WO2005079729A1 - 油性クレンジング組成物 - Google Patents
油性クレンジング組成物 Download PDFInfo
- Publication number
- WO2005079729A1 WO2005079729A1 PCT/JP2005/000176 JP2005000176W WO2005079729A1 WO 2005079729 A1 WO2005079729 A1 WO 2005079729A1 JP 2005000176 W JP2005000176 W JP 2005000176W WO 2005079729 A1 WO2005079729 A1 WO 2005079729A1
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- WO
- WIPO (PCT)
- Prior art keywords
- oil
- water
- component
- phase
- cleansing composition
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 87
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 23
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 20
- 239000003921 oil Substances 0.000 claims description 92
- 239000012071 phase Substances 0.000 claims description 46
- 239000000693 micelle Substances 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 16
- 239000000194 fatty acid Substances 0.000 claims description 16
- 229930195729 fatty acid Natural products 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 239000010696 ester oil Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 abstract description 14
- 238000004140 cleaning Methods 0.000 abstract description 9
- 230000007794 irritation Effects 0.000 abstract description 5
- 235000019198 oils Nutrition 0.000 description 80
- 239000004094 surface-active agent Substances 0.000 description 29
- 239000000243 solution Substances 0.000 description 13
- -1 fatty acid ester Chemical class 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 238000010587 phase diagram Methods 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 239000004973 liquid crystal related substance Substances 0.000 description 6
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 4
- 206010015946 Eye irritation Diseases 0.000 description 4
- 238000002835 absorbance Methods 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 231100000013 eye irritation Toxicity 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000013329 compounding Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000011086 high cleaning Methods 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- ZQXRINMCMHCYBD-UHFFFAOYSA-N 4-(2-ethylhexoxy)-4-oxobutanoic acid Chemical compound CCCCC(CC)COC(=O)CCC(O)=O ZQXRINMCMHCYBD-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ODMZDMMTKHXXKA-QXMHVHEDSA-N 8-methylnonyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCCCC(C)C ODMZDMMTKHXXKA-QXMHVHEDSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical class OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- DWMMZQMXUWUJME-UHFFFAOYSA-N hexadecyl octanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCC DWMMZQMXUWUJME-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 239000008384 inner phase Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940093629 isopropyl isostearate Drugs 0.000 description 1
- ASKIVFGGGGIGKH-UHFFFAOYSA-N isostearic acid monoglyceride Natural products CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0295—Liquid crystals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/068—Microemulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Definitions
- the present invention relates to an oil-based cleansing composition, particularly to prevention of a decrease in transparency due to mixing of water.
- Cleansing compositions can be broadly classified into aqueous cleansing and oil-based cleansing.
- aqueous cleansing include a lotion type in which a surfactant can be used in an aqueous ethanol solution, and an aqueous gel type in which a surfactant is thickened by a polymer.
- oil-based cleansing cream types in which oZw emulsions exhibit a washing function by phase inversion by massage and oil types comprising surfactant oil solutions are known.
- the oil type is particularly known to have a high cleaning effect.
- make-up palatability has been dominated by types that prevent secondary adhesion, such as foundation and lipstick, and types that include silicone with a high molecular weight, such as mascara. Is very growing.
- the oil type is composed of a nonionic surfactant, an oil component, and a small amount of water.
- the surfactant forms a reverse micelle oil solution in which an aggregate is formed in the oil with a hydrophilic group inside. Water is solubilized in the vicinity of the gathering of the hydrophilic groups to form a single phase and is completely transparent.
- the oil type Due to its microstructure, the oil type has a limit in its ability to completely and completely take in water, that is, the solubilization amount.
- a water-in-oil or oil-in-water emulsion composition is obtained in a coexistence state with other phases (two-phase state).
- the inner phase particles have a certain size or more, light is scattered due to the difference in refractive index between the two phases, and the whole becomes white and cloudy.
- detergent It is not possible to achieve the desired cleaning performance and smooth massage properties, and the cloudy state is not desirable because it strongly impresses consumers on the deterioration of performance.
