WO2005070372A1 - Composition solide transparente et preparation cosmetique solide transparente contenant ladite composition comme base - Google Patents

Composition solide transparente et preparation cosmetique solide transparente contenant ladite composition comme base Download PDF

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Publication number
WO2005070372A1
WO2005070372A1 PCT/JP2005/000774 JP2005000774W WO2005070372A1 WO 2005070372 A1 WO2005070372 A1 WO 2005070372A1 JP 2005000774 W JP2005000774 W JP 2005000774W WO 2005070372 A1 WO2005070372 A1 WO 2005070372A1
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WIPO (PCT)
Prior art keywords
transparent solid
acid
oil
mass
solid composition
Prior art date
Application number
PCT/JP2005/000774
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English (en)
Japanese (ja)
Inventor
Katsuyuki Kaneko
Takuma Kurahashi
Katsuyuki Hasegawa
Yoshimasa Miura
Original Assignee
Shiseido Company, Ltd.
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Application filed by Shiseido Company, Ltd. filed Critical Shiseido Company, Ltd.
Priority to CN2005800033381A priority Critical patent/CN1913864B/zh
Publication of WO2005070372A1 publication Critical patent/WO2005070372A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/85—Polyesters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Definitions

  • the present invention relates to a transparent solid composition and a transparent solid cosmetic containing the same as a base.
  • the present invention relates to a transparent solid composition and a transparent solid cosmetic containing the composition as a base.
  • Patent Document 1 discloses a transparent cosmetic containing a polyhydric alcohol ester of 12-hydroxystearic acid and rosin and a polyhydric alcohol side chain fatty acid partial ester or a polyhydric alcohol unsaturated fatty acid partial ester. Is disclosed.
  • Patent Literature 2 discloses a cosmetic composition using 12-hydroxystearic acid and a transparent base having a refractive index of 1.45 to 1.54 that also provides an oil component.
  • Patent Document 3 discloses a transparent solid cosmetic composition comprising 12-hydroxystearic acid, heavy liquid paraffin and liquid oily component
  • Patent Document 4 discloses 12-hydroxystearic acid and A transparent solid cosmetic containing a transparent liquid oil component having a hydroxyl value of 120 or less and methylphenol polysiloxane has been disclosed! Puru.
  • Patent Document 5 discloses a transparent cosmetic containing a dextrin fatty acid ester, heavy liquid paraffin, and a liquid oil component from the viewpoint of improving the gloss at the time of application.
  • a solid cosmetics cosmetic is disclosed.
  • Patent Document 6 discloses a transparent cosmetic comprising 0.2 to 40% of a dextrin fatty acid ester limited to a specific structure obtained by a specific manufacturing method and a liquid oil.
  • the cosmetic include a hair cosmetic (Example 1). , 2), suntan oil gels (Examples 3 and 4), oily foundations (Examples 5 and 6), WZO type foundation (Examples 7-9), cleansing cream (Example 10), etc.
  • a cosmetic formulation is disclosed!
  • Patent Document 7 discloses a transparent cosmetic containing 12-hydroxystearic acid and an oil component. Further, a transparent cosmetic composition comprising a dextrin fatty acid ester having a specific structure and a refractive index of an oil component of 1.44 to 1.54 is disclosed.
  • Patent Document 8 discloses a transparent solid cosmetic containing a dextrin fatty acid ester, amorphous silica of particle diameter of SOOO—0.05 m, and spherical silica of particle diameter of 0.1 to 30 wm. It has been disclosed.
  • Patent Document 9 discloses a PMMA powder having fine porous spheres or fine spheres, and silicone oil, and has an appearance which is stabilized by an oily gelling agent.
  • a cosmetic characterized by having polychromaticity is disclosed.
  • Patent Document 1 JP-A-63-119405
  • Patent Document 2 JP-A-1 163111
  • Patent Document 3 JP-A-2-264707
  • Patent Document 4 JP-A-4-91010
  • Patent Document 5 JP-A-9-235210
  • Patent Document 6 JP-A-2001-39817
  • Patent Document 7 JP 2001-39817 A
  • Patent Document 8 JP-A-11 255616
  • Patent Document 9 JP-A-2000-212039
  • the applicant of the present invention targeted 180 women in their twenties and fifties with regard to facial skin problems.
