WO2006070474A1 - 半導体装置の製造方法 - Google Patents
半導体装置の製造方法 Download PDFInfo
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- WO2006070474A1 WO2006070474A1 PCT/JP2004/019646 JP2004019646W WO2006070474A1 WO 2006070474 A1 WO2006070474 A1 WO 2006070474A1 JP 2004019646 W JP2004019646 W JP 2004019646W WO 2006070474 A1 WO2006070474 A1 WO 2006070474A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P50/00—Etching of wafers, substrates or parts of devices
- H10P50/69—Etching of wafers, substrates or parts of devices using masks for semiconductor materials
- H10P50/691—Etching of wafers, substrates or parts of devices using masks for semiconductor materials for Group V materials or Group III-V materials
- H10P50/693—Etching of wafers, substrates or parts of devices using masks for semiconductor materials for Group V materials or Group III-V materials characterised by their size, orientation, disposition, behaviour or shape, in horizontal or vertical plane
- H10P50/696—Process specially adapted to improve the resolution of the mask
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P50/00—Etching of wafers, substrates or parts of devices
- H10P50/69—Etching of wafers, substrates or parts of devices using masks for semiconductor materials
- H10P50/691—Etching of wafers, substrates or parts of devices using masks for semiconductor materials for Group V materials or Group III-V materials
- H10P50/693—Etching of wafers, substrates or parts of devices using masks for semiconductor materials for Group V materials or Group III-V materials characterised by their size, orientation, disposition, behaviour or shape, in horizontal or vertical plane
- H10P50/695—Etching of wafers, substrates or parts of devices using masks for semiconductor materials for Group V materials or Group III-V materials characterised by their size, orientation, disposition, behaviour or shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks or sidewalls or to modify the mask
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P50/00—Etching of wafers, substrates or parts of devices
- H10P50/71—Etching of wafers, substrates or parts of devices using masks for conductive or resistive materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P50/00—Etching of wafers, substrates or parts of devices
- H10P50/73—Etching of wafers, substrates or parts of devices using masks for insulating materials
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P76/00—Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography
- H10P76/40—Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography of masks comprising inorganic materials
- H10P76/408—Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography of masks comprising inorganic materials characterised by their sizes, orientations, dispositions, behaviours or shapes
- H10P76/4085—Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography of masks comprising inorganic materials characterised by their sizes, orientations, dispositions, behaviours or shapes characterised by the processes involved to create the masks
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P76/00—Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography
- H10P76/40—Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography of masks comprising inorganic materials
- H10P76/408—Manufacture or treatment of masks on semiconductor bodies, e.g. by lithography or photolithography of masks comprising inorganic materials characterised by their sizes, orientations, dispositions, behaviours or shapes
- H10P76/4088—Processes for improving the resolution of the masks
Definitions
- the present invention relates to a method for manufacturing a semiconductor device.
- Non-volatile semiconductor memory has a structure in which cell transistors are stacked with floating gates and control gates, and stores bit information by storing charges in the floating gates and changing the threshold value of the transistors.
- flash memories that can be electrically erased are widely used, and there are NOR, NAND, AND, and DINOR types depending on the cell transistor connection method.
- NAND-type flash memory is commonly used as a memory capable of highly integrating cell transistors, and SONOS cells that trap charges in an insulating film instead of floating gates are virtually used. Also known as a grounded array memory! /
- FIG. 1 is a plan view of a conventional NAND flash memory array.
- the planar pattern of the memory array is formed such that the control gate 101 which is a word line and the bit line 102 intersect each other, and the floating gate 103 is formed in the intersecting region.
- the element isolation region 104 is formed so as to extend in a direction perpendicular to the word line 101 and is positioned between the floating gates 103 to isolate adjacent cell transistors.
- the element isolation is generally STI (Shallow Trench Isolation), which is easy to miniaturize.
- An n-type diffusion layer that becomes the source and drain of the cell transistor is formed between adjacent word lines 101.
- the NAND flash memory has a string structure in which n-type transistors are connected in series, and a plurality of these are formed in parallel.
- a page buffer is connected to one end of the NAND string via a selection transistor, and the other end is grounded to the common source region via the selection transistor.
- the line width and spacing of STI, word lines, bit lines, etc. are limited by the minimum processing dimension F determined by the performance of photolithography. Therefore, as shown in Fig. 1, the minimum dimension of each of these line widths and intervals is F, and the minimum wiring pitch is 2F.
- the size is 4F 2 (2F X 2F).
- FIG. 2 (a) A conventional technique for machining with a width smaller than the minimum machining dimension F will be described.
- a silicon nitride film 106 is deposited on the force-treated layer 105, and a mask pattern 107 having a polycrystalline silicon force with a line width F and an interval F is formed.
- FIG. 2 (b) after forming a sidewall film 108 that also has silicon dioxide and silicon power on the sidewall of the mask pattern 107, the mask pattern 107 is removed as shown in FIG. 2 (c). To do. Thereafter, etching is performed using the sidewall film 108 as a mask, and the silicon nitride film 106 is covered.