- Patent Document 1 discloses a cleansing agent that uses a polyglycerol fatty acid ester having an HLB of 10 or more and a polyhydric alcohol having a valency of 3 or more to wet the skin! Has been described. However, in this method, it was not possible to prevent the appearance of cloudiness and the massage property was not sufficient.
- Patent Documents 2 and 3 disclose that a combination of a nonionic surfactant and an amphoteric surfactant and a combination of a nonionic surfactant and a glyceryl ether derivative have high detergency even with hands wet with water.
- the cleansing fee is described in the following. Massaging property: Preventing the appearance of white turbidity is not enough!
- Patent Document 1 JP-A-2000-327529
- Patent Document 2 JP-A-6-16524
- Patent Document 3 JP 2001-270809 A
- An object of the present invention is to maintain good washing performance even when water is mixed, prevent a decrease in massage performance in which the appearance becomes cloudy, and provide good safety with little irritation to the eyes.
- An object of the present invention is to provide an oil-based cleansing composition.
- the present invention is characterized in that (A) a nonionic surfactant having an HLB of 6-14 and (B) an oily component, and the following conditions (1) and (2) are satisfied. It is an oil-based cleansing composition.
- the amount of water is less than 5% by mass.
- compositions and water are mixed in a ratio of 4: 6, a micelle aqueous phase or a bicontinuous microemulsion phase is formed.
- the alkyl chain length of (A) the nonionic surfactant is 16 or more on average.
- the oil component (B) preferably contains at least 80% of hydrocarbon oil and Z or ester oil.
- the oily component (B) further contains 110% of silicone oil.
- (C) a liquid fatty acid or a liquid alcohol having an alkyl chain length of 16 or more is further contained.
- a method for preventing white turbidity when water is mixed into an oily composition a method of reducing the refractive index difference between an aqueous phase and an oil phase in order to suppress light scattering, or a method of preventing internal phase particles from being dispersed. It is conceivable that the particle size is smaller than the visible light wavelength region.However, in an oil-based cleansing composition, the added aqueous phase is usually tap water, and it is difficult to adjust the refractive index. It is difficult to reduce the particle size of the product to several hundreds of mm or less.
- the present inventors have found that even when water is added to the oil-based cleansing composition, the viscosity of the bicontinuous microemulsion phase, which is a low-viscosity one-phase region, and the micelle aqueous solution are shifted.
- the nonionic surfactant and the oily component were adjusted in advance.
- FIG. 1 is a diagram showing a pseudo three-component phase diagram (water, surfactant, oil) using the components of Example 1 and Comparative Examples 1 and 2.
- the (A) nonionic surfactant used in the present invention is a surfactant which does not have a charge when ionized in an aqueous solution.
- a type using alkyl and a type using dimethyl silicone are known.
- the former include, for example, dalyserine fatty acid ester, ethylene oxide derivative of glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, ethylene oxide derivative of propylene glycol fatty acid ester, polyethylene glycol fatty acid ester,
- Examples include polyethylene glycol alkyl ether, polyethylene glycol alkyl phenyl ether, polyethylene glycol castor oil derivatives, and polyethylene glycol hydrogenated castor oil derivatives.
- the latter include polyether-modified silicone and polyglycerin-modified silicone.
- the nonionic surfactant of the present invention has an HLB of 6 to 14, especially 8 to 10
- an HLB of 7 indicates that the solubility in water and the solubility in oil are balanced! That is, the surfactants suitable in the present invention have an intermediate solubility in oil-Z water and are slightly hydrophilic. If the HLB is less than 6, good washability cannot be obtained when the detergent is rinsed out, and if it exceeds 14, the solubility in oil is significantly reduced, so that an oil-based cleansing composition cannot be formed. In particular, when the HLB power is less than 10, there is an advantage that the selection of the oil component is easy. Further, it is preferable that the non-ionic surfactant of the present invention is liquid at room temperature.
- the nonionic surfactant used in the present invention is of the alkyl type, it preferably has an alkyl chain length of 16 or more. Shorter alkyl chains tend to increase eye irritation.
- the lipophilic group of the surfactant (A) is preferably a branched or unsaturated alkyl, more preferably an isostear group or an oleyl group, and most preferably an isostear group.