  • pores were ranked first in their 20s and 30s, and second in their 40s.
  • the present invention is a transparent cosmetic that has an effect of correcting unevenness of the skin, eliminates conspicuous pores, and gives a natural skin impression. It is another object of the present invention to provide a novel and useful transparent solid composition having good composition stability.
  • the present inventors have intensively studied to solve the above problems and to develop a more excellent transparent solid cosmetic formulation.
  • (d) A specific transparent solid composition having a refractive index of 1.3 to 1.6 and containing 15 to 60% by mass of a spherical powder having an average particle size of 3.1 to 30 ⁇ m has excellent transparency.
  • the present inventors have found that it is possible to provide a transparent solid cosmetic composition which has an effect of correcting unevenness of the skin, has an effect of making pores less noticeable, and gives an excellent feeling of use, and has completed the present invention.
  • the present invention provides (a) a dextrin fatty acid ester of 120% by mass, (b) a volatile oil component having a boiling point of 250 ° C. or less at normal pressure of 10 to 40% by mass, and (c) a refraction. And (d) a spherical powder with a refractive index of 1.3-1.6 and an average particle size of 3-30 m, and 15-60 mass%. It is intended to provide a transparent solid composition characterized by containing:
  • the (d) spherical powder having a refractive index of 1.3 to 1.6 and an average particle diameter of 3 to 30 m was selected from the group consisting of silica, polyurethane, and polyethylene. It is intended to provide the transparent solid composition described above, which is one or more powders.
  • the present invention is characterized in that the content of one or more selected from (e) higher alcohols, higher fatty acids, and POE / POP dimethyl ether is also 110 to 10% by mass.
  • the present invention provides the above transparent solid composition.
  • the present invention provides a transparent solid cosmetic containing the above-mentioned transparent solid composition as a base.
  • the transparent solid composition of the present invention has excellent transparency and stability.
  • This transparent solid composition provides a transparent solid cosmetic that can surprisingly exert an effect of making pores less noticeable when applied to the skin. In addition, its use feeling is extremely excellent.
  • FIG. 1 is a graph showing the intensity of light diffusion.
  • the dextrin fatty acid ester functioning as a transparent solidifying agent is an ester of dextrin and a fatty acid having a linear or branched alkyl group (preferably having 3 to 30 carbon atoms). It can be obtained by reacting fatty acid chloride under heating using pyridine as a basic catalyst.
  • Dextrin binds myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, linolenic acid, araquinic acid, and these fatty acids having a substituent such as a branch, a hydroxyl group or a phenyl group Are preferred.
  • dextrin palmitate is particularly preferred.
  • the blending amount of the dextrin fatty acid ester is 1 to 20% by mass, preferably 7 to 14% by mass, based on the total amount of the composition (in the case of cosmetics, based on the total amount of cosmetics: the same applies hereinafter).
  • isoparaffin about 225 ° C
  • otatamethylcyclotetrasiloxane 175 ° C
  • examples include cyclomethicone such as decamethylcyclopentasiloxane (210 ° C) and dodecamethylcyclopentasiloxane (245 ° C), low molecular weight dimethicone having a boiling point of 250 ° C or less, and derivatives thereof.
  • it is cyclomethicone.
  • the amount of the volatile oil having a boiling point at normal pressure of 250 ° C. or lower is 10 to 40% by mass, preferably 10 to 25% by mass, based on the total amount of the composition.
  • dimethylpolysiloxane about 1.40
  • glyceryl tri-2-ethylhexanoate about 1.44
  • 2-ethylhexanoic acid Cetyl (approx. 1.44)
  • trimethylolpropane trioctanoate approximately 1.45
  • squalane approximatelyx. 1.45
  • alpha-leufin oligomer approximatelyx. 1.46
  • glyceryl diisostearate approximatelyx.
