WO2008046831A1 - Wässrige dispersionen gefällter kieselsäuren und silikate zur steigerung der frühfestigkeit in zementartigen zubereitungen - Google Patents
Wässrige dispersionen gefällter kieselsäuren und silikate zur steigerung der frühfestigkeit in zementartigen zubereitungen Download PDFInfo
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- WO2008046831A1 WO2008046831A1 PCT/EP2007/061039 EP2007061039W WO2008046831A1 WO 2008046831 A1 WO2008046831 A1 WO 2008046831A1 EP 2007061039 W EP2007061039 W EP 2007061039W WO 2008046831 A1 WO2008046831 A1 WO 2008046831A1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
- C04B14/062—Microsilica, e.g. colloïdal silica
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
Definitions
- the invention relates to a dispersion based on silica and a flow agent, and their use as concrete admixtures.
- cementitious preparations Two essential criteria for the use of cementitious preparations are, on the one hand, their ability to be conveyed to the place of processing and, on the other hand, the duration to which this preparation attains a strength which permits further processing or processing. This duration is also described in the literature as early strength and is to be understood in the context of the present text as the strength of a cementitious preparation after ⁇ 48 h of cement hydration.
- conveyance can be influenced by the addition of so-called flow agents (cf .. EP-A 214 412, DE-PS 16 71 017, US 5,707,445 Bl, EP 1 110 981 A2, EP 1 142 847 A2).
- flow agents cf .. EP-A 214 412, DE-PS 16 71 017, US 5,707,445 Bl, EP 1 110 981 A2, EP 1 142 847 A2).
- WO02 / 070429 discloses a composite material containing inorganic aggregates, ultrafine particles, a cementitious binder and a concrete plasticizer.
- the composite material allows the production of a highly liquefied concrete in which no bleeding occurs.
- ultrafine particles become mainly Silica fume particles have a strong filler effect in cement or concrete compositions but are less reactive due to their low specific surface area.
- Alumina, fly ash, pozzolans, calcium carbonate, alumina, barium sulfate and titanium dioxide can be used as further particles of this size.
- the stated particles have the disadvantage that they have too low nucleation rates of the strength-forming phases and thus lead to low early strengths.
- the proportion of the ultrafine particles based on the total amount of the composite material, is 1 to 30% by weight or about 10 to 25% by weight in the exemplary embodiments, based on the sum of cement and ultrafine particles.
- the required proportion of ultrafine particles is very high.
- US6752866 there is disclosed a method of improving early strength by adding an aqueous dispersion containing a mineral filler and a specific dispersant to cement.
- Calcium carbonate, barium carbonate, limestone, dolomite, talc, silica, titanium dioxide, kieselguhr, iron oxide, manganese oxide, lime, kaolin, clay, mica, gypsum, fly ash, slag, calcium sulfate, zeolites, basalt, barium sulfate or aluminum trihydroxide can be used as mineral fillers.
- calcium carbonate is used.
- the disclosed mean particle diameter of the mineral fillers used are in the range of about 2 to about 10 microns.
- WO01 / 90024 discloses a concrete composition containing aggregates, a hydraulic binder, silica sol and a polycarboxylate.
- the BET surface area of the silica sol is preferably 300 to 900 m 2 / g.
- Silica sols are single particles with a diameter of 3 to 50 nm and only in dispersion resistant.
- WO01 / 90024 nothing is disclosed about the influence of the described silica sol on the early strength.
- silica sol concentrations in which a significant increase in the early strength is achieved, the processability is also significantly reduced, so that high amounts of flow agent are necessary. It is believed that this is because silica sols dissolve rapidly in the highly alkaline cement or concrete compositions. The silica sols are therefore available only to a small extent as a germ for the formation of the strength-forming calcium silicate hydrate phases available.
- the patent US 6761867 calls dispersions having a mean particle size d 5 o of less than 5 microns.
- the state of the art shows that there is a keen interest in developing concrete compositions which have a high early strength combined with good processability, without having to use large amounts of fluid.
- the prior art further shows that the currently available superplasticizers and particles in the cement or concrete composition constitute a sensitive system. For example, the order of addition and the concentration of starting materials have a decisive influence on the processability and early strength of the concrete.
- the object of the invention is therefore to provide a concrete additive and a process for its preparation, with which the disadvantages of the prior art can be minimized.
- the concrete admixture should significantly increase the early strength of concretes with good processability.
- the invention relates to dispersions, a process for their preparation and their use as defined and described in the claims, the description and the examples of the present application.
- At least one precipitated silica and / or a silicate has a BET surface area greater than 50 m 2 / g
- the aggregates and / or agglomerates of the precipitated silica and / or silicate in the dispersion have a mean diameter of less than 1 micron
- Another object of the invention is a process for the preparation of the dispersion according to the invention, in which
- the mixing in of the dispersion can in this case take place under very low shear energy, for example by means of a propeller stirrer.
- Another object of the invention is the use of the dispersion of the invention as concrete admixture.
- Another object of the invention is a cementitious preparation containing the dispersion of the invention.
- the proportion of silicon dioxide in the cementitious preparation is preferably from 0.01 to ⁇ 2% by weight, based on the cement.
- the novel dispersions are distinguished by the fact that the early strength of concrete is improved.
- the dispersions of the invention combine silica and plasticizers in a single composition, eliminating mixing during the concrete preparation, resulting in a simplified and accelerated concrete formulation. Furthermore, this reduces the number of possible different sequences of addition in the production of concrete preparations, which leads to a simplification of the process and to a reduction of error sources.