- the surfactant (A) is preferably glycerin POE isostearate.
- the compounding amount of the component (A) is 15 to 65% by mass, preferably 25 to 50% by mass. Below this level, the effect of preventing white turbidity is not sufficient, and if it is added further, an undesirably sticky feel is given.
- oil component (B) one or more types commonly used in cosmetics can be selected within a range that does not impair stability.
- the nonionic surfactant is selected from those of HLB8-10
- one or more oil components can be selected as the oily component so that the average IOB is 0.02-0.07.
- Desirable are hydrocarbon oils and polar oils. Mixing a small amount (112% by mass of oil-based component) of silicone oil with these will improve the cleaning performance.
- the component (C) described below is not included in the oil component (B).
- hydrocarbon oil examples include liquid paraffin, squalane, squalene, paraffin, isobaraffin, and ceresin.
- Polar oils include liquid fats and oils.
- Liquid oils include linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, apogado oil, sasanqua oil, castor oil, safflower oil, jojoba oil, castor oil, almond oil, rapeseed oil, There are sesame oil, soybean oil, peanut oil, triglycerin, glycerin trioctanoate, glycerin triisopalmitate and the like.
- Ester oils include cetyl octanoate, hexyl laurate, isopropyl myristate, octyl palmitate, isosetyl stearate, isopropyl isostearate, octyl isopalmitate, isodecyl oleate, glyceryl hexyl hexate, Examples include pentaerythrit tetra-2-ethylhexanoate, 2-ethylhexyl succinate, and getyl sebacate.
- Silicone oil added to improve the cleaning ability includes, for example, dimethylpolysiloxane.
- dimethylpolysiloxane There are chain silicones such as sun, methylphenol polysiloxane and methylhydrogenpolysiloxane, and cyclic silicones such as otatamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane.
- the blending amount of water in the present invention is less than 5% by mass, and it is not necessary to blend it. When the content is more than 5% by mass, the transparency as the cleansing composition may not be satisfied.
- the liquid fatty acid or liquid alcohol (C) having an alkyl chain length of 16 or more used in the present invention is branched or shows a liquid state by containing an unsaturated bond.
- Liquid fatty acids include isostearic acid and oleic acid
- liquid alcohols include isostearyl alcohol and oleyl alcohol. Most preferred are isostearic acid and isostearyl alcohol.
- condition (2) when the composition and water are mixed in a ratio of 4: 6, it is necessary to form a micelle aqueous solution phase or a bicontinuous microemulsion phase. It is.
- condition (3) when the composition and water were mixed in a ratio of 7: 3, the viscosity measured with a B-type viscometer was less than 100 mPa's (rotational speed 6 rpm, temperature 25 ° C , Measured with rotor No. 3).
- the mixture of oil and water is roughly divided into
- emulsified compositions are very common, and most of cosmetics and the like are mostly cloudy as represented by power creams and emulsions.
- the liquid crystal when used, the light scattering is small and the turbidity is not so much adjustable.
- an oil-based cleansing solution prepared by adjusting a nonionic surfactant and an oily component so as to form a micelle aqueous solution or a bicontinuous-us-microemulsion when hydrolyzed.
- the composition was developed.
- a triangular diagram it is widely known to use a triangular diagram to understand a system that also has a three-component power, which also includes an oily component, water, and a surfactant.
- Three components are arranged at each vertex of the triangular diagram, indicating that each component has a composition of 100% by mass.
- the region of the phase obtained by mixing the components is shown on the triangular diagram as the ternary phase diagram.
- the pseudo three-component phase diagram shows that the mixture is arranged at each vertex according to the properties of the components. For example, when a fixed concentration mixture of water and ethanol is placed at the top as an aqueous component, a pseudo three-component phase diagram can be created using four components, water, ethanol, a surfactant, and oil.
- the oil-based cleansing composition of the present invention comprises a nonionic surfactant and an oil component (one or more), and a three-component phase diagram is formed by adding water thereto.
- a nonionic surfactant and an oil component one or more
- a three-component phase diagram is formed by adding water thereto.
