WO2006101260A1 - 燃料電池及び燃料電池用セパレータ - Google Patents

燃料電池及び燃料電池用セパレータ Download PDF

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Publication number
WO2006101260A1
WO2006101260A1 PCT/JP2006/306590 JP2006306590W WO2006101260A1 WO 2006101260 A1 WO2006101260 A1 WO 2006101260A1 JP 2006306590 W JP2006306590 W JP 2006306590W WO 2006101260 A1 WO2006101260 A1 WO 2006101260A1
Authority
WO
WIPO (PCT)
Prior art keywords
refrigerant
manifold
flow path
fuel cell
separator
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2006/306590
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
Hiroya Nakaji
Tsutomu Ochi
Chisato Kato
Tsunemasa Nishida
Manabu Takahashi
Yasuyuki Asai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Motor Corp filed Critical Toyota Motor Corp
Priority to CA2602153A priority Critical patent/CA2602153C/en
Priority to DE112006000674.6T priority patent/DE112006000674B4/de
Priority to CN2006800081093A priority patent/CN101138117B/zh
Priority to US11/886,292 priority patent/US9099693B2/en
Publication of WO2006101260A1 publication Critical patent/WO2006101260A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0271Sealing or supporting means around electrodes, matrices or membranes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0267Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2483Details of groupings of fuel cells characterised by internal manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0223Composites
    • H01M8/0228Composites in the form of layered or coated products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0271Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0276Sealing means characterised by their form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the fuel cell of the present invention includes a separator in which a refrigerant flow path is formed, a laminated member laminated on a refrigerant flow path forming surface side of the separator, and the refrigerant flow path interposed between the separator and the laminated member. And a seal part that seals the refrigerant flowing through the separator, wherein a refrigerant regulating part that regulates a refrigerant flow to the seal part side is provided on the inner side in the separator surface direction than the seal part.
  • the fuel cell separator of the present invention is a fuel cell separator provided with a refrigerant flow path and a seal portion that seals the refrigerant flowing through the refrigerant flow path, and is located on the inner side in the separator surface direction than the seal portion.
  • a refrigerant restricting portion for restricting a refrigerant flow to the seal portion side may be provided.
  • the fuel cell is configured by stacking the separator configured as described above as one layered member of the fuel cell together with other layered members, an area where there is no need for cooling, such as the vicinity of the seal portion, that is, outside the power generation area Part of the refrigerant is restricted from flowing into the tank.
  • the separator for a fuel cell according to the present invention is a separator for a fuel cell in which a refrigerant flow path and a manifold for supplying the refrigerant to the refrigerant flow path are formed, and is at least one of the refrigerant regulating portions for regulating the refrigerant flow. A portion may be provided along the opening edge of the manifold.
  • FIG. 2 is a schematic plan view showing the entire separator.
  • Fig. 3 is a cross-sectional view along line AA in Fig. 1.
  • FIG. 4 is an exploded perspective view showing a single cell structure of a fuel cell according to an embodiment of the present invention.
  • FIG. 5 is a perspective view showing a part of a separator of a conventional fuel cell.
  • FIG. 6 is a partial cross-sectional view showing a state in which the separators are stacked.
  • the single cell 2 shown in FIG. 4 is composed of ME A 11 and a pair of separators 14 a and 14 b sandwiching the ME A 11, and has a laminated form as a whole.
  • the MEA 1 1 and the separators 14 a and 14 b are sealed by the first seal members 1 0 1 a and 1 0 1 b at the periphery between them. .
  • a plurality of oxidizing gas flow paths 3 1 a are formed on the inner surface of the separator 14 a that is on the electrode 2 2 a side, and the outer surface on the opposite side (refrigerant flow path shape)
  • a plurality of cooling water main flow paths 32 are formed on the surface.
  • a plurality of hydrogen gas flow paths 31 b are formed on the inner surface of the separator 14 b on the electrode 22 b side, and the opposite outer surface (refrigerant flow path forming surface) is A plurality of cooling water main flow paths 32 are formed.
  • the second seal member 1 0 1 c is similar to the first seal members 1 0 1 a and 1 0 1 b, and the first sub seal portions 1 1 2 c and 1 1 3 c for hydrogen gas and oxidizing gas
  • the first sub seal portion 1 1 6 c and 1 1 7 c for use are separated from the first main seal portion 1 1 1 c.
  • FIG. 1 is an enlarged view of the manifold 14 3 of the separator 14 a (1 4 b) shown in FIG. 4 and its peripheral portion.
  • a plurality of convex ribs 1 3 a are provided between the main hold 4 3 and the cooling water main flow path 3 2 (not shown), and cooling water from the main hold 43 is passed between these ribs 1 3 a. This is the cooling water introduction channel 3 2 a introduced into the cooling water main channel 3 2.
