WO2009087955A1 - 円筒式水蒸気改質器 - Google Patents
円筒式水蒸気改質器 Download PDFInfo
- Publication number
- WO2009087955A1 WO2009087955A1 PCT/JP2008/073984 JP2008073984W WO2009087955A1 WO 2009087955 A1 WO2009087955 A1 WO 2009087955A1 JP 2008073984 W JP2008073984 W JP 2008073984W WO 2009087955 A1 WO2009087955 A1 WO 2009087955A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal
- cylinder
- plate
- reforming catalyst
- wall surface
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 claims abstract description 419
- 239000002184 metal Substances 0.000 claims abstract description 419
- 239000003054 catalyst Substances 0.000 claims abstract description 259
- 238000002407 reforming Methods 0.000 claims abstract description 199
- 239000000463 material Substances 0.000 claims abstract description 132
- 238000005219 brazing Methods 0.000 claims description 55
- 239000000758 substrate Substances 0.000 claims description 49
- 238000004519 manufacturing process Methods 0.000 claims description 34
- 229910052739 hydrogen Inorganic materials 0.000 claims description 33
- 239000001257 hydrogen Substances 0.000 claims description 33
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 32
- 239000000470 constituent Substances 0.000 claims description 19
- 239000000446 fuel Substances 0.000 claims description 15
- 229910001220 stainless steel Inorganic materials 0.000 claims description 14
- 150000002739 metals Chemical class 0.000 claims description 8
- 239000005518 polymer electrolyte Substances 0.000 claims description 3
- 230000001185 psoriatic effect Effects 0.000 claims 1
- 238000012546 transfer Methods 0.000 abstract description 33
- 235000012054 meals Nutrition 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 34
- 238000010586 diagram Methods 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 14
- 238000005192 partition Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000005855 radiation Effects 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- 238000006057 reforming reaction Methods 0.000 description 4
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 3
- 238000004891 communication Methods 0.000 description 3
- 230000008602 contraction Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 230000002093 peripheral effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/2485—Monolithic reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/249—Plate-type reactors
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
- H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2454—Plates arranged concentrically
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2456—Geometry of the plates
- B01J2219/2458—Flat plates, i.e. plates which are not corrugated or otherwise structured, e.g. plates with cylindrical shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2456—Geometry of the plates
- B01J2219/2459—Corrugated plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2461—Heat exchange aspects
- B01J2219/2467—Additional heat exchange means, e.g. electric resistance heaters, coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2476—Construction materials
- B01J2219/2477—Construction materials of the catalysts
- B01J2219/2479—Catalysts coated on the surface of plates or inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2476—Construction materials
- B01J2219/2483—Construction materials of the plates
- B01J2219/2485—Metals or alloys
- B01J2219/2486—Steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2491—Other constructional details
- B01J2219/2497—Size aspects, i.e. concrete sizes are being mentioned in the classified document
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0225—Coating of metal substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0248—Coatings comprising impregnated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/044—Selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0816—Heating by flames
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0866—Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1023—Catalysts in the form of a monolith or honeycomb
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a cylindrical steam reformer, and more specifically, a cylindrical steam reformer in which a honeycomb reforming catalyst is disposed in a gap between double cylinders composed of an inner cylinder and an outer cylinder, and the cylindrical steam reformer.
- the present invention relates to an integrated cylindrical hydrogen production apparatus in which a mass device is incorporated as a reforming catalyst layer of a cylindrical hydrogen production apparatus having a reforming catalyst layer, a CO shift catalyst layer, and a CO removal catalyst layer.
- a hydrogen production apparatus that produces hydrogen, which is a fuel for a polymer electrolyte fuel cell
- a plurality of catalysts including a reforming catalyst, a CO shift catalyst, and a CO removal catalyst are used.
- reforming catalysts are used at high temperatures of 600 or more, for example 700, so when reactors with these catalysts are arranged separately, piping and heat insulation connecting each reactor are used. Materials are required and the equipment configuration becomes complicated.
- integrated cylindrical hydrogen production apparatus for simplification and miniaturization, for example, W00 / 63114 Al, WO 02/098790 Al, JP 2002-187705 A, JP 2005-193135 A, JP 2006-232611 A, As described in Japanese Patent Application Laid-Open No. 2007-112667, a cylindrical hydrogen production apparatus in which these reactors are integrated (hereinafter, referred to as “integrated cylindrical hydrogen production apparatus” as appropriate) has been considered. Disclosure of the invention
- the integrated cylindrical hydrogen production system integrates a reactor with a reforming catalyst, a reactor with a CO conversion catalyst, and a reactor with a CO removal catalyst.
- the reactor is configured by disposing a poor catalyst between the inner cylinder and the outer cylinder in an annular layer, and a granular reforming catalyst is usually used as the reforming catalyst.
- Fig. 1 is a diagram for explaining a reactor in which a granular reforming catalyst is arranged.
- Fig. 1 (b) is an enlarged view of a part of Fig. 1 (a).
- the granular reforming catalyst is arranged in an annular layer between the inner and outer cylinders.
- a burner is arranged in the inner cylinder, but the illustration is omitted.
- the raw fuel that is, the mixed gas of the fuel and steam before reforming in the reforming catalyst layer is introduced from one end of the reforming catalyst layer.
- the raw fuel is reformed with steam by the reforming catalyst of the reforming catalyst layer, and is derived as reformed gas from the other end.
- the reforming catalyst is used at a high temperature, and when a cylindrical steam reformer is used in, for example, a household cogeneration system (a cogeneration system) incorporating a solid polymer fuel cell, It is necessary to start and stop frequently. Therefore, when a granular reforming catalyst is used, the granularity that is filled in the reforming catalyst layer by repeatedly increasing and decreasing the temperature, etc. The problem is that the reforming catalyst is crushed and pulverized, resulting in a decrease in catalytic activity.
- the reforming reaction by the reforming catalyst is an endothermic reaction, and heat must be supplied from the inner wall surface side of the inner cylinder and the outer wall side of the outer cylinder for the reaction.
- Heat from the burner is supplied from the inner wall surface side of the inner cylinder, and heat of the reformed gas, that is, the reformed gas, is supplied from the outer wall side of the outer cylinder.
- the amount of heat supplied depends on the heat transfer area, heat transfer (ie overall heat transfer coefficient) and temperature difference. For this reason, if the temperature difference is the same, the heat transfer area can be reduced if the heat transfer is superior, and the size can be reduced.
- the honeycomb reforming catalyst is a catalyst in which the reforming catalyst and the fixed bed are integrated, and is a honeycomb structure base material that is a fixed bed, that is, a catalyst in which the reforming catalyst is supported on the honeycomb base material.
- the honeycomb reforming catalyst is also referred to as a monolith reforming catalyst.
- FIG. 2 is a diagram illustrating an embodiment in which a honeycomb reforming catalyst is arranged.
- the honeycomb reforming catalyst is arranged between the inner cylinder and the outer cylinder.
- a honeycomb reforming catalyst is a catalyst in which a reforming catalyst is supported on the surface of a honeycomb substrate, that is, a substrate having a large number of parallel through holes (a large number of cells).
- the catalyst does not settle against thermal displacement such as expansion and contraction of the inner and outer cylinders. it can.
- the honeycomb reforming catalyst is usually arranged by being produced separately and then fitted into a gap between the inner cylinder and the outer cylinder.
- the waves of the honeycomb base material are in contact with the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder, and as shown in Fig. 2 (b), the outer wall surface of the inner cylinder and the Between the waves, there is a “gap” between the inner wall of the outer cylinder and the waves of the honeycomb substrate. For this reason, the heat transfer is almost the same as that of the granular reforming catalyst.