  • Diisostearyl malate about 1.46
  • polyglyceryl triisostearate about 1.47
  • macadamia nut oil about 1.47
  • liquid paraffin about 1.47
  • methylphenol polysiloxane about 1.4-1 1.6
  • silicone ⁇ ⁇ F56 (refractive index: about 1.5, viscosity: 10-20 mmVs) of methyl phenol polysiloxane manufactured by Shin-Etsu-Dagaku Kogyo KK can be used.
  • the compounding amount of the oil component having a refractive index of 1.4 to 1.6 is 10 to 40% by mass based on the total amount of the composition, and (b) a volatile oil component having a boiling point at normal pressure of 250 ° C or less; (C)
  • the composition ratio of an oil having a refractive index of 1.4 to 1.6 cannot be determined unequivocally because it varies depending on the combination of the oil and the powder, and the blending amount.
  • polystyrene about 1.59), PET (about 1.58), nylon (about 1.53), polyethylene (about 1.51), polyurethane (about 1.50), silicic acid anhydride (about 1.45) -1.50), spherical silica with an average particle size of 3-30 ⁇ m, such as hydrous silicic acid (about 1.40-1.50), polytetrafluoroethylene (about 1.35-1.38) And preferably spheres of silicic acid, polyurethane or polyethylene Powder.
  • the numerical values in parentheses indicate the value of the refractive index.
  • PMMA powder is not preferred as the component (d) powder of the present invention.
  • the compounding amount of the spherical powder is 15 to 60% by mass, preferably 25 to 50% by mass based on the total amount of the composition.
  • One of the features of the present invention is that the spherical powder is highly blended.
  • the refractive index refers to oil content! Is a value measured by a digital refractometer (ATAGO type: RX5000a). did.
  • the present invention is a transparent solid composition or a transparent solid cosmetic based on the composition.
  • the transparency of the present invention is described in the following section.
  • the appearance of the Times New Roman font 88 in font 88 placed under a container at 25 ° C is described below. Can be evaluated by a method for measuring transparency.
  • a higher alcohol, a higher fatty acid, POE ⁇ POP dimethyl ether, and one or more selected from the group powers are also blended, so that oil floating and the like can be obtained. And a composition having excellent stability can be obtained.
  • This composition is preferably used for various bases such as foundations and makeup bases.
  • the higher alcohol is a higher alcohol having an alkyl group having 6 to 20 carbon atoms, and is preferably caproyl alcohol, capryl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, or arakinyl alcohol.
  • the alkyl group may be branched, or may have a substituent such as an unsaturated bond, a hydroxyl group, a carboxyl group, or a phenyl group.
  • the higher fatty acid is a fatty acid having an alkyl group having 9 to 130 carbon atoms, and is preferably ptyronic acid, lauric acid, myristic acid, palmitic acid, stearic acid, araquinic acid, behenic acid, or melicic acid.
  • the alkyl group may be branched or may have a substituent such as an unsaturated bond, a hydroxyl group, a carboxyl group, or a phenyl group.
  • unsaturated fatty acids such as palmitoleic acid, oleic acid, linoleic acid, linolenic acid, petroselinic acid, elaidic acid, ricinoleic acid, linoleic acid, arachidonic acid; branched fatty acids such as isostearic acid; 12-hydroxystearic acid Hydroxycarboxylic acids and the like are also preferred.
  • ⁇ ⁇ POP dimethyl ether is the alkyl dimethyl ether described in JP-A-2003-113023. An oxide derivative can be used.
  • the amounts of these components are appropriately determined, but are usually 110 to 10% by mass, preferably 2 to 7% by mass, based on the total amount of the composition.
  • the dosage form of the transparent solid cosmetics preparation is a gel composition or a solid composition, and its product form is not particularly limited.
  • makeup cosmetics such as foundations, lipsticks, lip darros, lip tales, eye shadows, etc.
  • makeup bases such as skin care cosmetics, hair sticks, and hair cosmetics such as pomade. It is used as a container for filling and as a stick-shaped transparent solid cosmetic.
  • the transparent solid composition of the present invention may contain any component as long as the effects of the present invention are not impaired.
