WO2008093684A1 - 誘電体磁器およびコンデンサ - Google Patents

誘電体磁器およびコンデンサ Download PDF

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Publication number
WO2008093684A1
WO2008093684A1 PCT/JP2008/051323 JP2008051323W WO2008093684A1 WO 2008093684 A1 WO2008093684 A1 WO 2008093684A1 JP 2008051323 W JP2008051323 W JP 2008051323W WO 2008093684 A1 WO2008093684 A1 WO 2008093684A1
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WO
WIPO (PCT)
Prior art keywords
dielectric ceramic
crystal grains
barium titanate
capacitor
terms
Prior art date
Application number
PCT/JP2008/051323
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English (en)
French (fr)
Inventor
Katsuyoshi Yamaguchi
Original Assignee
Kyocera Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyocera Corporation filed Critical Kyocera Corporation
Priority to CN200880003384.5A priority Critical patent/CN101595074B/zh
Priority to JP2008556117A priority patent/JP5069695B2/ja
Publication of WO2008093684A1 publication Critical patent/WO2008093684A1/ja
Priority to US12/510,975 priority patent/US7968486B2/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00—Fixed capacitors; Processes of their manufacture
    • H01G4/002—Details
    • H01G4/018—Dielectrics
    • H01G4/06—Solid dielectrics
    • H01G4/08—Inorganic dielectrics
    • H01G4/12—Ceramic dielectrics
    • H01G4/1209—Ceramic dielectrics characterised by the ceramic dielectric material
    • H01G4/1218—Ceramic dielectrics characterised by the ceramic dielectric material based on titanium oxides or titanates
    • H01G4/1227—Ceramic dielectrics characterised by the ceramic dielectric material based on titanium oxides or titanates based on alkaline earth titanates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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    • C04B35/4682—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates based on BaTiO3 perovskite phase
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Abstract

　チタン酸バリウムを主成分とする結晶粒子と、該結晶粒子間に形成された粒界相とを有する誘電体磁器であって、前記チタン酸バリウムを構成するバリウム１モルに対してマグネシウム、イットリウム、マンガンを酸化物換算で所定の割合で含有するとともに、チタン酸バリウム１００質量部に対してイッテルビウムを酸化物換算で所定の割合で含有し、結晶粒子の平均粒径が０．０５～０．２μｍである。また、上記誘電体磁器を誘電体層として適用することにより、高容量かつ容量温度特性の安定なコンデンサを形成できる。  
PCT/JP2008/051323 2007-01-29 2008-01-29 誘電体磁器およびコンデンサ WO2008093684A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN200880003384.5A CN101595074B (zh) 2007-01-29 2008-01-29 电介体瓷器及电容器
JP2008556117A JP5069695B2 (ja) 2007-01-29 2008-01-29 誘電体磁器およびコンデンサ
US12/510,975 US7968486B2 (en) 2007-01-29 2009-07-28 Dielectric ceramics and capacitor

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP2007-017860 2007-01-29
JP2007017860 2007-01-29
JP2007-055095 2007-03-06
JP2007055095 2007-03-06
JP2007072662 2007-03-20
JP2007-072663 2007-03-20
JP2007-072662 2007-03-20
JP2007072663 2007-03-20

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/510,975 Continuation-In-Part US7968486B2 (en) 2007-01-29 2009-07-28 Dielectric ceramics and capacitor

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WO2008093684A1 true WO2008093684A1 (ja) 2008-08-07

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PCT/JP2008/051323 WO2008093684A1 (ja) 2007-01-29 2008-01-29 誘電体磁器およびコンデンサ

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US (1) US7968486B2 (ja)
JP (1) JP5069695B2 (ja)
CN (1) CN101595074B (ja)
TW (1) TWI399767B (ja)
WO (1) WO2008093684A1 (ja)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2008114619A1 (ja) * 2007-03-16 2010-07-01 京セラ株式会社 誘電体磁器およびコンデンサ
JP2011029583A (ja) * 2009-06-25 2011-02-10 Kyocera Corp 積層セラミックコンデンサ
JP2011046560A (ja) * 2009-08-27 2011-03-10 Kyocera Corp 誘電体磁器およびコンデンサ
JP2011068524A (ja) * 2009-09-28 2011-04-07 Kyocera Corp 積層セラミックコンデンサ
JP2011114171A (ja) * 2009-11-27 2011-06-09 Kyocera Corp 積層セラミックコンデンサ
JP2011178632A (ja) * 2010-03-03 2011-09-15 Murata Mfg Co Ltd 誘電体セラミックおよび積層セラミックコンデンサ
JP2013067563A (ja) * 2013-01-09 2013-04-18 Murata Mfg Co Ltd 誘電体セラミックおよび積層セラミックコンデンサ
JP2019085278A (ja) * 2017-11-01 2019-06-06 サムソン エレクトロ−メカニックス カンパニーリミテッド． 誘電体磁器組成物、キャパシタ、及び、多層積層セラミックキャパシタ

