JP5553918B2 - クレンジング化粧料 - Google Patents
クレンジング化粧料 Download PDFInfo
- Publication number
- JP5553918B2 JP5553918B2 JP2013021601A JP2013021601A JP5553918B2 JP 5553918 B2 JP5553918 B2 JP 5553918B2 JP 2013021601 A JP2013021601 A JP 2013021601A JP 2013021601 A JP2013021601 A JP 2013021601A JP 5553918 B2 JP5553918 B2 JP 5553918B2
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- JP
- Japan
- Prior art keywords
- polyoxyethylene
- cleansing
- oil
- mass
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002537 cosmetic Substances 0.000 title claims description 49
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- 239000002736 nonionic surfactant Substances 0.000 claims description 10
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- 239000000839 emulsion Substances 0.000 claims description 2
- -1 polyoxyethylene lauryl ether Polymers 0.000 description 40
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- 239000012071 phase Substances 0.000 description 22
- 239000003921 oil Substances 0.000 description 19
- 235000019198 oils Nutrition 0.000 description 19
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- 238000002156 mixing Methods 0.000 description 13
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 9
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- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 4
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- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 2
- ZFGOPJASRDDARH-UHFFFAOYSA-N 3-[[10,13-dimethyl-17-(6-methylheptan-2-yl)-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl]oxy]-10,13-dimethyl-17-(6-methylheptan-2-yl)-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthrene Chemical compound C12CCC3(C)C(C(C)CCCC(C)C)CCC3C2CC=C(C2)C1(C)CCC2OC1CC2=CCC3C4CCC(C(C)CCCC(C)C)C4(C)CCC3C2(C)CC1 ZFGOPJASRDDARH-UHFFFAOYSA-N 0.000 description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 2
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- 238000003917 TEM image Methods 0.000 description 2
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- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 229940092738 beeswax Drugs 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000010437 gem Substances 0.000 description 2
- 229910001751 gemstone Inorganic materials 0.000 description 2
- GCXZDAKFJKCPGK-UHFFFAOYSA-N heptane-1,2-diol Chemical compound CCCCCC(O)CO GCXZDAKFJKCPGK-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000010466 nut oil Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 2
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- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
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- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
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- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- LQXBZWFNAKZUNM-UHFFFAOYSA-N 16-methyl-1-(16-methylheptadecoxy)heptadecane Chemical compound CC(C)CCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC(C)C LQXBZWFNAKZUNM-UHFFFAOYSA-N 0.000 description 1
- RNNHLXAEVKCLDG-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octamethyl-1,3,5,7,9,2,4,6,8,10-pentaoxapentasilecane Chemical compound C[Si]1(C)O[SiH2]O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 RNNHLXAEVKCLDG-UHFFFAOYSA-N 0.000 description 1
