WO2007083596A1 - Structure fibreuse - Google Patents

Structure fibreuse Download PDF

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Publication number
WO2007083596A1
WO2007083596A1 PCT/JP2007/050410 JP2007050410W WO2007083596A1 WO 2007083596 A1 WO2007083596 A1 WO 2007083596A1 JP 2007050410 W JP2007050410 W JP 2007050410W WO 2007083596 A1 WO2007083596 A1 WO 2007083596A1
Authority
WO
WIPO (PCT)
Prior art keywords
containing compound
compound
fiber structure
fiber
grade
Prior art date
Application number
PCT/JP2007/050410
Other languages
English (en)
Japanese (ja)
Inventor
Masao Seki
Rumi Karasawa
Wataru Abe
Toshiaki Shimizu
Takashi Kawasaki
Masanobu Sato
Original Assignee
Toray Industries, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries, Inc. filed Critical Toray Industries, Inc.
Priority to JP2007508200A priority Critical patent/JPWO2007083596A1/ja
Priority to US12/160,944 priority patent/US20100192272A1/en
Priority to EP07706744A priority patent/EP1978151A4/fr
Publication of WO2007083596A1 publication Critical patent/WO2007083596A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2938—Coating on discrete and individual rods, strands or filaments

Definitions

  • the present invention relates to a fiber structure having water repellency, oil repellency and antifouling properties having excellent durability.
  • Patent Document 1 As a means for imparting washing-resistant water and oil repellency to fiber fabrics, a method of mixing an isocyanate compound (Patent Document 1), a method of treating with a isocyanate compound and then treating with a water repellent (Patent Document 2), a method of treating with a compound containing a polymerizable vinyl group and a condensable methylol group (Patent Document 3), after treatment with an aqueous fluorinated water / oil repellent, and a solvent-based fluorinated water / oil repellent.
  • Patent Document 2 a method of mixing an isocyanate compound
  • Patent Document 2 a method of treating with a isocyanate compound and then treating with a water repellent
  • Patent Document 3 a method of treating with a compound containing a polymerizable vinyl group and a condensable methylol group
  • Examples include a method of treating with an oil (Patent Document 4) and a method of improving wear resistance during washing (Patent Document 5), but V and slippage are insufficient in washing durability and antifouling properties. Proposal of what has both, has been made.
  • swimsuits for swimming are aimed at low resistance, and general swimsuits have low water resistance. It is intended to reduce health energy loss due to wettability.
  • swimsuits that are not water repellent or swimsuits that are water repellent but have low water repellency If the swimsuit and Z or sand get wet, the sand will adhere to the swimsuit, causing problems in appearance, and part of the sand will temporarily adhere to the gaps in the woven or knitted fabric. There are problems such as being stuck in and not being able to be removed by washing, but there are no proposals focusing on this problem.
  • Patent Document 1 Japanese Patent Laid-Open No. 54-133486
  • Patent Document 2 Japanese Patent Laid-Open No. 54-139641
  • Patent Document 3 Japanese Patent Laid-Open No. 59-130374
  • Patent Document 4 JP-A-60-151380
  • Patent Document 5 Japanese Patent Laid-Open No. 7-216749
  • Patent Document 6 Japanese Patent Laid-Open No. 11-279810
  • Patent Document 7 Japanese Patent Application Laid-Open No. 2002-294563
  • An object of the present invention is to provide a fiber structure having both water repellency, oil repellency, and antifouling properties excellent in washing durability in view of the background of strong conventional technology.
  • the present invention employs the following means in order to solve the above problems.
  • the surface of a single fiber is formed using a fiber coated with an organic fluorine-containing compound-containing resin film via a triazine ring-containing compound-containing resin film or an organic fluorine compound and a triazine ring-containing compound-containing resin film.
  • a fiber structure, wherein the fiber structure has a water repellency of 20 or more after washing and an oil repellency of 4 or more.
  • a layer of a fluorine-based water-repellent / oil-repellent compound is formed on the fiber surface via an extremely thin polymer film, or contains a fluorine-based water-repellent / oil-repellent compound. Since a thin polymer film is formed, it is possible to stably supply a fiber structure having water repellency, oil repellency and antifouling properties excellent in washing durability.
  • the multifunctional fiber structure of the present invention can be effectively used especially for sports apparel, uniform apparel, casual apparel, general apparel, bedding, and interior.
  • a triazine ring is contained on the surface of a single fiber.
  • a resin film containing an organic fluorine compound and a triazine ring-containing compound via a compound-containing resin film, or by coating the surface of the single fiber with a resin film containing an organic fluorine compound and a triazine ring-containing compound. It was clarified to solve the profitable problem at once.
  • the fiber material used in the fiber structure of the present invention includes polyethylene terephthalate, polypropylene phthalate, polybutylene terephthalate, etc., aromatic polyester fiber obtained by copolymerizing these with a third component, and L-lactic acid.
  • Aliphatic polyester fiber represented by the main component polyamide fiber such as nylon 6 and nylon 66, poly Acrylic fibers mainly composed of acrylonitrile, polyolefin fibers such as polyethylene and polypropylene, synthetic fibers such as polysalts and bures, semi-synthetic fibers such as acetate and rayon, natural fibers such as cotton, silk and wool Etc.
  • a force polyester fiber or a fiber based on a polyamide fiber which can use these fibers alone or as a mixture of two or more, is preferably used.
  • Yarn, and a composite yarn of polymethylene terephthalate and polyethylene terephthalate can be used.
  • the fibers used in the present invention may be staple yarns such as false twisted yarns, strong twisted yarns, Taslan Kaye yarns, thick yarns and mixed yarns in addition to ordinary flat yarns. Fiber or tow, or may be various forms of fiber such as spun yarn.
