WO2006136541A3 - Ru-katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen - Google Patents

Ru-katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen Download PDF

Info

Publication number
WO2006136541A3
WO2006136541A3 PCT/EP2006/063323 EP2006063323W WO2006136541A3 WO 2006136541 A3 WO2006136541 A3 WO 2006136541A3 EP 2006063323 W EP2006063323 W EP 2006063323W WO 2006136541 A3 WO2006136541 A3 WO 2006136541A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogenating
groups
shell catalyst
catalyst
hydrogenable
Prior art date
Application number
PCT/EP2006/063323
Other languages
English (en)
French (fr)
Other versions
WO2006136541A2 (de
Inventor
Laar Frederik Van
Michael Becker
Ekkehard Schwab
Jochem Henkelmann
Peter Polanek
Original Assignee
Basf Ag
Laar Frederik Van
Michael Becker
Ekkehard Schwab
Jochem Henkelmann
Peter Polanek
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Laar Frederik Van, Michael Becker, Ekkehard Schwab, Jochem Henkelmann, Peter Polanek filed Critical Basf Ag
Priority to EP06777365A priority Critical patent/EP1899051A2/de
Priority to CA2612435A priority patent/CA2612435C/en
Priority to CN2006800305342A priority patent/CN101242895B/zh
Priority to JP2008517476A priority patent/JP2008543550A/ja
Priority to US11/993,777 priority patent/US8207327B2/en
Priority to KR1020087001732A priority patent/KR101354236B1/ko
Publication of WO2006136541A2 publication Critical patent/WO2006136541A2/de
Publication of WO2006136541A3 publication Critical patent/WO2006136541A3/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die Erfindung betrifft einen Schalenkatalysator enthaltend als Aktivmetall Ruthenium alleine oder zusammen mit mindestens einem weiteren Metall der Nebengruppen IB, VIIB oder VIII des Periodensystems der Elemente (CAS- Version), aufgebracht auf einen Träger enthaltend Siliziumdioxid als Trägermaterial, ein Verfahren zur Herstellung dieses Schalen katalysators, ein Verfahren zur Hydrierung einer organischen Verbindung, die hydrierbare Gruppen enthält, bevorzugt zur Hydrierung einer carbocyclischen aromatischen Gruppe zu der entsprechenden carbocyclischen aliphatischen Gruppen oder zur Hydrierung von Aldehyden zu den entsprechenden Alkoholen, unter Verwendüng des erfindungsgemäßen Schalenkatalysators sowie die Verwendung des erfindungsgemäßen Schalenkatalysators zur Hydrierung einer organischen Verbindung, die hydrierbare Gruppen enthält, bevorzugt zur Hydrierung einer carbocyclischen aromatichen Gruppe zu der entsprechenden carbocyclischen aliphatischen Gruppen oder zur Hydrierung von Aldehyden zu den entsprechenden Alkoholen.
PCT/EP2006/063323 2005-06-22 2006-06-20 Ru-katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen WO2006136541A2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP06777365A EP1899051A2 (de) 2005-06-22 2006-06-20 Katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen
CA2612435A CA2612435C (en) 2005-06-22 2006-06-20 Catalyst and method for hydrogenating organic compounds containing hydrogenable groups
CN2006800305342A CN101242895B (zh) 2005-06-22 2006-06-20 用于氢化含有能被氢化的基团的有机化合物的催化剂和方法
JP2008517476A JP2008543550A (ja) 2005-06-22 2006-06-20 水素化可能な基を含む有機化合物の水素化用触媒及び水素化方法
US11/993,777 US8207327B2 (en) 2005-06-22 2006-06-20 Catalyst and process for hydrogenating organic compounds comprising hydrogenatable groups
KR1020087001732A KR101354236B1 (ko) 2005-06-22 2006-06-20 수소화가능한 기를 포함하는 유기 화합물의 수소화용 촉매및 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005029200.3 2005-06-22
DE102005029200A DE102005029200A1 (de) 2005-06-22 2005-06-22 Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen

Publications (2)

Publication Number Publication Date
WO2006136541A2 WO2006136541A2 (de) 2006-12-28
WO2006136541A3 true WO2006136541A3 (de) 2007-04-12

