 1980-03-05 1982-01-26 General Electric Company Impact resistant double glazed structure
CA1248822A (en) * 1984-04-04 1989-01-17 Christopher W.G. Hall Impact resistant laminate
DE3432021A1 (de) * 1984-08-31 1986-03-13 Heinrich 3550 Marburg Sälzer Sicherheitsfenster oder -tuer
US4642255A (en) * 1984-12-20 1987-02-10 Frank C. Dlubak Laminated article and process for making same
IL88384A (en) * 1988-11-15 1993-07-08 Eagle Protective ballistic panel
JPH07507383A (ja) * 1992-02-28 1995-08-10 アールマービジョン・プラスティクス・アンド・グラス 防弾透明パネル並びにその製造方法およびプレス機
DE4223538C1 (de) * 1992-07-17 1993-11-04 Deutsche Aerospace Schutzeinrichtung fuer fenster
US5277952A (en) * 1992-07-29 1994-01-11 Watras Edward W Decorative cracked glass mirror tile and method
JP2572977Y2 (ja) * 1992-10-27 1998-05-25 日本鋪道株式会社 緩衝フェンス
US5612741A (en) * 1993-11-05 1997-03-18 Curtis Mathes Marketing Corporation Video billboard
IL108434A (en) * 1994-01-25 1998-01-04 Avraham Bornstein Ballistic panel
US5463929A (en) * 1994-07-20 1995-11-07 Mejia; Santiago Armoring material mounting assembly
US5496640A (en) * 1994-08-15 1996-03-05 Artistic Glass Products Company Fire resistant transparent laminates
EP0714764A3 (en) * 1994-12-02 1997-03-05 Gen Electric Improved impact resistant composite
FR2740211B1 (fr) * 1995-10-19 1997-12-26 France Etat Dispositif de blindage de protection contre des projectiles perforants
US5643666A (en) * 1995-12-20 1997-07-01 Eastman Chemical Company Solid surfaces which are prepared from copolyesters laminated onto a high resolution image
CN1073692C (zh) * 1996-04-02 2001-10-24 卢予阳 组合透明防弹板
EP0880902A1 (fr) * 1997-05-27 1998-12-02 Nestlé Produkte AG Procédé de traitement d'une matiére première lactosérique
US6025069A (en) * 1998-06-19 2000-02-15 Eastman Chemical Company Thermoplastic article having high-relief surface
US5958539A (en) * 1997-08-26 1999-09-28 Eastman Chemical Company Thermoplastic article having textile fiber fabric embedded therein
US5998028A (en) * 1997-08-26 1999-12-07 Eastman Chemical Company Thermoplastic article having metallic wire, rod or bar embedded therein
US6177368B1 (en) * 1998-03-16 2001-01-23 Russell J. Fisher Blast resistant laminate composite container wall construction
JPH11320797A (ja) * 1998-05-13 1999-11-24 Komatsu Ltd プラスチック積層体
GB2337497B (en) * 1998-05-22 2000-08-16 Neil Harriman Vehicle window security guard apparatus
EP0967453A1 (en) * 1998-06-25 1999-12-29 Armortec Incorporated Flexible, impact-resistant materials
CN2379472Y (zh) * 1999-06-16 2000-05-24 曹元� 轻质无溅射防弹防暴玻璃
US6266926B1 (en) * 1999-11-01 2001-07-31 Atlantic Research Corporation Gas generator deployed occupant protection apparatus and method
US6349505B1 (en) * 1999-11-01 2002-02-26 Atlantic Research Corporation Window protection apparatus
US6509071B1 (en) * 2000-02-09 2003-01-21 Arpal Aluminum Ltd. Reinforced window systems
US6401427B1 (en) * 2000-03-16 2002-06-11 Sandia Corporation Modular shield
CN2450624Y (zh) * 2000-05-26 2001-09-26 曹元� 用于防弹头盔的复合玻璃防弹面罩
US20030190439A1 (en) * 2002-04-03 2003-10-09 The United States Of America As Represented By The Secretary Of The Army Transparent armor structure
US6622607B1 (en) * 2002-09-26 2003-09-23 General Security Services Corporation Mobile bullet resistant barrier
JP2004188764A (ja) * 2002-12-11 2004-07-08 Sumitomo Chem Co Ltd 積層透明板
US20040226231A1 (en) * 2003-02-27 2004-11-18 Dlubak Francis C. Blast resistant assemblies
US20040261332A1 (en) * 2003-06-30 2004-12-30 Lakdas Nanayakkara Blast protective barrier system
