WO2005036674A1 - フィルム外装電池およびフィルム外装電池の製造方法 - Google Patents
フィルム外装電池およびフィルム外装電池の製造方法 Download PDFInfo
- Publication number
- WO2005036674A1 WO2005036674A1 PCT/JP2004/014364 JP2004014364W WO2005036674A1 WO 2005036674 A1 WO2005036674 A1 WO 2005036674A1 JP 2004014364 W JP2004014364 W JP 2004014364W WO 2005036674 A1 WO2005036674 A1 WO 2005036674A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- film
- battery
- bent
- covered
- heat
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 13
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- 229910052782 aluminium Inorganic materials 0.000 description 11
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- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7146—Battery-cases
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/172—Arrangements of electric connectors penetrating the casing
- H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
- H01M50/178—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for pouch or flexible bag cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/547—Terminals characterised by the disposition of the terminals on the cells
- H01M50/55—Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
- H01M50/557—Plate-shaped terminals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/4911—Electric battery cell making including sealing
Definitions
- the present invention relates to a film-covered battery in which battery elements are housed in a flexible package, and a method for manufacturing the film-covered battery.
- the laminate film can take a free shape as compared with a metal can, and is formed by laminating a metal thin film or a metal thin film and a heat-fusible resin film.
- a typical example of a laminate film used as a battery exterior material is a laminate of a heat-sealable resin film as a heat seal layer on one side of an aluminum thin film as a metal thin film and the other side. And a three-layer laminated film in which a protective film is laminated.
- a film-covered battery using a laminate film as a package material generally includes a battery element composed of a positive electrode, a negative electrode, an electrolyte, and the like, in which a heat-fusible resin film is on the inner side.
- the battery element is hermetically sealed (hereinafter simply referred to as “sealing”) by heat-sealing the exterior material around the battery element.
- the heat-fusible resin film for example, a polyethylene film or a polypropylene film is used
- the protective film for example, a nylon film or a polyethylene terephthalate film is used.
- a battery element in addition to a chemical battery such as a lithium battery or a nickel-metal hydride battery, a battery having a power storage function such as a capacitor can also be used as a packaging material.
- lead terminals are connected to the positive electrode and the negative electrode, respectively, so that the positive electrode and the negative electrode of the battery element are drawn out of the package. Connecting the lead terminals to the battery element prior to sealing the battery element And by ultrasonic welding or the like.
- the battery element is sandwiched between two exterior materials, and the peripheral edge of the exterior material is heat-sealed.
- the heat-sealing of the exterior material first, the three sides of the exterior material are heat-sealed first to form a bag. Thereafter, the interior of the exterior material is evacuated by evacuating air from the interior of the exterior material, and the exterior material is brought into close contact with the battery element by the atmospheric pressure. In this state, the remaining one side is heat-sealed.
- one of the exterior members is formed into a flanged container by deep drawing so that the battery element can be easily stored. It is common practice to cover the battery element with an exterior material formed on the battery element, and to bond the flange by heat fusion.
- a metal thin film such as aluminum is used as a barrier layer for the package body film in order to prevent invasion of external moisture and the like into the battery packaged inside the battery and to escape the electrolyte and the like inside the battery packaged battery to the outside.
- the heat-sealing resin film layer is exposed at the end of the junction around the battery element, it causes a leak path based on the molecular transport phenomenon of the resin itself. Therefore, in order to improve the sealing reliability of a film-covered battery, it is possible to reduce the leakage by increasing the width of the junction and lengthening the transmission path and increasing the resistance. There was a problem that the projected area of the battery increased. Therefore, it has been proposed in Japanese Patent Application Laid-Open No. 2002-25514 to bend the joint portion toward the battery element housing portion to reduce the projected area! Puru.
- the film-covered battery 101 has a shape in which a joint portion on two opposite sides is bent at a substantially right angle to the battery element housing portion side in order to reduce the projected area.
- the protective film 102c, the metal thin film 102d, and the heat-fused resin film 102e that constitute the laminated film is also in contact with each other. There is almost no change in the thickness of the joint.
- the present invention provides a film-covered battery in which battery elements are housed in a flexible cover, which can prevent damage to the cover when the joint is bent. And a method for producing a film-covered battery.