  • the fiber structure of the present invention includes a knitted fabric, a fabric-like material such as a woven fabric or a non-woven fabric, a string-like material, and the like using the fiber.
  • a triazine ring-containing compound-containing resin coating or an organic fluorine compound and a triazine ring-containing compound-containing resin coating is formed on the surface of a single fiber of the fiber material. That is, a resin film containing a triazine ring-containing compound as an essential component or a resin film containing an organic fluorine compound and a triazine ring-containing compound as essential components is formed on the surface of a single fiber. Is.
  • the triazine ring-containing compound of the present invention is a compound containing a triazine ring and having at least two polymerizable functional groups, and examples thereof include those represented by the following general formula.
  • R0 to R2 -H, -0H, -C6H5, -CnoH2nO + i (nO: 1 to 2), -C00CnlH2ni + i (nl: 1 to 20), -CONR3R4, -NR3R4 where R3, R4 : -H, -OCn3H2n3 + l,-
  • triazine ring-containing compound-containing resin coating or the organic fluorine compound and the triazine ring-containing compound-containing resin coating (hereinafter referred to as "triazine ring-containing compound-containing resin coating"). ) Is formed as follows.
  • a monomer for forming the above-mentioned resin coating and an aqueous liquid having a catalytic force are applied onto the fiber, and then heat treatment is performed for polymerization.
  • Examples of powerful catalysts include acetic acid, formic acid, acrylic acid, malic acid, tartaric acid, maleic acid, phthalic acid, sulfuric acid, persulfuric acid, hydrochloric acid, phosphoric acid and the like, and their ammonium salts, sodium salts, Potassium salts, magnesium salts and the like, and one or more of these can be used. Of these, ammonium persulfate and potassium persulfate can be preferably used as the catalyst. The amount of such catalyst is preferably 0.1 to 20% by weight based on the amount of monomer used.
  • the heat treatment for vigorous polymerization is preferably a dry heat treatment and a steam heat treatment at a temperature of 50 to 180 ° C for 0.1 to 30 minutes. It is easy to form a uniform film, and the texture after film formation is flexible.
  • saturated steam or superheated steam at 80 to 160 ° C is preferably used, more preferably 90 to 130 ° C saturated steam in the case of saturated steam, or 110 to 160 ° C. It is a superheated steam at a temperature, and both process for several seconds and several minutes.
  • the adhesion amount of the resin containing the triazine ring-containing compound is preferably 0.5 to 5% by weight, more preferably 1 to 3% by weight, based on the fiber weight.
  • the same treatment as described above is performed using a mixed solution of the triazine ring-containing compound and the organic fluorine compound.
  • the mixing weight ratio of the triazine ring-containing compound and the organic fluorine compound is preferably I / O.
  • the water repellency is 3rd grade or less, preferably when drying and heat treatment are performed after forming the coating so as not to impair the wettability and permeability of the processing agent. 2nd grade or lower It is preferable to determine the mixing ratio.
  • the organic fluorine compound may be the same compound as the fluorine compound used for the organic fluorine compound-containing resin coating performed after the treatment, or may be a different compound.
  • the triazine ring-containing compound-containing resin coating of the present invention preferably has a thickness of 5 to LOONm as observed at a magnification of 100000 using a transmission electron microscope (TEM).
  • TEM transmission electron microscope
  • inorganic particles can be contained in a resin film containing a triazine ring-containing compound. Examples of the inorganic particles include aluminum oxide, silicon oxide, titanium oxide, kaolinite, talc, calcium carbonate, calcium silicate, magnesium oxide, and these are used alone or in combination of two or more. be able to.
  • the particle diameter of the particles is preferably 5 to 400 nm in terms of number average particle diameter, and more preferably 10 to 100 nm.
  • the inorganic particles are preferably used in the state of an aqueous dispersion.
  • the inorganic particles of the present invention can be used by mixing with an aqueous solution of a polymerizable monomer, and the weight mixing ratio with the polymerizable monomer is preferably 0.03-1.0 with respect to the monomer 1, and more preferably. Is between 0.05 and 0.5.
  • an organic fluorine compound-containing resin film is formed on the triazine ring-containing compound-containing resin film.
  • the organic fluorine compound include attalylate compounds containing a perfluoroalkyl group represented by the following general formula.
  • m is an integer from 1 to 20
  • the fiber structure on which the coating of the triazine ring-containing composite is formed is immersed in an aqueous liquid or a solvent-based liquid to obtain a target adhesion amount.
  • a target adhesion amount preferably from 0.1 to 8% by weight, more preferably from 0.5 to 4% by weight, based on the fiber weight.
  • the organic fluorine compound preferably contains at least one of a triazine ring-containing compound and an isocyanate compound to form a coating layer.
  • a triazine ring-containing compound it is possible to use the same kind as that used for the above-mentioned film formation, or a different kind.
  • the isocyanate compound a compound having two or more isocyanate groups obtained by blocking isocyanate groups with oxime compounds such as sodium sulfite and methyl ethyl ketone oxime can be used.
  • a water absorbing agent such as a water absorbing agent, a hygroscopic agent, an ultraviolet absorber, a light stabilizer, a lubricant, a lubricant, an organic particle, an organic particle, an antistatic agent, and a deodorant as long as the effects of the present invention are not impaired.
  • Agents, antibacterial agents, flame retardants, colorants, deep colorants, water repellents, oil repellents, antifouling agents, and the like can be added.
  • the fiber structure of the present invention has water repellency after 20 washings of grade 4 or higher and oil repellency of grade 4 or higher.