  • any transparent solid cosmetic can be produced by a conventional method by adding components to be added to the cosmetic.
  • compositions that are preferably blended include powders, oil-soluble drugs, vegetable oils, ultraviolet absorbers, and the like within a range that does not impair transparency.
  • the powder component includes, for example, inorganic powders (for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, mica, biotite, permikilite, magnesium carbonate) , Calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulphate, calcined calcium sulphate (calcium acetate), calcium phosphate, fluorine apatite , Hydroxyapatite, ceramic powder, metal stone (eg, zinc myristate, calcium normitate, aluminum stearate), boron nitride, etc.); inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigments ( For example, iron oxide (silver), titanic acid Inorganic brown pigments (eg, ⁇ -iron oxide,
  • Red No. 405 Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401 and Blue No. 404, Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red 230, Red 401, Red 505, Orange 205, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Green 3, Blue 1, etc .; natural pigments (eg, chlorophyll, Rotin) and the like.
  • natural pigments eg, chlorophyll, Rotin
  • liquid fats and oils examples include apogado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, small wheat germ oil, southern oil, castor oil , Linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, teaseed oil, cocoa oil, rice oil, cinnamon oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, etc. .
  • solid fats and oils examples include cocoa butter, coconut oil, hydrogenated coconut oil, palm oil, palm kernel oil, molle kernel oil, hydrogenated oil, molle, and hydrogenated castor oil.
  • Examples of the wax include beeswax, candelilla wax, cotton wax, carnaupa wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, and lauric acid. Hexyl, reduced lanolin, jojoba wax, hard lanolin, shellac wax, ⁇ lanolin alcohol ether, ⁇ lanolin alcohol acetate, ⁇ cholesterol ether, lanolin fatty acid polyethylene glycol, ⁇ hydrogenation lanolin alcohol ether, ceresin, microcrystalline wax, etc. Is mentioned.
  • hydrocarbon oil examples include liquid paraffin, ozokerite, squalane, pristane, paraffin, squalene, petrolatum, and the like.
  • ester oils include isopropyl myristate, cetyl octoate, octyl dodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, lactic acid Cetyl, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethyl 2-diethylhexanoate Glycol, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptyldidecanoate, trimethylolpropane tri-2-ethyl
  • silicone oil examples include linear polysiloxane (eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxane (eg, otatamethylcyclotetrasiloxane, decamethyl) Cyclopentasiloxane, dodecamethylcyclohexasiloxane, etc.), silicone resins and silicone rubbers that form a three-dimensional network structure, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane) , Fluorine-modified polysiloxane, etc.).
  • linear polysiloxane eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.
  • lipophilic nonionic surfactant examples include sorbitan fatty acid esters (eg, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate) Sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate, etc.); glycerin polyglycerin fatty acids (for example, mono-cottonseed oil fatty acids) Glycerin, glycerin monoernic acid, glycerin sesquioleate, glycerin monostearate, glycerin ⁇ , ⁇ -oleic acid pyroglutamate, glyceryl monostearate malic acid, etc.); propylene glycol fatty acid esters ( For example, propylene
  • hydrophilic nonionic surfactant examples include POE-sorbitan fatty acid esters (eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan monooleate).
  • POE-sorbitan fatty acid esters eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan monooleate.
  • POE-sorbit fatty acid esters eg, POE-sorbit monolaurate, POE-sorbit monooleate, POE-sorbit pentaoleate, POE-sorbit monostearate, etc.
  • POE- Glycerin fatty acid esters eg, POE-monooleate such as POE-glycerin monostearate, POE-glycerin monoisostearate, POE-glycerin triisostearate
  • POE-fatty acid esters eg, POE-distearate) POE-monodioleate, ethylene glycol distearate, etc.
  • POE-alkyl POTELs eg, POE-lauryl ether, POE-oleinoleatenole, POE-steolinoleatenole, POE-behe-noleatenole, POE-2-otatyldodecyl ether, POE-cholestan
  • humectant examples include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucotin sulfate, caronic acid, atelocollagen, and cholesteryl-12.
