WO2005044964A1 - 防錆性油水分離型洗浄剤組成物及び洗浄方法 - Google Patents
防錆性油水分離型洗浄剤組成物及び洗浄方法 Download PDFInfo
- Publication number
- WO2005044964A1 WO2005044964A1 PCT/JP2004/015520 JP2004015520W WO2005044964A1 WO 2005044964 A1 WO2005044964 A1 WO 2005044964A1 JP 2004015520 W JP2004015520 W JP 2004015520W WO 2005044964 A1 WO2005044964 A1 WO 2005044964A1
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- Prior art keywords
- oil
- water
- cleaning
- water separation
- separation type
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 158
- 239000000203 mixture Substances 0.000 title claims abstract description 73
- 238000000926 separation method Methods 0.000 title claims abstract description 70
- 239000003599 detergent Substances 0.000 title claims abstract description 40
- 238000004140 cleaning Methods 0.000 title claims description 74
- 238000000034 method Methods 0.000 title claims description 19
- 239000003921 oil Substances 0.000 claims abstract description 83
- -1 polyol esters Chemical class 0.000 claims abstract description 77
- 239000002480 mineral oil Substances 0.000 claims abstract description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 15
- 239000000194 fatty acid Substances 0.000 claims abstract description 15
- 229930195729 fatty acid Natural products 0.000 claims abstract description 15
- 239000003784 tall oil Substances 0.000 claims abstract description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004519 grease Substances 0.000 claims abstract description 10
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 10
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 8
- 229920005862 polyol Polymers 0.000 claims abstract description 8
- 229920013639 polyalphaolefin Polymers 0.000 claims abstract description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 27
- 239000012188 paraffin wax Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 235000019198 oils Nutrition 0.000 description 65
- 238000005406 washing Methods 0.000 description 23
- 150000002430 hydrocarbons Chemical group 0.000 description 22
- 150000001875 compounds Chemical class 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 14
- 239000002699 waste material Substances 0.000 description 13
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 12
- 235000001014 amino acid Nutrition 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 229910000831 Steel Inorganic materials 0.000 description 7
- 239000012459 cleaning agent Substances 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 5
- ZUXWMZPBQLGDDY-UHFFFAOYSA-N n,n-dihydroxyethanamine Chemical compound CCN(O)O ZUXWMZPBQLGDDY-UHFFFAOYSA-N 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- LTHNHFOGQMKPOV-UHFFFAOYSA-N 2-ethylhexan-1-amine Chemical compound CCCCC(CC)CN LTHNHFOGQMKPOV-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000010721 machine oil Substances 0.000 description 4
- 239000010731 rolling oil Substances 0.000 description 4
- UYTOHYBIBPDOKX-ZDUSSCGKSA-N (2s)-2-(dodecanoylamino)propanoic acid Chemical class CCCCCCCCCCCC(=O)N[C@@H](C)C(O)=O UYTOHYBIBPDOKX-ZDUSSCGKSA-N 0.000 description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 229910003002 lithium salt Inorganic materials 0.000 description 3
- 159000000002 lithium salts Chemical class 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- MJROZKLSHJICLS-UHFFFAOYSA-N 2-(2-ethylhexylamino)ethanol Chemical compound CCCCC(CC)CNCCO MJROZKLSHJICLS-UHFFFAOYSA-N 0.000 description 2
- MCGROFKAAXXTBN-VIZOYTHASA-N 3,5-dihydroxy-N-[(E)-(4-hydroxy-3-nitrophenyl)methylideneamino]benzamide Chemical compound C1=CC(=C(C=C1/C=N/NC(=O)C2=CC(=CC(=C2)O)O)[N+](=O)[O-])O MCGROFKAAXXTBN-VIZOYTHASA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical class CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 2
- JWGGSJFIGIGFSQ-UHFFFAOYSA-N N-dodecanoylglycine Chemical class CCCCCCCCCCCC(=O)NCC(O)=O JWGGSJFIGIGFSQ-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 2
- 229940043276 diisopropanolamine Drugs 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 229940071085 lauroyl glutamate Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 238000001612 separation test Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- AVBJHQDHVYGQLS-AWEZNQCLSA-N (2s)-2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-AWEZNQCLSA-N 0.000 description 1
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 description 1
- LFJJOPDNPVFCNZ-UHFFFAOYSA-N 2-[hexadecanoyl(methyl)amino]acetic acid Chemical class CCCCCCCCCCCCCCCC(=O)N(C)CC(O)=O LFJJOPDNPVFCNZ-UHFFFAOYSA-N 0.000 description 1
