WO2008114550A1 - 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 - Google Patents

低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 Download PDF

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WO2008114550A1
WO2008114550A1 PCT/JP2008/052284 JP2008052284W WO2008114550A1 WO 2008114550 A1 WO2008114550 A1 WO 2008114550A1 JP 2008052284 W JP2008052284 W JP 2008052284W WO 2008114550 A1 WO2008114550 A1 WO 2008114550A1
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catalyst
zeolite
formation rate
aromatization
molybdenum
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PCT/JP2008/052284
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English (en)
French (fr)
Inventor
Shinichi Yamada
Tomohiro Yamada
Yuji Ogawa
Hirokazu Akiyama
Takuya Hatagishi
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Meidensha Corporation
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Priority claimed from JP2007293011A external-priority patent/JP5568834B2/ja
Priority claimed from JP2007293010A external-priority patent/JP5568833B2/ja
Application filed by Meidensha Corporation filed Critical Meidensha Corporation
Priority to EP08711142A priority Critical patent/EP2116301A4/en
Priority to US12/524,029 priority patent/US8278237B2/en
Priority to CN2008800049557A priority patent/CN101652177B/zh
Publication of WO2008114550A1 publication Critical patent/WO2008114550A1/ja

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    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68—Aromatisation of hydrocarbon oil fractions
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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Abstract

　メタン転化率、ベンゼン生成速度、ナフタレン生成速度及びベンゼンとトルエンとキシレンの合計生成速度の活性寿命安定性を向上させる低級炭化水素芳香族化触媒は、担体であるメタロシリケートにモリブデンと銅を担持した後に焼成してなる。芳香族化合物を製造する際に前記触媒を低級炭化水素と炭酸ガスとを含む反応ガスと反応させる。前記触媒を得るにあたり、メタロシリケートからなるゼオライトを、前記ゼオライトの細孔口径よりも大きな分子径であると共に前記ゼオライトのブレーンステッド酸点に選択的に反応するアミノ基と直鎖炭化水素基を有するシラン化合物で修飾処理した後に、モリブデンと銅を担持させるとよい。前記モリブデンはその担持量が焼成後の触媒全体量に対して２～１２重量％となると共に前記銅はモリブデンとのモル比Ｃｕ：Ｍｏ＝Ｘ：１の比率が０．０１～０．８となるように担持するとよい。
PCT/JP2008/052284 2007-03-20 2008-02-13 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 WO2008114550A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP08711142A EP2116301A4 (en) 2007-03-20 2008-02-13 CATALYST FOR AROMATISING LOW CARBON DIOXIDES AND METHOD FOR PRODUCING AROMATIC COMPOUNDS
US12/524,029 US8278237B2 (en) 2007-03-20 2008-02-13 Catalyst for aromatization of lower hydrocarbons and process for production of aromatic compounds
CN2008800049557A CN101652177B (zh) 2007-03-20 2008-02-13 低级烃的芳构化催化剂及芳族化合物的制备方法

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2007-073470 2007-03-20
JP2007073470 2007-03-20
JP2007-293010 2007-11-12
JP2007-293011 2007-11-12
JP2007293011A JP5568834B2 (ja) 2007-03-20 2007-11-12 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法
JP2007293010A JP5568833B2 (ja) 2007-11-12 2007-11-12 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法

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US (1) US8278237B2 (ja)
EP (1) EP2116301A4 (ja)
CN (1) CN101652177B (ja)
WO (1) WO2008114550A1 (ja)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009004843A1 (ja) * 2007-06-29 2009-01-08 Meidensha Corporation 低級炭化水素の芳香族化触媒、芳香族化合物の製造方法
US20110124935A1 (en) * 2008-07-29 2011-05-26 Meidensha Corporation Process for producing aromatic compound
JP5577587B2 (ja) * 2008-11-25 2014-08-27 株式会社明電舎 低級炭化水素芳香族化触媒の製造方法及び低級炭化水素芳香族化触媒
EA024080B1 (ru) 2009-10-08 2016-08-31 Басф Се Способ получения связанного с кремнием псевдоожиженного катализатора, получаемый им гранулированный псевдоожиженный катализатор, его применение для неокислительной дегидроароматизации c-c-алифатических соединений и способ неокислительной дегидроароматизации c-c-алифатических соединений
CN102746095B (zh) * 2011-04-20 2015-04-08 中国石油化工股份有限公司 苯和甲醇或二甲醚制石油级甲苯的方法
RU2515511C1 (ru) * 2012-12-25 2014-05-10 ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) Способ приготовления катализатора для получения ароматических углеводородов, катализатор, приготовленный по этому способу, и способ получения ароматических углеводородов с использованием полученного катализатора
WO2014191874A1 (en) * 2013-05-28 2014-12-04 Saudi Basic Industries Corporation Promoted molybdenum catalyst composition for production of aromatics from methane
WO2015054212A1 (en) 2013-10-08 2015-04-16 Saudi Basic Industries Corporation Integrated process for converting methane to aromatics and other chemicals
CN104557423B (zh) * 2013-10-21 2017-05-03 北京化工大学 一种甲烷直接转化制芳烃的方法
KR101985861B1 (ko) 2017-08-21 2019-06-04 서울대학교산학협력단 메탄 및 프로판 공동 반응물의 직접 탈수소방향족화 반응을 위한 중형기공성 hzsm-11에 담지된 금속 산화물 촉매의 제조 방법 및 상기 촉매를 이용한 btx 제조 방법
JP7066999B2 (ja) * 2017-08-24 2022-05-16 コニカミノルタ株式会社 定着装置、画像形成装置、および定着装置の設計方法
US11254882B2 (en) 2018-02-21 2022-02-22 Exxonmobil Chemical Patents Inc. Conversion of C2 hydrocarbons in the presence of methane
CN110882721A (zh) * 2018-09-10 2020-03-17 国家能源投资集团有限责任公司 芳构化催化剂及其制备方法和应用
KR102295224B1 (ko) 2019-10-17 2021-08-27 한국화학연구원 메탄의 탈수소방향족화 반응용 촉매 및 이을 이용한 방향족화 화합물의 제조방법