WO2005014964A1 (en) * 2003-07-18 2005-02-17 Hamilton Erskine Limited Improvements relating to impact-resistant structures and assemblies
US7597040B2 (en) * 2003-07-30 2009-10-06 The Boeing Company Composite containment of high energy debris and pressure
US20050066805A1 (en) * 2003-09-17 2005-03-31 Park Andrew D. Hard armor composite
US20100126797A1 (en) * 2004-02-12 2010-05-27 Humphries Eric C Panel Assembly For Traffic Noise Barrier Wall
JP2005241183A (ja) * 2004-02-27 2005-09-08 Mitsubishi Heavy Ind Ltd 防弾構造および防弾改造工法
US7380379B2 (en) * 2004-03-11 2008-06-03 Venegas Jr Frank Explosion-absorbing panels and wall structures
JP2005282168A (ja) * 2004-03-30 2005-10-13 Takiron Co Ltd 遮音パネル
US7037030B2 (en) * 2004-07-16 2006-05-02 Mclemore Keith Steven Project ‘M’—vehicular inspection Rigi-Frame and crash beam
JP2006037414A (ja) * 2004-07-23 2006-02-09 Hirokazu Kii 補強ガラス構造体およびこれを用いたガラスルーバ並びに補強ガラス構造体の製造方法
US7144186B1 (en) * 2004-09-28 2006-12-05 Kontek Industries, Inc. Massive security barrier
US20100242714A1 (en) * 2004-11-01 2010-09-30 Anthony Piscitelli Anti-ballistic egress window assembly
KR20070094748A (ko) * 2004-12-01 2007-09-21 라이프 실드 엔지니어드 시스템스 엘엘시 파편 및 발사체 격납 시스템과 장비 및 그 제조 방법
EP2115381A4 (en) * 2004-12-08 2011-09-07 Armordynamics Inc TECHNIQUES AND APPARATUS FOR BALISTIC PROTECTION
US20100098929A1 (en) * 2005-07-11 2010-04-22 John Anthony Dispenza Impact resistant composite material
US7159503B1 (en) * 2005-07-13 2007-01-09 John Weatherwax Modular, light weight, blast protective, check point structure
US7437987B1 (en) * 2005-09-27 2008-10-21 High Impact Technology Llc Blast shielding
US7520207B1 (en) * 2005-11-18 2009-04-21 Patriot3, Inc. Modular ballistic wall assembly
US7784389B2 (en) * 2006-03-20 2010-08-31 Technology Patents, Llc Anti-terrorist system
CN2923308Y (zh) * 2006-05-24 2007-07-18 陈东风 夹层树脂板
SI2027347T1 (sl) * 2006-06-13 2014-04-30 Kingspan Research And Developments Limited Prosojna plošča
US20090139091A1 (en) * 2007-09-27 2009-06-04 Honeywell International Inc, Field installation of a vehicle protection system
WO2009129293A2 (en) * 2008-04-15 2009-10-22 The Penn State Research Foundation Transparent sustainable wall system
US20100089229A1 (en) * 2008-09-23 2010-04-15 Ackerman Craig R Blast pressure, fragment and projectile resistant panel mounting systems
US10408576B2 (en) * 2008-10-27 2019-09-10 Plaskolite Massachusetts, Llc High-energy impact absorbing polycarbonate mounting method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of EP2209957A4 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013050783A1 (en) * 2011-10-05 2013-04-11 University Of Ulster Protective panels
RU2592291C1 (ru) * 2015-07-31 2016-07-20 Олег Савельевич Кочетов Взрывозащитная разрушающаяся конструкция кочетова ограждения зданий
RU2599811C1 (ru) * 2015-10-09 2016-10-20 Олег Савельевич Кочетов Взрывозащитная разрушающаяся конструкция кочетова для ограждения зданий
RU2638374C1 (ru) * 2017-01-13 2017-12-13 Олег Савельевич Кочетов Взрывозащитная разрушающаяся конструкция для взрывоопасных зданий

Also Published As

Publication number Publication date
CN104912218B (zh) 2019-09-10
IL204939A (en) 2013-01-31
US20110048219A1 (en) 2011-03-03
CN104912218A (zh) 2015-09-16
KR20100090771A (ko) 2010-08-17
IL204939A0 (en) 2010-11-30
EP2209957A4 (en) 2014-01-22
AU2008351442A1 (en) 2009-09-03
JP2011508679A (ja) 2011-03-17
WO2009108167A3 (en) 2009-10-22
EP2209957A2 (en) 2010-07-28
CN101855415A (zh) 2010-10-06

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