WO2006034853A1 - Mischkneter sowie verfahren zur herstellung von poly(meth)acrylaten unter verwendung des mischkneters - Google Patents
Mischkneter sowie verfahren zur herstellung von poly(meth)acrylaten unter verwendung des mischkneters Download PDFInfo
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- WO2006034853A1 WO2006034853A1 PCT/EP2005/010469 EP2005010469W WO2006034853A1 WO 2006034853 A1 WO2006034853 A1 WO 2006034853A1 EP 2005010469 W EP2005010469 W EP 2005010469W WO 2006034853 A1 WO2006034853 A1 WO 2006034853A1
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- WIPO (PCT)
- Prior art keywords
- mixing kneader
- opening
- waves
- product removal
- shaft
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
- B01F27/70—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with paddles, blades or arms
- B01F27/701—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with paddles, blades or arms comprising two or more shafts, e.g. in consecutive mixing chambers
- B01F27/702—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with paddles, blades or arms comprising two or more shafts, e.g. in consecutive mixing chambers with intermeshing paddles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/45—Closures or doors specially adapted for mixing receptacles; Operating mechanisms therefor
- B01F35/452—Closures or doors specially adapted for mixing receptacles; Operating mechanisms therefor by moving them in the plane of the opening
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/45—Closures or doors specially adapted for mixing receptacles; Operating mechanisms therefor
- B01F35/453—Closures or doors specially adapted for mixing receptacles; Operating mechanisms therefor by moving them perpendicular to the plane of the opening
- B01F35/4531—Closures or doors specially adapted for mixing receptacles; Operating mechanisms therefor by moving them perpendicular to the plane of the opening and moving them afterwards in another direction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/90—Heating or cooling systems
- B01F35/95—Heating or cooling systems using heated or cooled stirrers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
- B29B7/481—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws provided with paddles, gears or discs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
- B29B7/488—Parts, e.g. casings, sealings; Accessories, e.g. flow controlling or throttling devices
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
- B29B7/488—Parts, e.g. casings, sealings; Accessories, e.g. flow controlling or throttling devices
- B29B7/489—Screws
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/582—Component parts, details or accessories; Auxiliary operations for discharging, e.g. doors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/60—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
- B29B7/826—Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/90—Heating or cooling systems
- B01F2035/98—Cooling
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
- B29B7/485—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws with three or more shafts provided with screws
Definitions
- the invention relates to a mixing kneader having at least two corrugations, on the surfaces of which kneading bars are arranged on webs, and to a process for the preparation of poly (meth) acrylates using the mixing kneader.
- a mixing kneader with at least two axially parallel rotating shafts, on the surfaces of which surface surfaces of discs with kneading bars arranged on their circumference, is provided, e.g. from EP-A 0 517 068 known.
- the kneading bars are arranged so that those on one shaft engage in those on the other shaft.
- the number of kneading bars on the shafts may vary.
- a speed ratio of 1: 4 e.g. 8 kneading bars arranged on the circumference of the main shaft and 2 kneading bars on the second wave as the cleaning shaft, which rotates four times as fast as the main shaft.
- the kneading bars of the cleaning shaft also serve to clean the main shaft.
- they can be designed to oscillate back and forth in the axial direction as described in EP-A 0 603 525.
- An improved promotion of the product in the mixing kneader can be achieved in that the webs on which the kneading bars are mounted, axially offset or are arranged at an angle to the shaft axis, so that by the webs a helical gear is ge forms.
- Such an arrangement of the webs on the shafts is e.g. from WO 97/12666.
- WO-A 2004/022608 discloses the use of a mixing kneader with two rotatably mounted shafts, on the surfaces of which kneading bars are arranged, for the production of superabsorbents.
- Superabsorbers are gelatinous polymers. The polymerization is carried out either in a homogeneous aqueous monomer solution or in a heterogeneous base oil mixture.
- the use of the mixing kneader as the polymerization reactor produces small gel particles.
- the polymerization of monomers into water-absorbing, water-insoluble polymers in a reactor system comprising at least three zones is described in WO-A 03/022896.
- a monomer, an initiator and water are continuously fed in the first zone under conditions such that the polymerization of the monomer is initiated.
- a gel phase which is produced by the polymerization of the monomer and in the third zone the gel phase is granulated.
- WO-A-01/38402 also discloses a process for the continuous production of crosslinked finely divided gel-like polymerization.
- the reaction is carried out in a mixing kneader with at least two axially parallel rotating waves, which are several kneading and transport elements on the waves, which cause a promotion of the added at the beginning of the mixing kneader material in the axial direction to the end of the mixer.