- the sidewall film 108 is selectively removed, and the etched layer 105 is etched by using the processed silicon nitride film 106a as a mask, so that the minimum coverage is obtained as shown in FIG.
- a wiring pattern 105a having a width xl smaller than the dimension width F is formed.
- the wiring is arranged with a pitch F on average, and the wiring spacing is uneven.
- Non-Patent Document 1 Aritome, S, et.al. 1994 International Electron Devices Meeting
- Non-Patent Document 2 SUNG et al .: FABRICATION AND PROGRAM / ERASE
- the minimum width of the mask pattern for processing the wiring is F and the minimum interval is F. I could't.
- the conventional technique for forming a wiring pattern with a pitch F the side wall film formed on the side wall of the stripe pattern with the line width F and the interval F is masked and subjected to the calorie, so the wiring width is constant. There was a problem that various kinds of things occurred. That is, it is difficult to form a high density pattern having the same dimensions in each of the wiring width and the wiring interval.
- an object of the present invention is to solve the above-described conventional problems and provide a method for manufacturing a semiconductor device having a high degree of integration.
- the present invention includes a step of depositing a first film (11) on a layer to be processed (10a, 10b, 10c), and a predetermined step on the first film.
- the first mask pattern is made of a material having an etching selection ratio with respect to the first film, and the second film is etched with respect to the first film and the first mask pattern.
- the third film is a material having an etching selectivity with respect to the first film.
- the second sidewall film is formed on the vertical surface side and the curved surface side of the first sidewall film, and the second sidewall film is formed on the vertical surface side.
- the method further includes the step of forming the bottom width of the film so that the bottom width of the second sidewall film formed on the curved surface side and the first sidewall film is substantially the same. .
- the present invention includes a step of forming a third mask pattern (11a) by etching the first film using the second mask pattern after the step of forming the second mask pattern. And a step of etching the processed layer using the third mask pattern after removing the second mask pattern.
- the present invention further provides the second mask pattern after the step of forming the second mask pattern.
- the present invention includes a step of sequentially depositing a first gate insulating film and a first conductor layer on the semiconductor substrate to form the work layer, and using the third mask pattern
- the method further includes a step of forming a trench by etching until reaching the semiconductor substrate.
- the present invention includes a step of sequentially depositing a first gate insulating film and a first conductor layer on the semiconductor substrate to form the work layer, and using the second mask pattern
- the method further includes the step of etching to reach the semiconductor substrate to form a trench.
- the method further includes the step of depositing a stopper film (16) that can be removed.
- the first film, the first mask pattern, the second film, and the third film are an insulating film or a polycrystalline silicon film, and the stopper film is a metal film.
- the second sidewall film is formed on the vertical surface side and the curved surface side of the first sidewall film, and the second sidewall film formed on the vertical surface side. And a step of forming the bottom wall width so that the bottom wall width of the second sidewall film formed on the curved surface side and the first sidewall film is substantially the same.
- the present invention further includes, after forming the second mask pattern, etching the stopper film using the second mask pattern to form a third mask pattern (16a); After removing the second mask pattern, etching the first film using the third mask pattern to form a fourth mask pattern (1 la), and after removing the third mask pattern And V, using the fourth mask pattern, and etching the layer to be processed.
- the stopper film and the first film are etched using the second mask pattern to form a fourth mask made of the first film.
- Forming a mask pattern, and the second mask pattern and the third mask pattern And a step of etching the layer to be processed using the fourth mask pattern.
- the present invention includes a step of sequentially depositing a first gate insulating film and a first conductor layer on the semiconductor substrate to form the layer to be processed, and using the fourth mask pattern.
- the step of etching the layer to be processed further includes the step of etching until reaching the semiconductor substrate to form a trench.
- the present invention includes a step of sequentially depositing a first film and a second film on a layer to be processed, and a first mask pattern (18) at a predetermined pitch on the second film. Forming a third film and etching back after depositing the first film on the side wall of the first mask pattern
- the second side film is etched using the first sided film as a mask to form a second mask pattern (17a). And a step of removing the first sidewall film, depositing a fourth film and then etching back to form a second sidewall film (20) on both side walls of the second mask pattern. And etching the second sidewall film so as to leave the second sidewall film (20a) only on one sidewall of the second mask pattern, and the second sidewall left in the etching step. Forming a third mask pattern (15 ′) composed of the film and the second mask pattern. According to the present invention, it is possible to form a stripe pattern having the same pitch as the minimum processing dimension determined by the capability of the photolithographic method, and the same width, and the same interval between the wirings. High semiconductor devices can be provided.
- the present invention further includes a step of forming the second mask pattern and the second sidewall film left in the etching step so as to have substantially the same bottom surface width force.
- the present invention includes a step of forming a fourth mask pattern (11a) by etching the first film using the third mask pattern after the step of forming the third mask pattern. And a step of etching the layer to be processed using the fourth mask pattern.
