Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/53—Polyethers
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
  • D06M13/165—Ethers
  • D06M13/17—Polyoxyalkyleneglycol ethers
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
  • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
  • D06M13/402—Amides imides, sulfamic acids
  • D06M13/419—Amides having nitrogen atoms of amide groups substituted by hydroxyalkyl or by etherified or esterified hydroxyalkyl groups
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
  • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
  • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

• the present invention can remove wrinkles of textile products, and can effectively remove wrinkles without impairing the texture without performing heat treatment such as iron.
• the present invention relates to a wrinkle removal composition and a wrinkle removal method.
• Conventional technology In general, dry cleaning clothing such as suits is difficult to wash with water at home, and there is a general method for removing wrinkles such as ironing or steam press.
• JP-A1 0-2 5 6 60 as a means of stretching the wrinkle of clothing without heat treatment, a composition comprising a combination of water and a specific water-soluble solvent such as hexylene glycol Nyasoprendaricol After spraying on the part, a method of removing the wrinkled part by simply leaving it is disclosed.
• JP-A (W) 1 0— 5 0 8 9 1 1, WO-A 9 9/5 5 9 5 2, WO-A 9 9/5 5 9 5 3, JP-A 1-6 1 74 Discloses a fabric wrinkle remover composition and method. In these methods, the composition is sprayed on the fabric and then suspended and air-dried or ironed to remove wrinkles. However, natural drying alone can sufficiently remove wrinkles. In addition, ironing is very effective in removing wrinkles, but it is a time-consuming work and is insufficient to restore the texture.
• a wrinkle removal composition comprising a compound (a) represented by the following general formula (1) or (2) or (3).
• R is a hydrocarbon group having 10 to 22 carbon atoms
• EO represents C 2 H 40
• P 0 represents C 3 H 6
• m and n represent average added mole numbers, respectively.
• M is a number from 3 to 100
• n is a number from 1 to 10; (? 0) and (£ ⁇ ) can be either random addition or block addition, and (P ⁇ ) and (EO) The order of addition does not matter.
• 1111 and 1112 indicate the average number of moles added, and the sum of m 1 and m 2 is a number from 3 to 100, nl and n 2 indicate the average number of moles added, and the sum of n 1 and n 2 (P 0) and (EO) may be random addition or block addition, and the order of addition of (P 0) and (EO) does not matter.
• Y is 1 0 — — CN— — CO—
• R is a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms.
• the present invention relates to a method for removing wrinkles from a fiber product, which applies the wrinkle removal composition to a fiber product, or an application using the composition to remove wrinkles from a fiber product.
• the present invention is to provide a wrinkle removal composition and a wrinkle removal method capable of sufficiently removing wrinkles of a textile product without impairing the texture without performing heat treatment such as ironing or steam press. .
• the wrinkle-removing composition of the present invention can effectively remove wrinkles of a textile product simply by spraying on the textile product, and in particular, the texture is impaired without performing heat treatment such as eye opening or steam press.
• the wrinkles of the textile product can be effectively removed without any trouble.
• the component (a) according to the present invention is amphoteric, it can be washed after using the treated textile product, washed using a normal aqueous medium, or an organic solvent. Easily removed by dry cleaning using (A) ingredient>
• R is a carbon number of 10 to 2 A hydrocarbon group, preferably an alkyl group having 12 to 18 carbon atoms or an alkenyl group having 12 to 18 carbon atoms. More preferred is an alkyl group having 16 to 18 carbon atoms.
• propylene O dimethylsulfoxide (C 3 H 6 ⁇ group, hereinafter also may be referred as PO) m or m 1 + m 2 is an average addition number of moles of is the number from 3 1 0 0, good The number is preferably 3 to 60, more preferably 10 to 60. ml and m 2 are numbers exceeding 0 each.
• n or n 1 + n 2 which is the average added mole number of ethylene oxide (C 2 H 40 group, hereinafter may be expressed as EO) is a number of 1 to 10, preferably The number is from 1 to 8, more preferably from 1 to 3. nl and n2 are numbers exceeding 0, respectively.