- a disadvantage of the mixing kneaders known from the prior art is that with the anticipated and required drives due to the polymerization and the product consistency associated therewith, large shearing forces can occur in the mixing kneader which lead to cracking in the shafts and damage to the kneading bars being able to lead.
- the object of the invention is to provide a mixing kneader on a production scale whose waves are mechanically stable against the high shear forces occurring.
- a further object of the invention is to provide a process for preparing poly (meth) acrylates which can be operated continuously over a relatively long period of time.
- a mixing kneader comprising at least two shafts, on the surfaces of which kneading bars are arranged on webs and which are surrounded by a housing in which at least one opening above the shafts and at least one opening for product removal are formed the shafts are at least simply rotatably mounted at both ends and driven at least at one end. At least one of the following features is guaranteed:
- the construction of the waves is designed so that the bending natural frequencies of the waves have a distance of at least 5%, preferably at least 15% and in particular of at least 20% to the exciter frequencies,
- at least one shaft is a hollow shaft is formed and flows through a Tempe ⁇ riermedium, wherein the inlet is arranged on one side of the shaft and the outlet on the other side of the shaft,
- the at least one opening above the waves is closed by a displacer whose side facing the waves is formed such that there is a gap between the displacer and the kneading bars of the waves whose gap width is at most the continuous gap width between kneading bars and Housing corresponds,
- the opening area of the product removal port is adjustable during operation.
- the further object is achieved by a process for poly (meth) acrylate production, in which the mixing kneader according to the invention is used.
- the mixing kneader preferably has a reactor volume of at least 500 l, more preferably at least 2,000 l and particularly preferably at least 5,000 l.
- one shaft is called the main shaft and the second shaft is called the cleaning shaft.
- the number of distributed over the circumference Knetbarren on the main shaft may differ from that on the cleaning shaft.
- the cleaning shaft is the shaft which, distributed over the circumference, has fewer kneading bars and rotates faster.
- the Drehiereverrältältnis is the ratio of the number of kneading - such. described in EP-A 0 517 068 - depending.
- the waves can be driven either in the same direction or in opposite directions.
- a vibration excitation of the shaft is avoided if the natural bending frequencies of the shaft have at least 5%, preferably at least 15% and particularly preferably at least 20% distance to the exciter frequencies.
- the natural frequencies result from the shaft design, the shaft materials and the wall thickness of the shaft.
- the Er ⁇ regerfrequenzen result from the speed and the multiple of the speed. - A -
- the Ternperiermedium in this case preferably has an inlet temperature of at most 80 0 C, more preferably from maxi ⁇ times 40 0 C and particularly preferably of at most 20 0 C.
- the temperature control medium is supplied via an inlet on one side of the shaft and discharged via ei ⁇ NEN outlet on the other side of the shaft again.
- the cooling is preferably carried out in countercurrent. This means that the temperature control medium is added on the side of the waves on which the product is removed.
- Suitable tempering media are e.g. Water or thermal oils.
- the at least one opening above the waves is formed as a dome in the housing.
- product can accumulate and cake in the dome.
- these deposits lead to increased shear stress on the kneading bars and the waves, which in turn results in an increased tendency to crack formation.
- the at least one opening above the waves can be closed by a displacer, whose side facing the waves is formed so that between the displacer and the kneading of the waves, a gap is formed whose gap width is preferably maxi ⁇ times the continuous gap width between kneading and housing corresponds.
- At least one channel for educt feed is formed in the displacer, with which the dome is closed above the shafts in the housing.
- the channel for reactant feed is performed in different sized cross-sections.
- a metering device is accommodated in the channel for the educt feed.
- AJs metering device is, for example, a screw, a twin screw, a cellular or any other, known to those skilled in technical metering device.
- the displacer is preferably designed such that it is received by a sliding fit passge ⁇ exactly from the opening above the waves, so that the formation of dead zones between the opening above the waves and the displacer is avoided.
- the at least one channel for supplying educt in the displacer is provided with a plastic surface.
- the channel can be made either by a plastic channel, which is passed through the displacer, or the channel is coated with a plastic.
- Suitable plastics are, for example, polyolefins; polypropylene is particularly suitable.
- the openings facing the waves are preferably arranged close to one another.
- the mixing kneader is preferably operated in such a way that the formation of lumps of storage rods in dead zones is avoided by a sufficient degree of comminution of the product. These may e.g. also occur in the area of the opening for product removal or in other areas of the mixing kneader. It has been found that comminution increases as the degree of filling of the mixing kneader increases.