  • a plurality of convex ribs are provided between the cooling water main flow path 3 2 and the hold 5 3, and the cooling water is cooled from the cooling water main flow path 3 2 to the hold 5 3. This is the cooling water outlet flow path 3 2 b for extracting water.
  • the cooling water supplied to the refrigerant flow path forming surface side of the separator 14 a (1 4 b) through the manifold 4 3 is guided to the cooling water main flow path 3 2 through the cooling water introduction flow path 3 2 a. Then, while cooling the power generation region facing the cooling water main flow path 32, it is discharged to the manifold 53 through the cooling water introduction flow path 3 2 b.
  • These cooling water inlet channel 3 2 a and cooling water outlet channel 3 2 b are the same as the main cooling water channel 3 2 described above. It constitutes a part of the refrigerant flow path in Ming.
  • the separators 14 a and 14 b further include a manifold 43, a cooling water introduction passage 32 a, a cooling water main passage 32, a cooling water outlet passage 32 b, and a manifold 53 so as to comprehensively surround the outer periphery.
  • Ribs (refrigerant regulating portions, convex portions) 15 are provided.
  • the outer peripheral rib 15 is composed of a ridge-shaped projection formed in the shape of a bank formed in the separators 14a and 14b, and has a rectangular cross-sectional shape, for example.
  • the outer peripheral rib 15 is located on the inner side in the separator surface direction than the first main seal portion 1 1 1 c of the second seal member 1 0 1 c that seals the refrigerant flowing between the separators 14 a and 14 b.
  • the outer peripheral ribs 15 a and 15 b are connected to the inner walls 15 A and 15 B and the inner walls 43 A and 53 A of the manifolds 43 and 53, respectively. 14 b in the thickness direction), or so as to be substantially flush.
  • the first main seal part 1 1 1 c of the seal member 1 0 1 c is interposed, so that the holdup 4 3, the cooling water introduction flow path 3 2 a, the cooling water main flow path 3 2, and the cooling The cooling water flowing in this order through the water outlet channel 3 2 b and discharged from the manifold 5 3 is liquid-tightly sealed.
  • the outer peripheral rib 15 of the present embodiment is formed integrally with the separators 14 a, 14 b, and the second seal member 10 0 against the compressive load (clamping load) in the cell stacking direction. Since it has a sizing structure that does not easily deform like all other sealing members including 1c, it also functions as a spacer for laminating each separator 14a, 14b at a predetermined interval To do.
  • the flow of the cooling water that leaves the manifold 43 and spreads in the separator surface direction is guided to the power generation region side by the outer peripheral rib 15, thereby 4
  • the second seal as shown by arrow B in FIG. 7 is restricted from flowing into the area between 3 and the second seal member 1001c, that is, the non-heat generation area outside the power generation area.
  • Generation of cooling water flow along the member 1 0 1 c can be suppressed. Therefore, it becomes possible to improve the cooling efficiency of the fuel cell by the cooling water.
  • outer peripheral rib 15 (outer peripheral rib 15 b) is connected to the manifold main section 53 and the first main seal section 1 1 1 c disposed in the vicinity of the second hold section 2 0 2 c.
  • the cooling led out from the cooling water main flow path 3 2 to the hold 5 3 between the opening edge of the ma hold 5 3 and the inner wall 1 5 B of the outer peripheral rib 15 b Since there is no space (redundant gap) that allows water to enter the vicinity of the second manifold 2 0 2 c side, the cooling water exiting the cooling water outlet flow path 3 2 b While being guided by 15 (especially the outer peripheral rib 15 b), it is discharged to the manifold 53 without making a detour.
  • the seal portion interposed between the separator and the laminated member laminated on the refrigerant flow path forming surface side of the separator and sealing the refrigerant flowing through the refrigerant flow path is the second seal member 1 according to the embodiment. It is not limited to gaskets such as 0 1 c, but may be an adhesive. Industrial applicability
  • the refrigerant regulating portion is provided on the inner side in the separator surface direction than the seal portion, it is not necessary to perform cooling, the circulation of the refrigerant to the region is regulated, and the cooling efficiency of the fuel cell Can be improved.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
PCT/JP2006/306590 2005-03-23 2006-03-23 燃料電池及び燃料電池用セパレータ Ceased WO2006101260A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA2602153A CA2602153C (en) 2005-03-23 2006-03-23 Fuel cell and fuel cell separator having a cooling medium regulating portion
DE112006000674.6T DE112006000674B4 (de) 2005-03-23 2006-03-23 Brennstoffzelle und Brennstoffzellen-Separator
CN2006800081093A CN101138117B (zh) 2005-03-23 2006-03-23 燃料电池和燃料电池用隔板
US11/886,292 US9099693B2 (en) 2005-03-23 2006-03-23 Fuel cell and fuel cell separator