Family

ID=37433856

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/063323 WO2006136541A2 (de) 2005-06-22 2006-06-20 Ru-katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen

Country Status (8)

Country Link
US (1) US8207327B2 (de)
EP (1) EP1899051A2 (de)
JP (1) JP2008543550A (de)
KR (1) KR101354236B1 (de)
CN (1) CN101242895B (de)
CA (1) CA2612435C (de)
DE (1) DE102005029200A1 (de)
WO (1) WO2006136541A2 (de)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005049568A1 (de) 2005-10-17 2007-04-19 Basf Ag Verfahren zur kontinuierlichen Hydrierung oder hydrierenden Aminierung
CN101522300B (zh) 2006-07-31 2012-10-10 巴斯夫欧洲公司 适用于氢化的钌催化剂的再生方法
WO2008015170A2 (de) 2006-07-31 2008-02-07 Basf Se Verfahren zur regenerierung von rutheniumkatalysatoren für die hydrierung von benzol
ATE491515T1 (de) 2006-07-31 2011-01-15 Basf Se Verfahren zur regenerierung von rutheniumkatalysatoren für die kernhydrierung von phthalaten
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025356A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE202008017277U1 (de) 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
ES2602116T3 (es) * 2008-12-17 2017-02-17 Basf Se Procedimiento continuo de producción de ciclohexilmetanoles sustituidos
US20110144398A1 (en) 2009-12-11 2011-06-16 Basf Se Process for regenerating a ruthenium-containing supported hydrogenation catalyst
WO2011072992A1 (en) 2009-12-15 2011-06-23 Exxonmobil Chemical Patents Inc. Temperature control of an oligomerisation process and reactor
KR101833077B1 (ko) * 2009-12-15 2018-02-27 바스프 에스이 방향족 화합물의 수소화를 위한 촉매 및 방법
ES2719585T3 (es) * 2010-02-12 2019-07-11 Basf Se Procedimiento para la preparación de 4-isopropilciclohexilmetanol
US8889920B2 (en) 2010-02-12 2014-11-18 Basf Se Process for preparing 4-isopropylcyclohexylmethanol
US8450534B2 (en) 2010-03-24 2013-05-28 Basf Se Process for preparing 4-cyclohexyl-2-methyl-2-butanol
JP6076896B2 (ja) * 2010-03-24 2017-02-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ４−シクロヘキシル−２−メチル−２−ブタノールの調製方法
DE102010026462A1 (de) * 2010-07-08 2012-01-12 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
US9056812B2 (en) 2011-09-16 2015-06-16 Basf Se Process for preparing 4-cyclohexyl-2-methyl-2-butanol
ES2626479T3 (es) 2011-09-16 2017-07-25 Basf Se Procedimiento para la preparación de 4-ciclohexil-2-metil-2-butanol
US9340754B2 (en) 2012-11-27 2016-05-17 Basf Se Process for the preparation of cyclohexyl-substituted tertiary alkanols
CN106338551B (zh) * 2015-07-07 2019-03-08 中国石油化工股份有限公司 重整催化剂中不同形态硫元素含量的分析方法
JP6800965B2 (ja) * 2015-10-05 2020-12-16 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ ルテニウム／鉄／炭素担体触媒を生成する方法
JP6131370B1 (ja) * 2016-06-10 2017-05-17 千代田化工建設株式会社 合成ガス製造触媒用担体及びその製造方法、合成ガス製造触媒及びその製造方法、並びに合成ガスの製造方法
EP3510012A1 (de) 2016-09-09 2019-07-17 ExxonMobil Chemical Patents Inc. Verfahren zur hydrierung von phthalatestern
KR102324239B1 (ko) * 2017-11-06 2021-11-08 한화솔루션 주식회사 방향족 화합물의 수소화 반응용 촉매 및 이의 제조방법
EP4015079A1 (de) 2020-12-18 2022-06-22 Evonik Operations GmbH Verfahren zur regenerierung von hydrierkatalysatoren
CN114602463B (zh) * 2022-04-13 2023-12-05 宏业生物科技股份有限公司 一种对羟基苯甲酸乙酯加氢催化剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10128242A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Hydrierung organischer Verbindungen
DE10128204A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen
WO2005061105A1 (de) * 2003-12-22 2005-07-07 Basf Aktiengesellschaft Ruthenium-heterogenkatalysator, kernhydrierte bisglycidylether der bisphenole a und f und verfahren zu ihrer herstellung
DE10361151A1 (de) * 2003-12-22 2005-07-14 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Hydrierung einer carbocyclischen aromatischen Gruppe, insbesondere zur Herstellung eines Bisglycidylethers der Formel I