- the present invention provides the third mask pattern after the step of forming the third mask pattern. And further etching the first film and the layer to be processed. The invention's effect
- FIG. 1 is a plan view of a conventional NAND flash memory array.
- FIG. 2 is a cross-sectional view of a manufacturing process of a conventional semiconductor device.
- FIG. 3 is a plan view of a NAND flash memory array according to the present invention.
- FIG. 4 is a cross-sectional view taken along line AA ′ in FIG.
- FIG. 5 is a cross-sectional view taken along the line BB ′ in FIG.
- FIG. 6 is a cross-sectional view of a manufacturing process in the first embodiment.
- FIG. 7 is a cross-sectional view of a manufacturing process in the first embodiment.
- FIG. 8 is a cross-sectional view of a manufacturing process in the second embodiment.
- FIG. 9 is a sectional view of a manufacturing process in the second embodiment.
- FIG. 10 is a plan view of a NAND flash memory array according to the present invention.
- FIG. 11 is a cross-sectional view of a manufacturing process in a first modification of the second embodiment.
- FIG. 12 is a cross-sectional view of a manufacturing process in a second modification of the second embodiment.
- FIG. 13 is a cross-sectional view of a manufacturing process in a second modification of the second embodiment.
- FIG. 14 is a plan view of a bit line contact portion of a NAND flash memory array according to the present invention.
- FIG. 15 is a cross-sectional view along CC ′ in FIG.
- FIG. 16 is a cross-sectional view of a manufacturing process in a third modification of the second embodiment.
- FIG. 17 is a cross-sectional view of a manufacturing process in a third modification of the second embodiment.
- FIG. 18 is a cross-sectional view of a manufacturing process in a fourth modification of the second embodiment.
- FIG. 19 is a cross-sectional view of a manufacturing process in a fourth modification of the second embodiment.
- FIG. 3 is a plan view of a NAND flash memory array according to the present invention
- FIG. 4 is a cross-sectional view taken along the line AA ′ in FIG. 3
- FIG. 5 is a cross-sectional view taken along the line BB ′ in FIG. FIG.
- the planar pattern of the memory cell array is formed so that the control gate 8 and the bit line 10 intersect each other, and the floating gate 6 is formed in these intersecting regions.
- the element isolation region 3 is formed perpendicular to the control gate 8 and is located between the floating gates 6 so as to isolate adjacent cell transistors. As shown in FIG. 4, the memory cell array is formed on the surface of the silicon substrate 1. A trench 2 is formed in the silicon substrate 1, and an insulating film 3 for element isolation is embedded in the trench 2.
- the n-type diffusion layer 4 of the cell transistor is formed on the surface of the silicon substrate (semiconductor substrate) 1 so that the cell transistors are connected in series.
- a gate insulating film 5 which is a tunnel oxide film and a floating gate 6 are sequentially formed.
- the floating gate 6 is separated for each memory cell and is made of polycrystalline silicon.
- a control gate 8 is formed on the floating gate 6 via a second gate insulating film 7 having an ONO structure.
- the ONO structure is a three-layer structure composed of a silicon dioxide film, a silicon nitride film, and a silicon dioxide film, and is shown as one layer in the figure for simplicity.
- the control gate 8 has a two-layer structure of a polycrystalline silicon film 8a and a tungsten 'silicide layer 8b, which becomes a word line.
- the bit line 10 is formed through an interlayer insulating film (BPSG film) 9 made of BPSG (Boron Phosphorous Silicate Glass), and is made of aluminum.
- BPSG film interlayer insulating film
- a TiZTiN film 10a, an aluminum film 10b, and a TiN film 10c to be processed are deposited on the BPSG film 9 deposited on the control gate.
- a silicon nitride film (first film) 11 is deposited on the layer to be carburized.
- This first film is preferably an insulating film or a polycrystalline silicon film.
- the silicon nitride film 11 is selected as a film to be formed on the bit line 10 which is a layer to be processed, but a mask for finally processing the bit line 10 by RIE (Reactive Ion Etching). Therefore, the film is not limited to this as long as it has a sufficient etching selectivity with respect to the layer to be processed.
- the etching selectivity can be taken when two films are formed and one film is difficult to be etched and the other film is easily etched.
- a mask pattern (first mask pattern) 12 having a line width and a spacing force is formed by a polycrystalline silicon film with a thickness of about FZ2 by a photolithography method having a minimum cache dimensional force.
- the mask pattern 12 is formed on the silicon nitride film 11 at a predetermined pitch.
- This mask pattern 12 is composed of a polycrystalline silicon film.
- This mask pattern 12 may be an insulating film.
- a silicon dioxide film (second film) 13 having a thickness of about FZ4 is deposited by the CVD (Chemical Vapor D mark osition) method.
- Etching back by the RIE method forms a sidewall film (first sidewall film) 13a on the sidewall of the mask pattern 12, as shown in FIG. 6 (c).
- the bottom surface width of the sidewall film 13a is formed to be narrower than FZ4.
- the second film is preferably an insulating film or a polycrystalline silicon film.