- NGOZDSMNMIRDFP-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]acetic acid Chemical class CCCCCCCCCCCCCC(=O)N(C)CC(O)=O NGOZDSMNMIRDFP-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- NRBFOSKZAWRBJI-KRWDZBQOSA-N N-Palmitoyl alanine Chemical class CCCCCCCCCCCCCCCC(=O)N[C@@H](C)C(O)=O NRBFOSKZAWRBJI-KRWDZBQOSA-N 0.000 description 1
- KVTFEOAKFFQCCX-UHFFFAOYSA-N N-hexadecanoylglycine Chemical class CCCCCCCCCCCCCCCC(=O)NCC(O)=O KVTFEOAKFFQCCX-UHFFFAOYSA-N 0.000 description 1
- DYUGTPXLDJQBRB-UHFFFAOYSA-N N-myristoylglycine Chemical class CCCCCCCCCCCCCC(=O)NCC(O)=O DYUGTPXLDJQBRB-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000010710 diesel engine oil Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010711 gasoline engine oil Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001841 imino group Chemical group [H]N=* 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940070800 myristoyl glutamate Drugs 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229940070802 palmitoyl glutamate Drugs 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/46—Esters of carboxylic acids with amino alcohols; Esters of amino carboxylic acids with alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/48—Regeneration of cleaning solutions
Definitions
- the present invention relates to a water-resistant oil-water separation type cleaning composition and a cleaning method using the cleaning composition.
- Examples of the above-mentioned detergent include (A) a polyoxyalkylene adduct of alkylamine or alkylamide having a hydrocarbon group having 8 to 22 carbon atoms, and (B) carbonization of 8 to 22 carbon atoms. Selected from the group consisting of alkyldimethylamine oxide having a hydrogen group, alkyldi (aminomethyl) glycine having a hydrocarbon group having 6 to 22 carbon atoms, sodium linear dodecylbenzenesulfonate, and betaine lauryldimethylaminoacetate.
- a cleaning composition comprising at least one of the following components is disclosed.Furthermore, by blending the components (A) and (B) in a fixed blending ratio, the cleaning properties, foaming properties, and oil separation properties after washing are disclosed. There has been proposed a cleaning agent intended to be able to improve odor (see Patent Document 1, for example).
- Patent Document 1 JP-A-2003-119496
- Patent Document 2 Japanese Patent No. 3430147
- the oxyethylene unit of alkylamine or alkylamide is 2 to 50, and particularly preferably 10 to 50.
- a detergent composition using a polyoxyethylene adduct having a polyoxyethylene chain of the type described above is self-emulsifying and shows water-soluble properties. Oils and other oils (especially grease-based oils, naphthenic-based mineral oils, paraffin-based mineral oils, poly- ⁇ -olefins, polyol esters, and polydimethylsiloxane) have sufficient cleaning properties when used on machines and machine parts. There was a problem that it was not possible to achieve both the oil separation of the washing waste liquid and the washing target during washing or after washing.
- the present invention has been made in view of the above-mentioned problems of the prior art, and has been made of an adherend such as a machine or a machine part to which oils such as machine oil, rolling oil, and anti-dust oil have adhered, and fiber processing.
- removes oils especially grease-based oils, naphthenic-based mineral oils, paraffin-based mineral oils, poly- ⁇ -olefins, polyol esters, polydimethylsiloxanes
- a detergent composition that not only exhibits high detergency but also suppresses the generation of water on adherends and is excellent in oil-water separation properties of cleaning waste liquid, especially oil-water separation properties at low temperatures.
- An object of the present invention is to provide a water-soluble oil-water separation type detergent composition.
- Another object of the present invention is to provide a cleaning method for recycling a cleaning liquid by using the water-resistant oil-water separation type cleaning composition.
- the inventors of the present invention have conducted intensive studies in order to solve the above-mentioned problems, and as a result, a cleaning composition comprising a combination of a specific amine-based compound and a specific a-one surfactant has been developed. It has been found that it has cleanliness, suppresses the generation of ⁇ on the adherend, and is also excellent in the oil-water separation property of the washing waste liquid, especially at low temperatures. In addition, the present inventors have found that the washing waste liquid after washing can be easily separated into an oil layer portion and an aqueous layer portion, the oil layer portion can be recovered as an oil component, and the aqueous layer portion can be reused as a washing solution. Completed.