- the dispersions according to the invention have good storage stability. Without being bound to any particular theory, this very positive effect is due to a stabilizing interaction of the silica particles with the flow aid. In particular, the good storage stability allows the commercial use of the dispersions in the first place.
- the use of the dispersions of the invention has the advantage of significantly better handling in comparison to the separate use of silica powders and flow agents. Compared to powder products, the freedom from dust is improved and the dosage is simplified. Furthermore, an improvement in the early strength of concrete was found by the dispersions of the invention compared to the use of the same powdered silica and the same superplasticizer, each separately.
- Silica and silica particles the same substance. These include precipitated silicas and / or
- Understood silicates Particular preference is given to precipitated silicas.
- Precipitated silica may have BET surface areas up to 800 m 2 / g and is obtained by reacting at least one silicate, preferably an alkali and / or alkaline earth silicate, with at least one acidifier, preferably at least one mineral acid.
- precipitated silicas do not consist of a uniform three-dimensional SiO 2 network but of individual ones Aggregates and agglomerates.
- a particular feature of precipitated silica is the high level of so-called internal surface, which is reflected in a very porous structure with micro- and mesopores.
- Precipitated silicas differ from pyrogenic ones
- Pyrogenic silicic acids are obtained by flame hydrolysis of silicon tetrachloride. Due to the completely different manufacturing process, fumed silicas have, inter alia, a different surface finish than precipitated silicas. This expresses z. In the lower number of silanol groups on the surface. The behavior of pyrogenic silicic acids and precipitated silicic acids and thus also their behavior in aqueous dispersions is mainly determined by the surface properties. Therefore, these can not be compared. Precipitated silicic acid white compared to Among other things, the advantage of pyrogenic silicic acids is that they are considerably less expensive.
- Silica sols are to be understood as meaning particles according to Winnacker, Kuchler, 5th ed., Vol. 3, p. 868.
- the particles of the inventive silicic acid dispersions are secondary particles, ie aggregated primary particles.
- the dispersions according to the invention are preferably aqueous dispersions, ie, at least one constituent, particularly preferably the main constituent, of the liquid phase is water, preferably deionized water.
- dispersions according to the invention in the liquid phase additionally comprise at least one flow aid.
- the dispersions according to the invention otherwise contain no further liquid additives, especially those which prevent the sedimentation of the silica particles.
- binders are inorganic substances, such as cement, or organic substances to understand, which are processable in the plastic state, and harden in the course of a period of time birnir and thereby connect other substances together.
- dispersions of the invention are preferably free of inorganic dispersants and mechanical stabilizers, such as e.g. Latex.
- the dispersion of the invention contains the precipitated silica as a single solid. This may be particularly useful if the dispersion is to serve as a masterbatch for various applications.
- the BET surface area of the silica present in the dispersion according to the invention is preferably in the range from 50 to 800 m 2 / g, preferably 50 to 500 m 2 g, particularly preferably in the range from 100 to 400 m 2 / g. and most preferably in the range of 150-250 m 2 / g.
- the BET surface area of the silica present in the dispersion according to the invention is in the case of a silicate is in the range of 50-800 m 2 / g, more preferably in the range of 50-500 m 2 / g, most preferably in the range of 50-290 m 2 / g, particularly preferably in the range of 70-250 m 2 / g, and especially preferably 70-150 m 2 / g.
- the BET surface area is based on the total surface area formed by the silicas.
- the BET is preferably in the range of in the range of 50-800 m 2 / g, more preferably 50-500 m 2 g, most preferably in the range of 70-500 m 2 / g, and most preferably in the range of 70-250 m 2 / g.
- the average diameter d 5 o of the aggregates and / or agglomerates in the dispersion from 50 to 900 nm is from 50 to 750 nm, from 100 to 500 nm and from 150 to 350 nm. Values below 50 nm are technically difficult to implement and have no advantages in the application.
- the storage stability of the dispersions according to the invention is markedly improved. At the same time, this results in a greater number of individual particles being present in the same amount by weight of silica, so that more germs are available for forming the strength-forming calcium silicate hydrate phases and thus the early strength of concrete preparations is further improved.
- the proportion of precipitated silica in the dispersion of the invention is 5 to 50 wt .-%, based on the total amount of the dispersion.
- Dispersions according to the invention which have a silicon dioxide content of from 10 to 50% by weight, preferably from 20 to 40% by weight, particularly preferably from 20 to 35% by weight and very particularly preferably from 25 to 35% by weight usually better stability than higher filled dispersions. Dispersions containing less than 5% by weight of silica are not economical due to the high water content.
- the dispersions according to the invention preferably have a pH of from 8 to 12, preferably from 8.5 to 10, more preferably from 8.8 to 10 and especially preferably from 9 to 10. It has been found that the pH of the dispersions should not be too low.
- the pH of the dispersions according to the invention has a particular stabilizing effect on the sedimentation properties of the dispersion.
- the dispersion according to the invention contains at least one flow agent.
- Suitable flow agents may be: lignosulfonate, sulfonated naphthalene-formaldehyde polycondensates (cf EP0214412), sulfonated melamine-formaldehyde polycondensates (cf., DE1671017) and polycarboxylate ethers (cf., US5707445, EP1110981, EP1142847).
- the weight ratio of flow agent / silicon dioxide in the dispersion according to the invention is from 0.01 to 100. This ratio may preferably be from 0.01 to 50, particularly preferably from 0.05 to 20, very particularly preferably from 0.01 to 10, in particular 0.05. 5, more preferably 0.1 to 1 and most preferably 0.1 to 0.5.
- the dispersion of the invention may contain a copolymer having the components a), b), c), preferably with the components a), b), c), and d).