- the degree of filling within the mixing kneader can be adjusted through the opening cross section of the product removal opening. Thus, a reduction in the opening cross-section leads to an increase in the degree of filling at a constant speed of the shafts and for the same product. Therefore, the opening area of the product removal port is preferably adjustable during operation. This makes it possible to adjust the degree of filling without repeatedly starting and stopping the mixing kneading, which requires a great deal of time.
- the adjustment of the opening cross-section is effected in a first embodiment by a flap which can be displaced in the axial direction.
- a flap which is simultaneously displaceable in the axial and tangential direction is from bottom to top.
- the opening for product removal can be arranged either on the side of the main shaft, on the side of the cleaning shaft or on the front side of the mixing kneader.
- the opening for product removal preferably has a rectangular cross-section and has an opening angle which is in the range of 10 to 20 °, preferably in the range of 15 to 20 ° and particularly preferably 15 °.
- the tip of the opening angle lies on the axis of the shaft, on whose side the opening for product removal is arranged.
- the lower edge of the opening for product removal is at tangentially adjustable flap for adjusting the opening cross-section, preferably at an angle in the range of 30 to 55 ° relative to the vertical from above, wherein the apex of the angle is also on the axis of the shaft, on whose side the Opening is arranged.
- the opening for product removal is formed by a weir which is variable in operation during the operation in the housing wall.
- the height of the jaw also allows the degree of filling in the mixing kneader to be adjusted.
- the degree of filling is furthermore dependent on the product formulation, the throughput and the speed.
- the upper edge of the weir forms the lower edge of the opening for product removal.
- the height of the Weh ⁇ res is preferably set by tangential displacement of the weir during operation.
- the mixing kneader In order to avoid that large shear forces are transmitted to the shafts when approaching the mixing kneader, the mixing kneader is completely emptied during or before a standstill. If the mixing kneader is not emptied, the product hardens further, in particular in the case of poly (meth) acrylate production, as a result of which large lumpy products can be formed which initially have to be comminuted when restarting. These lumpy products lead to an increased shear stress of the kneading bars and the webs on which the kneading bars are attached.
- a Ent ⁇ emptying opening formed on the product removal side.
- the discharge opening is preferably located below the central axis in the housing and has a cross-sectional area of preferably at least 10,000 mm, more preferably at least 40,000 mm and particularly preferably at least 80,000 mm 2 .
- the emptying flap in a preferred embodiment is formed in the weir forming the opening for product removal, since the weir is preferably designed as a simple wall and not as a double jacket ,
- the opening for product removal is preferably followed by a downcomer whose walls are provided with insulation.
- All high-alloy austenitic steels, ferritic-austenitic duplex materials, nickel-base alloys and titanium are suitable materials for the shafts, webs, kneading bars and housing as well as the displacers.
- the suitable material it must be ensured that the material is stable in the range of pH 3 to 10, preferably pH 5 to 8, against the pH values occurring in the case of poly (meth) acrylate preparation.
- the mixing kneader formed according to the invention is preferably used for the preparation of crosslinked, finely divided, gelled poly (meth) acrylates.
- Poly (meth) acrylates or related polymers are generally prepared by copolymerizing
- Water-soluble monoethylenically unsaturated monomers of group (a) are, for example, ethylenically unsaturated C 3 -C 6 -carboxylic acids, their amides and esters with amino alcohols of the formula
- R 4 C 2 to Cs-alkylene and R 1 , R 2 , R 3 are independently hydrogen, methyl, ethyl or propyl.
- These compounds are, for example, acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid, fumaric acid and the alkali metal or ammonium salts of these acids, acrylamide, methacrylamide, crotonic acid amide, dimethylaminoethyl acrylate, diethylaminoethyl acrylate, dimethylaminopropyl acrylate, dimethylaminobutyl acrylate, diethylaminoethyl methacrylate, dimethylaminoethyl methacrylate, Dimethylaminopropylmethacrylat, Dimethylaminoneopentylacrylat and Dimethylami- noneopentylmethacrylat.
- the basic acrylates and methacrylates are used in the form of salts with strong mineral acids, sulfonic acids or carboxylic acids or in quaternized form.
- the anion X " for the compounds of the formula I is the acid radical of the mineral acids or of the carboxylic acids or methosulfate, ethosulfate or halide from a quaternizing agent.
- Further water-soluble monomers of group (a) are N-vinylpyrrolidone, acrylamidopro panensulfonic acid, vinylphosphonic acid and / or alkali metal or ammonium salts of vinylsulfonic acid.
- the other acids can also be used either in non-neutralized form or in partially or up to 100% neutralized form in the polymerization.