  • UV absorbers The following compounds may be mentioned as UV absorbers.
  • noraminobenzoic acid hereinafter abbreviated as PABA
  • PABA monoglycerin ester ⁇ , ⁇ -dipropoxy PABA ethyl ester, ⁇ , ⁇ -diethoxy PABA ethyl ester, ⁇ , ⁇ -dimethyl PABA ethyl ester, ⁇ , ⁇ -dimethyl PABA butyl Esters, ⁇ , ⁇ -dimethyl PABA ethyl ester and the like.
  • homomenthyl-N-acetylanthra-rate For example, homomenthyl-N-acetylanthra-rate.
  • amyl salicylate menthyl salicylate, homomenthyl salicylate, octenoresalicylate, fu-noresalicylate, penzinoresalicylate, p-isopropanolphenyl salicylate and the like.
  • octylcinnamate ethyl-4-isopropylcinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p -Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-P-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyxyl -p- Methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl- ⁇ -cyano-j8-phenylcinnamate, 2-ethylhexyl-a-cyano-13-phenylcinnamate,
  • Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyxietan-1,1-diphosphonic acid tetrasodium salt, disodium edetate, and edetate trina. Thorium, tetrasodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate, dalconic acid, phosphoric acid, citrate, ascorbic acid, conodic acid, edetate, trisodium ethylenediaminehydroxyethyl triacetate, etc. Is mentioned.
  • vitamins examples include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, and biotin.
  • antioxidants examples include tocopherols, dibutylhydroxytoluene, butyrhydroxy-sol, gallic acid esters and the like.
  • antioxidant aid examples include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylenediamine tetraacetic acid and the like. Is mentioned.
  • Other compoundable ingredients include, for example, preservatives (methyl paraben, ethyl paraben, butyl paraben, phenoxyethanol, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, thiotaurine, hypotaurine, hinokitiol, Zinc oxide, allantoin, etc.); whitening agents (eg, saxifrage extract, arbutin, tranexamic acid, magnesium L-ascorbic acid, magnesium salt of L-ascorbic acid, darcoside L-ascorbic acid, potassium 4-methoxysalicylate, etc.); various extractions Objects (eg, Obatata, Oren, Sikon, Peony, Assemblage, Perch, Sage, Beetle, Carrot, Aloe, Zeniay, Iris, Grape, Grass, Grasshopper, Hetima, Li
  • the present invention will be described more specifically with reference to examples.
  • the present invention is not limited by the following examples.
  • the compounding amount is mass%.
  • the examples and comparative examples were produced by a conventional method.
  • the methylphenolpolysiloxane of the component (c) was silicone KF56 (refractive index: 1.4
  • the sample was poured into a transparent resin container to a thickness of 5 mm and placed at 25 ° C at the bottom of the container. .
  • the transparent solid composition of the present invention has excellent transparency. 5: It looks very clear and very clear.
  • the transparent solid composition of the present invention has excellent stability.
  • the effect of making the skin irregularities inconspicuous while being transparent was evaluated by measuring the light diffusion intensity over time. In other words, if the effect of scattering light is high, it can be evaluated that the effect of correcting unevenness of the skin is high. This mechanism can be evaluated by measuring the light diffusion intensity of the transparent solid composition over time.
  • the graph of the volatile oil content is the composition of Example 17 in which the essential components (a), (b), (c), (d) and (e) are all blended.
  • the unblended graph is a composition in which only (a), (c), and (d) are used, and (b) is replaced with (c) instead of (b).
  • the transparent solid composition of the present invention exhibits a more excellent unevenness correction effect than the specific composition of the present invention due to the component (b).
  • Increasing the amount of the volatile oil reduces the amount of residual oil, reduces the feeling of oil residue, and provides excellent squashiness and smoothness.
  • the feeling of use of the powder varies depending on the amount. With this base, it was clear that at least 15% of the blend was necessary to give a smooth feeling to the spherical powder.