- the proportion of the assembly a) is 51 to 95 mol%, the assembly b) 1 to 48.9 mol%, the assembly c) 0.1 to 5 mol% and the assembly d) 0 to 47, 9 mol%.
- the first component a) represents a mono- or dicarboxylic acid derivative having the general formula Ia, Ib or Ic.
- R 1 is hydrogen or an aliphatic hydrocarbon radical having 1 to 20 carbon atoms, preferably a methyl group.
- X in the structures Ia and Ib stands for - OM a and / or - O - (C m H 2m O) n -R 2 or -NH- (C m H 2m O) n -R 2 with the following meaning for M , a, m, n and R 2 :
- M is hydrogen, a mono- or di-valent
- Organic amine radicals are preferably substituted ammonium groups which derive from primary, secondary or tertiary Ci- 2 o ⁇ alkylamines, Ci 2 o ⁇ alkanolamines, C5 - 8 - cycloalkylamines and Cs 14 -Arylaminen.
- Examples of the corresponding amines are methylamine, dimethylamine, trimethylamine, ethanolamine, diethanolamine, triethanolamine, methyldiethanolamine, cyclohexylamine, dicyclohexylamine, phenylamine, diphenylamine in the protonated (ammonium) form.
- the aliphatic hydrocarbons may hereby be linear or branched and saturated or unsaturated.
- Preferred cycloalkyl radicals are cyclopentyl or cyclohexyl radicals, and the preferred aryl radicals are phenyl or naphthyl radicals, which may in particular be substituted by hydroxyl, carboxyl or sulfonic acid groups.
- the second module b) corresponds to formula II
- R 3 represents hydrogen or an aliphatic hydrocarbon radical having 1 to 5 C atoms, which may also be linear or branched or unsaturated, p may assume values between 0 and 3.
- m 2 and / or 3, so that they are polyalkylene oxide groups which are derived from polyethylene oxide and / or polypropylene oxide.
- p in formula II is 0 or 1, d. H. they are vinyl and / or alkyl polyalkoxylates.
- the third assembly c) corresponds to the formula IHa or IHb
- R 4 can be H or CH 3 , depending on whether it is acrylic or methacrylic acid derivatives.
- S can be -H, -COOM a or -COOR 5 , where a and M have the abovementioned meaning and R 5 is an aliphatic hydrocarbon radical having 3 to 20 C atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 C atoms or Aryl radical having 6 to 14 carbon atoms can be.
- the aliphatic hydrocarbon radical may also be linear or branched, saturated or unsaturated.
- the preferred cycloaliphatic hydrocarbon radicals are in turn cyclopentyl or cyclohexyl radicals and the preferred aryl radicals phenyl or naphthyl radicals.
- T -COOR 5
- S COOM a or -COOR 5 .
- the assemblies c) may have other hydrophobic structural elements. These include the polypropylene oxide or polypropylene oxide-polyethylene oxide derivative with
- T - U 1 - (CH - CH 2 - O) x - (CH 2 - CH 2 - O) y - R 6
- x assumes a value of 1 to 150 and y of 0 to 15.
- the polypropylene oxide (polyethylene oxide) derivatives may hereby be linked via a grouping U 1 to the ethyl radical of the group c) corresponding to formula IUa, where U 1 is -CO-NH-, -O- or -CH 2 -O- can.
- U 1 is -CO-NH-, -O- or -CH 2 -O- can.
- R 6 here again can be R (meaning of R see above) or
- the polydimethylsiloxane grouping can not only be bonded directly to the ethylene radical according to formula IUa, but also via the groupings
- R 7 can also still
- the fourth group d) is derived from an unsaturated dicarboxylic acid derivative of the general formula
- IVa and / or IVb as defined above for a, M, X and Y.
- the copolymers preferably contain 55 to 75 mol% of the structural groups of the formula Ia and / or Ib, 19.5 to 39.5 mol% Structural groups of the formula II, 0.5 to 2 mol% of structural groups of the formula IIIa and / or IIIb and 5 to 20 mol% of structural groups of the formula IVa and / or IVb.
- the copolymers according to the invention additionally contain up to 50 mol%, in particular up to 20 mol% based on the sum of the components a to d, structures based on monomers based on vinyl or (meth) acrylic acid -Derivaten such as styrene, methyl styrene, vinyl acetate, vinyl propionate, ethylene, propylene, isobutene, hydroxyalkyl (meth) acrylates, acrylamide, methacrylamide, N-vinylpyrrolidone, allylsulfonic acid, Methallylsulfonklare, vinylsulfonic acid, vinylphosphonic acid, AMPS, methyl methacrylate, methyl acrylate, butyl acrylate, allylhexyl acrylate, inter alia based.
- acrylic acid -Derivaten such as styrene, methyl styrene, vinyl acetate, vinyl propionate, ethylene, propylene
- the number of repeating structural units in the copolymers is not limited. However, it has proven to be particularly advantageous to set average molecular weights of from 1,000 to 100,000 g / mol.
- the preparation of the copolymers can be carried out in various ways. It is essential here that 51 to 95 mol% of an unsaturated mono- or dicarboxylic acid derivative, 1 to 48.9 mol% of an oxyalkylene-alkenyl ether, 0.1 to 5
- the unsaturated mono- or dicarboxylic acid derivatives which form the structural groups of the formulas Ia, Ib or Ic are preferably used: acrylic acid, methacrylic acid, itaconic acid, itaconic anhydride, itaconic acid imide and itaconic acid monoamide.
- acrylic acid methacrylic acid, itaconic acid and itaconic monoamide can also their mono- or divalent Metal salts, preferably sodium, potassium, calcium or ammonium salts are used.