- the inventors increased the manufacturing accuracy so that the double cam base material is completely attached to the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder. Attempts were made to make close contact, but if the constituent material of the cylinder and the constituent material of the honeycomb base material were different, the difference in thermal expansion coefficient during operation caused the difference between the outer wall surface of the inner cylinder and the eighty cam base material. There was a gap between the inner wall surface of the outer cylinder and the honeycomb substrate. Then, the heat transfer from the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder to the honeycomb base material is deteriorated, and the heat necessary for the reforming reaction cannot be sufficiently transmitted.
- a doughnut-shaped honeycomb reforming catalyst is attached to the inner cylinder. Attempts were made to fit between outer cylinders, but it was quite difficult to produce a doughnut-shaped honeycomb substrate with a high yield.
- WO 0 2/0 9 8 7 9 0 A 1 includes a honeycomb between the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder.
- a buffer member such as a wire mesh that absorbs the thermal displacement of the monolith reforming catalyst is disposed between the honeycomb reforming catalyst and the inner cylinder outer wall surface.
- the buffer member needs to have a predetermined thickness for the purpose of disposing it, and therefore the size of the reforming catalyst layer is increased rather than downsizing.
- a honeycomb substrate formed of a plurality of metal zigzag plate bodies and a plurality of metal flat plate bodies was used as an inner cylinder and an outer cylinder. After being placed between the two, a brazing method using a metal brazing material was applied, and it was found that the above-mentioned “clearance” did not occur and the heat conductivity could be improved satisfactorily.
- a brazing method using a metal brazing material was applied, and it was found that the above-mentioned “clearance” did not occur and the heat conductivity could be improved satisfactorily.
- the present invention solves the above-mentioned problems in the granular reforming catalyst and the conventional 820 cam reforming catalyst based on these findings and facts.
- the present invention provides a cylindrical steam reformer in which a honeycomb reforming catalyst is disposed in the gap between the inner cylinder and the outer cylinder, in which the above-mentioned “gap” does not occur and heat conductivity is improved.
- the present invention provides an integrated cylindrical hydrogen production apparatus in which the cylindrical steam reformer is incorporated into a cylindrical hydrogen production apparatus having a CO conversion catalyst layer and a CO removal catalyst layer. The purpose is to do this.
- the present invention (1) is a cylindrical steam reformer in which a honeycomb reforming catalyst having a reforming catalyst supported on a honeycomb base material is disposed in a gap between a double cylinder of an inner cylinder and an outer cylinder,
- the surface of the metal plate-like plate body on the outer wall surface side of the inner cylinder, the surface of each metal zigzag plate body, the surface of each metal plate-like plate body, and the outer cylinder constituting the 820 cam base material A cylindrical steam reformer characterized by comprising a reforming catalyst supported on the surface of a metal flat plate on the inner wall surface side.
- the present invention (2) is a cylindrical steam reformer in which a honeycomb reforming catalyst having a reforming catalyst supported on an 820 cam base material is disposed in a gap between a double cylinder of an inner cylinder and an outer cylinder.
- ferritic stainless steel can be used as the constituent material of the inner cylinder, honeycomb base material and outer cylinder.
- the present invention (3) is a cylindrical steam reformer in which a honeycomb reforming catalyst having a reforming catalyst supported on a honeycomb substrate is disposed in a gap between a double cylinder of an inner cylinder and an outer cylinder,
- a cylindrical steam reformer characterized by comprising a reforming catalyst supported on the surface of a metal flat plate on the inner wall surface side.
- the present invention (4) is a cylindrical steam reformer in which a honeycomb reforming catalyst having a reforming catalyst supported on a honeycomb base material is disposed in a gap between the inner cylinder and the outer cylinder.
- ferritic stainless steel is used as a constituent material of at least the inner cylinder and the honeycomb base material among the inner cylinder, the honeycomb base material, and the outer cylinder.
- ferritic stainless steel or austenitic stainless steel may be used.
- the present invention (5) is a cylindrical steam reformer in which a honeycomb reforming catalyst carrying a reforming catalyst is disposed on a honeycomb substrate disposed in a gap between a double cylinder of an inner cylinder and an outer cylinder.
- the metal plate-like plate body on the outer wall side of the inner cylinder constituting the 82 cam base material A cylinder characterized by supporting a reforming catalyst on the surface of a U-shaped metal corrugated plate and the surface of the metal flat plate on the inner wall surface side of the outer cylinder.
- This is a steam reformer.
- the present invention (6) is a cylindrical steam reformer in which a honeycomb reforming catalyst carrying a reforming catalyst is disposed on a honeycomb substrate disposed in a gap between a double cylinder of an inner cylinder and an outer cylinder.
- the surface of the metal plate-like plate body on the outer wall side of the inner cylinder constituting the 82-cam base material, the surface of the U-shaped metal corrugated plate body on the end cross-section flat bottom, The surface of the metal flat plate body, the end cross-section flat bottom, and the modified catalyst are supported on the surface of the U-shaped metal corrugated plate body and the surface of the metal annual plate plate on the inner wall surface side of the outer cylinder. It is a cylindrical steam reformer characterized by these.
- ferritic stainless steel can be used as a constituent material of the inner cylinder, the honeycomb base material, and the outer cylinder.
- the present invention (7) includes the cylindrical steam reformer according to any one of the present inventions (1) to (6), and an integrated cylindrical hydrogen production having a reforming catalyst layer, a CO shift catalyst layer, and a CO removal catalyst layer This is an integrated cylindrical hydrogen production system built into the system. The invention's effect
- the overall heat transfer coefficient can be improved better than that of the granular reforming catalyst, and 1.3 times that of the granular reforming catalyst.
- the steam reformer can be operated stably over a long period of time without changing the heat balance of the steam reformer.
- Fig. 1 is a diagram (prior art) for explaining a reactor in which a granular reforming catalyst is arranged.
- FIG. 2 is a diagram (prior art) illustrating an embodiment in which a honeycomb reforming catalyst is arranged.
- FIG. 3 is a diagram for explaining the formation process of the unit body and the structure of the unit body in the present invention (1).
- FIG. 4 is a diagram for explaining the formation process of the unit body and the structure of the unit body in the present invention (1).
- FIG. 5 is a diagram for explaining the formation process of the unit body and the structure of the unit body in the present invention (1).
- FIG. 6 is a view for explaining the structure of the honeycomb reforming catalyst of the present invention (1) and a cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 7 is a diagram for explaining the structure of the honeycomb reforming catalyst of the present invention (2) and a cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 8 is a diagram for explaining the formation process of the unit body and the structure of the unit body in the present invention (3).
- FIG. 9 is a diagram for explaining the formation process of the unit body and the structure of the unit body in the present invention (3).
- FIG. 10 is a diagram for explaining the structure of the honeycomb reforming catalyst of the present invention (3) and a cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 11 is a diagram for explaining the structure of the honeycomb reforming catalyst of the present invention (3) and a cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 12 is a view for explaining the structure of the honeycomb reforming catalyst of the present invention (3) and a cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 13 is a diagram for explaining the structure of the honeycomb reforming catalyst of the present invention (4) and a cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 14 is a diagram illustrating an example of an embodiment of an integrated cylindrical hydrogen production apparatus having a CO shift catalyst layer and a CO removal catalyst layer in which the cylindrical steam reformer of the present invention is disposed. Explanation of symbols
- the present invention (1) includes: (a) an inner cylinder, an outer cylinder, and a plurality of metal zigzag shapes such that a metal flat plate is positioned on the inner cylinder outer wall surface and the outer cylinder inner wall surface therebetween.
- a unit body composed of a plate body and a plurality of metal plate-like plate bodies alternately arranged, and (b) an inner cylinder outer wall surface and a metal plate-like plate in the unit body A contact portion between the metal flat plate plate and the metal zigzag plate member, and a contact portion between the metal flat plate plate and the inner wall surface of the outer cylinder.
- a honeycomb base material by brazing with a metal brazing material and (c) the surface of the metal plate-like plate body on the outer surface of the inner cylinder constituting the honeycomb base material, the surface of each metal zigzag plate body
- a unit body comprising: a plurality of metal zigzag plate bodies and a honeycomb substrate in which a plurality of metal flat plate bodies are alternately arranged so that the plate bodies are positioned is formed.