- Suitable water-soluble monomers of group (a) are also diallylammonium compounds, such as dimethyldiallylammonium chloride, diethyldiallylammonium chloride or dialylpiperidinium bromide, N-vinylimidazolium compounds, such as salts or quaternization products of N-vinylimidazole and 1-vinyl-2-methylimidazole, and N- Vinylimidazolines, such as N-vinylimidazoline, l-vinyl-2-methylimidazoline, l-vinyl-2-ethylimidazoline or l-vinyl-2-n-propylimidazoline, which are also used in quaternized form or as a salt in the polymerization.
- Preferred monomers of group (a) are acrylic acid, methacrylic acid and the alkali or ammonium salts of these acids, acrylamide and / or methacrylamide. These monomers can be copolymerized with each
- the polymerization of the monomers of group (a) takes place in the presence of crosslinkers (monomers of group (b)).
- the crosslinkers contain at least two ethylenically unsaturated double bonds.
- Suitable crosslinkers are, for example, N, N'-methylenebisacrylamide, polyethylene glycol diacrylates and polyethylene glycol dimethacrylates which are each derived from polyethylene glycols having a molecular weight of 126 to 8500, preferably 400 to 2000, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, ethylene glycol diacrylate, propylene glycol diacrylate, butanediol diacrylate, Hexanediol diacrylate, hexanediol dimethacrylate, diacrylates and dimethacrylates of block copolymers of ethylene oxide and propylene oxide, polyhydric or trihydric polyhydric alcohols esterified with acrylic acid or methacrylic acid, such as glycerol or pentaerythritol, triallylamine, tetraallylethylenediamine, divinylbenzene, dialyl phthalate, polyethylene glycol divinyl
- water-soluble crosslinkers for. N, N-methylenebisacrylamide, polyethylene glycol diacrylate, polyethylene glycol dimethacrylate, pentaerythritol triallyl ether and / or divinylurea.
- the monomers of group (b) are used in amounts of from 0.001 to 5, preferably 0.005 to 0.5 mol%, based on the monomers (a) in the copolymerization.
- the copolymerization of the monomers of groups (a) and (b) can additionally be carried out in the presence of monomers of group (c).
- Suitable monomers of group (c) are, for example, hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate, acrylonitrile and / or methacrylonitrile.
- esters of acrylic acid or methacrylic acid with monohydric alcohols containing 1 to 18 carbon atoms eg.
- the water-insoluble monomers if they are used in the copolymerization with, be dispersed with the aid of emulsifiers in the aqueous solution.
- Suitable emulsifiers are, for example, ethoxylated nonylphenols, ethoxylated castor oil, alkyl sulfates, sorbitan fatty acid esters, ethoxylated sorbitols, ethoxylated sorbitan fatty acid esters and alkyl sulfonates.
- Such emulsifiers are used in an amount of 0 to 3 wt .-% based on the monomers (a).
- Suitable polymerization regulators are, for example, thio compounds, such as thioglycolic acid, mercaptoalcohols, e.g. 2-mercaptoethanol, mercaptopropanol and mercapto butanol, dodecylmercaptan, formic acid, ammonia and amines, e.g. Ethanolamine, diethanolamine, triethanolamine, triethylamine, morpholine and piperidine.
- thio compounds such as thioglycolic acid, mercaptoalcohols, e.g. 2-mercaptoethanol, mercaptopropanol and mercapto butanol, dodecylmercaptan, formic acid, ammonia and amines, e.g. Ethanolamine, diethanolamine, triethanolamine, triethylamine, morpholine and piperidine.
- the monomers (a), (b) and optionally (c) are copolymerized with one another in 20 to 80, preferably 20 to 50, in particular 30 to 45% by weight aqueous solution in the presence of polymerization initiators.
- polymerization initiators it is possible to use all compounds which decompose into free radicals under the polymerization conditions, eg. As peroxides, hydroperoxides, hydrogen peroxide, persulfates, azo compounds and the so-called redox catalysts. Preference is given to the use of water-soluble catalysts. In some cases it is advantageous to use mixtures of different polymerization initiators, eg. B. mixtures of hydrogen peroxide and sodium or Kaliumpe- roxodisulfat.
- Suitable organic peroxides are, for example, acetylacetone peroxide, methyl ethyl ketone peroxide, tert-butyl hydroperoxide, cumene hydroperoxide, tert-amyl perpivalate, tert-butyl perpivalate, tert-butyl perohexanoate, tert-butyl perisobutyrate, tert-butyl per-2-ethylhexanoate tert-butyl perisononanoate, tert-butyl permaleate, tert-butyl perbenzoate, tert-butyl per 3,5,5-tri-methylhexanoate and tert-amylperneo-decanoate.