- a film-covered battery of the present invention includes a battery element having a structure in which a positive electrode and a negative electrode are opposed to each other, at least a heat-fusible resin layer and a metal thin film layer, A heat sealing resin layer surrounds the battery element, and an outer peripheral film that seals the battery element by heat-sealing a peripheral joint is provided. At least one bent portion is formed at the joint portion of each of the film-covered batteries, and the thickness of the bent portion is larger than the thickness of the joint portion around the bent portion. It is characterized by being thin.
- a bent portion having a reduced thickness is formed at the joint. That is, since the bent portion has a reduced thickness, the outer peripheral side of the bent portion is not excessively stretched when bent at the bent portion. For this reason, it is possible to prevent the occurrence of cracks due to stretching of the outer package film. Also, the presence of the bent portion determines the bending position, so that an unfavorable position is not bent. This makes it easy to align the dimensions of the film-covered battery after bending.
- the film-covered battery of the present invention may be configured such that the bent portion is a groove, or the groove is formed on at least one surface of the joint portion.
- the film-covered battery of the present invention may have a structure in which a plurality of bent portions are formed at the joint portion, and the joint portion is bent at each bent portion.
- the film-covered battery of the present invention includes a battery element having a structure in which a positive electrode and a negative electrode are opposed to each other; At least a heat-fusible resin layer and a metal thin-film layer are laminated, the heat-fusible resin layer is on the inside, the battery element is surrounded, and the peripheral junction is heat-sealed to seal the battery element.
- a film-covered battery having an outer body film that stops and at least one side of the joint is bent, a plurality of bent portions are formed at the joint, and the thickness of the bent portion is reduced at the joint.
- the bent portion is a groove formed on at least one surface of the joint, and the joint is bent at each bent portion.
- the battery element may be any one of a chemical battery and a capacitor.
- the method for manufacturing a film-covered battery according to the present invention is directed to a film-covered battery in which at least one of the joints formed around the battery element of the package body housing the battery element is bent.
- the method for manufacturing a battery includes a step of forming at least one bent portion in the joint portion that is thinner than a peripheral thickness of the joint portion, and a step of bending the joint portion at the bent portion.
- the method for manufacturing a film-covered battery of the present invention may include a step of forming a bent portion by pressing at least one surface of a joint portion with a member having a convex portion.
- the method may include a step of heat-sealing and joining the joint portion of the exterior body film having heat-fusibility by heating and pressing by a member.
- the method for producing a film-covered battery according to the present invention may include a step of preparing any one of a chemical battery and a cannon as a battery element!
- the bendable portion of the exterior body film joint is thinned. Since it is formed, the bending work is facilitated, and since the elongation on the outer peripheral side at the time of bending is reduced, damage to the exterior material can be prevented. According to the present invention, it is possible to prevent a crack from entering in the middle of the joint portion, thereby forming a short permeation path into the inside of the battery, and also prevent the infiltration of water and the escape of electrolyte solution from being accelerated. In addition, the performance and reliability of the battery can be improved.
- FIG. 1 is a perspective view of a conventional film-covered battery.
- FIG. 2 is a cross-sectional view of a long side junction of the film-covered battery shown in FIG. 1 before bending.
- FIG. 3 is a cross-sectional view of a long-side junction of the film-covered battery shown in FIG. 1.
- FIG. 4 is a perspective view of the film-covered battery according to the first embodiment of the present invention.
- FIG. 5 is an exploded perspective view of the film-covered battery shown in FIG.
- FIG. 6 is a perspective view showing a state before bending the joint portion of the film-covered battery shown in FIG.
- FIG. 7 is a cross-sectional view showing a state when the long side of the film-covered battery shown in FIG. 4 is joined.
- FIG. 8 is a cross-sectional view of a long side joint of the film-covered battery shown in FIG. 4 before bending.
- FIG. 9 is a cross-sectional view of a long-side junction of the film-covered battery shown in FIG. 4.
- FIG. 10 is a perspective view of a film-covered battery according to a second embodiment of the present invention.
- FIG. 11 is a perspective view showing a state before bending a joint at the film-covered battery shown in FIG. 10.
- FIG. 12 is an exploded perspective view of the film-covered battery shown in FIG.
- FIG. 13 is a perspective view of another film-clad battery according to the second embodiment of the present invention.
- FIG. 14 is a perspective view showing a state before bending a joint of the film-covered battery shown in FIG. 13.