• the molar ratio of PO and EO in general formula (1) or (2) or (3) mZn or (m 1 + m 2) / (n 1 + n 2) is 4 to 1 2 or 6 to 10 is preferred.
• the compound (a) preferably also includes a compound represented by the general formula (1 ′).
• the component (a) of the present invention is ROH or the following
• (? ⁇ ) and (£ ⁇ ) may be random addition or block addition, and the addition order of (? 0) and (£ ⁇ ) does not matter. Including the order of (P ⁇ ), (£ 0) and (? 0).
• the wrinkle removal composition of the present invention preferably contains an oily compound (b) [hereinafter referred to as the component (b)] in order to further enhance the wrinkle removal effect.
• the component (b) is preferably at least one oily compound selected from the following (bl) to (b7).
• R 1 is a saturated or unsaturated linear or branched monovalent hydrocarbon group having 8 to 20 carbon atoms
• R 2 is a saturated or unsaturated linear chain having 1 to 20 carbon atoms
• a branched monovalent hydrocarbon group, R 3 and R 4 each independently represents a saturated or unsaturated linear or branched monovalent hydrocarbon group having 4 to 18 carbon atoms.
• the hydrocarbon of (b 1) is a saturated or unsaturated linear or branched hydrocarbon having an average molecular weight of 100 to 500, for example, a paraffinic compound separated and refined from petroleum.
• a paraffinic compound separated and refined from petroleum for example, distillates mainly containing products, paraffinic oils such as liquid paraffin, etc.
• liquid paraffin having an average molecular weight of 2 to 400 is preferred.
• Examples of the primary or secondary alcohol having an average molecular weight of 100 to 300 in (b 2) include primary or secondary alcohols having 8 to 20 carbon atoms, and alcohols having 14 to 20 carbon atoms. preferable.
• R 1 is an alkyl group or alkenyl group having 8 to 20 carbon atoms
• R 2 is 1 carbon atom.
• An ester compound which is an alkyl group having ⁇ 20 and an ether compound wherein R 3 and R 4 are alkyl groups having 4 to 10 carbon atoms are preferred.
• the fatty acid having an average molecular weight of 100 to 500 in (b4) may be a saturated or unsaturated fatty acid having a straight chain or branched chain. Specific examples include fatty acids having 6 to 20 carbon atoms, and hexanoic acid, octanoic acid and decanoic acid are preferred.
• Examples of the tri-, di- or monodallylide of the fatty acid having 12 to 24 carbon atoms of (b5) include tri, di or monomyristin, tri, di or monostearin, tri, di or monoolein, tri, di or monoerucine, etc.
• Preferred are glycerides of saturated fatty acids such as tri, di or monomyristine, tri, di or monostearin, and more preferred are tridaricelides such as trimyristin and tristearin.
• the wrinkle removal composition of the present invention preferably contains an emulsifier (c) (hereinafter referred to as (a) component) and water.
• Component emulsifiers include polyoxyalkylene alkyl or alkenyl ether, polyoxyalkylene alkyl phenyl ether, fatty acid alkanolamide or its alkylene oxide adduct, sucrose fatty acid ester, alkyl darcoside, etc.
• Nonionic surfactants Cationic surfactants such as mono long chain alkyl quaternary ammonium salts, di long chain alkyl quaternary ammonium salts, tri long chain alkyl quaternary ammonium salts; alkylbenzene sulfonic acids or salts thereof, alkyl sulfates Anionic surfactants such as stealth salts, polyoxyalkylene alkyl ether sulfates, olefin sulfonates, alkane sulfonates, and fatty acid salts; amphoteric surfactants such as amine oxides, sulfobetaines, carbobetaines, etc.
• HLB ( Riffin method, the same shall apply hereinafter) 4.0 to 1 5.
• At least one selected from anionic surfactants having a monovalent hydrocarbon group of ⁇ 14 is preferred.