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- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
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- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 229940114937 microcrystalline wax Drugs 0.000 description 1
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- 229940105132 myristate Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- LJZULWUXNKDPCG-UHFFFAOYSA-N nonane-1,2-diol Chemical compound CCCCCCCC(O)CO LJZULWUXNKDPCG-UHFFFAOYSA-N 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
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- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
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- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
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Description
〔試料の調製〕
表1に記した組成に従い、実施例1〜2及び比較例1〜3のクレンジング化粧料を調製した。すなわち、成分A1の多価アルコール水溶液に、成分Bを攪拌しながら投入し、成分Bの溶解温度まで加熱した。続いて成分Cを撹拌しながらゆっくりと加えて各比較例のクレンジング化粧料を得た。また、成分Cを加えたのち、成分A2の1,2−アルカンジオールを投入することで、各実施例のクレンジング化粧料を得た。
外観試験、偏光板による光透過試験、水性及び油性色素の分散試験、透過型電子顕微鏡観察、粘度測定により、以下の判定基準に基づき相状態を判定した。結果を表1に併記する。
各試料の透明度及び性状を目視にて判定した。
実施例及び比較例の各試料の粘度は、デジタル型粘度計(TV−22型粘度計、東機産業株式会社製)を用い、No.2ローターで、回転数12rpm、測定時間60秒の条件で測定した。
宝石鑑定に用いられる光源と2枚の偏光板を備えた宝石偏光器を用い、2枚の偏光板が直行するように配置した。実施例及び比較例の各試料を偏光板の間に配置し、光の透過・屈折を観察し、光学等方性或いは光学異方性の判定をした。
30mL容ガラス製スクリュー管に実施例及び比較例の各試料を充填し、0.01質量%の青色1号水溶液を適量添加して軽く振盪し、各試料が青色透明溶液となるかを確認した。また、0.01質量%青色1号水溶液を0.1質量%β-カロテンのスクワラン溶液に替え、同様に操作して、黄色透明溶液となるかを確認した。
実施例及び比較例の各試料を凍結割断レプリカ法によりレプリカを作成した。相状態の観察は、作成したレプリカを透過型電子顕微鏡(JEM1200EX型、日本電子株式会社製)を用いて倍率50000倍にて実施した。
BC:バイコンティニュアスマイクロエマルション
粘度は1000mP・s以下であり、光学等方性の透明な液状を示し、水性色素および油性色素を30秒以内に分散し、透過型電子顕微鏡観察で連続的なチャネルが相互に入り組んだ構造が観察された。
D:D相ゲル
粘度は1000mP・sより高く、光学等方性の透明なゲル状を示し、水性色素および油性色素を30秒以内に分散することができず、透過型電子顕微鏡観察で連続的なチャネルが相互に入り組んだ構造が観察されない。
O/D:D相ゲル中油型エマルション
粘度は1000mP・sより高く、光学等方性の白濁したゲル状を示し、水性色素および油性色素を30秒以内に分散することができず、透過型電子顕微鏡観察で連続的なチャネルが相互に入り組んだ構造が観察されない。
LC:液晶
粘度は1000mP・sより高く、光学異方性の透明なゲル状を示し、水性色素および油性色素を30秒以内に分散することができず、透過型電子顕微鏡観察で連続的なチャネルが相互に入り組んだ構造が観察されない。
。
前腕内側部に口紅(商品名:クレージュ ルージュ ア レーヴル 502、株式会社ビューコス社製)を適量塗布し、実施例及び比較例の各クレンジング化粧料0.2gを塗布し、指でクレンジング動作を上下に15往復し、メイク汚れとの馴染みの度合いを評価した。その後、流水で洗い流し、メイク汚れの洗い流し性(クレンジング効果)及び使用後のさっぱり感を評価した。評価は、被験者20名で実施し、下記評価基準に従い判定した。結果を表1に併記する。
◎:18〜20名がメイク汚れとの馴染みが良いと回答。
○:14〜17名がメイク汚れとの馴染みが良いと回答。
△:10〜13名がメイク汚れとの馴染みが良いと回答。
×:0〜9名がメイク汚れとの馴染みが良いと回答。
◎:18〜20名が十分に洗い流しが良いと回答。
○:14〜17名が十分に洗い流しが良いと回答。
△:10〜13名が十分に洗い流しが良いと回答。
×:0〜9名が十分に洗い流しが良いと回答。
◎:18〜20名がさっぱりとした使用感であると回答。
○:14〜17名がさっぱりとした使用感であると回答。
△:10〜13名がさっぱりとした使用感であると回答。
×:0〜9名がさっぱりとした使用感であると回答。
表2〜3の組成に従い、上記と同様に実施例及び比較例の各クレンジング化粧料を調製し、上記と同様に相状態の判定及びクレンジング化粧料の評価を行った。結果を表2〜3に併記する。
流動パラフィン 19.0
スクワラン 1.0
ミリスチン酸デカグリセリル 40.0
1,2−オクタンジオール 5.0
グリセリン 17.5
精製水 残 量
合 計 100.0
パルミチン酸オクチル 40.0
ホホバ油 1.0
オリーブ油 0.1
メチルポリシロキサン 0.1
ポリオキシエチレン(40)硬化ヒマシ油 20.0
1,2−ペンタンジオール 1.0
1,2−ヘキサンジオール 2.0
1,2−オクタンジオール 2.0
グリセリン 19.5
トコフェロール 適 量
香料 適 量
精製水 残 量
合 計 100.0
流動パラフィン 20.0
スクワラン 0.5
デカメチルシクロペンタシロキサン 0.1
マカデミアナッツ油 0.1
イソステアリン酸ポリオキシエチレン(5)グリセリル 40.0
1、3−ブチレングリコール 16.5
ジプロピレングリコール 1.0
1,2−オクタンジオール 5.0
1,2−デカンジオール 1.0
香料 適 量
精製水 残 量
合 計 100.0
Claims (2)
- 非イオン性界面活性剤、油性成分、水、炭素数5〜10の1,2−アルカンジオール以外の多価アルコール、及び炭素数6の1,2−アルカンジオールを含有し、バイコンティニュアスマイクロエマルション構造を有し、透明液状であり、粘度が1000mPa・S以下1mPa・S以上であることを特徴とするクレンジング化粧料。
- 非イオン性界面活性剤が、HLB値8以上の非イオン性界面活性剤であることを特徴とする請求項1に記載のクレンジング化粧料。
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