- Suitable polymerization initiators are azo initiators, for example 2,2'-azobis (2-amidinopropane) dihydrochloride, 2,2'-azobis (N, N-dimethylene) isobutyramidide dihydrochloride, 2- (carbamoylazo) isobutyronitrile and 4,4 '. Azobis (4-cyano-valeric acid).
- the polymerization initiators mentioned are used in customary amounts, for example in amounts of 0.01 to 5, preferably 0.1 to 2 mol%, based on the monomers to be polymerized.
- the redox catalysts contain as oxidizing component at least one of the abovementioned per compounds and, as reducing component, for example ascorbic acid, glucose, sorbose, ammonium or alkali metal hydrogensulfite, sulfite, thiosulfate, hyposulfite, pyrosulfite or sulfide, metal salts, such as Iron-H-ions or silver ions or sodium hydroxymethylsulfoxylate.
- reducing component of the redox catalyst is preferred ascorbic acid or sodium pyrosulfite.
- MO 5 to 1 mol% of the reducing component of the redox catalyst system
- MO 5 to 5 mol% of the oxidizing component of the redox catalyst.
- the oxidizing component of the redox catalyst or in addition one can also use one or more water-soluble azo initiators.
- a redox system consisting of hydrogen peroxide, sodium peroxodisulfate and ascorbic acid.
- these components are used in the concentrations MO 2 mol% hydrogen peroxide, 0.084 mol% sodium peroxodisulfate and 2.5-10 3 mol% ascorbic acid, based on the monomers.
- the aqueous monomer solution may contain the initiator dissolved or dispersed. However, the initiators can also be fed to the mixing kneader separately from the monomer solution.
- the monomer solution is freed of residual oxygen before the polymerization. This is done by means of inert gas, which can be introduced in cocurrent, countercurrent or intermediate inlet angles. Good mixing can be achieved, for example, with nozzles, static or dynamic mixers or bubble columns.
- the monomer solution is also passed through the reactor with an inert gas stream.
- Nitrogen a noble gas such as argon, carbon monoxide, carbon dioxide, sulfur hexafluoride or mixtures of these gases can be used independently of each other as inert gases. It is possible to generate the inert gas in whole or in part by a chemical reaction in the mixing kneader. Nitrogen is preferably used as the inert gas.
- the kneader mixer is in a preferred process variant at or" in front of a stop completely across the Emptying flap emptied.
- the mixing kneader is preheated prior to the addition of the educts during startup.
- the heating takes place via the housing.
- the housing is provided with a double jacket which forms a gap through which a temperature-regulating medium flows for heating the mixing kneader.
- a temperature-regulating medium flows for heating the mixing kneader.
- water vapor, thermal oils or molten salts are suitable as the temperature control medium.
- the heating can take place by adding a warm medium into the mixing kneader. Suitable media are for example warm air, warm nitrogen or water vapor.
- An improved comminution of the poly (meth) acrylate is achieved by first adding the monomers as starting materials to the mixing kneader and, preferably, at the position at which the monomer is reacted to 99.5% of the polymer, further components in the form of Solid particles are added.
- solid particles for example, finely divided, crosslinked poly (meth) acrylate, which is present in powder form. More preferably, the poly (meth) acrylate powder and the product produced in the mixing kneader are identical in their chemical composition. In addition to the addition of the solid particles to the gel after 99.5% conversion, any further technically meaningful addition is possible.
- the addition of the solid particles prevents agglomeration, since the frictional forces between the product and the solid particles largely contribute to comminution. As a result, the shear stress on the kneading bars and webs is reduced, thus reducing the stress on the shaft and thus avoiding cracking in the shaft.
- the solid particles have a maximum particle size of 50 ⁇ m, particularly preferably 300 ⁇ m.
- the shaft is cooled in a preferred process variant during operation of the mixing kneader. By cooling, a condensate film forms on the shaft, which prevents sticking of the poly (meth) acrylate with the shaft.
- FIG. 1 shows a section through a mixing kneader in plan view
- 2 shows a section through a housing cutout of the mixing kneader in the region of the opening for product removal
- FIG. 1 shows a section through a mixing kneader in plan view
- 2 shows a section through a housing cutout of the mixing kneader in the region of the opening for product removal
- FIG. 1 shows a section through a mixing kneader in plan view
- 2 shows a section through a housing cutout of the mixing kneader in the region of the opening for product removal
- FIG. 3 shows an opening formed by a weir for product removal with an additional discharge flap in the weir
- Figure 4 shows a section through a displacer with channel for Eduktzuschreib.