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005-084435 2005-03-23
JP2005084435A JP5051606B2 (ja) 2005-03-23 2005-03-23 燃料電池

Publications (1)

Publication Number Publication Date
WO2006101260A1 true WO2006101260A1 (ja) 2006-09-28

Family

ID=37023899

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2006/306590 Ceased WO2006101260A1 (ja) 2005-03-23 2006-03-23 燃料電池及び燃料電池用セパレータ

Country Status (6)

Country Link
US (1) US9099693B2 (enExample)
JP (1) JP5051606B2 (enExample)
CN (1) CN101138117B (enExample)
CA (1) CA2602153C (enExample)
DE (1) DE112006000674B4 (enExample)
WO (1) WO2006101260A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008282776A (ja) * 2007-05-14 2008-11-20 Honda Motor Co Ltd 燃料電池
JP2015097145A (ja) * 2013-11-15 2015-05-21 トヨタ自動車株式会社 燃料電池用セパレータおよび燃料電池スタック

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5248036B2 (ja) * 2007-05-01 2013-07-31 本田技研工業株式会社 燃料電池
JP5202870B2 (ja) * 2007-05-22 2013-06-05 本田技研工業株式会社 燃料電池
KR101106308B1 (ko) * 2010-06-03 2012-01-18 에스비리모티브 주식회사 배터리 팩
JP5809093B2 (ja) * 2012-03-26 2015-11-10 本田技研工業株式会社 燃料電池
JP6036652B2 (ja) 2013-11-11 2016-11-30 トヨタ自動車株式会社 燃料電池に用いられるセパレータおよび燃料電池
JP6098948B2 (ja) 2014-11-06 2017-03-22 トヨタ自動車株式会社 燃料電池用セパレータ、燃料電池セル及び燃料電池
US10340533B2 (en) 2015-07-17 2019-07-02 Nissan Motor Co., Ltd. Fuel cell stack
DE102015220689A1 (de) * 2015-10-22 2017-04-27 Volkswagen Aktiengesellschaft Bipolarplatte für eine Brennstoffzelle und Brennstoffzelle
FR3074969A1 (fr) * 2017-12-13 2019-06-14 Commissariat A L'energie Atomique Et Aux Energies Alternatives Systeme incluant une pile a combustible a membrane echangeuse de protons limitant les fuites de carburant
CN109830705B (zh) * 2019-03-01 2021-02-05 山东大学 一种燃料电池极板结构及电堆
US12355120B2 (en) * 2021-06-10 2025-07-08 Nimbus Power Systems, Inc. Four-fluid bipolar plate for fuel cell
JP7673700B2 (ja) * 2022-07-08 2025-05-09 トヨタ自動車株式会社 燃料電池

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08306371A (ja) * 1995-05-09 1996-11-22 Honda Motor Co Ltd 固体高分子電解質膜型燃料電池の制御方法
JPH09289029A (ja) * 1996-04-24 1997-11-04 Tanaka Kikinzoku Kogyo Kk 固体高分子型燃料電池用ガスシール構造、冷却部構造及びスタック
JP2000228207A (ja) * 1999-02-09 2000-08-15 Nissan Motor Co Ltd 燃料電池用セパレータおよび燃料電池
JP2000231929A (ja) * 1999-02-09 2000-08-22 Honda Motor Co Ltd 燃料電池
JP2001110434A (ja) * 1999-10-08 2001-04-20 Toyota Motor Corp 燃料電池用冷却板
JP2004158217A (ja) * 2002-11-01 2004-06-03 Honda Motor Co Ltd 燃料電池