  • Example 7 Example 9 Example 10 Example 1 1 Example 12 Example 13 Example 14 Example 15 Example 16 Methylphenylpolysiloxane 30 28.8 28.8 28.8 28.8 28.8 28.8 28.8 28.8 28.8 Decamethylcyclopentasiloxane 20 19.2 19.2 19.2 19.2 19.2 19.2 19.2 Spherical gay anhydride powder (average particle size: 4-6 im) 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 Dextrin palmitate 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 Palmitic acid-2---- ---Stearic acid--2------Isostearic acid---2--------
  • the transparent cosmetics of the above examples are excellent in transparency of the appearance of the base (all evaluated by the above-mentioned transparency test are 5), and are clear cosmetics that have a good feeling in use and make the pores stand out.
  • the transparent solid composition of the present invention has excellent transparency and is preferably used as a base for transparent solid cosmetics.
  • a transparent solid shampoo that exhibits outstanding transparency and has excellent transparency, and has a skin unevenness-correcting effect that makes the pores and fine lines on the face stand out. Further, its stability and feeling of use are extremely excellent.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Cosmetics (AREA)

Abstract

L'invention concerne une composition solide transparente se caractérisant en ce qu'elle comprend (a) de 1 à 20 % en masse d'un ester d'acide gras de dextrine, (b) de 10 à 40 % en masse d'une matière grasse volatile avec un point de fusion de 250 °C ou moins sous pression ordinaire, (c) de 10 à 40 % en masse d'une matière grasse avec un indice de réfraction de 1,4 à 1,6, et (d) de 15 à 60 % en masse de particules sphériques avec un indice de réfraction de 1,3 à 1,6 et un diamètre de particule moyen de 3 à 30νm. L'invention concerne également une préparation cosmétique solide transparente donnant une excellente sensation de transparence, lissant les irrégularités de surface de la peau et camouflant les pores, et donnant d'agréables sensations en cours d'utilisation.
PCT/JP2005/000774 2004-01-27 2005-01-21 Composition solide transparente et preparation cosmetique solide transparente contenant ladite composition comme base WO2005070372A1 (fr)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009535355A (ja) * 2006-05-03 2009-10-01 イーエルシー マネージメント エルエルシー 透明な化粧品組成物およびその使用方法
EP3834809A4 (fr) * 2018-08-10 2022-05-04 Shiseido Company, Ltd. Produit cosmétique à base d'huile
US11501457B2 (en) 2020-05-08 2022-11-15 The Procter & Gamble Company Methods for identifying dendritic pores
US11776161B2 (en) 2018-08-21 2023-10-03 The Procter & Gamble Company Methods for identifying pore color

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4606187B2 (ja) * 2004-03-01 2011-01-05 株式会社コーセー 化粧料
JP5409046B2 (ja) * 2009-02-27 2014-02-05 株式会社コーセー 凹凸補正粉末化粧料
KR101064056B1 (ko) 2009-05-29 2011-09-08 (주)아모레퍼시픽 투명 그라데이션 화장료 조성물
JP5170779B2 (ja) * 2009-10-06 2013-03-27 株式会社トキワ 油性固形化粧料
JP6169899B2 (ja) * 2013-06-14 2017-07-26 株式会社 資生堂 凹凸補正用化粧料
CA3006697A1 (fr) * 2015-12-22 2017-06-29 Unilever Plc Composition benefique pour la peau a base d'un solvant a fonctionnalite hydroxy