- the water-resistant oil-water separation type cleaning composition of the present invention is selected from the group consisting of grease-based oil, naphthenic-based mineral oil, paraffin-based mineral oil, poly- ⁇ -olefin, polyol ester, and polydimethylsiloxane.
- a water-resistant oil / water separator that is brought into contact with an adherend to which at least one type of oil has adhered to separate the oil from the adherend, impart heat resistance to the adherend, and form an oil layer containing the oil.
- a mold cleaning composition is selected from the group consisting of grease-based oil, naphthenic-based mineral oil, paraffin-based mineral oil, poly- ⁇ -olefin, polyol ester, and polydimethylsiloxane.
- (X) an ethylene oxide adduct of a monoalkylamine represented by the following general formula (1); and ( ⁇ ) a ⁇ monoalkyl ⁇ -(2-hydroxyalkyl) imino having a hydrocarbon group having 8 to 22 carbon atoms.
- R represents a linear or branched alkyl group having 7 to 9 carbon atoms
- m is an integer of 0 to 2
- n is 0 — It is an integer of 2 and (m + n) is 1-3.
- the (m + n) force in the above general formula (1) is preferably 112.
- R in the general formula (1) is a 2-ethylhexyl group.
- the mass ratio [(W) / (W)] between the component (X) and the component (Y) is 3Z7-7Z3.
- the adherend to which the oil has adhered is brought into contact with a cleaning liquid containing any one of the above-mentioned oil-water-separable detergent compositions of the present invention to remove the oil. Separates from the adherend and imparts water resistance to the adherend, forms an oil layer containing oil, and The cleaning liquid after contact is characterized in that the water layer obtained by removing the oil layer is reused as the cleaning liquid.
- the pH of the cleaning liquid containing the water-resistant oil-water separation type cleaning composition is adjusted to 7.5 or more.
- oils and the like attached to an object to be cleaned are removed.
- a water-resistant oil-water separation type detergent composition that has high detergency, suppresses the generation of water on the object to be cleaned, and excels in oil-water separation of the washing waste liquid after cleaning, especially oil-water separation at low temperatures. Things can be provided. Further, according to the present invention, it is possible to provide a cleaning method capable of recycling a cleaning liquid containing a water-resistant oil-water separation type cleaning composition.
- the water-resistant oil-water separation type cleaning composition of the present invention comprises (X) an ethylene oxide adduct of a monoalkylamine represented by the following general formula (1), and ( ⁇ ) a hydrocarbon having 8 to 22 carbon atoms. ⁇ ⁇ monoalkyl ⁇ - (2-hydroxyalkyl) iminoethylene carboxylate, acylated amino acid salt having a hydrocarbon group having 8 to 22 carbon atoms, alkyl acid having a hydrocarbon group having 8 to 22 carbon atoms At least one selected from the group consisting of luzarcosin salt and tall oil fatty acid salt.
- R represents a linear or branched alkyl group having 7 to 9 carbon atoms
- m is an integer of 0 to 2
- n is an integer of 0 to 2
- (m + n) is 1-3 is there.
- R is a 2-ethylhexyl group from the viewpoints of imparting detergency to the washability and the body to be washed, and more reliably obtaining oil-water separation.
- the water-soluble oil-water separation type detergent composition has a high water solubility, and therefore, the oil-removing property of the oil to be washed is strong. The effect of can not be obtained.
- (m + n) is 0, that is, when ethylene oxide is not added, since it functions as an oily component, the cleaning effect of the water-resistant oil-water separation type cleaning composition is obtained. I can't.
- the water-solubility of the water-resistant oil-releasing cleaning composition further increases, the effect as a surfactant is reduced, and the oil removing property from the body to be cleaned is reduced. Effect cannot be obtained.
- (m + n) is preferably 112 from the viewpoint of easily and reliably obtaining the effects of the present invention.
- the compound of the above general formula (1) used in the present invention includes, for example, N-2-ethylhexyl
- N-hydroxyethylamine N-2-ethylhexyl N, N-dihydroxyethylamine, N-2-ethylhexyl N-hydroxyethyl-N-hydroxyethoxytylamine.