- the preferred substituents on the aryl radical are -OH, -COO- or -SU 3 groups.
- the unsaturated monocarboxylic acid derivatives can only be present as monoesters, while diester derivatives are also possible in the case of the dicarboxylic acid itaconic acid.
- the derivatives of the formulas Ia, Ib and Ic can also be present as a mixture of esterified and free acids and are used in an amount of preferably 55 to 75 mol%.
- the second component for the preparation of the copolymers of the invention is an oxyalkylene glycol alkenyl ether, which is preferably used in an amount of 19.5 to 39.5 mol%.
- oxyalkylene glycol alkenyl ethers corresponding to the formula V
- a third component for introducing the assembly c) is preferably 0.5 to 2 mol% of a vinylic polyalkylene glycol, polysiloxane or ester compound used.
- a vinylic polyalkylene glycol compound derivatives corresponding to formula VI are used,
- R 6 can either be R 1 again or
- R 6 R 2 and R 2 preferably H is the polypropylene glycol (-Polyethylenglykol) -Monamide or
- R 6 ⁇ R 2 are bifunctional vinyl compounds whose polypropylene glycol (polyethylene glycol) derivatives via amide or ether groups (-O- or -OCH 2 -) are interconnected.
- examples of such compounds are polypropylene glycol bismaleamic acid, polypropylene glycol diacrylamide, polypropylene glycol dimethacrylamide, polypropylene glycol divinyl ether, polypropylene glycol dialkyl ether.
- the preferred vinylic polysiloxane compound used are derivatives corresponding to formula VII,
- monomers are monovinylpolydimethylsiloxanes.
- S is preferably hydrogen
- Examples of such monomers having a vinyl function are polydimethylsiloxanepropylmaleamic acid or polydimethylsiloxanedipropyleneaminomaleamic acid. In the case of R 7 ⁇ R 2 are Divinylharmen such.
- vinylic polysiloxane compound is a preferred derivative according to the formula:
- R 7 can either be R 2 or else
- R 7 R 1
- examples of such monovinylic compounds are polydimethylsiloxane (1-propyl-3-acrylate) or polydimethylsiloxane (1-propyl-3-methacrylate).
- R 7 ⁇ R 2 are Divinyltellen such. Polydimethylsiloxane bis (1-propyl-3-acrylate) or polydimethylsiloxane bis (1-propyl-3-methacrylate).
- vinylic ester compound in the context of the present invention it is preferred to use derivatives corresponding to the formula X,
- ester compounds are di-n-butylmaleinate or fumarate or mono-n-butylmaleinate or fumarate.
- V can be W (ie a polydimethylsiloxane grouping), which corresponds to a dialkenylpolydimethylsiloxane compound such as divinylpolydimethylsiloxane.
- V can also be -O-CO-CeH 4 -CO-O-.
- These compounds are dialkenylphthalic acid derivatives.
- a typical example of such phthalic acid derivatives is diallyl phthalate.
- the molecular weights of the compounds which form the assembly c) can be varied within wide limits and are preferably between 150 and 10,000.
- As the fourth component for the preparation of the copolymers it is preferable to use 5 to 20 mol% of an unsaturated dicarboxylic acid derivative (XII):
- the unsaturated dicarboxylic acid derivative is derived from maleic acid, fumaric acid, mono- or divalent metal salts of these dicarboxylic acids, such as the sodium, potassium, calcium or ammonium salt or salts with an organic amine radical.
- monomers which form the unit Ia are polyalkylene glycol monoesters of the abovementioned acids having the general formula XIII:
- the fourth component can also be derived from the unsaturated dicarboxylic anhydrides and imides of the general formula XIV (5 to 20 mol%)
- up to 50 preferably up to 20 MoI%, based on the sum of the components a) to d
- the dispersion according to the invention can furthermore contain a copolymer whose base is an oxyalkenylglycol alkenyl ether and the copolymer contains the components a), b) and c).
- the proportion of the assembly a) is 10 to 90 mol%, the assembly b) 1 to 89 mol%, the assembly c) 0.1 to 5 mol% and the assembly d) 0.1 to 10 mol% %.
- the first component a) represents an unsaturated dicarboxylic acid derivative corresponding to the formula IVa or IVb.
- the monovalent or divalent metal cation is preferably sodium, potassium, calcium or magnesium ions.
- Substituted ammonium groups which are derived from primary, secondary or tertiary C 1 - to C 2 -alkylamines, C 1 - to C 2 -alkanolamines, C 5 - to C 8 -cycloalkylamines and C 6 -to C 4 -arylamines are preferably used as organic amine radicals , Examples of corresponding amines are methylamine, dimethylamine, trimethylamine, ethanolamine, diethanolamine, triethanolamine, cyclohexylamine, dicyclohexylamine, phenylamine, diphenylamine in the protonated (ammonium) form.
- the aliphatic hydrocarbon radicals may hereby be linear or branched as well as saturated or unsaturated.
- Preferred cycloalkyl radicals are cyclopentyl or cyclohexyl radicals
- the preferred aryl radicals are phenyl or naphthyl radicals, which may in particular be substituted by hydroxyl, carboxyl or sulfonic acid groups.
- X may be -NHR 2 and / or - NR 2 2 , which corresponds to the mono- or disubstituted monoamides of the corresponding unsaturated dicarboxylic acid, where R 2 may in turn be identical to R 1 or instead may be -CO-NH 2 .
- R 3 is in turn hydrogen or an aliphatic hydrocarbon radical having 1 to 5 C atoms (which may also be linear or branched or unsaturated).
- the third assembly c) corresponds to the formula IHa or IHb
- R 4 can be H or CH 3 , depending on whether it is acrylic or methacrylic acid derivatives.