• a particularly preferred emulsifier in the present invention is a nonionic surfactant represented by the general formula (III).
• R 5 -0— (R 6 0) p -H (III) [wherein R 5 represents a linear or branched chain group having 8 to 22 carbon atoms, preferably 10 to 20 carbon atoms.
• R 6 is an alkyl group or an alkenyl group, and R 6 is an alkylene group having 2 carbon atoms, that is, an ethylene group.
• P is an average added mole number of 0.5 to 30; preferably 2 to 20; and particularly preferably 4 to 10.
• Examples of the compound represented by the general formula (III) include a compound represented by the formula (IV).
• R 7 is a linear or branched alkyl group having 10 to 18 carbon atoms, and r is a number of 1 to 10, preferably 3 to 8, indicating the average number of moles added.
• the wrinkle removal composition of the present invention preferably contains a silicone compound (d) [hereinafter referred to as (d) component].
• silicone compound as component (d) those that can be used as a fiber lubricant are particularly preferable.
• dimethylpolysiloxane hereinafter referred to as dimethylsilicone
• organopolysiloxane hereinafter referred to as hydroxysilicone
• Organopolysiloxane hereinafter referred to as modified silicone
• a part of the methyl group (preferably the methyl group in the side chain) of dimethyl silicone or hydroxy silicone is an organic group other than a methyl group
• organic in the dimethyl siloxane chain An organic group other than a methyl group is introduced.
• Organic groups other than methyl groups of the modified silicone include organic groups including amino groups, organic groups including quaternary ammonium groups, organic groups including amide groups, organic groups including polyether groups, and organic groups including epoxy groups.
• silicone oils 0-40 Silicone compounds that are liquid at a temperature of C are preferred.
• the wrinkle removing composition of the present invention is a composition containing (b) component, (c) component, (d) component, and water, if necessary, in addition to the above component (a). It can be an OZW emulsion type composition.
• the average particle size of the emulsified droplets in the case of 0 / W emulsion is that the component (a) is uniformly applied to the fiber in as small a quantity as possible to reduce the transpiration rate of water and suppress wrinkles, and From the viewpoint of suppressing stains due to the oil, 0.1 to 10 / xm, more preferably 0.1 to 3 xm is preferable.
• the average particle size of the emulsified droplets of the present invention can be measured using a dynamic light scatterometer (ELS-800, manufactured by Otsuka Electronics Co., Ltd.).
• the content of the component (a) in the wrinkle removal composition of the present invention is preferably 0.1 to 5% by weight, and 0.2 to 4% by weight, from the viewpoint of the wrinkle removal effect and the solution stability of the blended composition. But More preferred is 0.2 to 2% by weight.
• the content of the component (b) in the wrinkle removal composition of the present invention is from the viewpoint of reducing the transpiration rate of water, reducing the drying rate, and suppressing the generation of wrinkles.
• the content of the component (c) is preferably from 0 to 1 to 20% by weight, more preferably from 0.1 to 10% by weight, from the viewpoint of efficiently emulsifying the component (a) and further the component (b). Preferably, 0.2 to 1.0% by weight is particularly preferable.
• the composition of the present invention preferably contains the component (d) in order to improve the slipping property between the fibers when the garment is dry, and the content of the component (d) is 0.002 ⁇ 3.0 wt% is preferable, and 0.1 to 0.5 wt% is more preferable.
• the wrinkle removal composition of the present invention can contain a fragrance, a bactericidal agent, a preservative, and the like in addition to the component (a) and further the components (b) to (d).
• the production method when the composition of the present invention is a 0 / W emulsion type wrinkle removal composition is not particularly limited.
• each of the above components is mixed with water, and the average particle size of the emulsified droplets is 0.1. It can be obtained by stirring with a homomixer or the like so as to be ⁇ 10 m.