- the component (Y) used in the present invention includes N-monoalkyl N- (2-hydroxyalkyl) iminoethylene carboxylate having a hydrocarbon group having 8 to 22 carbon atoms, and a hydrocarbon having 8 to 22 carbon atoms. At least one selected from the group consisting of an acylated amino acid salt having a C.sub.2 group, an alkyl sarcosine salt having a hydrocarbon group having 8 to 22 carbon atoms, and a tall oil fatty acid salt.
- the hydrocarbon group No. 22 is a hydrocarbon group having a straight or branched chain.
- the component (Y) used in the present invention preferably has water solubility.
- the effects of the present invention can be more reliably obtained. Also, when post-treatment (for example, coagulation treatment) of the washing liquid after oil-water separation, the removal of the surfactant (Y component) tends to be easier. In addition, biodegradability tends to be good.
- N monoalkyl N- (2— having a hydrocarbon group having 8 to 22 carbon atoms used for the component (Y) (Hydroxyalkyl) as a monoalkyl group of iminoethylene carboxylate, for example,
- 2-ethylhexyl group decyl group, dodecyl group, tetradecyl group, hexadecyl group, octadecyl group and the like.
- the hydroxyalkyl group include a hydroxyethyl group and a hydroxypropyl group.
- N monoalkyl N- (2-hydroxyalkyl) iminoethylenecarboxylate having a hydrocarbon group having 8 to 22 carbon atoms is selected from the group consisting of N-2-alkyl Ethylhexyl-N- (2-hydroxyethyl) iminoethylenecarboxylate, N-decyl-N- (2-hydroxyethyl) iminoethylenecarboxylate, N-dodecyl-N- (2-hydroxyethyl) -iminoethylene Carboxylates can be preferably used.
- Examples of the salt of N-monoalkyl N- (2-hydroxyalkyl) iminoethylene carboxylate include sodium salt, potassium salt, lithium salt, ammonium salt, monoethanolamine, and diethanolamine.
- organic amine salts such as triethanolamine, monoisopropanolamine, diisopropanolamine and triisopropanolamine.
- N monoalkyl N- (2-hydroxyalkyl) iminoethylenecarboxylate having a hydrocarbon group having 8 to 22 carbon atoms may be used alone or in combination of two or more. They may be used together.
- Examples of the acylated amino acid salt having a hydrocarbon group having 8 to 22 carbon atoms used in the component (Y) include lauroylglycine salt, lauroylalanine salt, lauroyl monoalanine salt, lauroylglutamate, Myristoyl glycine salt, myristoyl alanine salt, myristoyl j8-alanine salt, myristoyl glutamate, palmitoyl glycine salt, palmitoyl alanine salt, normitoyl j8-alanine salt, palmitoyl glutamate, and the like, particularly lauroyl glycine salt, lauroyl Alanine salt, lauroyl
- Examples of the salt of an acylyl amino acid salt having a hydrocarbon group having 8 to 22 carbon atoms include sodium salt, potassium salt, lithium salt, ammonium salt, monoethanolamine, diethanolamine, and the like.
- Organic amine salts such as amine, triethanolamine, monoisopropanolamine, diisopropanolamine, and triisopropanolamine.
- the above-mentioned acylyl amino acid salt having a hydrocarbon group having 8 to 22 carbon atoms may be used alone or in combination of two or more.
- alkylol sarcosine salt having a hydrocarbon group having 8 to 22 carbon atoms used in the component (Y) include lauroyl sarcosine salt, myristoyl sarcosine salt, palmitoyl sarcosine salt, and oleylzar.
- Cosin salts and the like can be mentioned, and in particular, lauroyl sarcosine salts are preferable because they can more reliably obtain detergency, oil-water separation property, and water resistance.
- Alkyl sarcosine salts having a hydrocarbon group having 8 to 22 carbon atoms include, for example, sodium salt, potassium salt, lithium salt, ammonium salt, monoethanolamine, diethanolamine and the like.
- organic amine salts such as triamine, triethanolamine, monoisopropanolamine, disopropanolamine and triisopropanolamine.
- alkylol sarcosine salt having a hydrocarbon group having 8 to 22 carbon atoms one kind may be used alone, or two or more kinds may be used in combination.
- the mass ratio of the component (X) to the component (Y) [(W) / (W
- XY;)] is preferably 3Z7-7Z3, more preferably 4Z6-7Z
- Mass ratio [(W) / (W;)] is smaller than 3Z7
- the water-resistant oil-water separation type cleaning composition of the present invention further comprises a chelating agent, a water-proofing agent, an inorganic builder, an organic builder, a water-soluble solvent and the like within a range not impairing the effect of the present invention.