- S can be -H, COOM a or -COOR 5 , where a and M have the abovementioned meaning and R 5 is an aliphatic hydrocarbon radical having 3 to 20 C atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 C atoms or an aryl radical with 6 to 14 carbon atoms can be.
- the aliphatic hydrocarbon radical may also be linear or branched, saturated or unsaturated.
- the preferred cycloaliphatic hydrocarbon radicals are again cyclopentyl or cyclohexyl radicals and the preferred aryl radicals are phenyl or naphthyl radicals.
- T -COOR 5
- S COOM a or -COOR 5 .
- x assumes a value of 1 to 150 and y of 0 to 15.
- the polypropylene oxide (polyethylene oxide) derivatives may be linked here via a grouping U 1 with the ethyl radical of the group c) corresponding to formula IIIa, where U 1 is -CO-NH-, -O- or -CH 2 -O- can.
- U 1 is -CO-NH-, -O- or -CH 2 -O- can.
- R 6 here again can be R 1 (meaning of R 1 see above) or
- the polydimethylsiloxane group W can not only be bonded directly to the ethylene radical of the formula IUa, but also via the groupings
- R 7 can also still
- R 1 , V and z have the meaning already described.
- these copolymers consist of 40 to 55 mol% of groups of the formula IVa and / or IVb, 40 to 55 mol%
- the copolymers additionally contain up to 50 mol%, in particular up to 20 mol%, based on the sum of the components a), b) and c), assemblies whose
- Monomer is a vinyl, acrylic acid or methacrylic acid derivative.
- the monomeric vinyl derivatives may preferably be derived from a compound selected from the group consisting of styrene, ethylene, propylene, isobutene or vinyl acetate.
- the additional components are derived in particular from acrylic acid or methyl acrylate.
- Preferred monomeric methacrylic acid derivative is methacrylic acid, methyl methacrylate and hydroxyethyl methacrylate.
- the number of repeating structural elements of the copolymers is not limited, but it has proved to be particularly advantageous to adjust the number of structural elements so that the copolymers have an average molecular weight of 1000 to 200,000.
- the second component of the copolymers is an oxyalkylene glycol alkenyl ether, which is preferably used in an amount of 40 to 55 mol%. Both preferred oxyalkylene glycol alkenyl ethers corresponding to the formula V
- CH2 CR - (CH2) p ⁇ O ⁇ (C m H2m0) n ⁇ R
- R 1 , m and n have the meaning already mentioned above.
- n preferably having values between 2 and 15.
- the third component essential to the invention for introducing the components c) is preferably 1 to 5 mol% of a vinylic polyalkylene glycol, polysiloxane or ester compound.
- a vinylic polyalkylene glycol compound derivatives corresponding to formula VI are used,
- R 6 can either be R 1 again or
- Examples of such monomers are maleic acid N- (methylpolypropylene glycol) monoamide, maleic acid N- (methoxy-polypropylene glycol-polyethylene glycol) monoamide, polypropylene glycol vinyl ether and polypropylene glycol allyl ether.
- R 6 ⁇ R 1 are bifunctional vinyl compounds whose Polvpropylenglykol- (polyethylene glycol) derivatives via amide or ether groups (-O- or -OCH 2 -) are interconnected.
- Examples of such compounds are polypropylene glycol bismaleamic acid, polypropylene glycol diacrylamide,
- the preferred vinylic polysiloxane compound used are derivatives corresponding to formula VII,
- monomers are monovinylpolydimethylsiloxanes.
- R 7 ⁇ R 1 divinyl compounds such as polydimethylsiloxane bis (propylmaleinamidklare) or polydimethylsiloxane bis (dipropylenaminomaleinamidklare).
- R 7 can either be R 1 or else
- RR 1 monovinylic compounds
- RR 1 monovinylic compounds
- examples of such monovinylic compounds (RR 1 ) are polydimethylsiloxane (1-propyl-3-acrylate) or polydimethylsiloxane (1-propyl-3-methacrylate;
- Divinyl compounds e.g. Polydimethylsiloxane bis (1-propyl-3-acrylate) or polydimethylsiloxane bis (1-propyl-3-methacrylate).
- S COOM a or -COOR 5 and R 5 can be an aliphatic hydrocarbon radical having 3 to 20 C atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 C atoms and an aryl radical having 6 to 14 C atoms, a and M have the above meaning.
- ester compounds are di-n-butyl maleate or fumarate or mono-n-butyl maleate or fumarate.
- V can be W (ie a polydimethylsiloxane grouping), which is a dialkenylpolydimethylsiloxane compound, such as. B. Divinylpolydimethylsiloxane corresponds. Alternatively, V can also be -O-CO-C 6 H 4 -CO-O-. These compounds are dialkenylphthalic acid derivatives. A typical example of such phthalic acid derivatives is diallyl phthalate.
- the molecular weights of the compounds which form the assembly c) can be varied within wide limits and are preferably between 150 and 10,000.
- a vinyl, acrylic or methacrylic acid derivative can be polymerized.
- the monomeric vinyl derivative used is preferably styrene, ethylene, propylene, isobutene or vinyl acetate, acrylic acid or methyl acrylate is preferably used as the monomeric acrylic acid derivative, while methacrylic acid methacrylic acid derivatives are preferably used in preference to methacrylic acid methacrylate and hydroxyethyl methacrylate.
- the aforementioned copolymers are disclosed in EP-A-736553.