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4072628A (en) * 1974-11-05 1978-02-07 Ici Americas Inc. Regeneration of supported ruthenium catalyst
BE882279A (fr) 1980-03-18 1980-07-16 Raffinerie Tirlemontoise Sa Procede de reactivation d'un catalyseur, a base de metaux du groupe du platine, pour l'hydrogenation des sucres
US4431750A (en) 1982-05-19 1984-02-14 Phillips Petroleum Company Platinum group metal catalyst on the surface of a support and a process for preparing same
DE3881012T2 (de) * 1988-01-14 1993-10-14 Huels Chemische Werke Ag Verfahren zur Produktion von 4,4'-Diaminodicyclohexylmethan mit niedrigem trans-trans-Isomergehalt durch katalytische Hydrogenierung von 4,4'-Diaminodiphenylmethan.
US4923842A (en) * 1988-10-11 1990-05-08 Allied-Signal Inc. Lanthanum containing catalyst for treating automotive exhaust
US5102850A (en) * 1990-10-17 1992-04-07 W. R. Grace & Co. - Conn. Catalyst supports having promoter oxide gradient, resulting catalyst and method of making the supports
FR2689517B1 (fr) * 1992-04-02 1995-07-28 Inst Francais Du Petrole Procede d'hydrogenation selective des hydrocarbures.
US5399535A (en) * 1993-08-17 1995-03-21 Rohm And Haas Company Reticulated ceramic products
DE4328007A1 (de) * 1993-08-20 1995-02-23 Huels Chemische Werke Ag Katalysator zur Herstellung von Bis-Para-aminocyclohexylmethan mit niedrigem Anteil an trans-trans-Isomer durch Hydrierung von Methylendiamin
US6248924B1 (en) * 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
EP0813906A3 (de) * 1996-06-19 1998-11-18 Basf Aktiengesellschaft Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines geträgerten Rutheniumkatalysators
JPH11222447A (ja) * 1998-02-04 1999-08-17 Mitsubishi Chemical Corp 芳香族化合物の部分水素添加によるシクロオレフィン類の製造方法
KR101516812B1 (ko) * 1998-02-16 2015-04-30 스미또모 가가꾸 가부시끼가이샤 염소의 제조방법
DE19827844A1 (de) 1998-06-23 1999-12-30 Aventis Res & Tech Gmbh & Co Verfahren zur Herstellung von Schalenkatalysatoren durch CVD-Beschichtung
DE19832087A1 (de) * 1998-07-16 2000-01-20 Basf Ag Verfahren zur Umsetzung von organischen Verbindungen mit boroxidhaltigen, makroporösen Trägerkatalysatoren
CN1117623C (zh) * 2000-11-23 2003-08-13 中国科学院生态环境研究中心 汽车尾气净化三效催化剂及其制备方法
DE10128205A1 (de) * 2001-06-11 2002-12-12 Basf Ag Ruthenium-Katalysatoren
ATE422962T1 (de) * 2002-05-31 2009-03-15 Evonik Degussa Gmbh Geträgerter rutheniumkatalysator und verfahren zur hydrierung eines aromatischen amins in gegenwart dieses katalysators
DE10253802A1 (de) * 2002-11-18 2004-06-03 Degussa Ag Verfahren zur Hydrierung von aromatischen Urethanen in Gegenwart eines geträgerten Rutheniumkatalysators
DE10253803A1 (de) * 2002-11-18 2004-05-27 Degussa Ag Verfahren zur Herstellung von aliphatischen Isocyanaten aus aromatischen Isocyanaten
US7230035B2 (en) * 2002-12-30 2007-06-12 Conocophillips Company Catalysts for the conversion of methane to synthesis gas
WO2005061106A1 (de) 2003-12-22 2005-07-07 Basf Aktiengesellschaft Ruthenium-heterogenkatalysator, verfahren zur hydrierung einer carbocyclischen aromatischen gruppe und kernhydrierte bisglycidylether der bisphenole a und f