- a chelating agent e
- the water-resistant oil-water separation type detergent composition of the present invention may be used as it is without dilution, and may be diluted to an appropriate concentration with a known diluent such as water. May be used.
- the water-resistant oil-water separation type detergent composition is preferably used after being diluted with water, and the nonvolatile content of the water-resistant oil-water separation type detergent composition is 0.1 to 10% by mass, more preferably. Preferably, it is used after being diluted to 0.3 to 5% by mass.
- the pH of the cleaning solution is preferably adjusted to 7.5 or more when the water-resistant oil-water separation type cleaning composition of the present invention is adjusted to 8.0 or more. Is adjusted to Is more preferable.
- the pH becomes 8.0 or more, so that it can be used without particularly adjusting the pH.
- the water-resistant oil-water separation type detergent composition of the present invention can be used in various fields without particular limitation.
- general machinery and machine parts to which machine oil, rolling oil, fire prevention oil, etc. adhere, dyeing machines and scouring machines to which oil etc. adhere in the fiber processing process, and oils, etc.
- It can be used as a cleaning agent for attached bodies (automobiles, trains, airplanes, etc.) and walls and floors inside and outside buildings.
- the washing waste liquid after washing has an oil-water separation property, the water layer portion obtained by separating into an oil layer and an aqueous layer can be reused as a washing liquid without draining.
- the adherend to which the oil is adhered (the body to be cleaned) is brought into contact with the cleaning liquid containing the above-described water-resistant oil-water separation type cleaning composition of the present invention, and the oil is coated. Separates from the body to be cleaned (substrate to be cleaned) and imparts water resistance to the substrate to be cleaned (substrate to be cleaned), forms an oil layer containing oil, and contacts the substrate to be cleaned (substrate to be cleaned).
- the water layer obtained by removing the oil layer from the cleaning liquid is reused as the cleaning liquid.
- the cleaning method of the present invention is preferably applied to at least one oil selected from the group consisting of grease-based oil, naphthenic-based mineral oil, paraffin-based mineral oil, poly- ⁇ -olefin, polyol ester and polydimethylsiloxane. It is preferably used for the body.
- the cleaning method of the present invention uses the water-resistant oil-water separation type detergent composition of the present invention having excellent detergency, water resistance, and oil-water separation properties. It is possible to reduce the amount of water on the body to be cleaned (the body to be washed), reduce the load of oil-water separation treatment, and reuse the water layer obtained from the waste liquid after washing as a cleaning agent without draining it. An excellent cleaning system with low load can be constructed.
- the cleaning method of the present invention can be used in various fields without particular limitation.
- general machinery and machine parts to which machine oil, rolling oil, fireproof oil, etc. are attached textile processing machines such as dyeing machines and scouring machines to which oils are attached in the fiber processing process, and attachment of oils etc.
- textile processing machines such as dyeing machines and scouring machines to which oils are attached in the fiber processing process, and attachment of oils etc.
- N 2 -ethylhexyl N-hydroxyethylamine obtained by adding 1 mol of ethylene oxide to 1 mol of 2-ethylhexylamine.
- N2-ethylhexyl N, N-dihydroxyethylamine obtained by adding 2 mol of ethylene oxide to 1 mol of 2-ethylhexylamine.
- N-2-ethylhexyl N-hydroxyethyl-N-hydroxyethoxyxylamine obtained by adding 1 mol of 2-ethylhexylamine to 3 mol of ethylene oxide.
- N 2-ethylhexyl N, N-dihydroxyethoxyxylamine obtained by adding 1 mol of 2-ethylhexylamine to 4 mol of ethylene oxide.
- Asilui-Dani amino acid salt (trade name "ATC-12 (coconut oil fatty acid acyl-alanine triethanolamine salt)” manufactured by Ajinomoto Co., Inc.).
- Alkyloyl sarcosine salt (Kawaken Fine Chemical Co., Ltd.
- Tall oil fatty acid salt (manufactured by Harima Co., Ltd., trade name "Hartur 30 (tall oil fatty acid Z rosin tall oil fatty acid mixture)", a sodium hydroxide neutralized salt).