- the dispersion of the invention may further comprise a copolymer whose base is an oxyalkenylglycol (meth) acrylic ester and the copolymer contains the following components:
- R 1 represents a hydrogen atom or the methyl group
- R 2 O represents a genus or a mixture of two or more genera of an oxyalkylene group having 2-4 carbon atoms, with the proviso that two or more genera of the mixture may be added either in the form of a block or in random form,
- R 3 is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms
- n is a value which is the average number of moles of oxyalkylene groups, m being an integer in the range of 1 to 200. 95 to 2 wt .-% of a monomer of the (meth) acrylic acid type (b) of the general formula XVI
- R 4 represents a hydrogen atom or the methyl group
- M 1 represents a hydrogen atom, a monovalent metal atom, a divalent metal atom, an ammonium group or an organic amine group
- Typical monomers (a) are:
- Methoxypolyethylene glycol mono (meth) acrylate Methoxypolypropylene glycol mono (meth) acrylate,
- Ethoxypolyethylene glycol polypropylene glycol polybutylene glycol mono (meth) acrylate Ethoxypolyethylene glycol polypropylene glycol polybutylene glycol mono (meth) acrylate.
- Typical monomers (b) are: acrylic acid and methacrylic acid, mono- and divalent metal salts, ammonium salts and / or organic amine salts thereof.
- Typical monomers (c) are: esters of aliphatic alcohols having 1 to 20 carbon atoms with (meth) acrylic acid; unsaturated
- Dicarboxylic acids such as maleic acid, fumaric acid, citraconic acid, mono- and divalent metal salts, ammonium salts and / or organic amine salts thereof; Mono- or diesters of unsaturated dicarboxylic acids such as maleic acid, fumaric acid,
- Citraconic acid with aliphatic alcohols of 1 to 20 carbon atoms, with glycols of 2 to 4 carbon atoms, with
- Vinyl acetate and vinyl propionate aromatic vinyl compounds such as styrene; unsaturated sulfonic acids, such as (meth) allylsulfonic acid, sulfoethyl (meth) acrylate,
- Styrenesulfonic acid mono- and divalent metal salts
- Ammonium salts and / or organic amine salts thereof are provided.
- the dispersions of the invention can be prepared by a process in which
- a polycarboxylate ether is used as a flow agent for the preparation of the dispersions.
- silica particles are dispersed in a liquid component, preferably water, more preferably deionized water. But it is also possible to redisperse a filter cake, d. H. Do not dry the silica particles first.
- This second embodiment is of course with economic advantages compared. connected to the first embodiment. Any hybrid forms of these two embodiments are also possible, d. H. it is possible to redisperse a filter cake and then add dried silica and vice versa. It is also possible to prepare base dispersions of mixtures of at least two different silicas.
- the preparation of the predispersions is carried out in a manner known per se by means of suitable dispersing aggregates.
- the dispersion of the silica powder can be carried out in apparatuses which introduce a comparatively low shear energy into the system (e.g., dissolvers, rotor-stator systems).
- a comparatively low shear energy e.g., dissolvers, rotor-stator systems.
- the pH of the predispersion or of the dispersion can, in an optional further step, be adjusted to the desired value, ie a value of 8.0 to 12, particularly preferably 8.5 to 12, very particularly preferably 8.7 to 10 and 9 to 9.5 are particularly preferably set.
- a basic component or an acidifier preferably an alkali metal or alkaline earth metal hydroxide or organic bases or ammonia.
- any acidic agent can be used as acidulant, for. As mineral acids, organic acids.
- the pH of the silica can be adjusted in one of the steps of preparing the silica, for example during precipitation or during drying, by adding suitable basic or acidic agents.
- suitable basic or acidic agents for example during precipitation or during drying.
- the silica to be dispersed and brought into contact with the liquid phase or the predispersion, whose pH has optionally been adjusted accordingly, are comminuted by means of a suitable aggregate.
- any suitable dispersing aggregate can be used. So z. B. Dispergieraggregate suitable whose energy input is sufficient, the
- High-pressure systems such as Nanomizer, Microfluidizer and other nozzle systems, in which the dispersion flows through a nozzle under high pressure of up to 50 to 5000 bar and is dispersed by the energy dissipation in and after the nozzle, achieve very high energy inputs of already 5,000 kJ in a single passage / m 3 to 500,000 kJ / m 3 .
- Agitator mills lead to significantly lower specific energy inputs per passage of 5 to 500 kJ / m 3 .
- the dispersion In order to achieve sufficient particle fineness, the dispersion must pass through the mill much more frequently, which leads to significantly higher stress frequencies than in high-pressure systems.
- the high frequency of use at low intensity has a positive effect on the structure and the surface of the particles and thus the stability of the dispersion.
- shearing energies of> 1000 kJ / m 3 should advantageously be applied.
- Particularly good results are achieved with agitator ball mills, high-pressure homogenizers or planetary ball mills. The operation of these mills is known to the person skilled in the art.
- the product flow through the mill can be done in pendulum or in circulation mode. Due to high circulation numbers, an arrangement in circulation mode is easier to realize here.
- the circulation rate can vary from 10 to 300 kg / h and is advantageously in the range from 25 to 200 kg / h, more preferably in the range from 50 to 150 kg / h and particularly preferably in the range from 80 to 120 kg / h.
- the agitator may be in the form of disks, pins, pin-to-pin arrangements, an annular gap, or the like. A disk arrangement is preferred.
- the grinding time depends on the dispersibility of the product and the amount used for 10 minutes to 80 hours, preferably 0.5 to 50 hours, more preferably 1 to 25 hours and particularly preferably 5 to 15 hours.
- specific energy inputs based on kg dispersion
- energy inputs of 0.01 to 10 kWh / kg can be achieved.