- the surfactant and the liquid alcohol or fatty acid are regarded as one component, and when two or more oils are used, they are regarded as one component.
- a phase diagram of the separation system can be created.
- the composition of the present invention is obtained by mixing oil with a surfactant or a mixture of a surfactant and a liquid fatty acid, and then adding a small amount of water as needed.
- the surface moved slightly from the point on the axis connecting the top of the surfactant containing liquid fatty acid and the top of the oil to the top of the water. (If water is not included, the top of the surfactant and the top of the oil are connected. On the axis). The change that mixes water with this corresponds to changing the composition from this point toward the water top.
- the micelle aqueous solution phase and the bicontinuous microemulsion phase generated when water is mixed under the condition (2) of the present invention have the following features, respectively, and can be distinguished. Both the aqueous micelle phase and the bicontinuous microemulsion phase are optically isotropic, transparent, low-viscosity solutions. The only other isotropic, transparent, low-viscosity solutions obtained with surfactant systems are reverse micelle oil solutions. The method for determining these is described below.
- the micelle aqueous phase is a state in which water forms a continuous state, and a spherical or rod-like aggregate with the lipophilic group directed inward is dispersed.
- the size of the aggregate is about 100 nm at most, and it is optically isotropic and has a translucent appearance that is transparent and slightly bluish.
- the composition is obtained by adding a surfactant and oil to water, and the amount of soluble oil increases with the amount of the surfactant. It is often obtained as a connected area.
- the bicontinuous-us microemulsion phase is one in which the number of associations of surfactants increases and associates indefinitely, and as a result, the amount of water and oil soluble increases dramatically, Both water and oil form continuous channels.
- This phase is determined by external appearance, preparation of phase equilibrium diagram, measurement of electrical conductivity, measurement of self-diffusion coefficient by NMR, observation of replica prepared using freeze fracture method, etc.
- the iconic-us microemulsion is a transparent, low-viscosity one-phase region and is optically isotropic.
- the optically anisotropic liquid crystal phase can be distinguished from the liquid crystal phase by holding the sample while combining two polarizing plates with a phase difference of 90 degrees and confirming that no light is transmitted.
- the noise-ease microemulsion phase and other isotropic eye regions The following method is more effective for distinguishing between micelle aqueous solution and reverse micelle oil solution.
- the mass ratio of the nonionic surfactant of component (A) to the oil of component (B) of the present composition is 1: 4 to 2: 1, and water is further added in a ratio of 4: 6.
- the composition ratio of water and oil is 3.2: 6 1.3: 6, i.e. water will occupy a 65- 82 mass 0/0 of the total yarn ⁇ , optically
- An isotropic clear, low viscosity solution is a micellar aqueous solution, or it may be a bicontinuous microemulsion.
- the detergent composition of the present invention When the detergent composition of the present invention is mixed with water at a ratio of 4: 6, if the aqueous solution does not become a micelle aqueous solution or a bicontinuous microemulsion, the desired properties of the present invention cannot be exhibited.
- the surfactant used in the present invention has an HLB of 6-14 and is hydrophilic. Therefore, on the phase diagram, in the present invention, the surfactant is continuously formed as a bicontinuous-us microemulsion phase from the top of the water through the region of the aqueous micelle solution. In many cases.
- the region becomes an OZw emulsified region that is completely clouded as judged by the HLB force.
- surfactants form micelles in water Since the oil is dispersed in a size of about several / zm, the light is white because all wavelengths are scattered. Further, since the continuous external phase is water, the desired cleaning effect cannot be satisfied.
- liquid crystal is often formed in a region where the surfactant concentration is higher than this range. In the region containing the liquid crystal, the region becomes cloudy and has a high viscosity, so that the massage property desired in the present invention cannot be satisfied.
- the region of the micelle aqueous solution is very small and can be obtained only in the region limited near the water peak.
- the composition according to the present invention is mixed with water at a ratio of 4: 6, a transparent state cannot be obtained.
- Such a phenomenon often occurs when the surfactant has insufficient solubilizing power or a structure in which oil is hardly solubilized.
- the oil is silicone-based even though the surfactant is alkyl-based, or vice versa, and furthermore, when the oil has a large molecular weight.