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US11123269B2 (en) 2016-08-08 2021-09-21 Shiseido Company, Ltd. Transparent solid composition
JP6991780B2 (ja) * 2016-08-10 2022-01-13 株式会社コーセー 油性化粧料
KR102336132B1 (ko) * 2016-11-11 2021-12-07 (주)아모레퍼시픽 흡유능, 도포성 및 성형성이 향상된 메이크업 화장료 조성물 및 이의 제조방법
KR20190084968A (ko) 2016-11-17 2019-07-17 가부시키가이샤 시세이도 유성 조성물 및 유성 화장료
JP6859152B2 (ja) * 2017-03-27 2021-04-14 株式会社コーセー 固形化粧料
JP7320914B2 (ja) 2017-04-26 2023-08-04 株式会社 資生堂 透明組成物および透明化粧料

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63275518A (ja) * 1987-05-08 1988-11-14 Terumo Corp 半固形組成物
JPH09235210A (ja) * 1996-02-29 1997-09-09 Shiseido Co Ltd 固形化粧料
JPH11222413A (ja) * 1998-02-02 1999-08-17 Nippon Shikizai Inc 固形化粧料
JPH11255616A (ja) * 1998-03-10 1999-09-21 Nippon Shikizai Inc 固形化粧料
JP2000026232A (ja) * 1998-07-03 2000-01-25 Noevir Co Ltd 固形状化粧料
JP2001019613A (ja) * 1999-07-05 2001-01-23 Asanuma Sogyo Kk ペンシル状又はスティック状固形化粧料
JP2002308731A (ja) * 2001-04-11 2002-10-23 Chifure Keshohin:Kk 固形化粧料
JP2002322030A (ja) * 2001-04-26 2002-11-08 Kose Corp 凹凸補正化粧料
JP2003063933A (ja) * 2001-08-24 2003-03-05 Kose Corp 毛穴・しわ隠し化粧料
JP2003137760A (ja) * 2001-10-29 2003-05-14 Asahi Glass Co Ltd 肌用化粧料
JP2003146840A (ja) * 2001-11-12 2003-05-21 Shiseido Co Ltd 油性ファンデーション
JP2003327508A (ja) * 2002-05-13 2003-11-19 Takashi Yokota 透明性基剤及びそれを配合した化粧料

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000212039A (ja) * 1999-01-14 2000-08-02 Naris Cosmetics Co Ltd 多色性を有する化粧料

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63275518A (ja) * 1987-05-08 1988-11-14 Terumo Corp 半固形組成物
JPH09235210A (ja) * 1996-02-29 1997-09-09 Shiseido Co Ltd 固形化粧料
JPH11222413A (ja) * 1998-02-02 1999-08-17 Nippon Shikizai Inc 固形化粧料
JPH11255616A (ja) * 1998-03-10 1999-09-21 Nippon Shikizai Inc 固形化粧料
JP2000026232A (ja) * 1998-07-03 2000-01-25 Noevir Co Ltd 固形状化粧料
JP2001019613A (ja) * 1999-07-05 2001-01-23 Asanuma Sogyo Kk ペンシル状又はスティック状固形化粧料
JP2002308731A (ja) * 2001-04-11 2002-10-23 Chifure Keshohin:Kk 固形化粧料
JP2002322030A (ja) * 2001-04-26 2002-11-08 Kose Corp 凹凸補正化粧料
JP2003063933A (ja) * 2001-08-24 2003-03-05 Kose Corp 毛穴・しわ隠し化粧料
JP2003137760A (ja) * 2001-10-29 2003-05-14 Asahi Glass Co Ltd 肌用化粧料
JP2003146840A (ja) * 2001-11-12 2003-05-21 Shiseido Co Ltd 油性ファンデーション
JP2003327508A (ja) * 2002-05-13 2003-11-19 Takashi Yokota 透明性基剤及びそれを配合した化粧料

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009535355A (ja) * 2006-05-03 2009-10-01 イーエルシー マネージメント エルエルシー 透明な化粧品組成物およびその使用方法
EP3834809A4 (fr) * 2018-08-10 2022-05-04 Shiseido Company, Ltd. Produit cosmétique à base d'huile
US11771630B2 (en) 2018-08-10 2023-10-03 Shiseido Company, Ltd. Oil-based cosmetic
US11776161B2 (en) 2018-08-21 2023-10-03 The Procter & Gamble Company Methods for identifying pore color
US11501457B2 (en) 2020-05-08 2022-11-15 The Procter & Gamble Company Methods for identifying dendritic pores

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JP2005213145A (ja) 2005-08-11
JP4442751B2 (ja) 2010-03-31
CN1913864B (zh) 2010-05-05
KR20060130101A (ko) 2006-12-18
CN1913864A (zh) 2007-02-14
TWI350181B (fr) 2011-10-11
TW200528135A (en) 2005-09-01

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