- energy inputs of 0.05 to 5 kWh / kg, more preferably 0.1 to 1 kWh / kg, very particularly preferably 0.1 to 0.5 kWh / kg and particularly preferably 0.25 to 0.3 kWh / kg
- the grinding media may consist of glass, aluminum oxide, zirconium oxide or other inorganic oxides as well as various mixtures of inorganic oxides.
- the size of the grinding media can vary from 20 ⁇ m to a few mm, advantageously grinding bodies of the size from 0.02 to 10 mm, particularly preferably from 0.05 to 5 mm, very particularly preferably from 0.1 to 1 mm and particularly preferably from 0.2 to 0, 4 mm used.
- the MahlSystem alternllgrad, based on the free volume of the grinding chamber can vary from 60 to 99%, preferably 70 to 95%, more preferably 80 to 95% and most preferably 90 to 95%.
- the peripheral speed of the grinding tool can vary from 1 m / s to 15 m / s, preferably 5 m / s to 15 m / s, more preferably 8 m / s to 12 m / s.
- the dispersion is optionally concentrated to the desired silica content.
- This concentration can be carried out by any technique known in the art, for example by reduction of the liquid medium such. B. by vacuum evaporation, cross-flow filtration, continuous or discontinuous centrifugation, filtration, or by increasing the solids content.
- the dispersion of the silica powder can also be carried out in apparatuses which introduce a comparatively low shear energy into the system (for example dissolvers, rotor-stator systems).
- the determination of the particle distribution of the dispersions of the invention is carried out according to the principle of laser diffraction on a laser diffractometer (Horiba, LA-920).
- the particle distribution corresponds to the particle distribution of all particles present in the dispersion.
- a sample of the silica dispersion is removed with stirring, transferred to a beaker and diluted by the addition of water without the addition of dispersing additives so that a dispersion having a weight fraction of about 1 wt .-% SiÜ2 is formed.
- the particle size distribution is determined from a partial sample of the dispersion with the laser diffractometer (Horiba LA-920 with standard software). For the measurement a relative refractive index of 1.09 has to be chosen.
- silica is not present as a solid but in aqueous dispersion, the following sample preparation must be carried out before the BET surface area is determined:
- the silica dispersion 100 ml of the silica dispersion are removed with stirring, transferred to a porcelain dish and dried for 72 h at 105 0 C. To remove organic components, the dried silica is heated to 500 ° C. for 24 h. After the silica sample has cooled, it is comminuted with a spatula and the BET surface area determined.
- the BET surface area of silica as a solid is determined according to ISO 5794-1 / Annex D with the TRISTAR 3000 device (Micromeritics) after the multipoint determination in accordance with DIN ISP 9277.
- the pH of the aqueous dispersions is based on DIN EN ISO 787-9 at 20 0 C. To determine the pH, the dispersions are diluted with water to a weight fraction of 5% SiO 2.
- DBP number which is a measure of the absorbency of the precipitated silica
- dibutyl phthalate is added dropwise at room temperature through the "Dosimaten Brabender T 90/50" dibutyl phthalate into the mixture at a rate of 4 ml / min Towards the end of the determination, the mixture becomes pasty as indicated by a steep increase in power demand, and when 600 digits (torque of 0.6Nm) are displayed, an electrical contact will cause both kneader and DBP dosing
- the synchronous motor for the DBP supply is coupled to a digital counter, so that the consumption of DBP in ml can be read.
- the DBP recording is given in g / (100 g) and calculated using the following formula:
- V consumption of DBP in ml
- the DBP uptake is defined for anhydrous, dried silica. If moist precipitated silicas are used, the correction value K must be taken into account for calculating the DBP absorption. This value can be determined from the following correction table, eg. For example, a water content of the silica of 5.8% would mean a 33 g / (100 g) addition for DBP uptake.
- the moisture content of the silicic acid is determined according to the method "Determination of moisture or loss of drying".
- the moisture of silica is determined according to ISO 787-2 after drying for 2 hours in a convection oven at 105 0C. This drying loss consists predominantly of water moisture. Determination of the loss on ignition
- the moisture content (TV) of the tested sample is determined according to the previously described method "Determination of moisture or dry loss” according to DIN EN ISO 787-2.
- Al2O3 The determination of the Al content is carried out as Al2O3, the Na content as Na2 ⁇ . Both determinations are carried out according to ISO 3262-18 by means of flame atomic adsorption spectroscopy.
- the determination of the SiO 2 content is carried out according to ISO 3262-19.
- the dispersions are prepared in a stirred ball mill (LME 4, Netzsch).
- the grinding chamber and the disc agitator are made of abrasion-resistant ceramic (AI 2 O 3 or ZrÜ 2) •
- the grinding balls of yttrium-stabilized ZrÜ 2 have a diameter of 0.2 to 0.4 mm and fill the grinding chamber to 90% (8.84 kg).
- 22.5 kg of deionized water are placed in a 501 container Bottom outlet submitted.
- the pH of the dispersion is adjusted to 9 with KOH.
- the pH is checked regularly and readjusted if necessary.
- the dispersion is circulated through the ball mill. In all tests, the peripheral speed remains constant at 10 m / s and the throughput at approximately 100 kg / h.
- the concentration of the dispersion of SiC> 2 is further increased.
- the mill is still operated here in the cycle.
- the ratio of PCE to silica is adjusted according to Table 2.
- the composition of the dispersions is shown in Table 2.
- the comparative example contains no silica but only PCE and is not a dispersion.
- the dispersions according to the invention show, within a period of 6 months, no appreciable change with regard to sedimentation stability and viscosity.