- the compounding amount represents mass%.
- ⁇ Substantially a single micelle aqueous solution or bicontinuous microemulsion phase.
- ⁇ Absorbance is 1 or more and less than 4
- Example 1 A cleansing composition was prepared according to the formulation shown in Table 1 below.
- Example A pseudo three-component phase diagram (water surfactant oil) using the components of Comparative Examples 1 and 2 is as shown in FIG. From the phase equilibrium diagram, Example 1 formed an aqueous micelle solution (L)
- composition was evaluated based on the above evaluation criteria. Table 1 also shows the results.
- the L1 region slightly fluctuates.
- the ratio of the nonionic surfactant to the oily component is in a ratio of 1: 4 to 2: 1, a suitable oily cleansing is preferable. It has been found that a composition is obtained.
- the solubility of the nonionic surfactant in the aqueous phase must be somewhat similar to the solubility in the oil phase. Since tap water is usually added to the oil-based cleansing composition of the present invention, it is difficult to adjust the tap water, and the correlation between the oil phase and the nonionic surfactant is inevitable. It becomes extremely important.
- the suitable IOB of the oily component also tends to increase. It is understood that the component IOB is preferably 0.02-0.07.
- a cleansing composition was prepared according to the formulation shown in Table 2 below.
- Example 2 a bicontinuous microemulsion phase (D) was formed by mixing water, and it was confirmed that Comparative Example 3 and Comparative Example 4 had other phase states.
- the oil phase used was a 2: 1 mixed oil of liquid paraffin: cetinoleisooctanoate.
- silicone oil decamethylcyclopentasiloxane
- Cleansing compositions were prepared according to the formulations shown in Tables 7-9 below. The obtained cleansing composition was evaluated based on the above evaluation criteria. The results are shown in Table 7-9.
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Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/585,146 US7879779B2 (en) | 2004-01-09 | 2005-01-11 | Oil-cleansing composition |
EP05703415.9A EP1704848B1 (en) | 2004-01-09 | 2005-01-11 | Oily cleansing composition |
KR1020067010334A KR101296942B1 (ko) | 2004-01-09 | 2005-01-11 | 유성 클렌징 조성물 |
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JP2004-004055 | 2004-01-09 | ||
JP2004004055A JP4757446B2 (ja) | 2004-01-09 | 2004-01-09 | 油性クレンジング組成物 |
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PCT/JP2005/000176 WO2005079729A1 (ja) | 2004-01-09 | 2005-01-11 | 油性クレンジング組成物 |
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US (1) | US7879779B2 (ja) |
EP (1) | EP1704848B1 (ja) |
JP (1) | JP4757446B2 (ja) |
KR (1) | KR101296942B1 (ja) |
CN (1) | CN100508936C (ja) |
TW (2) | TWI358452B (ja) |
WO (1) | WO2005079729A1 (ja) |
Cited By (1)
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DE102018219633A1 (de) | 2018-11-16 | 2020-05-20 | Beiersdorf Ag | Reinigungszubereitung enthaltend Mizellen |