- the mask pattern 12 of the polycrystalline silicon film is selectively etched with respect to the sidewall film 13a of the silicon dioxide film and the silicon nitride film 11 by using an etching solution having an etching selectivity.
- the silicon dioxide film (third film) 14 is deposited thicker (thicker than FZ2) than when the silicon dioxide film 13 is formed. Etching may be carried out using a fluorinated nitric acid-based chemical or by RIE. good.
- the third film is preferably an insulating film or a polycrystalline silicon film.
- the silicon dioxide film 14 is etched back by the RIE method, so that the sidewall film is formed on the side wall surface perpendicular to the sidewall film 13a as shown in FIG. 6 (e).
- a (second sidewall film) 14a is formed on the curved surface side, and a sidewall film (second sidewall film) 14b is formed.
- the sidewall film 14a is formed so that the bottom surface width is FZ2, and the combined bottom wall width of the sidewall film 13a and the sidewall film 14b is also F / 2. That is, the bottom surface width of the sidewall film 14a formed on the vertical surface side and the bottom surface width of the combined sidewall film 14b and sidewall film 13a formed on the curved surface side are substantially the same. .
- the sidewall film 14b is formed thinner than the sidewall film 14a. This is also the force with which the silicon dioxide film 14 is formed thicker on the vertical surface side of the sidewall film 13a than the curved portion of the sidewall film 13a.
- the second silicon oxide film 14 is made thicker than the first silicon oxide film 13.
- Etch back the silicon oxide film 14 for the second time so that the bottom surface width of the sidewall film 14a becomes the sw force FZ2.
- the thickness of the first silicon oxide film 13 in (1) is set in consideration of the bottom surface width of the sidewall film 14b formed by the second etch back of the silicon oxide film 14. .
- a mask pattern (second mask pattern) 15 having a line width of F / 2 and an interval of about FZ2 is completed by the three sidewall films 13a, 14a and 14b.
- the bottom width xl and the interval xs of the mask pattern 15 are about FZ2, respectively, but when forming the three sidewall films described above, the bottom width thereof is adjusted.
- the mask pattern 15 having a desired line width and interval can be formed.
- the silicon nitride film 11 is etched by the RIE method using the mask pattern 15. Thereafter, the silicon oxide film mask pattern 15 is selectively removed by etching with an etching solution such as HF (hydrofluoric acid) solution, and as shown in FIG. Third mask pattern) 11a is formed. Next, as shown in FIG. 7 (g), the mask pattern 11a is used to etch the TiZTiN film 10a, the aluminum film 1Ob, and the TiN film 10c, which are the layers to be coated, by the RIE method. Form.
- an etching solution such as HF (hydrofluoric acid) solution
- the bit line 10 may be formed by etching the silicon nitride film 11, the Ti ZTiN film 10a, the aluminum film 10b, and the TiN film 10c by the RIE method using the mask pattern 15. .
- the bit line forming method of the NAND flash memory in the photolithography method having the minimum cache size F, the wiring width and the wiring interval with the pitch force. Each can form a fine pattern formed with the same dimensions.
- the present invention is not limited to the bit line of the NAND flash memory, and the same applies to the word line. In addition, it is of course applicable to obtaining fine wiring patterns of semiconductor devices other than memories.
- FIGS. 8 (a)-(d) and 9 (e). ) the specific manufacturing process of STI is shown in FIGS. 8 (a)-(d) and 9 (e). ) —Explain with reference to (g).
- a silicon dioxide film (first gate insulating film) 5 that becomes a tunnel oxide film
- a polycrystalline silicon film (first film) that becomes a floating gate.
- One conductor layer) 6 and a silicon nitride film 11 are sequentially deposited.
- the silicon dioxide film 5 and the polycrystalline silicon film 6 are processed layers.
- a mask pattern 12 having a line width and an interval of the minimum processing dimension F is formed with a polycrystalline silicon film by photolithography.
- a mask having a line width of about FZ2 and an interval of about FZ2 is formed by the sidewall films 13a, 14a and 14b by the same manufacturing method as the bit line forming method described above.
- RIE is performed using the mask pattern 15, and then the silicon oxide film mask pattern 15 is removed by etching with an etchant such as HF solution as shown in FIG. 8C.
- an etchant such as HF solution as shown in FIG. 8C.
- the mask pattern 11a of the silicon nitride film is formed.
- the mask pattern 15 may be left without being etched as will be described later.
- FIG. 8 (d) by using the mask pattern 11a, the polycrystalline silicon layer 6, the silicon dioxide silicon film 5, and the silicon substrate 1 are etched by the RIE method to form the floating gate 6a. Trenches 2 are formed. In the process of etching the target layer using the mask pattern 1 la, the trench 2 is formed by etching until reaching the silicon substrate 1.
- the depth of trench 2 is set in consideration of the punch-through withstand voltage between adjacent elements.
- the mask pattern 11a may have a thickness corresponding to the depth at which the trench 2 is formed.