- FIG. 15 is an exploded perspective view of the film-covered battery shown in FIG.
- FIG. 16 is a perspective view of a film-covered battery according to a third embodiment of the present invention.
- FIG. 17 is a perspective view showing a state before bending a bonding portion of the film-covered battery shown in FIG. 16.
- FIG. 18 is a perspective view of another film-clad battery according to the third embodiment of the present invention.
- FIG. 19 is a perspective view showing a state before bending a joint at the film-covered battery shown in FIG. 18.
- FIG. 20 is an exploded perspective view showing a configuration of a battery element in an example of the present invention.
- FIG. 4 is a perspective view showing the appearance of the film-covered battery according to the first embodiment of the present invention
- FIG. 5 is an exploded perspective view showing the configuration of the film-covered battery shown in FIG. 4
- FIG. 6 is the film-covered battery shown in FIG.
- FIG. 3 is a perspective view showing a state before bending of a joint portion. Note that FIG. 5 shows a film-covered battery in a state where a groove which is a feature of the present invention is formed.
- the film-covered battery 1 of the present embodiment is a laminated battery element 5 having a positive electrode plate 8 and a negative electrode plate 9 stacked with a separator 10 interposed therebetween (see FIG. 20). ), A rectangular outer package film 2a, 2b for accommodating the battery element 5 together with the electrolytic solution, and a positive electrode lead terminal 3 and a negative electrode lead terminal 4 connected to the positive electrode body and the negative electrode body of the battery element 5, respectively. .
- package films 2a and 2b well-known package materials generally used for film-packaged batteries, such as a laminate film in which a metal thin film and a heat-fusible resin are laminated, can be used.
- the package films 2a and 2b of the present embodiment are formed by laminating a protective film 2f, a metal thin film 2d, and a heat-fusible film 2e (see FIG. 8).
- the exterior body 2a is provided with a storage part 2al for storing the battery element 5.
- the storage section 2al may be formed by, for example, deep drawing.
- the battery element 5 is housed in the housing portion 2al of the exterior body 2a, surrounds the battery element 5 with the exterior body film 2b from above and below, and heat-fuses the peripheral edges of these exterior body films 2a and 2b. It is sealed.
- the exterior body films 2a and 2b are first heat-sealed on three sides to form a bag. After the bag-shaped outer package films 2a and 2b are filled with the electrolytic solution, the internal air force S is exhausted from the remaining one open side.
- the bag-shaped exterior body films 2a and 2b are then hermetically sealed by heat-sealing the remaining one side.
- the exterior body films 2a and 2b have convex portions 7a and Thermal fusion is performed using a thermal fusion head 7 having a flat portion 7b.
- the heat-fusion head 7 heat-fuses the package films 2a and 2b while sandwiching them from both sides.
- Fig. 8 shows a partial cross-sectional view of the joint after heat fusion.
- the portion thermally fused by the flat portion 7b is formed as a flat surface 6 'having a thickness t
- the portion thermally fused by the projection 7a is formed as a groove 6 having a thickness t.
- the groove 6 is a bent portion for bending the side 2c toward the storage portion 2al to reduce the projected area of the film-covered battery 1.
- the force required for bending is reduced by bending the groove 6 that is a portion thinner by At than the flat surface 6 'on the side 2c.
- the bending position is determined by the presence of the groove 6, there is no possibility of bending an unfavorable position. Thereby, it becomes easy to make the dimensions of the film-covered battery 1 after the bending uniform.
- the groove 6 has a thickness t smaller by At than the flat surface 6 ′, the thickness When the part of t is bent
- the elongation on the outer peripheral side 6a of the exterior films 2a and 2b can be reduced as compared with the case. Therefore, in the present embodiment, it is possible to prevent the occurrence of cracks due to excessive elongation of the outer peripheral side 6a of the bent portion, and to improve reliability.
- the film-covered battery 1 of the present embodiment in which the groove 6 is formed on the side 2c, has an improved folding workability, uniform dimensions, and a film-covered battery.
- the reliability as 1 can be improved.
- the grooves 6 are formed on two opposing sides 2c and then bent, and the formation of the force grooves 6 may be arbitrarily one or more sides. Further, the groove 6 does not have to be formed over the entire length of the side. For example, it may not be formed at the end of the side.