- a mixing kneader 1 as shown in FIG. 1, comprises a main shaft 2 and a cleaning shaft 3. Both on the main shaft 2 and on the cleaning shaft 3, kneading bars 4 are arranged over the circumference and are connected with webs 5 Main shaft 2 and 3 Putzwelle are ver ⁇ connected. In the embodiment shown here, eight kneading bars 4 are arranged on the main shaft 2, distributed over the circumference of the main shaft 2. In contrast, only two kneading bars 4 are arranged on the cleaning shaft 3 distributed over the circumference.
- the kneading bars 4 are preferably U-shaped and engage - as shown in FIG. 1 - on the side on which the cleaning shaft 3 and the main shaft 2 are adjacent, inein ⁇ other. As a result, by the cleaning shaft 3, the material which accumulates on the main shaft between the webs, removed.
- 8 kneading bars 4 are arranged distributed over the circumference on the main shaft and on the cleaning shaft 2 two kneading bars 4, the cleaning shaft 3 rotates four times as fast as the main shaft 2. This ensures that the kneading 4 of the Putzwelle 3 engage in all kneading 4 of the main shaft 2.
- any other combination of kneading 4 on cleaning shaft 3 and main shaft 2 is conceivable.
- the speed ratio of main shaft 2 is set to cleaning shaft 3.
- the main shaft 2 and the cleaning shaft 3 are enclosed by a housing 6.
- the housing 6 is preferably designed with a double jacket. As a result, a gap 7 is formed in the housing, which can be flowed through by a temperature control medium.
- the shafts are preferably driven by a motor 8 and a gear 9. About the transmission, the speed of the waves 2, 3 is defined. So it is possible that the
- Main shaft 2 and the cleaning shaft 3 rotate at different speeds, it is also possible that the main shaft 2 and the cleaning shaft 3 rotate at the same speed Ren, furthermore, the main shaft 2 and the cleaning shaft 3 can be operated either in the same direction or in opposite directions.
- the openings 10 can be supplied to the mixing kneader 1 E- products. It is also possible that the product produced in the mixing kneader 1 is degassed via the openings 10.
- an opening 11 is formed in the housing 6.
- the opening 11 for product removal is preferably arranged on the side of the cleaning shaft 3, but may also be arranged on the side of the main shaft 2.
- a temperature control medium To cool the main shaft 2 and the cleaning shaft 3, they are flowed through by a temperature control medium.
- the arrows denoted by reference numeral 12 show the point at which the temperature control of the main shaft 2 and 3 Putzwelle is supplied.
- the temperature control medium is withdrawn again from the main shaft 2 or the cleaning shaft 3.
- temperature control of the shafts 2, 3 in cocurrent is also possible.
- the temperature control medium is dispensed counter to the direction of the arrow at the point designated by reference numeral 13 and removed at the point designated by reference numeral 12.
- FIG. 2 shows a section through a housing section of a mixing kneader designed according to the invention in the region of the opening for product removal.
- the housing 6 preferably designed as a hollow shaft cleaning shaft 3 and main shaft 2 are added.
- the Eduktzussel takes place via the openings 10 above the waves 2, 3, which are preferably designed as a dome 20.
- the opening 11 is formed in the housing.
- the opening 11 is partially closed by a weir 14.
- the end edge 21 of the weir 14, which simultaneously forms the lower edge of the discharge opening is preferably arranged at an angle ⁇ to the vertical in the range of 30 to 55 °.
- the opening angle ⁇ of the product removal opening is preferably in the range of 10 to 20 °.
- the cross-sectional area of the product removal opening can be adjusted by a flap 15.
- the flap 15 in the embodiment shown in Figure 2 in axially displaceable.
- the movement of the flap 15 takes place via a drive 16.
- the degree of filling in the mixing kneader 1 is set via the cross-sectional area of the opening for product removal. The smaller the opening cross-section is, the greater the filling level for the same product and constant speed.
- FIG. 2 In the embodiment shown in Figure 2 is located in the lower part of the weir 14 an emptying flap 17.
- the emptying flap 17 is actuated by means of a handwheel 19 via a spindle 18.
- the open position of the discharge flap 17 is shown in dashed lines.
- the emptying flap 17 can be angeord ⁇ net at any other position in the housing 6.
- the emptying flap 17 is preferably arranged on the product removal side in the housing 6.
- the weir 14 and thus the opening for product removal and the emptying flap 17 can be arranged either on the side of the cleaning shaft 3 or on the side of the main shaft 2 in the housing 6.
- Figure 3 shows a plan view of the weir and the opening for product removal.
- the discharge flap 17 is formed in the weir 14.
- the emptying flap 17 is actuated via the handwheel 19.
- the weir 14 closes an opening in the housing 6 so far that only the opening to the Artsab ⁇ drove 22 remains free.