- a silicon dioxide film is deposited by CVD so that the trench 2 is sufficiently filled.
- TEOS Tetra Ethyl Ortho Silicate
- CMP Chemical Mechanical Polish
- an ONO layer 7 is formed as a second gate insulating film.
- a polycrystalline silicon film 8a and a WSi (tungsten silicide) film 8b are sequentially deposited and processed by photolithography to form the control gate 8.
- the control gate 8 is covered with the minimum processing dimension F by a known manufacturing method.
- an n-type diffusion layer that becomes the source and drain of the cell transistor is formed by ion implantation, and a BPSG film 9 is deposited.
- the STI formation method of the NAND flash memory according to the second embodiment as described above even in the photolithography method having the minimum cache size F, the pitch is F, the STI wiring width and Fine patterns with equal wiring intervals can be obtained, and at the same time, floating gates having the same pattern can be formed.
- bit lines and STIs arranged at a pitch F are obtained, and word lines are formed at a pitch 2F by a conventional manufacturing method, as shown in FIG.
- the arrangement and formation method of the bit line contacts will be described.
- FIG. 14 is a plan view of the vicinity of the bit line contact in the NAND flash memory array of the present invention.
- both word line patterns of 16 units not shown in the figure are used.
- select gates 8 ' are arranged, and on one of the select gates shown in the figure, the bit line 10 is in contact with the substrate, that is, the drain diffusion layer.
- 16 word line patterns with selection gates on both sides are arranged so that they are mirror images of the common source region. Is taken. Therefore, there are 4 select gates and 32 word lines between two contacts on the same bit line.
- FIG. 14 is a cross-sectional view taken along the line CC ′ of FIG.
- a contact plug 23 made of tungsten is formed in a contact hole opened with a diameter F in the BPSG film 9 deposited on the substrate 1, and the bit line 10 is connected to the n-type diffusion layer 24 which is a drain region.
- bit line contacts are formed in a zigzag shape, the degree of integration slightly decreases in the direction in which the bit lines extend.
- peripheral circuits according to the memory cell array.
- page buffers are arranged on both sides of the memory array, and bit lines are alternately connected to both page buffers. It can be formed by the following manufacturing method.
- word decoders are arranged on both sides of a memory array for word lines arranged at a narrow pitch, and they are alternately arranged on both decoders in units of several word lines.
- the circuit in the decoder can be formed by a conventional manufacturing method.
- the word decoder is driven at a voltage Vpp higher than the voltage Vcc used in peripheral circuits such as a page buffer, a large transistor size is required.
- FIG. 10 shows a plan view of the NAND flash memory in the case where the lead wires are formed by the same manufacturing method as described in the first embodiment.
- 1 cell size is F 2, which is manufactured in the conventional method Compared to the case of building, it is a quarter size.
- the silicon nitride film 1 1 The surface is slightly etched. Since the silicon nitride film 11 is used as a mask when the work layer is masked by RIE, the surface is not etched much and a flat surface state is formed before the mask pattern is formed. It is desirable to be. If the surface of the silicon nitride film 11 is flat, the mask pattern 15 can be formed with higher accuracy.
- the mask pattern 12 is made of a material having an etching selection ratio with respect to the silicon nitride film 11 serving as the first film, and the silicon dioxide film 13 serving as the second film is the first film.
- the silicon nitride film 11 and the mask pattern 12 to be used are materials having an etching selectivity, and the silicon nitride film 14 to be a third film is a material having an etching selectivity to the silicon nitride film 11 to be a first film. It ’s good!
- a silicon substrate 1 is formed on a silicon dioxide film 5 serving as a tunnel oxide film, a polycrystalline silicon film 6 serving as a floating gate, a silicon nitride film 11 and a tungsten film. Deposit 16 in order.
- a mask pattern 12 having a line width and interval of the minimum processing dimension F is formed by a photolithographic method using a polycrystalline silicon film having a thickness of about FZ2.
- the mask pattern 15 composed of the three side films 13a, 14a, and 14b is formed by the same manufacturing method as in the first embodiment described above. ⁇ ⁇ Formed with a silicon film.
- the tungsten film 16 is a stopper film used for the purpose of not etching the silicon nitride film 11 on the layer to be processed during etching in the process of forming the mask pattern 15.
- a metal film having a sufficient etching selectivity with respect to the insulating films of the polycrystalline silicon film 12 the silicon dioxide films 13, 14a, and the silicon nitride film 11, a tungsten film 16
- the tungsten film 16 is etched by the RIE method using the mask pattern 15 to form a mask pattern (third mask pattern) 16a.
- the mask 15 of the silicon dioxide film is etched away with HF solution, and the exposed tungsten film 16a is masked as shown in FIG. 11 (d), and the silicon nitride film 11 is removed by the RIE method.
- Etching is performed to form a mask pattern (fourth mask pattern) 11a made of a silicon nitride film.
- the tungsten film 16a is removed, and the target layers 5 and 6 are etched using the mask pattern 1la. In the step of etching the target layers 5 and 6 using the mask pattern 11a, etching is performed until the silicon substrate 1 is reached, thereby forming a trench.