- 3 to 5 are diagrams illustrating the formation process of the unit body and the structure of the unit body.
- Figure 3 (a) shows the inner cylinder 1.
- the metal flat plate 41 is wound around the outer periphery of the metal zigzag plate 42 wound as described above.
- two layers of metal zigzag plates are arranged, and a metal plate plate is arranged on the outer peripheral surface.
- the metal zigzag plate 42 is wound around the outer periphery of the metal flat plate wound as described above. Although not shown, three layers of metal zigzag plates are arranged.
- the outer cylinder 2 is fitted on the outer periphery of the annular laminated body in the state shown in FIG. 5 (c) to form a unit body.
- the appearance is as shown in Fig. 6 (a).
- a unit body in which a plurality of metal flat plate bodies and a plurality of metal zigzag plate bodies are alternately arranged between the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder is obtained.
- the unit body has not undergone the following process (the brazing of the unit body of the present invention (1) with a metal brazing material), but each metal flat plate as shown in Fig. 6 (b) described later.
- the structure has a large number of parallel through-holes, that is, cells 43, between the surface of the plate plate and the surface of each metal zigzag plate (the surface of the cross section ⁇ shape or V shape). Also, since the metal flat plate bodies are arranged on the inner cylinder outer wall surface and the outer cylinder inner wall surface, the number of metal flat plate bodies is one more than the number of metal zigzag plate bodies.
- the “brazing” improves the adhesion at the contact portion, particularly the contact portion between the inner cylindrical outer wall surface and the metal flat plate body, and the contact portion between the metal flat plate member and the outer cylinder inner wall surface.
- heat from the inner cylinder outer wall surface and the outer cylinder inner wall surface can be efficiently transferred.
- brazing with metal brazing material is applied to automobile exhaust gas treatment equipment and the like. However, this is mainly intended to improve the strength of the 82 cam itself.
- Brazing with a metal brazing material is not performed to join the contact portion between the metal zigzag plate body and the contact portion between the metal flat plate body and the outer cylinder inner wall surface.
- the method of brazing with the metal brazing material is not limited.
- the inner wall surface of the inner cylinder and the outer wall surface of the outer cylinder of the unit body, and the upper surface of the inner cylinder and the upper surface of the outer cylinder of the upper surface of the unit body, Sealed and melted metal brazing material can be made by pouring through a large number of cells, ie, parallel through-holes, formed between the metal jig plate and the metal plate plate. .
- the type of the metal brazing material is appropriately selected according to the type of the constituent material of the honeycomb substrate to be used.
- examples thereof include, but are not limited to, a metal brazing material containing Ni as defined in “JISZ 3 2 6 5: 1 9 9 8”.
- reforming catalysts such as Ni catalysts, Ru catalysts, and other metal catalysts. In the present invention, these are appropriately selected and used. Metal catalysts are usually used by supporting them on a support such as alumina. Is done.
- washko is a method of adhering alumina powder or metal compound-supported alumina powder to the surface of each cell in the unit body by immersing the unit body in a slurry and shaking it to wash things. It is.
- Each cell is composed of a metal zigzag plate cross section ⁇ -shaped or V-shaped surface and a metal flat plate plate surface, so that the cross-section is triangular triangle ⁇ or inverted triangle shape ⁇ is there.
- those surfaces constituting the cell are also referred to as “inner surface of the cell”.
- FIG. 6 is a diagram for explaining the structure of the honeycomb reforming catalyst configured as described above and the cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 6 (a) is a perspective view
- FIG. 6 (b) is an enlarged view of a part of the cross section.
- the diameter of the outer circumference of the inner cylinder is about 60 mm
- the diameter of the inner circumference of the outer cylinder is about 75 mm
- the height is about 1550 mm.
- the metal flat plate bodies and the four metal zigzag plate bodies are alternately stacked in an annular shape.
- FIG. 6 (c) is an enlarged view of a part of FIG. 6 (b), and shows a state where the reforming catalyst particles are supported. As shown in FIG. 6 (c), the reforming catalyst particles are supported on the inner surface of the cell composed of each metal flat plate and each metal zigzag plate constituting the honeycomb substrate.
- the diameter of the inner cylinder, the diameter of the outer cylinder, and the height can be appropriately set according to the required amount of hydrogen production.
- the diameter of the outer circumference of the inner cylinder is 40 to 80 mm
- the diameter of the inner circumference of the outer cylinder is 60 to 100 mm
- the height is 100 to 20 It can be appropriately set within a range of 0 mm.
- the number of metal flat plates and metal zigzag plates stacked alternately is 3-7 metal flat plates, 2-6 metal flat plates, and 5-5 total. 1 It can be set appropriately as 3 sheets.
- the metal flat plate bodies are arranged on the inner cylinder outer wall surface side and the outer cylinder inner wall surface side. One more.
- honeycomb reforming catalyst having the structure thus configured and the cylindrical steam reformer having the structure of the honeycomb reforming catalyst are used either vertically or horizontally, but are preferably used vertically.
- When used vertically either (a) introducing a mixed gas of raw fuel and water vapor from the upper end side of the honeycomb reforming catalyst and deriving hydrogen-rich reformed gas from the lower end side, or (b) Eighty cam A mixed gas of raw fuel and steam is introduced from the lower end side of the reforming catalyst, and hydrogen-rich reformed gas is derived from the upper end side.
- the present invention (2) includes (a) an inner cylinder, an outer cylinder, and a metal zigzag on the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder.
- ⁇ Configuration of Unit Body of the Present Invention (2) and its Production> In place of the above-described ⁇ Structure of Unit Body of the Present Invention (1) and Its Production>, first, a metal zigzag plate Wrap the body, then wrap the metal flat plate, then sequentially metal zigzag plate ⁇ metal flat plate ⁇ metal zigzag plate ⁇ Metal plate Alternatively, the unit body may be formed by alternately arranging the outer cylinders in the outermost metal zigzag plate body. This is an embodiment of the unit body of the present invention (2).
- metal zigzag plate bodies are arranged on the inner cylinder outer wall surface and the outer cylinder inner wall surface, so the number of metal zigzag plate bodies is more than the number of metal flat plate bodies. One more.
- the present invention is arranged on the inner cylinder outer wall surface and the outer cylinder inner wall surface, so the number of metal zigzag plate bodies is more than the number of metal flat plate bodies. One more.
- the unit body of (2) is between the outer surface of the inner cylinder and the surface of the metal zigzag plate, between the surface of each metal plate and the surface of each metal zigzag plate,
- the structure has a large number of parallel through-holes or cells between the surface of the plate-like plate and the inner cylinder inner wall surface.
- Each cell has an inner cylinder outer wall surface and a metal zigzag plate cross section ⁇ -shaped or V-shaped surface, a metal zigzag plate cross-section ⁇ -shaped or V-shaped surface and a metal flat plate surface
- the cross section of the metal zigzag plate body is composed of a ⁇ -shaped or V-shaped surface and the inner wall surface of the outer cylinder, so that the cross-section thereof is a triangular shape ⁇ or an inverted triangular shape ⁇ .
- ⁇ Brazing of unit body of the present invention (2) with metal brazing material> in the unit body having such a structure, the contact portion between the outer wall surface of the inner cylinder and the metal zigzag plate, The contact portion with the zigzag plate body made of metal,..., The contact portion between the metal zigzag plate body and the inner wall surface of the outer cylinder is brazed with a metal brazing material to form a honeycomb substrate.
- the method of brazing with the metal brazing material and the type of the metal brazing material are the same as those described in the above ⁇ Brazing with unit metal brazing material of the present invention (1)>.
- ⁇ Supporting of reforming catalyst on honeycomb substrate of the present invention (2)> The inner surface of the cell in the brazed unit configured as described above, that is, the inner wall surface of the inner cylinder, the surface of each metal zigzag plate
- the reforming catalyst is supported on the surface of each metal flat plate body and the inner cylinder inner wall surface.