- test specimens of size 40 mm x 40 mm x 160 mm are produced. Based on this standard, the determination of the flexural strength and compressive strength after 8 h of aging of the test specimens is carried out on these test specimens.
- the results obtained show a marked increase in the early strength (measured as flexural tensile strength after 8 h and compressive strength after 8 h) when using the dispersions according to the invention. It is also interesting that the dispersion 2 is more effective than the identical silica in dry form.
- the cement used is CEM I 42.5 Bernburg.
- the dispersions of the invention used are Example 1 to Example 3.
- the dispersions are metered so that the proportion of silicon dioxide 0.5 wt .-% based on the cement used.
- the water / cement ratio is constant at 0.5.
- the comparison is made against Comparative Example 1, which contains no silica, but PCE. In all experiments, the initial flow was 24 +/- learning.
- the curves obtained show the released energy in [mW / g CEM] versus time in [h] in the cement paste specimen.
- the heat development is due to the exothermic reaction of the silicate phases in the cement with water.
- the maximum of the curve obtained by calorimetry can be correlated with the strength development in the cement, i. a maximum occurring earlier means early development of early strength in the component.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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ES07821404.6T ES2599756T3 (es) | 2006-10-20 | 2007-10-16 | Dispersiones acuosas de ácidos silícicos precipitados y silicatos para el aumento de la resistencia temprana en preparados tipo cemento |
EP07821404.6A EP2079670B1 (de) | 2006-10-20 | 2007-10-16 | Wässrige dispersionen gefällter kieselsäuren zur steigerung der frühfestigkeit in zementartigen zubereitungen |
CN200780047726.9A CN101568499B (zh) | 2006-10-20 | 2007-10-16 | 用于提高水泥质制剂的初期强度的沉淀二氧化硅和硅酸盐的含水分散体 |
KR1020097007898A KR101390555B1 (ko) | 2006-10-20 | 2007-10-16 | 시멘트 제제의 초기 강도를 증가시키기 위한 실리카의 수분산액 |
US12/446,333 US8835535B2 (en) | 2006-10-20 | 2007-10-16 | Aqueous dispersions of silica for increasing early strength in cementitious preparations |
JP2009532786A JP5268924B2 (ja) | 2006-10-20 | 2007-10-16 | セメント系調製物の早強性を増加させるための二酸化珪素の水性分散液 |
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DE102006049524.1 | 2006-10-20 | ||
DE102006049524A DE102006049524A1 (de) | 2006-10-20 | 2006-10-20 | Wässrige Dispersionen gefällter Kieselsäuren und Silikate zur Steigerung der Frühfestigkeit in zementartigen Zubereitungen |
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US (1) | US8835535B2 (de) |
EP (1) | EP2079670B1 (de) |
JP (1) | JP5268924B2 (de) |
KR (1) | KR101390555B1 (de) |
CN (1) | CN101568499B (de) |
DE (1) | DE102006049524A1 (de) |
ES (1) | ES2599756T3 (de) |
HU (1) | HUE031486T2 (de) |
PL (1) | PL2079670T3 (de) |
PT (1) | PT2079670T (de) |
WO (1) | WO2008046831A1 (de) |
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WO2013150145A1 (fr) | 2012-04-05 | 2013-10-10 | Chryso | Adjuvant pour compositions hydrauliques |
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BR112014025138A8 (pt) * | 2012-04-20 | 2018-04-03 | Grace W R & Co | Antiespumantes estabilizados para composições de cimento |
JP6621763B2 (ja) | 2014-01-17 | 2019-12-18 | マルティキップ インコーポレイティドMultiquip,Inc. | コンクリートへのコロイダルシリカの添加 |
RS56983B1 (sr) * | 2014-02-14 | 2018-05-31 | Rhodia Operations | Proces za pripremu taloženih silicijum dioksida, taloženi silicijum dioksidi i njihove primene, posebno za ojačavanje polimera |
EP3221103B1 (de) | 2014-11-21 | 2022-05-11 | GCP Applied Technologies Inc. | Betonplattenherstellung mit nasspressen |
EP3053901A1 (de) * | 2015-02-09 | 2016-08-10 | Sika Technology AG | Nichtinvasive Reparatur und Nachrüstung von gehärteten verstärkten Betonkonstruktionen |
CN108535309B (zh) * | 2018-04-16 | 2020-06-09 | 安徽工业大学 | 一种原位测量低碳合金钢中Fe3C析出量的方法 |
CN108726912A (zh) * | 2018-06-15 | 2018-11-02 | 山西中铁铁诚建材科技有限公司 | 一种聚羧酸减水剂及其制备工艺 |
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Cited By (1)
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---|---|---|---|---|
WO2013150145A1 (fr) | 2012-04-05 | 2013-10-10 | Chryso | Adjuvant pour compositions hydrauliques |
Also Published As
Publication number | Publication date |
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PL2079670T3 (pl) | 2017-05-31 |
US20100324173A1 (en) | 2010-12-23 |
JP2010506987A (ja) | 2010-03-04 |
DE102006049524A1 (de) | 2008-04-24 |
JP5268924B2 (ja) | 2013-08-21 |
PT2079670T (pt) | 2016-09-19 |
CN101568499B (zh) | 2014-04-23 |
CN101568499A (zh) | 2009-10-28 |
KR101390555B1 (ko) | 2014-04-30 |
EP2079670A1 (de) | 2009-07-22 |
EP2079670B1 (de) | 2016-08-03 |
KR20090081373A (ko) | 2009-07-28 |
ES2599756T3 (es) | 2017-02-03 |
US8835535B2 (en) | 2014-09-16 |
HUE031486T2 (en) | 2017-07-28 |
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