- the mask pattern 15 is used to etch the tungsten film 16 and the silicon nitride film 11 by the RIE method, and then the mask pattern 15 and the mask are formed.
- the formed tungsten film 16a may be sequentially removed to form a mask pattern 11a made of a silicon nitride film.
- the STI and the floating gate are formed by the same manufacturing method as in the second embodiment described above.
- the surface of the silicon nitride film serving as a mask for processing the layer to be processed is formed. It can be obtained in a flat state before it is processed, and the subsequent etching process of the layer to be processed can be performed with high accuracy.
- the STI formation method has been described as an example, but the present invention can be applied to processing of a wiring such as a bit line by a similar manufacturing method.
- FIGS. 12 (a)-(d) and 13 (e)-(h) the second embodiment of the second embodiment is used.
- a modification will be described.
- a silicon dioxide film 5 serving as a tunnel oxide film and a polycrystalline silicon film 6 serving as a floating gate are deposited on the silicon substrate 1.
- a silicon nitride film (first film) 11 is formed on the layer to be processed. The process up to this point is the same as the manufacturing method described in the second embodiment.
- the silicon dioxide film 5 and the polycrystalline silicon film 6 are processed layers.
- a mask pattern (first mask pattern) 18 having a minimum processing dimension F is formed on the polycrystalline silicon film 17 using a silicon nitride film. At a predetermined pitch.
- etch back is performed, and as shown in FIG. 12 (a), a sidewall film (first side wall film) is formed on the side wall of the mask pattern 18. 19 is formed.
- the mask pattern 18 is removed by etching, leaving the sidewall film 19.
- the polycrystalline silicon film 17 is etched by the RIE method to form a mask pattern (second mask pattern) 17a.
- the mask pattern 19 of the silicon dioxide film is selectively etched away with an HF solution or the like, and then silicon dioxide film (fourth film) is deposited and etched back. As shown in FIG. 12 (d), a sidewall film (second sidewall film) 20 is formed on the sidewall of the mask pattern 17a.
- the bottom surface width of the sidewall film 20 is equal to the bottom surface width of the polycrystalline silicon film 16a formed earlier, that is, the bottom surface width sw of the sidewall film 19 described with reference to FIG. To form.
- the bottom width sw should be about FZ4.
- each of the photoresist 21a and the photoresist 21b is alternately arranged so that the ends thereof are located on the adjacent polycrystalline silicon film 17a. Form in order.
- the photoresists 21a and 21b can be aligned within the margin of the width of the polycrystalline silicon film 17a (about FZ4 in FIG. 13 (e)).
- the side wall film 20 is selected so that the side wall film 20a is left only on one side wall of the mask pattern 17a using the photoresists 21a and 21b as a mask. Etch. Thereafter, as shown in FIG.
- a mask pattern (third mask pattern) 15 is formed, which is formed only on the sidewall film 20a and has a bottom surface width of about FZ4. Therefore, the bottom surface widths of the mask pattern 17a and the sidewall film 20a left in the etching process are formed to be substantially the same.
- the bottom width of the mask pattern 15 ' is about FZ2.
- the bottom width xl of the mask pattern 15 'and the distance xs are forces that are about FZ2, respectively.
- the bottom width By adjusting sw, a mask pattern 15 ′ having a desired line width and interval can be formed.
- the silicon nitride film 11 is etched by the RIE method, and then the mask pattern 15 ′ is selectively etched.
- a mask pattern (fourth mask pattern) 11a of the silicon nitride film is formed.
- the mask pattern 11a is used to etch the silicon dioxide film 5 and the polycrystalline silicon film 6 to be processed, and the STI is manufactured by the same manufacturing method as described in the second embodiment. And a floating gate is formed.
- the silicon dioxide film 5 and the polycrystalline silicon film 6 are the layers to be coated.
- the mask pattern 15 ′ is used to form the silicon nitride film 11 serving as the first film, the silicon dioxide film 5 serving as the layer to be processed, and the polycrystalline silicon.
- the film 6 may be etched.
- a mask pattern having a pitch F can be formed by a manufacturing method different from that described in the first and second embodiments.
- the STI formation method has been described as an example.
- the same manufacturing method can be applied to processing of wiring such as a bit line.
- FIG. 11 As a first modification of the second embodiment, an additional step of forming a stopper film 16 on the silicon nitride film 11 on the work layer is added. The form was explained. Next, with respect to the second modification of the second embodiment, on the layer to be processed An embodiment in which a step of forming a stopper film 16 on the silicon nitride film 11 will be described with reference to FIGS. 16 and 17.
- FIG. 16 and 17 are cross-sectional views of the manufacturing process in the third modification of the second embodiment.