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JP2002231274A (ja) 2001-02-01 2002-08-16 Fuji Electric Co Ltd 固体高分子型燃料電池
EP1291946A3 (en) * 2001-09-11 2006-03-08 Matsushita Electric Industrial Co., Ltd. Polymer electrolyte fuel cell and conductive separator plate thereof
KR100494402B1 (ko) * 2001-10-16 2005-06-13 마쯔시다덴기산교 가부시키가이샤 고분자 전해질형 연료전지
JP3830805B2 (ja) * 2001-11-07 2006-10-11 本田技研工業株式会社 燃料電池
JP2003157866A (ja) 2001-11-22 2003-05-30 Nok Corp 燃料電池用ガスケット
JP4344500B2 (ja) 2002-01-07 2009-10-14 本田技研工業株式会社 燃料電池
CA2417213C (en) 2002-01-25 2010-09-14 Toyota Jidosha Kabushiki Kaisha Seal arrangement for fuel cells
US20030211376A1 (en) 2002-03-26 2003-11-13 Matsushita Electric Industrial Co., Ltd. Polymer electrolyte fuel cell, method of manufacturing the same and inspection method therefor
JP3599280B2 (ja) 2002-05-17 2004-12-08 本田技研工業株式会社 燃料電池
JP3751911B2 (ja) 2002-07-02 2006-03-08 松下電器産業株式会社 高分子電解質型燃料電池およびそのセパレータ板の製造方法
EP1568092A4 (en) * 2002-11-18 2009-06-17 Protonex Technology Corp ELECTROCHEMICAL CELL STACK ON MEMBRANE BASE
JP2004213972A (ja) 2002-12-27 2004-07-29 Hitachi Ltd 積層形燃料電池
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DE102004021253B4 (de) 2003-05-01 2009-06-04 Honda Motor Co., Ltd. Brennstoffzelle
DE10323882A1 (de) 2003-05-26 2004-12-23 Siemens Ag Brennstoffzelle und Heizeinrichtung einer Brennstoffzelle

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08306371A (ja) * 1995-05-09 1996-11-22 Honda Motor Co Ltd 固体高分子電解質膜型燃料電池の制御方法
JPH09289029A (ja) * 1996-04-24 1997-11-04 Tanaka Kikinzoku Kogyo Kk 固体高分子型燃料電池用ガスシール構造、冷却部構造及びスタック
JP2000228207A (ja) * 1999-02-09 2000-08-15 Nissan Motor Co Ltd 燃料電池用セパレータおよび燃料電池
JP2000231929A (ja) * 1999-02-09 2000-08-22 Honda Motor Co Ltd 燃料電池
JP2001110434A (ja) * 1999-10-08 2001-04-20 Toyota Motor Corp 燃料電池用冷却板
JP2004158217A (ja) * 2002-11-01 2004-06-03 Honda Motor Co Ltd 燃料電池

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008282776A (ja) * 2007-05-14 2008-11-20 Honda Motor Co Ltd 燃料電池
JP2015097145A (ja) * 2013-11-15 2015-05-21 トヨタ自動車株式会社 燃料電池用セパレータおよび燃料電池スタック
WO2015072096A1 (ja) * 2013-11-15 2015-05-21 トヨタ自動車株式会社 燃料電池用セパレータおよび燃料電池スタック
US10658681B2 (en) 2013-11-15 2020-05-19 Toyota Jidosha Kabushiki Kaisha Separator for fuel cell and fuel cell stack

Also Published As

Publication number Publication date
JP2006269208A (ja) 2006-10-05
CA2602153C (en) 2010-11-23
US9099693B2 (en) 2015-08-04
US20080166608A1 (en) 2008-07-10
CA2602153A1 (en) 2006-09-28
DE112006000674B4 (de) 2017-05-24
DE112006000674T5 (de) 2008-05-08
CN101138117A (zh) 2008-03-05
CN101138117B (zh) 2012-11-07
JP5051606B2 (ja) 2012-10-17

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