- the opening for product removal 22 is located in the upper third of the housing 6.
- the opening for product removal 22 can be further closed by the flap 15 in the embodiment shown here, as a result of which the opening cross section thereof is reduced.
- the flap 15 is driven via the A ⁇ itechnisch 16.
- Flap 15 is set, the opening cross-section of the opening for product removal 21 can also be adjusted by a movable flap in the tangential direction.
- the tangent tial flap can either close the opening from above.
- the end edge 21 of the weir 14- can be displaced in the direction of the opening for product discharge 22 and thus reduce the opening cross section of the opening for the product discharge 22.
- FIG. 4 shows a displacer 23 with which the opening 10 can be closed.
- the displacer 23 is placed in the dome 20 and preferably screwed via a flange with this.
- the displacer 23 is preferably formed as a hollow body.
- an annular circumferential rib 24 is arranged in the displacer 23.
- a channel 25 is formed in the displacer 23 in a preferred embodiment. Via the channel 25, either solid or liquid educts can be fed to the mixing kneader 1. In the embodiment of the channel 25 shown in FIG. 4, the educts are supplied above one of the corrugations.
- the channel 25 extends perpendicularly in the displacer 23.
- the point of addition can also be arranged centrally between the shafts.
- a further channel 26 can also be accommodated in the displacer 23, which has a smaller cross-section compared to the channel 25.
- the position at which the further channel 26 opens into the mixing kneader is preferably close to the mouth position of the channel 25.
- the channel 25 and the further channel 26 are provided with a plastic surface.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Accessories For Mixers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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JP2007532859A JP4881309B2 (ja) | 2004-09-28 | 2005-09-28 | 混合混練機並びに、混合混練機を使用してポリ(メタ)アクリレートを製造する方法 |
CN2005800405454A CN101065179B (zh) | 2004-09-28 | 2005-09-28 | 混合捏合机和使用所述混合捏合机来生产聚(甲基)丙烯酸化物的方法 |
DE502005007757T DE502005007757D1 (de) | 2004-09-28 | 2005-09-28 | Mischkneter sowie verfahren zur herstellung von poly(meth)acrylaten unter verwendung des mischkneters |
US11/663,753 US8070351B2 (en) | 2004-09-28 | 2005-09-28 | Mixing kneader and process for preparing poly(meth)acrylates using the mixing kneader |
EP05793749A EP1796823B1 (de) | 2004-09-28 | 2005-09-28 | Mischkneter sowie verfahren zur herstellung von poly(meth)acrylaten unter verwendung des mischkneters |
US13/284,012 US20120071613A1 (en) | 2004-09-28 | 2011-10-28 | Mixing Kneader and Process for Preparing Poly(Meth)Acrylates Using the Mixing Kneader |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102004047430 | 2004-09-28 | ||
DE102004047430.3 | 2004-09-28 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/663,753 A-371-Of-International US8070351B2 (en) | 2004-09-28 | 2005-09-28 | Mixing kneader and process for preparing poly(meth)acrylates using the mixing kneader |
US13/284,012 Division US20120071613A1 (en) | 2004-09-28 | 2011-10-28 | Mixing Kneader and Process for Preparing Poly(Meth)Acrylates Using the Mixing Kneader |
Publications (1)
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WO2006034853A1 true WO2006034853A1 (de) | 2006-04-06 |
Family
ID=35431579
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2005/010469 WO2006034853A1 (de) | 2004-09-28 | 2005-09-28 | Mischkneter sowie verfahren zur herstellung von poly(meth)acrylaten unter verwendung des mischkneters |
Country Status (7)
Country | Link |
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US (2) | US8070351B2 (de) |
EP (3) | EP2275197B1 (de) |
JP (2) | JP4881309B2 (de) |
CN (2) | CN101065179B (de) |
DE (1) | DE502005007757D1 (de) |
TW (1) | TW200626227A (de) |
WO (1) | WO2006034853A1 (de) |
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- 2005-09-28 WO PCT/EP2005/010469 patent/WO2006034853A1/de active Application Filing
- 2005-09-28 DE DE502005007757T patent/DE502005007757D1/de active Active
- 2005-09-28 CN CN2005800405454A patent/CN101065179B/zh active Active