- the positive lead terminal 3 and the negative lead terminal 4 may also project forces of two or more different sides.
- the joint may be bent in any direction and at any angle, for example, by being bent at approximately 180 ° to the opposite side of the battery element 5 housing portion. Further, in the present embodiment, the heat-sealing head having the convex portions 7a on both sides of the side 2c is used.
- the force shown in the example in which the groove 6 is formed by the groove 7 may be formed only on one surface.
- FIGS. a film-covered battery according to a second embodiment of the present invention will be described with reference to FIGS. Note that the basic structure, the method of forming the grooves, and the structure of the film-covered battery of the present embodiment are the same as those of the film-covered battery of the first embodiment, and thus detailed description is omitted.
- the first embodiment shows a configuration in which the battery element is housed in two sheets of the outer package film and the four sides around the battery element are sealed by heat sealing.
- Reference numerals 21 denote a single outer package film 12, 22 which is folded to accommodate the battery elements 15, 25, and which is sealed by heat-sealing three sides.
- FIG. 10 is a perspective view showing the appearance of the film-covered battery
- FIG. 11 is a perspective view showing the state of the film-covered battery shown in FIG. 10 before the joint is bent
- FIG. 12 is a film cover shown in FIG.
- FIG. 2 is an exploded perspective view illustrating a configuration of a battery.
- the film-covered battery 11 shown in FIG. 10 to FIG. 12 has the side where the package film 12 is adjacent to the side where the positive electrode lead terminal 13 and the negative electrode lead terminal 14 protrude. It is bent at the folded portion 12 'of 12c'.
- this film-covered battery 11 as shown in FIG. 11, three sides other than the folded portion 12 'are joined by heat fusion, and the groove 16 is formed only on the side 12c facing the folded portion 12'. .
- the method and structure of forming the groove 16 are basically the same as the method shown in the first embodiment.
- the film-sheathed battery 11 also has the side 12c bent along the groove 16 toward the storage portion 12al, thereby forming the film-sheathed battery 11 shown in FIG.
- FIG. 13 is a perspective view showing the appearance of the film-covered battery
- FIG. 14 shows the film-covered battery shown in FIG. 13 before the joint is bent
- FIG. 15 is an exploded perspective view showing the configuration of the film-covered battery shown in FIG.
- the film-covered battery 21 shown in Fig. 13 to Fig. 15 has the outer film 22 facing the side from which the positive electrode lead terminal 23 and the negative electrode lead terminal 24 protrude. It is bent at the folded portion 22 'of the side 22c'.
- the film-covered battery 21 has three sides other than the folded portion 22 'joined by heat fusion.
- a groove 26 is formed on each of the sides 22c ′ and the two sides 22c other than the sides from which the positive electrode lead terminal 23 and the negative electrode lead terminal 24 protrude.
- the formation method and configuration of these grooves 26 are basically the same as the method shown in the first embodiment.
- the film-covered battery 21 has two sides 22c bent along the groove 26 so that each side 22c is bent toward the storage portion 22al. It becomes the exterior battery 21.
- the film-covered batteries 11 and 21 of the present embodiment in which the side grooves 12 and the side 22c are formed, have the same bending workability as the film-covered battery 1 of the first embodiment. Improvements and dimensions can be aligned.
- the battery element is accommodated using the two package films by folding the single package film 12, 22 and storing the battery element.
- the exposed side of the heat-fusible resin film 2e that can be a leak path can be reduced compared to when it is stored, and the performance of the film-covered batteries 11, 22 due to intrusion of external moisture and dissipation of the electrolyte can be reduced. It is possible to further prevent a decrease in reliability.
- the groove does not have to be formed over the entire length of the side.
- the groove may not be formed at the end of the side.
- the positive electrode lead terminal and the negative electrode lead terminal may be made to protrude by two or more different forces.
- the joint may be bent at an arbitrary direction or angle, such as by bending the joint at about 180 ° to the opposite side to the battery element storage section.
- the grooves 16 and 26 may be formed on both sides or formed on only one side, or may be shifted.
- FIGS. a film-covered battery according to a third embodiment of the present invention will be described with reference to FIGS. Note that the basic structure of the film-covered battery of the present embodiment and the method of forming the groove Since the structure and the structure are the same as those of the film-covered battery in the first embodiment, detailed description is omitted.