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10128242A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Hydrierung organischer Verbindungen
DE10128204A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen
WO2005061105A1 (de) * 2003-12-22 2005-07-07 Basf Aktiengesellschaft Ruthenium-heterogenkatalysator, kernhydrierte bisglycidylether der bisphenole a und f und verfahren zu ihrer herstellung
DE10361151A1 (de) * 2003-12-22 2005-07-14 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Hydrierung einer carbocyclischen aromatischen Gruppe, insbesondere zur Herstellung eines Bisglycidylethers der Formel I
DE10361157A1 (de) * 2003-12-22 2005-07-21 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I
DE102004055764A1 (de) * 2003-12-22 2006-05-24 Basf Ag Ruthenium-Heterogenkatalysator, kernhydrierte Bisglycidylether der Bisphenole A und F und Verfahren zu ihrer Herstellung

Also Published As

Publication number Publication date
CA2612435C (en) 2015-02-24
WO2006136541A2 (de) 2006-12-28
CA2612435A1 (en) 2006-12-28
KR101354236B1 (ko) 2014-01-22
CN101242895B (zh) 2012-01-11
JP2008543550A (ja) 2008-12-04
US20100152436A1 (en) 2010-06-17
DE102005029200A1 (de) 2006-12-28
CN101242895A (zh) 2008-08-13
US8207327B2 (en) 2012-06-26
KR20080027871A (ko) 2008-03-28
EP1899051A2 (de) 2008-03-19

Similar Documents

Publication Publication Date Title
WO2006136541A3 (de) Ru-katalysator und verfahren zur hydrierung von hydrierbare gruppen enthaltenden organischen verbindungen
TW200700152A (en) Hydrogenation catalyst and hydrogenation method
AR043840A1 (es) Catalizadores de esponja con deposicion de niquel y cobalto
WO2007062148A3 (en) Chemical compounds
WO2007062151A3 (en) Chemical compounds
WO2007062190A3 (en) Chemical compounds
WO2007033348A3 (en) Process for the synthesis of rocuronium bromide
WO2007062145A3 (en) Chemical compounds
WO2007062067A3 (en) Chemical compounds
CL2004001399A1 (es) Catalizador para la hidrogenacion de un compuesto organico que comprende un compuesto de paladio soportado en un material de soporte de alumina, donde dicho catalizador comprende un compuesto de lantanido; y proceso de hidrogenacion que comprende dic
WO2007041451A3 (en) Ruthenium-catalyzed cycloaddition of alkynes and organic azides
WO2004046102A3 (en) Novel graphite nanocatalysts
MY147359A (en) Process for producing product of hydrogenolysis of polyhydric alcohol
AU2002314150A1 (en) Method for hydrogenating organic compounds by means of RU/SIO2 catalysts
EP1997378A3 (de) Repellentien gegen Wespen
WO2009106237A3 (en) Catalyst for the synthesis of alkyl carbamates, the method for preparing the same and the use thereof
BRPI0607784A2 (pt) método para produzir produtos metabólicos secundários de fungos ou bactérias e produto metabólico secundário de fungos ou bactérias, marcado de forma isotópica
WO2005021496A3 (en) Synthesis of derivatives of ginkgolide c
FR2891142B1 (fr) Composition cosmetique comprenant un compose organique du silicium, et procede de mise en forme des cheveux
EP2039693A3 (de) Neuartige Synthese von Irbesartan
CY1110688T1 (el) Διεργασια για την παρασκευη καρβεδιλολης και εναντιομερων αυτης
FR2891141B1 (fr) Composition cosmetique comprenant un compose organique du silicium, et procede de mise en forme des cheveux
WO2009084034A3 (en) Chromane derivatives as trpv3 modulators
MX2009010696A (es) Derivados de 2,6-naftiridina como moduladores de cinasa de proteina.
WO2007047972A3 (en) Process for the preparation of highly pure 1-[2-dimethylamino-(4-methoxyphenyl) ethyl]cyclohexanol hydrochloride

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2612435

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2008517476

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 11993777

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Ref document number: DE

REEP Request for entry into the european phase

Ref document number: 2006777365

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2006777365

Country of ref document: EP

Ref document number: 1020087001732

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 200680030534.2

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2006777365

Country of ref document: EP