- the reforming catalyst is also carried on the inner cylinder inner wall surface and the outer cylinder inner wall surface.
- the type of reforming catalyst and the way of supporting the reforming catalyst are the same as in the case of ⁇ Supporting the reforming catalyst on the honeycomb substrate of the present invention (1)>.
- FIG. 7 is a view for explaining the structure of the honeycomb reforming catalyst configured as described above and the cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- FIG. 7 (a) is a perspective view
- FIG. 7 (b) is an enlarged view of a part of the cross section.
- the diameter of the outer circumference of the inner cylinder is about 60 mm
- the diameter of the inner circumference of the outer cylinder is about 75 mm
- the height is about 1550 mm.
- the metal zigzag plate and the four metal flat plates are alternately stacked in an annular shape.
- the contact portion between the outer wall of the inner cylinder and the metal zigzag plate body, the contact portion between each metal zigzag plate body and each metal flat plate body, and the contact between the metal zigzag plate body and the inner wall of the outer cylinder The parts were joined by brazing, and the reforming catalyst was supported on the surface of the outer wall surface of the inner cylinder, the surface of each metal zigzag plate, the surface of each metal plate, and the surface of the inner wall surface of the outer cylinder. It has a structure.
- the structure of the honeycomb reforming catalyst of the present invention (2), the diameter of the inner cylinder, the diameter of the outer cylinder, and the height in the cylindrical steam reformer having the structure of the 820 cam reforming catalyst are the required amount of hydrogen production It can be set appropriately according to the situation.
- the diameter can be appropriately set within a range of 40 to 80 mm of the outer circumference of the inner cylinder, a diameter of 60 to 100 mm of the inner circumference of the outer cylinder and a height of 100 to 200 mm.
- the number of metal zigzag plates and metal flat plates stacked alternately is 3-7 metal zigzag plates, 2-6 metal flat plates, 5-13 in total. It can be set as appropriate.
- the present invention (3) includes: (a) an inner cylinder, an outer cylinder, and an inner cylinder outer wall surface and an outer cylinder inner wall surface between which a metal flat plate A unit body composed of a honeycomb base material in which a plurality of metal zigzag plate bodies and a plurality of metal plate-like plate bodies are alternately arranged so that the plate-like plate bodies are positioned, (b) In the unit body, a contact portion between the outer wall surface of the inner cylinder and the metal flat plate member, and a contact portion between the alternately arranged metal flat plate member and the metal zigzag plate member, a metal brazing material Brazed to make a 802 cam base material, And (C) the surface of the metal flat plate on the outer surface of the inner cylinder, the surface of each metal zigzag plate, the surface of each metal flat plate, This is a cylindrical steam reformer in which a reforming catalyst is supported on the surface of a metal flat plate on
- the part to be brazed with the metal brazing material is a contact portion between the inner cylindrical outer wall surface and the metal flat plate member in the unit body, and the metal flat plate plates arranged alternately.
- a contact portion between the body and the metal zigzag plate body, and a contact portion between the metal flat plate body and the inner wall surface of the outer cylinder, and the honeycomb base material is configured by brazing these portions.
- the unit body includes a contact portion between the inner cylindrical outer wall surface and the metal flat plate body.
- the contact portions between the alternately arranged metal flat plate bodies and metal zigzag plate bodies are brazed with a metal brazing material to form a honeycomb substrate.
- the portions to be brazed with the metal brazing material are alternately arranged with the contact portions between the inner cylindrical outer wall surface and the metal flat plate body in the unit body.
- the contact portion between the metal flat plate and the inner cylinder wall is not brazed.
- austenitic stainless steel is used as the constituent material of the inner and outer cylinders. is doing.
- ferritic stainless steel can be used as the constituent material of the inner cylinder and the outer cylinder as in the honeycomb base material.
- different materials such as austenitic stainless steel and ferritic stainless steel have different coefficients of thermal expansion, so the degree of expansion and contraction differs when the cylindrical steam reformer starts and stops.
- such problems can be avoided by using the same material as the 82-cam base material for the inner cylinder and outer cylinder.
- the temperature of the outer cylinder far from the heating part (burner) may be lower than that of the inner cylinder and the honeycomb base material.
- the contact portion between the plate-shaped plate and the inner cylinder wall surface is not brazed and is kept free to avoid such problems due to temperature differences.
- the contact portion between the outermost metal flat plate and the inner wall surface of the outer cylinder is not brazed, and the two members are left free so that the constituent material of the honeycomb substrate and the outer cylinder
- the constituent material of the honeycomb base material for example, ferritic stainless steel.
- the present invention (4) includes (a) an inner cylinder, an outer cylinder, and a metal zigzag on the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder therebetween.
- a unit body consisting of a plurality of metal zigzag plate bodies and a honeycomb substrate in which a plurality of metal flat plate bodies are alternately arranged so that the plate-like plate bodies are located, and (b) In the unit body, a contact portion between the outer wall surface of the inner cylinder and the metal zigzag plate member, and a contact portion between the alternately arranged metal zigzag plate member and the metal flat plate member are made of metal.
- (C) a surface of the outer wall surface of the inner cylinder, a surface of each metal zigzag plate body constituting the honeycomb base material, and a metal base material constituting the honeycomb base material.
- This is a cylindrical steam reformer in which a reforming catalyst is supported on the surface of a flat plate body and the surface of the inner cylinder inner wall surface.
- the portion to be brazed with the metal brazing material as in the configuration (b)
- the part to be brazed with the metal brazing material is intersected with the contact portion between the outer wall surface of the inner cylinder and the metal zigzag plate body in the unit body.
- the contact part of the metal zigzag plate body and metal flat plate body which are mutually arrange
- the contact part between the metal zigzag plate and the inner cylinder wall is not brazed.
- the present invention (5) includes: (a) an inner cylinder, an outer cylinder, a metal flat plate, and a flat U-shaped end section between them. And a unit body composed of a metal corrugated plate body and a metal flat plate body in this order, and (b) among the unit bodies,
- This is a cylindrical steam reformer that has a reforming catalyst supported on the surface of a metal flat plate, a U-shaped metal corrugated plate, and a metal flat plate. is there.
- FIGS. 8 to 12 are diagrams for explaining the formation process of the unit body and the structure of the unit body.
- FIGS. 10 to 12 are diagrams for explaining the structure of the honeycomb reforming catalyst of the present invention (5) and the cylindrical steam reformer having the structure of the honeycomb reforming catalyst.
- Figure 8 (a) shows the inner cylinder 1.
- FIG. 10 (a) is a perspective view
- FIG. 10 (b) is a cross-sectional view taken along line AA in FIG. 10 (a).
- the upper and lower surfaces in Fig. 10 (a) have the same structure as the AA line cross section.
- the honeycomb substrate in which the inner cylinder, the outer cylinder, the metal flat plate body, the U-shaped metal corrugated plate body, and the metal flat plate body in this order are arranged in this order.
- a metal flat plate, a U-shaped metal corrugated plate and a metal flat plate arranged in this order are configured as an eighty cam base,
- the unit is a combination of the cylinder, outer cylinder, and honeycomb substrate.
- FIG. 11 is a diagram illustrating the structure of the unit body, and is also a diagram illustrating the structure of the honeycomb reforming catalyst of the present invention (5) and the cylindrical steam reformer having the structure of the honeycomb reforming catalyst. .
- Fig. 11 (a) is an enlarged view of the part surrounded by frame B in Fig. 10 (b), and Fig. 11 (b)
- FIG. 11 (c) is an enlarged view of a portion surrounded by a frame C in FIG. 10 (b).
- FIG. 11 (c) is a diagram showing an “end-shaped flat bottom U-shaped metal corrugated plate”.
- Figure 11 (b) is a slightly enlarged view compared to Figure 11 (a).