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JP5220271B2 (ja) * | 2005-10-20 | 2013-06-26 | 株式会社 資生堂 | 泡状エアゾールメーキャップ洗浄料 |
JP4680798B2 (ja) * | 2006-02-28 | 2011-05-11 | 三洋化成工業株式会社 | 油性クレンジング用組成物 |
DE102007006778A1 (de) * | 2007-02-08 | 2008-08-14 | Beiersdorf Ag | Neues Duschöl |
JP5311842B2 (ja) * | 2008-02-20 | 2013-10-09 | 株式会社マンダム | クレンジング化粧料並びにその製造方法 |
JP2010090111A (ja) * | 2008-09-10 | 2010-04-22 | L'oreal Sa | クレンジング用組成物 |
WO2010134562A1 (ja) * | 2009-05-19 | 2010-11-25 | 株式会社 資生堂 | 化粧料 |
JP5468314B2 (ja) * | 2009-06-08 | 2014-04-09 | クラシエホームプロダクツ株式会社 | 皮膚洗浄剤組成物 |
JP4834775B2 (ja) | 2010-03-04 | 2011-12-14 | 株式会社 資生堂 | 日焼け止め用組成物 |
JP5855389B2 (ja) * | 2011-08-16 | 2016-02-09 | クラシエホームプロダクツ株式会社 | 皮膚洗浄剤組成物 |
JP6343802B2 (ja) * | 2013-07-03 | 2018-06-20 | ポーラ化成工業株式会社 | 皮膚洗浄用組成物 |
JP6255204B2 (ja) * | 2013-10-07 | 2017-12-27 | 川研ファインケミカル株式会社 | 極性油剤増粘方法及びそれを利用したオイル化粧料洗浄剤組成物 |
JP2015134741A (ja) * | 2013-12-18 | 2015-07-27 | ポーラ化成工業株式会社 | 皮膚外用剤並びに化粧料組成物及び医薬部外組成物 |
WO2016131687A1 (en) | 2015-02-19 | 2016-08-25 | Unilever Plc | Fast rinsing cleansing composition |
JP2017031326A (ja) * | 2015-07-31 | 2017-02-09 | Jxエネルギー株式会社 | W/oマイクロエマルション型洗浄剤の洗浄性の評価方法、w/oマイクロエマルション型洗浄剤による洗浄方法、および被膜形成方法 |
JP6576165B2 (ja) * | 2015-08-28 | 2019-09-18 | ポーラ化成工業株式会社 | 皮膚洗浄用組成物 |
KR102076003B1 (ko) * | 2015-11-27 | 2020-02-12 | (주)아모레퍼시픽 | 양친매성 이방성 분체를 포함하는 이중 연속상 유화 조성물 |
WO2019054362A1 (ja) * | 2017-09-13 | 2019-03-21 | 株式会社資生堂 | 油性洗浄料 |
JP6882148B2 (ja) | 2017-11-29 | 2021-06-02 | 信越化学工業株式会社 | 両連続型マイクロエマルション組成物及び化粧料 |
CN114555041A (zh) * | 2019-10-17 | 2022-05-27 | 株式会社资生堂 | 多层清洁组合物 |
CN112891253B (zh) * | 2019-11-19 | 2023-05-02 | 株式会社漫丹 | 皮肤清洗剂组合物 |
CN115044274B (zh) * | 2022-07-19 | 2023-04-28 | 宁波科鑫腐蚀控制工程有限公司 | 一种陶瓷颗粒改性纤维环氧复合涂层及其制备方法和应用 |
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- 2005-01-11 WO PCT/JP2005/000176 patent/WO2005079729A1/ja not_active Application Discontinuation
- 2005-01-11 EP EP05703415.9A patent/EP1704848B1/en active Active
- 2005-01-11 US US10/585,146 patent/US7879779B2/en active Active
- 2005-01-11 CN CNB2005800022118A patent/CN100508936C/zh active Active
- 2005-01-11 KR KR1020067010334A patent/KR101296942B1/ko active IP Right Grant
- 2005-02-04 TW TW094103560A patent/TW200628172A/zh unknown
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DE102018219633A1 (de) | 2018-11-16 | 2020-05-20 | Beiersdorf Ag | Reinigungszubereitung enthaltend Mizellen |
WO2020099036A1 (de) | 2018-11-16 | 2020-05-22 | Beiersdorf Ag | Reinigungszubereitung enthaltend mizellen |
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CN1909873A (zh) | 2007-02-07 |
JP2005194249A (ja) | 2005-07-21 |
EP1704848B1 (en) | 2017-07-26 |
TW200528555A (en) | 2005-09-01 |
US20080293603A1 (en) | 2008-11-27 |
EP1704848A4 (en) | 2011-12-28 |
KR20060111534A (ko) | 2006-10-27 |
JP4757446B2 (ja) | 2011-08-24 |
CN100508936C (zh) | 2009-07-08 |
TW200628172A (en) | 2006-08-16 |
KR101296942B1 (ko) | 2013-08-14 |
TWI358452B (en) | 2012-02-21 |
US7879779B2 (en) | 2011-02-01 |
EP1704848A1 (en) | 2006-09-27 |
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