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5025570B2 (ja) * 2008-04-24 2012-09-12 京セラ株式会社 積層セラミックコンデンサ
JP4877367B2 (ja) * 2009-07-22 2012-02-15 株式会社村田製作所 誘電体セラミックおよび積層セラミックコンデンサ
KR101070095B1 (ko) * 2009-12-10 2011-10-04 삼성전기주식회사 적층 세라믹 커패시터 및 그 제조방법
KR20110072938A (ko) * 2009-12-23 2011-06-29 삼성전기주식회사 적층 세라믹 커패시터 및 그 제조방법
JP5146852B2 (ja) * 2010-03-05 2013-02-20 株式会社村田製作所 積層セラミックコンデンサ
KR101792268B1 (ko) * 2012-03-13 2017-11-01 삼성전기주식회사 적층 세라믹 전자 부품
JP6137147B2 (ja) * 2014-11-28 2017-05-31 株式会社村田製作所 積層セラミックコンデンサ及び積層セラミックコンデンサの製造方法
JP6707850B2 (ja) * 2015-12-11 2020-06-10 株式会社村田製作所 積層セラミックコンデンサおよびその製造方法
CN110066172B (zh) * 2019-05-31 2021-09-03 太原师范学院 一种正温度系数陶瓷介质材料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62256422A (ja) * 1986-04-29 1987-11-09 京セラ株式会社 積層型磁器コンデンサ
JPS63103861A (ja) * 1986-10-21 1988-05-09 京セラ株式会社 非還元性誘電体磁器組成物
JPH11322414A (ja) * 1998-05-12 1999-11-24 Murata Mfg Co Ltd 誘電体磁器組成物および積層セラミックコンデンサ
JP2004210604A (ja) * 2003-01-06 2004-07-29 Murata Mfg Co Ltd 誘電体セラミック、及び積層セラミックコンデンサ

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61111957A (ja) 1984-11-02 1986-05-30 堺化学工業株式会社 セラミック誘電体の製造方法
JP3878778B2 (ja) 1999-07-21 2007-02-07 Ｔｄｋ株式会社 誘電体磁器組成物および電子部品
JP3642282B2 (ja) 2000-02-09 2005-04-27 松下電器産業株式会社 誘電体磁器組成物とこれを用いた積層セラミックコンデンサ
JP2004203626A (ja) 2002-10-29 2004-07-22 Kyocera Corp 誘電体組成物
JP3874278B2 (ja) * 2002-12-25 2007-01-31 Ｔｄｋ株式会社 誘電体磁器組成物、電子部品およびこれらの製造方法
JP2005289737A (ja) * 2004-03-31 2005-10-20 National Institute Of Advanced Industrial & Technology チタン酸バリウム微粒子及びその製造方法
JP5089870B2 (ja) 2004-08-27 2012-12-05 昭和電工株式会社 チタン酸バリウムカルシウムおよびその製造方法ならびにコンデンサ
US8052954B2 (en) 2004-08-27 2011-11-08 Showa Denko K.K. Barium calcium titanate, production process thereof and capacitor
JP4789449B2 (ja) * 2004-10-27 2011-10-12 京セラ株式会社 誘電体磁器およびそれを用いた積層セラミックコンデンサ
JP4937522B2 (ja) * 2005-04-04 2012-05-23 Ｔｄｋ株式会社 電子部品、誘電体磁器組成物およびその製造方法
TW200927698A (en) * 2007-09-28 2009-07-01 Tdk Corp Dielectric ceramic composition and electronic device
JP5025570B2 (ja) * 2008-04-24 2012-09-12 京セラ株式会社 積層セラミックコンデンサ

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62256422A (ja) * 1986-04-29 1987-11-09 京セラ株式会社 積層型磁器コンデンサ
JPS63103861A (ja) * 1986-10-21 1988-05-09 京セラ株式会社 非還元性誘電体磁器組成物
JPH11322414A (ja) * 1998-05-12 1999-11-24 Murata Mfg Co Ltd 誘電体磁器組成物および積層セラミックコンデンサ
JP2004210604A (ja) * 2003-01-06 2004-07-29 Murata Mfg Co Ltd 誘電体セラミック、及び積層セラミックコンデンサ

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2008114619A1 (ja) * 2007-03-16 2010-07-01 京セラ株式会社 誘電体磁器およびコンデンサ
JP5185924B2 (ja) * 2007-03-16 2013-04-17 京セラ株式会社 誘電体磁器およびコンデンサ
JP2011029583A (ja) * 2009-06-25 2011-02-10 Kyocera Corp 積層セラミックコンデンサ
JP2011046560A (ja) * 2009-08-27 2011-03-10 Kyocera Corp 誘電体磁器およびコンデンサ
JP2011068524A (ja) * 2009-09-28 2011-04-07 Kyocera Corp 積層セラミックコンデンサ
JP2011114171A (ja) * 2009-11-27 2011-06-09 Kyocera Corp 積層セラミックコンデンサ
JP2011178632A (ja) * 2010-03-03 2011-09-15 Murata Mfg Co Ltd 誘電体セラミックおよび積層セラミックコンデンサ
US8404607B2 (en) 2010-03-03 2013-03-26 Murata Manufacturing Co., Ltd. Dielectric ceramic and laminated ceramic capacitor
KR101366632B1 (ko) * 2010-03-03 2014-02-25 가부시키가이샤 무라타 세이사쿠쇼 유전체 세라믹 및 적층 세라믹 콘덴서
JP2013067563A (ja) * 2013-01-09 2013-04-18 Murata Mfg Co Ltd 誘電体セラミックおよび積層セラミックコンデンサ
JP2019085278A (ja) * 2017-11-01 2019-06-06 サムソン エレクトロ−メカニックス カンパニーリミテッド． 誘電体磁器組成物、キャパシタ、及び、多層積層セラミックキャパシタ
JP7005852B2 (ja) 2017-11-01 2022-01-24 サムソン エレクトロ－メカニックス カンパニーリミテッド． 誘電体磁器組成物、キャパシタ、及び、多層積層セラミックキャパシタ

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