  • the durability of washing with organic fluorine compounds is greatly improved by being fixed to single fibers, and the water and oil repellency is 4th grade or higher after 20 washings. It is shown.
  • the film thickness of the triazine ring-containing compound-containing resin film is 5 to: LOOnm, and since it has a thin film structure, it is possible to further prevent the resin from falling off by washing and to improve washing durability. This is a significant improvement. Because of such high water and oil repellency, the fiber structure of the present invention exhibits excellent antifouling properties.
  • the fiber structure of the present invention has a soiling property of food stains after 20 washings, that is, it is difficult to attach 3 Grade and above, washability is grade 3 and above.
  • Organic fluorinated compound and triazine ring-containing compound are uniformly formed on the fiber, and water and oil repellency after washing 20 times has the performance of grade 4 or more. It also exhibits excellent performance against contaminated food stains with a contamination level of 3 or higher and a laundry removal level of 3 or higher.
  • the fiber structure of the present invention has a stain resistance of the ink-stained soil after 20 washings, that is, the hard-to-attach strength S3 or higher and the laundry removal power or higher.
  • Ink juice contains glue and carbon, in addition to carbon, and has a property of being easily attached and difficult to fall off.
  • an organic fluoride compound and a compound containing a triazine ring are used.
  • a uniform film is formed on the fiber, and it has a water repellency and oil repellency level of 20 or more after washing. It exhibits performance that is above the grade.
  • the fiber structure of the present invention has a sand adhesion preventing property after 20 washings, that is, the non-stickiness is grade 3 or higher.
  • the fiber structure of the present invention When the fiber structure is worn as a swimsuit on a sandy beach, for example, the adhesion of sand is small, and the performance of the water repellency after washing 20 times or more is improved. The adhesion preventing effect can be improved. In addition, considering the adhesion of the sun oil wrapped in sun oil and the sun oil itself in the swimsuit, it is necessary to have high oil repellency.
  • the fiber structure of the present invention also has oil repellency of grade 4 or higher after 20 washings. Therefore, it is possible to obtain a fiber structure having a sand adhesion preventing property of grade 3 or higher. Therefore, the fiber structure of the present invention is suitably used as a swimsuit.
  • the mud dirt removing property after 20 washings of the fiber structure of the present invention is 4th grade or more. Mud is often rubbed in water and oil in daily life and sports.
  • the coating using the organic fluorine-based compound and the triazine ring-containing compound is uniformly formed on the fiber, and the water repellency and oil repellency strength after washing 20 times or more are higher. It is possible to prevent mud stains from directly adhering to the fiber, and it is possible to improve the anti-stain property of mud stains, and to obtain a fiber structure with a removability of grade 4 or higher.
  • 'Sesame oil (kadoya genuine sesame oil) is used at room temperature.
  • the amount of the contaminant dropped is 0.1 lcc for the liquid and 0.1 lg for the paste.
  • test specimen after contamination is placed in an automatic inversion swirl electric washing machine with 25 L of a solution obtained by dissolving a weak alkaline synthetic detergent specified in JIS K 337 to a concentration of 0.1% in a bath. Wash for 5 minutes under strong conditions at a ratio of 1:50 at 40 ⁇ 2 ° C, then drain and wash for 5 minutes. Take out the test piece after washing without squeezing it, press lightly with filter paper to drain the water, and dry naturally in a horizontal state.
  • the completely submerged state is a state in which a washing machine or the like is used and the fabric is submerged in water or the water penetrates into the ground and penetrates through.
  • the mud dirt removal property was evaluated by the following method.
  • test specimen after contamination is placed in an automatic inversion swirl electric washing machine with 25 L of a solution prepared by dissolving a weak alkaline synthetic detergent specified in JIS K 337 to a concentration of 0.1% in a bath. Wash for 5 minutes under strong conditions at a ratio of 1:50 at 40 ⁇ 2 ° C, then drain and wash for 5 minutes. Take out the test piece after washing without squeezing it, press lightly with filter paper to drain the water, and dry naturally in a horizontal state.
  • the above-mentioned soiling property of food soil, washing removability, etc. are measured as the performance of the fiber structure after washing 20 times by the washing method shown below.
  • a weak alkaline synthetic detergent specified in JIS K 337 is dissolved in an automatic inversion swirl electric washing machine to a concentration of 0.2%, and the bath ratio is 1:50 at a temperature of 40 ⁇ 2 ° C. Washing was performed under strong conditions for 5 minutes, then draining and washing with water for 5 minutes. This was repeated 20 times, and then air-dried.
  • NK Guard SR-108 (Fluorine cocoon-based fat, solid content 20%, manufactured by Nikka Chemical Co., Ltd.) And dipped the dyed cloth in an aqueous solution in which 3gZL of ammonium persulfate as a catalyst is dissolved, and squeezed with a mandala so that the amount of the aqueous solution attached becomes 90% by weight, and a saturated steam atmosphere at 104 ° C The treatment was performed for 5 minutes.
  • aqueous liquid using at least one of the above compounds in the ratio shown in Table 1 2 gZL of Becamine M-3 (a triazine ring-containing compound solid content 80%, manufactured by Dainippon Ink Co., Ltd.), Pekka Minax Sererator ACX (Dainippon Ink) Chemical Industry Co., Ltd. Catalyst Solid content 35%) Dissolve 0.5gZ L, adjust the treatment liquid, immerse the dyed cloth and squeeze with mandar so that the adhesion amount of aqueous liquid is 90%. It was dried at a temperature of ° C, and a pin tenter set at a temperature of 170 ° C.
  • the product according to the present invention has both excellent water repellency, oil repellency and antifouling property.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