• the wrinkle removing method of the present invention is a method of removing wrinkles from a textile product by applying the above-described wrinkle removing composition of the present invention to the textile product. Ironing or steam press The wrinkles can be removed without performing a heat treatment such as the above. Also, If necessary, heat treatment may be performed.
• a spray method is preferable, and it is preferable to fill the wrinkle removal composition of the present invention in a container equipped with a spraying device and to spray the textile product. .
• a spraying device a set of triggers is preferable, especially
• JP-A (U) 4-3 7 5 5 4 It is preferable to use a pressure accumulating trigger having excellent liquid dripping and spray uniformity as shown in FIG. Examples
• the following examples describe the practice of the present invention. The examples are illustrative of the invention and are not intended to limit the invention.
• Examples 1 to ⁇ 8 and Comparative Examples 1 to 8 The following components were used in the proportions shown in Table 1, and (c) component was mixed into (a) component and (b) component, and (b) component and equal weight Were mixed with each other and stirred at 40 00 r 1] 111 for 10 minutes using a homomixer. After stirring, the remaining components and water were added and stirred at 30 00 rpm for 10 minutes to obtain a wrinkle removal composition. About the obtained composition, the wrinkle removal property was evaluated by the following method. Table 1 shows the evaluation results.
• R in the general formula (1) is a linear alkyl group having 18 carbon atoms, m is 3 8 and n is 6, the number of carbon atoms in the alkyl group and the number of moles of PO and EO added
• R is a linear alkyl group having 18 carbon atoms
• m is 38
• n is 6, and the compound is represented by C18 (EO) 6 (PO) 38
• R is a linear alkyl group having 18 carbon atoms, m is 20, n is 5, and C18 (PO) 10 (EO) 5 (PO) 10 Compound
• R is a linear alkyl group having 18 carbon atoms, m is 30, n is 5, and is represented by C18 (PO) 10 (EO) 5 (PO) 20 Compound
• R in the general formula (1) is a straight-chain alkyl group having 18 carbon atoms, m is 55, n is 2 and the compound is represented by C18 (EO) 2 (PO) 55
• R in the general formula (1) is a straight-chain alkyl group having 18 carbon atoms, m is 3, n is 3, and the compound is represented by C18 (EO) 3 (PO) 3
• R in general formula (1) is a straight-chain alkyl group having 18 carbon atoms, m is 10 and n is 5 and the compound is represented by C18 (PO) 10 (EO) 5
• R in the general formula (1) is a linear alkyl group having 18 carbon atoms, m is 15, n is 5, and the compound is represented by C18 (PO) 10 (EO) 5 (PO) 5
• R in the general formula (1) is a linear alkyl group having 20 carbon atoms, m is 15 and n is 7 and C20 (EO) 7 (PO) 15
• R in the general formula (1) is a straight-chain alkyl group having 12 carbon atoms, m is 12 and n is 12 and is represented by C12 (PO) 12 (EO) 12
• R1 in the general formula (1) is a straight chain alkyl group having 1 to 2 carbon atoms, m is 0, n is 8, and the compound is represented by C12 (EO) 8
• R in the general formula (1) is a straight-chain alkyl group having 18 carbon atoms, m is 0, n is 30 and is represented by C18 (EO) 30'-4):
• R in the general formula (1) is a straight-chain alkyl group having 18 carbon atoms, m is 18 and n is 3 2 and C18 (EO) 3 (PO) 3 (EO) 29 ( Compound represented by PO) 15

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• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
• Detergent Compositions (AREA)

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• 2005
  • 2005-09-07 WO PCT/JP2005/016875 patent/WO2006028261A1/ja not_active Ceased
  • 2005-09-07 US US11/662,054 patent/US7763180B2/en not_active Expired - Fee Related
  • 2005-09-07 EP EP05783105A patent/EP1788147B1/en not_active Expired - Lifetime
  • 2005-09-07 DE DE602005026952T patent/DE602005026952D1/de not_active Expired - Lifetime
  • 2005-09-07 JP JP2005259181A patent/JP4509898B2/ja not_active Expired - Lifetime

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