- 2005-09-28 US US11/663,753 patent/US8070351B2/en active Active
- 2005-09-28 TW TW094133756A patent/TW200626227A/zh unknown
- 2005-09-28 EP EP08170459A patent/EP2052773B1/de active Active
- 2005-09-28 EP EP05793749A patent/EP1796823B1/de active Active
- 2005-09-28 CN CN2010105780618A patent/CN102091551B/zh active Active
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2011
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CN1305262C (zh) * | 1997-07-29 | 2007-03-14 | 皇家菲利浦电子有限公司 | 无线联网消息的路由 |
US8076436B2 (en) | 2006-10-19 | 2011-12-13 | Basf Se | Method for the production of superabsorbers |
WO2013167397A1 (de) | 2012-05-07 | 2013-11-14 | Basf Se | Verfahren zum betrieb eines mischkneters |
US8853333B2 (en) | 2012-05-07 | 2014-10-07 | Basf Se | Process for operating a mixing kneader |
EP2846903A1 (de) | 2012-05-07 | 2015-03-18 | Basf Se | Verfahren zum betrieb eines mischkneters |
WO2013167561A1 (de) | 2012-05-08 | 2013-11-14 | Basf Se | Verfahren zum betrieb eines apparates mit mindestens einer rotierenden welle |
US9415529B2 (en) | 2012-05-08 | 2016-08-16 | Basf Se | Method for operating an apparatus with at least one rotating shaft |
WO2013186176A1 (de) | 2012-06-13 | 2013-12-19 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel in einem polymerisationsreaktor mit mindestens zwei achsparallel rotierenden wellen |
US9248429B2 (en) | 2012-06-13 | 2016-02-02 | Basf Se | Process for producing water-absorbing polymer particles in a polymerization reactor with at least two axially parallel rotating shafts |
WO2014118024A1 (de) | 2013-01-29 | 2014-08-07 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit hoher quellgeschwindigkeit und hoher zentrifugenretentionskapazität bei gleichzeitig hoher permeabilität des gequollenen gelbetts |
US9822203B2 (en) | 2013-01-29 | 2017-11-21 | Basf Se | Method for producing water-absorbing polymer particles with high swelling rate and high centrifuge retention capacity with simultaneously high permeability of the swollen gel bed |
US10179185B2 (en) | 2014-05-08 | 2019-01-15 | Basf Se | Method for producing water-absorbing polymer particles |
WO2017108888A1 (de) | 2015-12-23 | 2017-06-29 | Basf Se | Wärmeübertrager zur erwärmung von gas und verwendung des wärmeübertragers |
US11933552B2 (en) | 2015-12-23 | 2024-03-19 | Basf Se | Heat exchanger for heating gas and use of the heat exchanger |
WO2020079149A1 (en) | 2018-10-18 | 2020-04-23 | Basf Se | Method of providing homogeneous aqueous polyacrylamide concentrates and use thereof |
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US11608468B2 (en) | 2018-10-18 | 2023-03-21 | Basf Se | Process of fracturing subterranean formations |
US11725102B2 (en) | 2018-10-18 | 2023-08-15 | Basf Se | Method of providing homogeneous aqueous polyacrylamide concentrates and use thereof |
WO2020109601A1 (en) | 2018-11-29 | 2020-06-04 | Basf Se | Prediction of physical properties of superabsorbent polymers |
WO2021209148A1 (en) | 2020-04-17 | 2021-10-21 | Basf Se | Process for making an aqueous injection fluid |
WO2021209149A1 (en) | 2020-04-17 | 2021-10-21 | Basf Se | Process and devices for making aqueous wellbore treating fluids |
WO2021209150A1 (en) | 2020-04-17 | 2021-10-21 | Basf Se | Processes and devices for making aqueous wellbore treating fluids |
WO2023156293A1 (en) | 2022-02-17 | 2023-08-24 | Basf Se | Improved process and device for making aqueous wellbore treating fluids |
Also Published As
Publication number | Publication date |
---|---|
JP2012055887A (ja) | 2012-03-22 |
EP1796823A1 (de) | 2007-06-20 |
CN102091551B (zh) | 2013-07-17 |
EP1796823B1 (de) | 2009-07-22 |
CN101065179A (zh) | 2007-10-31 |
EP2275197A1 (de) | 2011-01-19 |
EP2052773A2 (de) | 2009-04-29 |
JP2008514396A (ja) | 2008-05-08 |
TW200626227A (en) | 2006-08-01 |
EP2052773A3 (de) | 2009-05-06 |
CN102091551A (zh) | 2011-06-15 |
US20120071613A1 (en) | 2012-03-22 |
CN101065179B (zh) | 2011-02-02 |
US8070351B2 (en) | 2011-12-06 |
EP2052773B1 (de) | 2012-07-18 |
DE502005007757D1 (de) | 2009-09-03 |
EP2275197B1 (de) | 2013-04-03 |
JP4881309B2 (ja) | 2012-02-22 |
US20080080300A1 (en) | 2008-04-03 |
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