- a metal flat plate 51 is disposed on the outer periphery of the inner cylinder 1
- a U-shaped metal corrugated plate 52 is disposed on the outer periphery
- a metal is disposed on the outer periphery.
- a flat plate 53 is disposed, and an outer cylinder is disposed on the outer periphery of the metal flat plate 53 to form a unit body.
- the unit body includes a plurality of parallel through-holes between the metal flat plate body 51, the end cross-sectional flat bottom U-shaped metal corrugated plate body 52, and the metal flat plate body 53. In other words, it has a structure with cell 55.
- the corrugated plate 52 made of metal with a flat bottom U-shaped section is bent at the end on the inner cylinder side into a U-shaped cross section, and the end on the outer cylinder side
- the U-shaped metal corrugated plate 52 having a flat bottom has an end on the inner cylinder side and an end on the outer cylinder side. Both are constructed in a U-shape, but as shown in Fig. 11 (c), the bottom of the U-shape is flat as shown as "flat bottom” in Fig. 11 (c). And it has a curved part on both sides of the plane. That is, it is essential that the corrugated metal plate having a U-shaped cross-section has a flat bottom, that is, a flat bottom. In this specification, “cross-sectional flat bottom U-shaped” means this.
- the cross-section flat bottom U-shaped part at the end on the inner cylinder side, the cross-section flat bottom U-shaped part at the end on the outer cylinder side, and the plate part between them is shown as a wave plate-like plate body.
- the outer wall surface of the flat bottom at the end on the inner cylinder side is in contact with the metal flat plate member on the inner cylinder side
- the outer wall surface of the flat bottom at the end on the outer cylinder side is the outer cylinder. It has a structure in contact with the metal flat plate on the side.
- the thickness of the metal flat plate 51 may be the same as or different from the thickness of the corrugated metal plate 52 having a U-shaped cross-section. Also, the contact portion between the outer wall surface of the inner cylinder and the U-shaped metal corrugated plate body with the flat bottom of the end section, the contact portion of the U-shaped metal corrugated plate body with the flat bottom of the end section, The contact part may be brazed with a metal brazing material, but brazing is not essential.
- FIG. 12 is a diagram for explaining the supported state of the reforming catalyst particles.
- the reforming catalyst particles are made of a metal flat plate, a U-shaped metal corrugated plate, and a metal flat plate constituting the 820-cam base material. It is carried on the inner surface of each constructed cell 54. That is, the reforming catalyst particles constitute the inner surface of each cell, the surface of the metal flat plate, the surface of the U-shaped metal corrugated plate with the flat bottom of the end, the metal flat plate It is carried on the surface of the body.
- the overall structure of the honeycomb reforming catalyst configured as described above and the cylindrical steam reformer having the honeycomb reforming catalyst structure are as shown in FIG.
- the diameter of the outer circumference of the inner cylinder is about 60 mm
- the diameter of the inner circumference of the outer cylinder is about 75 mm
- the height is about 150 mm.
- a metal plate-like plate body, an end-section flat bottom U-shaped metal corrugated plate-like plate body, and a metal flat plate-like plate body are arranged in this order.
- the reforming catalyst is supported on the surface of the two metal flat plate bodies and the surface of the one end corrugated flat U-shaped metal corrugated plate body.
- the diameter of the inner cylinder, the diameter of the outer cylinder, and the height thereof are set to the required amount of hydrogen production. It can be set as appropriate.
- the diameter can be appropriately set within a range of 40 to 80 mm of the outer circumference of the inner cylinder, a diameter of 60 to 100 mm of the inner circumference of the outer cylinder, and a height of 100 to 200 mm.
- the heat from the inner cylinder and the outer cylinder is efficiently improved via the contact portion between the plate-like plate body and the metal flat plate body, and the contact portion between the metal plate-like plate body and the inner wall surface of the outer cylinder. Can tell.
- the present invention (6) includes: (a) an inner cylinder, an outer cylinder, a metal flat plate, and a flat bottom U-shaped end section.
- a metal flat plate body, an end cross-section flat bottom U-shaped metal corrugated plate body, a metal flat plate body, an end cross section A flat-bottom U-shaped corrugated metal plate and a metal flat plate are arranged in this order to form a honeycomb substrate. Then, the honeycomb substrate is arranged between the inner cylinder and the outer cylinder to form a unit body.
- FIG. 13 is a diagram for explaining the structure of the honeycomb reforming catalyst of the present invention (6) and a cylindrical steam reformer having the structure of the honeycomb reforming catalyst, and a cross section corresponding to FIG. 10 (b). It is shown as a diagram. As shown in FIG. 13, between the inner cylinder 1 and the outer cylinder 2, a metal flat plate 51 from the inner cylinder 1 side, and a corrugated metal plate 52 with a U-shaped end cross section, flat bottom, and A metal flat plate member 53, an end cross-sectional flat bottom U-shaped metal corrugated plate member 52, and a metal flat plate member 51 are disposed.
- the present invention (5) uses one (one) corrugated metal plate having a U-shaped end cross section
- the present invention (6) Is different in that it uses two (two) corrugated metal plates with a U-shaped end cross-section, with one metal plate 53 added between them.
- the points other than this point are the same as those described in the section of the aspect of the present invention (5).
- ferritic stainless steel used as a constituent material for the inner cylinder, outer cylinder, and 820 cam base examples include (1) to (6) below, but are not limited thereto.
- C r 19 to 21% (mass%, the same shall apply hereinafter), A1: 4.5 to 6.0%, C: 0.15% or less, Si: 1.00% or less, Mn : 1.0% or less, P: 0.0040% or less, S: 0.030% or less, T i: ⁇ 0.10%, balance: Fe. (20C r-5A 1).
- Cr 11.50 to: 14.50%, C: 0.08% or less, Si: 1.00% or less, Mn: 1.00% or less, P: 0.040% or less, S: 0.040% or less, A1: 0.10-0.30%, balance: Fe. (SUS405)
- the cylindrical steam reformers of 1) to (6) include a plurality of circular cylinders composed of a first cylinder, a second cylinder, and a third cylinder having large diameters arranged concentrically at intervals.
- a radial cylinder that is arranged coaxially with the inside of the first cylinder, a burner that is arranged at a central portion in the radial direction of the radiation cylinder, and a first cylinder and a second cylinder.
- a reforming catalyst layer filled with a reforming catalyst is provided in the gap, and a CO shift catalyst layer and a CO removal catalyst layer are provided in the gap between the second cylinder and the third cylinder, which are the outer periphery of the reforming catalyst layer.
- the CO conversion catalyst layer is formed in a gap in which the flow direction is reversed at one end in the axial direction with the reforming catalyst layer. That is preferably applied as a reforming catalyst layer.
- the integrated cylindrical hydrogen production apparatus described below is an example, but the cylindrical steam reformers of the present invention (1) to (6) include a reforming catalyst layer, a CO shift catalyst layer, and a C0 removal catalyst layer. It can be applied to any integrated cylindrical hydrogen production apparatus. Further, the integrated cylindrical hydrogen production apparatus to which the cylindrical steam reformer according to the present invention (1) to (6) is applied is suitably applied to supply hydrogen as a fuel for a polymer electrolyte fuel cell.
- FIG. 14 shows an example of the vertical sectional view.
- the first cylindrical body 1, the second cylindrical body 2, and the third cylindrical body 3 with the diameters increased sequentially are arranged with the same central axis and spaced apart from each other.
- a fourth cylinder 4 having a diameter larger than that of the third cylinder 3 is disposed at the top.
- the alternate long and short dash line indicates the central axis, and the arrow indicates the direction of the central axis, that is, the axial direction.
- a cylindrical heat transfer partition wall having a diameter smaller than that of the first cylindrical body 1, that is, the radiation cylinder 5, is disposed, and in the radiation cylinder 5, a burner 6 is disposed. ing.
- the burner 6 is arranged at the central shaft, and the upper lid / burner is placed inside the radiation tube 5. It is attached via one mount 7.