- N-2 Nethylhexyl N, N-Dihydroxyethylamine (5 g of compound X-2), 5 g of toluene oil fatty acid salt (compound Y-4), and 90 g of water are mixed to form a uniform mixture. A water-resistant oil-water separation type cleaning composition was obtained.
- Example 7 5 g of N 2 -ethylhexyl N, N-dihydroxyethylamine (I-Drug X2) and sodium salt of N-2 -ethylhexyl N- (2-hydroxyethyl) iminoethylene carboxylate (Compound Y — 1) lg, acylated amino acid salt (Y-Dai Yaku Y) 2) lg, alkyloyl sarcosine salt (Y-Dy Y Y Y), lg, tall oil fatty acid salt (Y-Dy Y Y) -4) 2 g and 90 g of water were mixed to obtain a water-resistant oil-water separation type detergent composition evenly.
- a mixture of 10 g of the amino acid salt of acylyl-dani (distilled compound Y-2) and 90 g of water was obtained to obtain a uniform water-resistant oil-water-separable detergent composition.
- a mixture of 10 g of N-2-ethylhexyl N, N-dihydroxyethoxyshetilamine (distilled compound X-4) and 90 g of water is mixed to form a uniform oil-water-separable detergent composition. Obtained.
- Example 119 and Comparative Example 118 were evaluated by conducting a detergency test, an oil-water separation test, and a water-proof test. did.
- the test method is as follows.
- SPCC-SB rolled steel sheets (60 mm X 80 mm X 1.2 mm) were washed twice alternately with toluene and acetone, air-dried, and the mass (W1) of the air-dried steel sheet was measured.
- the following mixed oil (0.1 lg) is applied to this steel sheet, heat-treated at 110 ° C for 10 minutes, cooled to room temperature (about 20 ° C) in a desiccator, and the mass (W2) of the steel sheet is measured. did.
- this steel sheet is immersed in 300 mL of an aqueous solution (cleaning liquid) having a concentration of 1% by mass (in terms of nonvolatile content) of the obtained water-resistant oil-water separation type cleaning composition, and stirred at 20 ° C for 10 minutes (60 r. p.m), and washing was performed. After that, they were rinsed in running water for 30 seconds, dried at 105 ° C for 5 minutes, cooled to room temperature in a desiccator, and the mass (W3) of the steel sheet was measured. The cleaning rate (%) was calculated by the following equation (2), and the cleaning property was evaluated. The results are shown in Tables 1 and 2.
- Class 4 Water layer volume 69-50mL
- Class 1 Water layer volume 9 mL or less
- SPCC-SB rolled steel plate 60 mm x 80 mm x 1.2 mm was washed twice alternately with toluene and acetone as test specimens, and air-dried, and the resulting water-resistant oil-water separation type detergent composition was obtained.
- the test piece was half immersed in an aqueous solution (washing solution) having a concentration of 1% by mass (converted to non-volatile components) and left at room temperature (about 20 ° C). After 48 hours, the presence or absence of ⁇ was visually determined.
- Tables 1 and 2 with the presence of water being rated as "presence” as having protection, and those with generation of water being "no" as having no protection.
- the water-resistant oil-water separation type cleaning composition of the present invention can be efficiently used for oil-adhered machines, machine parts, textile processing machines, car bodies (automobiles, trains, airplanes, etc.) and walls and floors inside and outside buildings. It can be used for cleaning to remove oils. Further, the cleaning method of the present invention can be used for constructing a cleaning system with a low environmental load.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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EP04792686A EP1683853A1 (en) | 2003-11-11 | 2004-10-20 | Antirust oil water separation type detergent composition and method of cleaning |