- a nitric acid silicon film 5 to be a tunnel acid film and a polycrystalline silicon film 6 to be a floating gate are deposited on the silicon substrate 1. Further, a silicon nitride film 11 and a tungsten film 16 are sequentially deposited on the work layer. The silicon dioxide film 5 and the polycrystalline silicon film 6 are the layers to be coated. The tungsten film 16 is a stopper film used for the purpose of not etching the silicon nitride film 11 on the target layer during the etching in the process of forming the mask pattern 15.
- a mask pattern 18 having a minimum processing dimension F is formed on the polycrystalline silicon film 17 with predetermined pits using a silicon nitride film.
- etch back is performed to form a sidewall film 19 on the side wall of the mask pattern 18 as shown in FIG.
- the mask pattern 18 is removed by etching, leaving the sidewall film 19.
- the polycrystalline silicon film 17 is etched by the RIE method using the sidewall film 19 to form a mask pattern 17a.
- the sidewall film 19 of the silicon dioxide film is selectively removed by etching with an HF solution or the like, and then silicon dioxide film is deposited and etched back to obtain the structure shown in FIG. As shown, a sidewall film 20 is formed on the sidewall of the mask pattern 17a.
- the bottom surface width of the sidewall film 20 is equal to the bottom surface width of the previously formed polycrystalline silicon film 16a, that is, the bottom surface width sw of the sidewall film 19 described with reference to FIG. To form.
- the bottom width sw should be about FZ4.
- each of the photoresist 21a and the photoresist 21b is arranged alternately so that each end is located on the adjacent polycrystalline silicon film 17a. Form in order.
- the photoresists 21a and 21b can be aligned within the margin of the width of the polycrystalline silicon film 17a (about FZ4 in FIG. 17E).
- the side wall film 20 is selected so that the side wall film 20a is left only on one side wall of the mask pattern 17a using the photoresists 21a and 21b as a mask. Etch. Thereafter, as shown in FIG. 17 (g), by removing the photoresists 21a and 21b, a rectangular polycrystalline silicon film 17a having a width of about FZ4 is left in the etching process, and one side wall thereof is left.
- the bottom width of the mask pattern 15 is about FZ2.
- the silicon nitride film 11 is etched by the RIE method using the mask pattern 15 ′′, and then the mask pattern 15 ′ ′ is selectively etched.
- the mask pattern 11a of the silicon nitride film is formed, and the subsequent process uses the mask pattern 11a to etch the silicon dioxide film 5 and the polycrystalline silicon film 6 to be processed.
- the STI and the floating gate are formed by the same manufacturing method as described in the second embodiment, and after the process of forming the mask pattern 15 ′ ′, the mask pattern 15 ′ ′ is used to form the first pattern.
- the silicon nitride film 11 to be a film, the silicon dioxide film 5 to be processed, and the polycrystalline silicon film 6 may be etched.
- a mask pattern having a pitch F can be formed by a manufacturing method different from that described in the first and second embodiments.
- the STI formation method has been described as an example.
- the same manufacturing method can be applied to processing of wiring such as a bit line.
- FIGS. 18 and 19 are cross-sectional views of the manufacturing process in the fourth modification of the second embodiment.
- a silicon dioxide film 5 serving as a tunnel oxide film
- a polycrystalline silicon film 6 serving as a floating gate
- a second film having an ONO structure on a silicon substrate 1
- a gate insulating film 7, a polycrystalline silicon film 8a, a tungsten silicide layer 8b, a silicon dioxide silicon film 25, a silicon nitride film 11, and a tungsten film 16 are sequentially deposited.
- Silicon dioxide film 5 polycrystalline silicon film 6, second gate insulating film 7, polycrystalline silicon film 8a, tungsten 'silicide layer 8b Becomes the coated layer.
- the polycrystalline silicon film 8a and the tungsten 'silicide layer 8b become the control gate 8, which becomes the word line.
- a mask pattern 12 having a line width and interval of the minimum cache size F is formed by a photolithographic method using a polycrystalline silicon film having a thickness of about FZ2.
- a mask pattern 15 composed of the three sidewall films 13a, 14a and 14b is formed of a silicon dioxide film by the same manufacturing method as in the first embodiment described above.
- the tungsten film 16 is a stopper film used for the purpose of not etching the silicon nitride film 11 on the layer to be processed during etching in the process of forming the mask pattern 15 ′ ′′.
- the tungsten film 16 is etched by the RIE method using the mask pattern 15 ”to form the mask pattern 16a. Thereafter, the diacid salt is formed by HF solution.
- the silicon film mask 15 ′ ′′ is removed by etching, the exposed tungsten film 16a is masked, and the silicon nitride film 11 is etched by RIE to form a mask pattern 11a of the silicon nitride film.
- the tungsten film 16a is removed, and the silicon dioxide film 5, the polycrystalline silicon film 6, the second gate insulating film 7, and the polycrystalline film are formed using the mask pattern 11a.
- the silicon film 8a, the tungsten 'silicide layer 8b, and the silicon dioxide film 25 are etched.
- an n-type diffusion layer 4 serving as the source and drain of the cell transistor is formed by ion implantation, and after the BPSG film 9 is deposited, etching is performed using the CMP method until the mask pattern 11a disappears. Thereafter, the contact is opened, and the bit line 10 is formed by the method described in the first embodiment.