- the first cylinder 1 corresponds to the inner cylinder 1 in the cylindrical steam reformer of the present invention (1) to (6)
- the second cylinder 2 is the cylinder of the present invention (1) to (6).
- the radiation tube 5 is arranged with a gap between its lower end and the bottom plate 8 of the first cylindrical body 1, and this gap and the gap between the radiation tube 5 and the first cylindrical body 1 are connected to this gap.
- An exhaust passage 9 for combustion exhaust gas from the burner 6 is formed.
- the bottom plate 8 has a disk shape with a diameter corresponding to the diameter of the first cylindrical body 1.
- the upper part of the exhaust passage 9 passes through the gap between the upper cover of the exhaust passage 9 (the lower surface of the upper lid and burner mounting base 7) and the partition wall 10 (the upper cover of the preheating layer 14 described later) to the exhaust gas exhaust outlet 11.
- the combustion exhaust gas is discharged from here.
- Reference numeral 1 2 denotes a hydrocarbon-based raw fuel (fuel before reforming), that is, a raw material gas supply pipe.
- a preheating layer 14 is provided in the upper part, and a reforming catalyst layer 16 is provided in the lower part following the preheating layer 14.
- a single round bar 15 is spirally arranged inside the preheating layer 14, thereby forming one continuous spiral gas passage inside the preheating layer 14.
- the reforming catalyst of the reforming catalyst layer 16 is supported at its lower end by a support 17 such as a perforated plate or a mesh body.
- the raw material gas supplied from the supply pipe 1 2 is mixed with water (steam) in the mixing section 1 3 and then introduced into the reforming catalyst layer 1 6 through the preheating layer 1 4 and carbonized in the mixed gas.
- the hydrogen-based raw fuel is reformed by steam while descending.
- the reforming reaction in the reforming catalyst layer 16 is an endothermic reaction, and the reforming reaction proceeds by absorbing the combustion heat generated in the burner 6. That is, when the combustion gas in the burner 6 flows through the exhaust passage 9 between the radiation cylinder 5 and the first cylindrical body 1 and passes through, the heat of the combustion gas is absorbed by the reforming catalyst layer 16 and reformed. The reaction proceeds.
- the lower end of the second cylindrical body 2 is arranged with a space between the bottom plate 18 of the third cylindrical body 3, and the flow path of the reformed gas is between the second cylindrical body 2 and the third cylindrical body 3. Consists of 1-9.
- the bottom plate 18 is formed in a disk shape with a diameter corresponding to the diameter of the third cylindrical body 3.
- the reformed gas is folded between the lower end of the second cylinder 2 and the bottom plate 18 of the third cylinder 3, and is formed between the second cylinder 2 and the third cylinder 3 19.
- a fourth cylinder 4 having a diameter larger than that of the third cylinder 3 is disposed above the third cylinder 3, and a CO shift catalyst layer 22 is provided between the second cylinder 2 and the fourth cylinder 4. It is.
- the upper end portion of the third cylindrical body 3 and the lower end portion of the fourth cylindrical body 4 have a plate body 20 (the portion corresponding to the diameter of the third cylindrical body 3 is occupied by the third cylindrical body 3,
- the support plate 2 1 having a plurality of holes for gas flow at intervals on the plate body 20 (the portion corresponding to the diameter of the second cylinder 2 is the second cylinder 2).
- Donut-shaped support plate is arranged.
- the CO shift catalyst layer 2 2 is composed of a support plate 2 1 and a support plate 2 3 having a plurality of holes for gas circulation (the portion corresponding to the diameter of the second cylindrical body 2 is occupied by the second cylindrical body 2 so that it has a donut shape.
- the support plate and the upper cover of the CO conversion catalyst layer 22 are provided.
- the support plates 21 and 23 may be made of a mesh body made of metal or the like, and in this case, the mesh of the mesh body serves as a gas flow hole.
- the reformed gas that has flowed through the flow path 19 is supplied to the CO conversion catalyst layer 22 through the holes of the support plate 21.
- the CO shift catalyst layer 22 is provided between the second cylindrical body 2 and the fourth cylindrical body 4.
- the cylindrical body 25 is spaced apart from the outer periphery of the fourth cylindrical body 4. Arranged, and insulation material 24 is arranged between them.
- a heat transfer tube 27 connected from the water supply tube 26 is directly wound around the outer periphery of the cylindrical body 25.
- the heat transfer tube 27 acts as a cooling mechanism for indirectly cooling the CO shift catalyst layer 22.
- CO in the reformed gas is converted to carbon dioxide by the CO conversion reaction, and hydrogen is also generated.
- the heat insulating material 24 is wound to a thickness that can be uniformly maintained at an appropriate temperature without causing the temperature of the CO conversion catalyst layer 22 2 to be excessively lowered by the cooling action of the heat transfer tube 27.
- a partition plate 28 having one communication hole 29 is provided above the support plate 23 at a predetermined interval. CO removal air is supplied to the space between both plates through an air supply pipe 30. Is done. Divider
- An annular passage 31 is provided above 28.
- the CO removal catalyst layer 36 is disposed with a space between the second cylinder 2, the cylinder 37 having a larger diameter, and the lower and upper portions between the second cylinder 2 and the cylinder 37.
- the support plate 3 4 having a plurality of holes 3 5 (the portion corresponding to the diameter of the second cylindrical body 2 is occupied by the second cylindrical body 2, and a donut-shaped plate body), and for gas distribution
- a support plate 3 8 having a plurality of holes 3 9 (a portion corresponding to the diameter of the second cylindrical body 2 is occupied by the second cylindrical body 2), and is provided in a space between It has been.
- the annular passage 31 is a passage formed by the cylindrical body 25, the partition plate 28, the partition plate 32, and the cylindrical body 37, and includes a plurality of holes 33 and a plurality of support plates 34.
- the CO gas removal catalyst layer 3 6 communicates with the CO removal catalyst layer 3 6 through the individual holes 3 5, and the reformed gas mixed with the CO removal air passes through the plurality of holes 3 3 and 3 5. Introduced in 6.
- the C0 removal catalyst layer 36 communicates with the reformed gas take-out pipe 40 through a gap between the partition plate 38 having a plurality of holes 39 serving as an upper lid and the partition wall 10.
- the C0 removal catalyst layer 3 6 is surrounded by a cylindrical body 3 7.
- a heat transfer tube 27 connected from the heat transfer tube 27 on the outer periphery of the cylinder 25 is directly spiraled.
- the reformed gas from which the CO has been removed is discharged from a plurality of holes 39 provided in the partition plate 38 which is the upper lid, and the reformed gas is taken out through the gap between the partition plate 38 and the partition wall 10. Taken from tube 40.
- a heat insulating material 41 is disposed on the outer peripheral portion including the third cylindrical body 3, the cylindrical body 25, and the cylindrical body 37 to prevent the heat from radiating to the outside.
- the reforming catalyst section is configured by filling the gap between the first cylindrical body 1, that is, the inner cylinder and the second cylindrical body 2, that is, the outer cylinder, with the reforming catalyst.
- the integrated cylindrical hydrogen production apparatus of the present invention (7) includes the reforming catalyst section in the integrated cylindrical hydrogen production apparatus having the reforming catalyst layer, the CO shift catalyst layer, and the C0 removal catalyst layer. It is comprised by incorporating the cylindrical steam reformer of this invention (1)-(6).
- a cylindrical steam reformer with a granular reforming catalyst as shown in Fig. 1 a cylindrical steam reformer with a conventional honeycomb reforming catalyst as shown in Fig. 2, and as shown in Fig. 6
- Table 1 shows the test conditions and results.
- Comparative Example 1 shows the case of a cylindrical steam reformer with a granular reforming catalyst
- Comparative Example 2 shows the case of a cylindrical steam reformer with a conventional honeycomb reforming catalyst
- Metal of the present invention Examples 1 and 2 are cylindrical steam reformers in which a honeycomb reforming catalyst composed of a zigzag plate body made of metal and a flat plate body made of metal is arranged.