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07826A (ja) * 1993-02-24 1995-01-06 Inst Fr Petrole ハロゲン、貴金属及び少なくとも一つの追加金属を包む複合触媒、及び炭素原子数２〜１２の炭化水素の芳香族化にその触媒を使用する方法
JPH1024237A (ja) * 1996-07-10 1998-01-27 Idemitsu Kosan Co Ltd 排ガス浄化用触媒の製造方法
JPH10128123A (ja) * 1996-11-01 1998-05-19 Nissan Motor Co Ltd 排気ガス浄化用触媒及びその製造方法
JPH10272366A (ja) 1997-03-19 1998-10-13 Osaka Sekiyu Kagaku Kk 低級炭化水素の芳香族化触媒及び該触媒を用いた芳香族化合物の製造方法
JPH1160514A (ja) 1997-08-21 1999-03-02 Osaka Sekiyu Kagaku Kk 低級炭化水素を原料とする芳香族化合物の製造方法
JP2002336704A (ja) * 2001-05-18 2002-11-26 Masaru Ichikawa メタンの芳香族化反応触媒およびその調製方法
JP2004269398A (ja) 2003-03-07 2004-09-30 Masaru Ichikawa 低級炭化水素の芳香族化触媒反応方法および芳香族化触媒反応装置ならびに芳香族化合物および水素の製造方法
JP2007014894A (ja) 2005-07-08 2007-01-25 Masaru Ichikawa 低級炭化水素の芳香族化触媒とその製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4100262A (en) * 1977-08-15 1978-07-11 Mobil Oil Corporation Synthesis of zeolite ZSM-5
GB8309585D0 (en) * 1983-04-08 1983-05-11 British Petroleum Co Plc Catalyst composition
US6051520A (en) 1998-05-19 2000-04-18 Phillips Petroleum Company Hydrotreating catalyst composition and processes therefor and therewith
WO2009004843A1 (ja) 2007-06-29 2009-01-08 Meidensha Corporation 低級炭化水素の芳香族化触媒、芳香族化合物の製造方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07826A (ja) * 1993-02-24 1995-01-06 Inst Fr Petrole ハロゲン、貴金属及び少なくとも一つの追加金属を包む複合触媒、及び炭素原子数２〜１２の炭化水素の芳香族化にその触媒を使用する方法
JPH1024237A (ja) * 1996-07-10 1998-01-27 Idemitsu Kosan Co Ltd 排ガス浄化用触媒の製造方法
JPH10128123A (ja) * 1996-11-01 1998-05-19 Nissan Motor Co Ltd 排気ガス浄化用触媒及びその製造方法
JPH10272366A (ja) 1997-03-19 1998-10-13 Osaka Sekiyu Kagaku Kk 低級炭化水素の芳香族化触媒及び該触媒を用いた芳香族化合物の製造方法
JPH1160514A (ja) 1997-08-21 1999-03-02 Osaka Sekiyu Kagaku Kk 低級炭化水素を原料とする芳香族化合物の製造方法
JP2002336704A (ja) * 2001-05-18 2002-11-26 Masaru Ichikawa メタンの芳香族化反応触媒およびその調製方法
JP2004269398A (ja) 2003-03-07 2004-09-30 Masaru Ichikawa 低級炭化水素の芳香族化触媒反応方法および芳香族化触媒反応装置ならびに芳香族化合物および水素の製造方法
JP2007014894A (ja) 2005-07-08 2007-01-25 Masaru Ichikawa 低級炭化水素の芳香族化触媒とその製造方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
JOURNAL OF CATALYSIS, vol. 165, 1997, pages 150 - 161
QI S. ET AL.: "Methane aromatization using Mo-based catalysts prepared by microwave heating", CATALYSIS TODAY, ELSEVIER B.V., vol. 98, no. 4, 14 December 2004 (2004-12-14), pages 639 - 645, XP004657597 *
See also references of EP2116301A4

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