- NAND flash memory having a quarter cell size can be manufactured.
Landscapes
- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
- Drying Of Semiconductors (AREA)
- Element Separation (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2004/019646 WO2006070474A1 (ja) | 2004-12-28 | 2004-12-28 | 半導体装置の製造方法 |
| JP2006550540A JPWO2006070474A1 (ja) | 2004-12-28 | 2004-12-28 | 半導体装置の製造方法 |
| US11/317,083 US9299578B2 (en) | 2004-12-28 | 2005-12-21 | Transistor formation method using sidewall masks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2004/019646 WO2006070474A1 (ja) | 2004-12-28 | 2004-12-28 | 半導体装置の製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US11/317,083 Continuation US9299578B2 (en) | 2004-12-28 | 2005-12-21 | Transistor formation method using sidewall masks |
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| WO2006070474A1 true WO2006070474A1 (ja) | 2006-07-06 |
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| PCT/JP2004/019646 Ceased WO2006070474A1 (ja) | 2004-12-28 | 2004-12-28 | 半導体装置の製造方法 |
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| Country | Link |
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| US (1) | US9299578B2 (ja) |
| JP (1) | JPWO2006070474A1 (ja) |
| WO (1) | WO2006070474A1 (ja) |
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| JP2009164205A (ja) * | 2007-12-28 | 2009-07-23 | Tokyo Electron Ltd | パターン形成方法、半導体製造装置及び記憶媒体 |
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| JP2010511306A (ja) * | 2006-11-29 | 2010-04-08 | マイクロン テクノロジー, インク. | 半導体デバイスのクリティカルディメンジョンを縮小する方法、及び、部分的に作製される縮小クリティカルディメンジョンを有する半導体デバイス |
| JP2011507308A (ja) * | 2007-12-18 | 2011-03-03 | マイクロン テクノロジー, インク. | ピッチマルチプリケーションされた材料のループの一部分を分離するための方法およびその関連構造 |
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| JP2024044090A (ja) * | 2022-09-20 | 2024-04-02 | キオクシア株式会社 | 半導体記憶装置、および半導体装置の製造方法 |
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| JP2010501119A (ja) * | 2006-08-16 | 2010-01-14 | サンディスク コーポレイション | 成形されたフローティングゲートを持つ不揮発性メモリ |
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| JP2010511306A (ja) * | 2006-11-29 | 2010-04-08 | マイクロン テクノロジー, インク. | 半導体デバイスのクリティカルディメンジョンを縮小する方法、及び、部分的に作製される縮小クリティカルディメンジョンを有する半導体デバイス |
| US8338304B2 (en) | 2006-11-29 | 2012-12-25 | Micron Technology, Inc. | Methods to reduce the critical dimension of semiconductor devices and related semiconductor devices |
| US10515801B2 (en) | 2007-06-04 | 2019-12-24 | Micron Technology, Inc. | Pitch multiplication using self-assembling materials |
| JP2009038382A (ja) * | 2007-08-03 | 2009-02-19 | Samsung Electronics Co Ltd | ビットラインレイアウトの構造を改善したフラッシュメモリ装置及びそのレイアウト方法 |
| US9941155B2 (en) | 2007-12-18 | 2018-04-10 | Micron Technology, Inc. | Methods for isolating portions of a loop of pitch-multiplied material and related structures |
| US8932960B2 (en) | 2007-12-18 | 2015-01-13 | Micron Technology, Inc. | Methods for isolating portions of a loop of pitch-multiplied material and related structures |
| US9666695B2 (en) | 2007-12-18 | 2017-05-30 | Micron Technology, Inc. | Methods for isolating portions of a loop of pitch-multiplied material and related structures |
| JP2011507308A (ja) * | 2007-12-18 | 2011-03-03 | マイクロン テクノロジー, インク. | ピッチマルチプリケーションされた材料のループの一部分を分離するための方法およびその関連構造 |
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| JP2009164205A (ja) * | 2007-12-28 | 2009-07-23 | Tokyo Electron Ltd | パターン形成方法、半導体製造装置及び記憶媒体 |
| JP2013172070A (ja) * | 2012-02-22 | 2013-09-02 | Toshiba Corp | 半導体装置および半導体装置の製造方法 |
| JP2014053565A (ja) * | 2012-09-10 | 2014-03-20 | Toshiba Corp | 半導体記憶装置およびその製造方法 |
| JP2024044090A (ja) * | 2022-09-20 | 2024-04-02 | キオクシア株式会社 | 半導体記憶装置、および半導体装置の製造方法 |
| JP7853180B2 (ja) | 2022-09-20 | 2026-04-28 | キオクシア株式会社 | 半導体記憶装置、および半導体装置の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US9299578B2 (en) | 2016-03-29 |
| US20060276032A1 (en) | 2006-12-07 |
| JPWO2006070474A1 (ja) | 2008-06-12 |
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