- Example 2 is a cylindrical steam reformer having the same configuration as that of the cylindrical steam reformer of Example 1, but having different inner and outer diameters and height direction dimensions of the honeycomb reforming catalyst.
- Ru metal was used as the reforming catalyst
- alumina was used as the support.
- the cylindrical steam reformer of Comparative Example 1 was fabricated as shown in Fig. 1 (a) using a granular reforming catalyst having an average particle diameter (diameter) of 3 mm.
- a cylindrical water steam reformer using the conventional honeycomb reforming catalyst of Comparative Example 2 was manufactured as shown in FIG.
- the cylindrical steam reformers using the honeycomb reforming catalysts of Examples 1 and 2 were produced as shown in FIGS.
- the heat transfer area is the area of the outer surface of the inner cylinder in both Comparative Examples 1-2 and Examples 1-2. Heat transfer is also performed from the inner wall of the outer cylinder, but since the heat transfer from the outer wall of the inner cylinder is the main, this performance test uses the area of the outer wall of the inner cylinder as a guide.
- the volume of the reforming catalyst is the volume between the outer wall surface of the inner cylinder and the inner wall surface of the outer cylinder where the reforming catalyst is arranged in both Comparative Examples 1-2 and Examples 1-2.
- No. 1 and No. 2 of Comparative Example 1, No. 1 and No. 2 of Comparative Example 2, and N 0.1 and No. 2 of Example 1 are cylindrical steam reforming. This is an example in which the scale of the equipment is the same, but each was operated under different conditions with different raw material 13 A flow rates and S / C ratios.
- City gas (1 3 A) is desulfurized and used as the hydrocarbon-based raw fuel, and the reforming catalyst inlet and outlet of the cylindrical steam reformers of Comparative Examples 1-2 and 1-2 are used respectively.
- a temperature sensor was set and the temperature during operation was measured. JI
- the heat transfer area and reforming catalyst volume in No. 3 of Comparative Example 1 are almost the same as the heat transfer area and reforming catalyst volume of No. 1 and No. 2 in Example 2.
- the CH 4 conversion in No. 3 of Example 1 is the same as that of Example 2: No. It is much lower than the CH 4 conversion of ⁇ 2. This is considered to be due to the fact that the amount of heat transfer is reduced due to the film resistance because of the granular catalyst.
- the heat transfer area and the reforming catalyst volume in Example 2 are smaller than the heat transfer area and the reforming catalyst volume in Example 1, but the CH 4 conversion rate in Example 2 also conforms to the CH 4 conversion rate in Example 1. 4 shows the conversion rate. This indicates that the cylindrical steam reformer in which the honeycomb reforming catalyst of the present invention is arranged has little influence on the amount of heat transfer due to the scale of the apparatus.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020107017472A KR101245910B1 (ko) | 2008-01-08 | 2008-12-26 | 원통식 수증기 개질기 |
CA2711433A CA2711433C (en) | 2008-01-08 | 2008-12-26 | Cylindrical steam reformer |
JP2009548897A JP5443173B2 (ja) | 2008-01-08 | 2008-12-26 | 円筒式水蒸気改質器 |
AU2008345826A AU2008345826B2 (en) | 2008-01-08 | 2008-12-26 | Cylindrical steam reformer |
EP08869752A EP2230209A4 (en) | 2008-01-08 | 2008-12-26 | CYLINDRICAL STEAM REFORMER |
US12/735,066 US20100254864A1 (en) | 2008-01-08 | 2008-12-26 | Cylindrical steam reformer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008-001720 | 2008-01-08 | ||
JP2008001720 | 2008-01-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009087955A1 true WO2009087955A1 (ja) | 2009-07-16 |
Family
ID=40853070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/073984 WO2009087955A1 (ja) | 2008-01-08 | 2008-12-26 | 円筒式水蒸気改質器 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20100254864A1 (ja) |
EP (2) | EP2230209A4 (ja) |
JP (2) | JP5443173B2 (ja) |
KR (1) | KR101245910B1 (ja) |
AU (1) | AU2008345826B2 (ja) |
CA (2) | CA2792173C (ja) |
WO (1) | WO2009087955A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015517175A (ja) * | 2012-03-08 | 2015-06-18 | ヘルビオ ソシエテ アノニム ハイドロジェン アンド エナジー プロダクション システムズ | 燃料電池のための触媒を支持する置換可能な構造化支持部を含む触媒加熱式燃料処理装置 |
JP2021169092A (ja) * | 2015-07-24 | 2021-10-28 | ヌヴェラ・フュエル・セルズ,エルエルシー | 同心管の触媒反応器アセンブリを製造する方法 |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009087955A1 (ja) | 2008-01-08 | 2009-07-16 | Tokyo Gas Company Limited | 円筒式水蒸気改質器 |
GB201105691D0 (en) * | 2011-04-04 | 2011-05-18 | Davy Process Techn Ltd | Apparatus |
DE102011107669B4 (de) * | 2011-07-12 | 2022-02-10 | Eberspächer Climate Control Systems GmbH & Co. KG | Kraftstoffbehandlungsvorrichtung |
WO2022100899A1 (en) | 2020-11-13 | 2022-05-19 | Technip France | A process for producing a hydrogen-comprising product gas from a hydrocarbon |
EP4105170A1 (en) | 2021-06-18 | 2022-12-21 | Technip Energies France | Process and plant for flexible production of syngas from hydrocarbons |
PL4279446T3 (pl) | 2022-05-17 | 2024-08-26 | Technip Energies France | Instalacja i proces produkcji wodoru z węglowodorów |
PL4279445T3 (pl) | 2022-05-17 | 2024-08-19 | Technip Energies France | Instalacja i proces produkcji i separacji gazu syntezowego |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000063114A1 (fr) | 1999-04-20 | 2000-10-26 | Tokyo Gas Co., Ltd. | Reformeur cylindrique monotube et procede pour faire fonctionner ledit reformeur |
WO2001047800A1 (fr) * | 1999-12-28 | 2001-07-05 | Daikin Industries,Ltd. | Dispositif de modification par oxydation partielle |
JP2002187705A (ja) | 2000-10-10 | 2002-07-05 | Tokyo Gas Co Ltd | 単管円筒式改質器 |
WO2002098790A1 (fr) | 2001-06-04 | 2002-12-12 | Tokyo Gas Company Limited | Unite de reformage a vapeur d'eau cylindrique |
JP2004175580A (ja) * | 2002-11-22 | 2004-06-24 | Toyo Radiator Co Ltd | 水蒸気改質装置 |
JP2005169319A (ja) * | 2003-12-12 | 2005-06-30 | Mikuni Corp | 触媒担持体及び触媒コンバータ |
JP2005193135A (ja) | 2004-01-06 | 2005-07-21 | Tokyo Gas Co Ltd | 触媒反応装置 |
JP2006219334A (ja) * | 2005-02-10 | 2006-08-24 | Kinzo Ri | 水素生成装置 |