L'invention concerne la production stable d'une structure fibreuse qui a un caractère hydrofuge et oléofuge, n'est pas sujette à l'encrassement et présente une excellente résistance au lavage. L'invention concerne une structure fibreuse formée à partir de fibres, la surface de chaque fibre ayant été recouverte d'un revêtement d'une résine comprenant un composé organique du fluor, d'un revêtement d'une résine comprenant un composé contenant un cycle triazine ou d'un revêtement d'une résine comprenant un composé organique du fluor et un composé contenant un cycle triazine. La structure fibreuse est caractérisée en ce qu'après une succession de 20 lavages, la structure fibreuse a un caractère hydrofuge de niveau supérieur ou égal à 4 et un caractère oléofuge de niveau supérieur ou égal à 4.
PCT/JP2007/050410 2006-01-18 2007-01-15 Structure fibreuse WO2007083596A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2007508200A JPWO2007083596A1 (ja) 2006-01-18 2007-01-15 繊維構造物
US12/160,944 US20100192272A1 (en) 2006-01-18 2007-01-15 Fiber structure
EP07706744A EP1978151A4 (fr) 2006-01-18 2007-01-15 Structure fibreuse

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2006009667 2006-01-18
JP2006-009667 2006-01-18
JP2006-154361 2006-06-02
JP2006154361 2006-06-02

Publications (1)

Publication Number Publication Date
WO2007083596A1 true WO2007083596A1 (fr) 2007-07-26

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US (1) US20100192272A1 (fr)
EP (1) EP1978151A4 (fr)
JP (1) JPWO2007083596A1 (fr)
WO (1) WO2007083596A1 (fr)

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Publication number Priority date Publication date Assignee Title
CN103435738B (zh) * 2013-04-15 2016-06-15 多喜爱家纺股份有限公司 一种医用面料用活性三防助剂的制备工艺
WO2020203434A1 (fr) * 2019-04-01 2020-10-08 東レ株式会社 Structure fibreuse contenant un fil de polyuréthane élastique

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US3087905A (en) 1960-05-03 1963-04-30 American Cyanamid Co Durable fluorochemical-melamine resin textile finish
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US20100192272A1 (en) 2010-08-05
EP1978151A1 (fr) 2008-10-08
EP1978151A4 (fr) 2011-03-30

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