CA002543371A CA2543371A1 (en) | 2003-11-11 | 2004-10-20 | A rust-preventive water-oil separating cleaner composition and a cleaning method using the same |
US10/577,877 US7399367B2 (en) | 2003-11-11 | 2004-10-20 | Rust-preventive water-oil separating cleaner composition and a cleaning method using the same |
Applications Claiming Priority (2)
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JP2003-381205 | 2003-11-11 | ||
JP2003381205A JP4154312B2 (ja) | 2003-11-11 | 2003-11-11 | 防錆性油水分離型洗浄剤組成物及び洗浄方法 |
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WO2005044964A1 true WO2005044964A1 (ja) | 2005-05-19 |
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US (1) | US7399367B2 (ja) |
EP (1) | EP1683853A1 (ja) |
JP (1) | JP4154312B2 (ja) |
KR (1) | KR100732362B1 (ja) |
CN (1) | CN1856566A (ja) |
CA (1) | CA2543371A1 (ja) |
TW (1) | TW200519194A (ja) |
WO (1) | WO2005044964A1 (ja) |
Cited By (1)
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CN102759581A (zh) * | 2011-04-29 | 2012-10-31 | 中国石油化工股份有限公司 | 评价防锈油脱水性能的测试方法 |
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JP4154312B2 (ja) * | 2003-11-11 | 2008-09-24 | 日華化学株式会社 | 防錆性油水分離型洗浄剤組成物及び洗浄方法 |
US7332463B2 (en) * | 2005-04-22 | 2008-02-19 | On Legal Grounds, Inc. | Colloidal cleaning system comprising a saponified fatty acid and an anionic/nonionic surfactant mixture |
CN101176800B (zh) * | 2007-10-13 | 2011-07-13 | 山东新华医疗器械股份有限公司 | 医疗器械上光养护油及其制备方法 |
US8394751B2 (en) * | 2010-01-29 | 2013-03-12 | W. M. Barr & Company | Organic residue remover composition |
WO2012073385A1 (en) | 2010-12-01 | 2012-06-07 | Empire Technology Development Llc | Compositions comprising reverse micelles and methods for their use |
JP6014380B2 (ja) * | 2011-06-30 | 2016-10-25 | 川研ファインケミカル株式会社 | 増泡剤及びそれを含有する洗浄剤組成物 |
CN102330106B (zh) * | 2011-09-01 | 2012-12-12 | 华阳新兴科技(天津)集团有限公司 | 一种环保型清洗切水剂及其制备方法及所用的置换剂 |
JP6216185B2 (ja) * | 2012-08-31 | 2017-10-18 | 川研ファインケミカル株式会社 | ポリオキシアルキレンアルキルアミン型増粘剤、増粘剤組成物及び高粘度液体洗浄剤組成物 |
JP2014047275A (ja) * | 2012-08-31 | 2014-03-17 | Kawaken Fine Chemicals Co Ltd | 洗浄剤組成物 |
CN103254785A (zh) * | 2013-04-16 | 2013-08-21 | 马鞍山采石矶涂料有限公司 | 一种长效防锈油及其制备方法 |
CN103254765A (zh) * | 2013-04-17 | 2013-08-21 | 马鞍山拓锐金属表面技术有限公司 | 一种以甲基苯基硅油为基础油的防锈油及其制备方法 |
CN103254789A (zh) * | 2013-04-17 | 2013-08-21 | 马鞍山拓锐金属表面技术有限公司 | 一种以桐油为基础油的防锈油及其制备方法 |
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CN105063649B (zh) * | 2015-08-14 | 2018-04-10 | 芜湖黄燕实业有限公司 | 铝合金轮毂模具清洁剂及其制备方法 |
CN110201870A (zh) * | 2019-07-10 | 2019-09-06 | 陕西宝光真空电器股份有限公司 | 一种具有透明水溶性防护膜的电磁纯铁零件及其制备方法 |
JP7150376B1 (ja) | 2022-02-28 | 2022-10-11 | 大同化学株式会社 | 冷間圧延機洗浄用スカム溶解剤及びその使用方法 |
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- 2004-10-20 EP EP04792686A patent/EP1683853A1/en not_active Withdrawn
- 2004-10-20 CN CNA2004800273111A patent/CN1856566A/zh active Pending
- 2004-10-20 CA CA002543371A patent/CA2543371A1/en not_active Abandoned
- 2004-10-20 KR KR1020067009052A patent/KR100732362B1/ko not_active IP Right Cessation
- 2004-10-20 US US10/577,877 patent/US7399367B2/en not_active Expired - Fee Related
- 2004-10-28 TW TW093132789A patent/TW200519194A/zh unknown
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Also Published As
Publication number | Publication date |
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KR100732362B1 (ko) | 2007-06-28 |
CN1856566A (zh) | 2006-11-01 |
EP1683853A1 (en) | 2006-07-26 |
CA2543371A1 (en) | 2005-05-19 |
US20070173425A1 (en) | 2007-07-26 |
TW200519194A (en) | 2005-06-16 |
KR20060111501A (ko) | 2006-10-27 |
JP2005146004A (ja) | 2005-06-09 |
JP4154312B2 (ja) | 2008-09-24 |
US7399367B2 (en) | 2008-07-15 |
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