JP2006232611A (ja) | 2005-02-24 | 2006-09-07 | Tokyo Gas Co Ltd | 炭化水素系燃料の水蒸気改質器 |
JP2007112667A (ja) | 2005-10-20 | 2007-05-10 | Tokyo Gas Co Ltd | 水蒸気改質器 |
JP2007523042A (ja) * | 2004-02-17 | 2007-08-16 | モーディーン・マニュファクチャリング・カンパニー | 分散型水素生産のための一体型燃料処理装置 |
JP2008247727A (ja) * | 2007-03-29 | 2008-10-16 | Samsung Sdi Co Ltd | 反応容器および反応装置 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5346675A (en) * | 1988-12-16 | 1994-09-13 | Usui Kokusai Sangyo Kabushiki Kaisha | Exhaust gas cleaning apparatus |
JPH0380939A (ja) * | 1989-08-23 | 1991-04-05 | Toyota Motor Corp | 排気ガス浄化触媒用金属担体の製造方法 |
JPH08131839A (ja) * | 1994-11-14 | 1996-05-28 | Showa Aircraft Ind Co Ltd | 電気加熱式触媒装置用メタル担体 |
JPH10296090A (ja) * | 1997-04-25 | 1998-11-10 | Nippon Steel Corp | 金属製触媒コンバータおよびその製造方法 |
JP4305973B2 (ja) * | 1997-07-23 | 2009-07-29 | トヨタ自動車株式会社 | 燃料改質装置 |
JP4644892B2 (ja) * | 1999-12-16 | 2011-03-09 | ダイキン工業株式会社 | 改質装置 |
JP3668885B2 (ja) * | 2000-04-13 | 2005-07-06 | 日本冶金工業株式会社 | 自己発熱可能なメタルハニカム構造体 |
US20030044331A1 (en) * | 2001-08-31 | 2003-03-06 | Mcdermott Technology, Inc. | Annular heat exchanging reactor system |
JP2005306658A (ja) * | 2004-04-21 | 2005-11-04 | Matsushita Electric Ind Co Ltd | 水素生成装置 |
US7566487B2 (en) * | 2004-07-07 | 2009-07-28 | Jonathan Jay Feinstein | Reactor with primary and secondary channels |
US7501102B2 (en) * | 2005-07-28 | 2009-03-10 | Catacel Corp. | Reactor having improved heat transfer |
JP5038648B2 (ja) * | 2006-03-31 | 2012-10-03 | 株式会社神戸製鋼所 | メタノール水蒸気改質触媒およびその製造方法 |
WO2009087955A1 (ja) | 2008-01-08 | 2009-07-16 | Tokyo Gas Company Limited | 円筒式水蒸気改質器 |
-
2008
- 2008-12-26 WO PCT/JP2008/073984 patent/WO2009087955A1/ja active Application Filing
- 2008-12-26 KR KR1020107017472A patent/KR101245910B1/ko not_active IP Right Cessation
- 2008-12-26 EP EP08869752A patent/EP2230209A4/en not_active Withdrawn
- 2008-12-26 EP EP13005248.3A patent/EP2695854A1/en not_active Withdrawn
- 2008-12-26 AU AU2008345826A patent/AU2008345826B2/en not_active Ceased
- 2008-12-26 JP JP2009548897A patent/JP5443173B2/ja active Active
- 2008-12-26 CA CA2792173A patent/CA2792173C/en not_active Expired - Fee Related
- 2008-12-26 US US12/735,066 patent/US20100254864A1/en not_active Abandoned
- 2008-12-26 CA CA2711433A patent/CA2711433C/en not_active Expired - Fee Related
-
2013
- 2013-07-12 JP JP2013147112A patent/JP2013212988A/ja active Pending
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000063114A1 (fr) | 1999-04-20 | 2000-10-26 | Tokyo Gas Co., Ltd. | Reformeur cylindrique monotube et procede pour faire fonctionner ledit reformeur |
WO2001047800A1 (fr) * | 1999-12-28 | 2001-07-05 | Daikin Industries,Ltd. | Dispositif de modification par oxydation partielle |
JP2002187705A (ja) | 2000-10-10 | 2002-07-05 | Tokyo Gas Co Ltd | 単管円筒式改質器 |
WO2002098790A1 (fr) | 2001-06-04 | 2002-12-12 | Tokyo Gas Company Limited | Unite de reformage a vapeur d'eau cylindrique |
JP2004175580A (ja) * | 2002-11-22 | 2004-06-24 | Toyo Radiator Co Ltd | 水蒸気改質装置 |
JP2005169319A (ja) * | 2003-12-12 | 2005-06-30 | Mikuni Corp | 触媒担持体及び触媒コンバータ |
JP2005193135A (ja) | 2004-01-06 | 2005-07-21 | Tokyo Gas Co Ltd | 触媒反応装置 |
JP2007523042A (ja) * | 2004-02-17 | 2007-08-16 | モーディーン・マニュファクチャリング・カンパニー | 分散型水素生産のための一体型燃料処理装置 |
JP2006219334A (ja) * | 2005-02-10 | 2006-08-24 | Kinzo Ri | 水素生成装置 |
JP2006232611A (ja) | 2005-02-24 | 2006-09-07 | Tokyo Gas Co Ltd | 炭化水素系燃料の水蒸気改質器 |
JP2007112667A (ja) | 2005-10-20 | 2007-05-10 | Tokyo Gas Co Ltd | 水蒸気改質器 |
JP2008247727A (ja) * | 2007-03-29 | 2008-10-16 | Samsung Sdi Co Ltd | 反応容器および反応装置 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2230209A4 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015517175A (ja) * | 2012-03-08 | 2015-06-18 | ヘルビオ ソシエテ アノニム ハイドロジェン アンド エナジー プロダクション システムズ | 燃料電池のための触媒を支持する置換可能な構造化支持部を含む触媒加熱式燃料処理装置 |
JP2021169092A (ja) * | 2015-07-24 | 2021-10-28 | ヌヴェラ・フュエル・セルズ,エルエルシー | 同心管の触媒反応器アセンブリを製造する方法 |
Also Published As
Publication number | Publication date |
---|---|
CA2792173C (en) | 2014-04-08 |
AU2008345826A1 (en) | 2009-07-16 |
CA2792173A1 (en) | 2009-07-16 |
KR20100112608A (ko) | 2010-10-19 |
EP2695854A1 (en) | 2014-02-12 |
AU2008345826B2 (en) | 2013-07-18 |
JP2013212988A (ja) | 2013-10-17 |
CA2711433A1 (en) | 2009-07-16 |
EP2230209A4 (en) | 2012-07-18 |
CA2711433C (en) | 2014-02-25 |
KR101245910B1 (ko) | 2013-03-20 |
JPWO2009087955A1 (ja) | 2011-05-26 |
JP5443173B2 (ja) | 2014-03-19 |
US20100254864A1 (en) | 2010-10-07 |
EP2230209A1 (en) | 2010-09-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5443173B2 (ja) | 円筒式水蒸気改質器 | |
US11253831B2 (en) | Catalytically heated fuel processor with replaceable structured supports bearing catalyst for fuel cell | |
CA2396191C (en) | Catalytic reactor | |
US20050072048A1 (en) | Compact light weight autothermal reformer assembly | |
JP4762496B2 (ja) | 触媒反応装置 | |
CN115532201A (zh) | 增强型微通道或中通道装置及其增材制造方法 | |
EP1977822B1 (en) | Reaction vessel and reaction device | |
JP3313766B2 (ja) | 水蒸気改質用薄膜状触媒 | |
KR20060078943A (ko) | 금속모노리스 촉매를 이용한 컴팩트형 수증기개질구조촉매 및 이를 이용한 수소의 제조방법 | |
JP5329944B2 (ja) | 燃料電池用水蒸気改質装置 | |
JP5351527B2 (ja) | 燃料電池用円筒型水蒸気改質器 | |
JPH0867502A (ja) | 燃料改質装置 | |
AU2013203724A1 (en) | Cylindrical steam reformer | |
EP1321185A1 (en) | Steam reforming reactor | |
JP3675946B2 (ja) | 燃料電池用の燃料改質器 | |
WO2024154754A1 (ja) | メタネーション反応装置及びメタネーション反応方法 | |
JPH06287003A (ja) | 燃料改質装置 | |
JPH05305229A (ja) | 改質装置 | |
JPH0329723B2 (ja) | ||
JP2008222501A (ja) | Co選択酸化方法及びco選択酸化反応器 | |
KR20120056069A (ko) | 메탈폼층을 구비하는 연료전지용 배기가스 연소기 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08869752 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2009548897 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12735066 Country of ref document: US Ref document number: 2008869752 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2711433 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008345826 Country of ref document: AU |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2008345826 Country of ref document: AU Date of ref document: 20081226 Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 20107017472 Country of ref document: KR Kind code of ref document: A |