- the film-covered battery according to the third embodiment of the present invention is obtained by turning the heat-sealed portion of the package body film a plurality of times to make the projected area of the film-covered battery smaller, as shown in Figs. 17 shows an example in which two grooves are formed on one side, and FIGS. 18 and 19 show examples in which three grooves are formed on one side.
- FIG. 16 is a perspective view showing the appearance of a film-covered battery having two grooves on one side according to the third embodiment of the present invention
- FIG. 17 is a perspective view of the film-covered battery shown in FIG.
- FIG. 3 is a perspective view showing a state before bending a connection portion of a battery.
- two grooves 36a and 36b are formed substantially parallel to two sides 32c where the positive electrode lead terminal 33 and the negative electrode lead terminal 34 do not project.
- the groove 36a is for bending the side 32c to the storage portion 32al side as in the above-described embodiments.
- the groove 36b formed outside of the groove 36a is for further folding back the side 32c that is formed by bending the groove 36a as a corner. That is, the groove 36b is located at the top of the side 32c bent in a mountain shape.
- the film-covered battery 31 has a smaller projected area because the side 32c is bent along the grooves 36a and 36b.
- FIG. 18 is a perspective view showing the appearance of a film-covered battery according to the third embodiment of the present invention in which three grooves are formed on one side
- FIG. FIG. 4 is a perspective view showing a state before bending the joint portion of the film-covered battery shown.
- three grooves 46a, 46b, and 46c are formed substantially parallel to two sides 42c from which the positive electrode lead terminal 43 and the negative electrode lead terminal 44 do not protrude.
- the groove 46a is for bending the side 42c to the storage portion 42al side similarly to the above-described embodiments.
- the grooves 46b and 46c formed outside the groove 46a are formed close to each other, and are used to further fold the side 42c which is formed by bending the groove 46a as a corner. That is, also in this example, the force that turns the side 42c into a mountain-like shape is used. As shown in the examples shown in Figs. ° By bending near, the damage to the exterior film due to sharp bending is further reduced.
- the finolem exterior battery 41 also has these grooves 46a, 46b, 46c The projection area becomes smaller due to the bending.
- the film-covered batteries 31 and 41 of the present embodiment in which the grooves 36a and 36b are formed on the side 32c and the grooves 46a, 46b and 46c are formed on the side 42c are the same as the film-covered battery 1 of the first embodiment.
- the bending workability can be improved, the dimensions can be made uniform, and the reliability as a film-covered battery can be improved.
- the projected area becomes smaller by folding the package films 32 and 42 into a mountain shape and housing the battery element.
- the groove may not be formed over the entire length of the side, and may not be formed at the end of the side.
- the positive lead terminal and the negative lead terminal may project forces of two or more different sides.
- the number of grooves formed may be three or more, for example, the joint may be bent to the side opposite to the battery element housing part.
- the bent portion has a so-called groove shape.
- the bent portion may have any shape as long as the thickness of the bent portion is smaller than the thickness of the joint portion other than the bent portion. You may.
- the bent portion may have a gentle concave shape.
- the groove has an example in which the groove shape on the outer circumferential side and the groove shape on the inner circumferential side are substantially the same, but the present invention is not limited to this.
- the groove and the inner peripheral groove may have different cross-sectional shapes.
- the bottom of the groove on the outer peripheral side may be formed wider than the inner peripheral side, or vice versa.
- the grooves having concave shapes on both sides are shown as an example.
- the present invention is not limited to this. It may be! /.
- a lithium manganate powder having a spinel structure, a carbonaceous material for imparting conductivity, and polyvinylidene fluoride were mixed in a mass ratio of 90: 5: 5 by N-methylpyrrolidone (expressed as NMP).
- NMP N-methylpyrrolidone
- the coating was uniformly applied to one surface of a 20 / zm-thick aluminum foil to be the positive electrode plate 8. At the time of coating, a slightly uncoated part (a part where the aluminum foil is exposed) was made streak-like. Next, the aluminum foil coated with the slurry was vacuum dried at 100 ° C. for 2 hours. Thereafter, the slurry was similarly applied to the other surface of the aluminum foil, and dried in vacuum. At this time, the slurry was applied such that the uncoated portions on the front and back correspond.
- Amorphous carbon powder and polyvinylidene fluoride were mixed in NMP at a mass ratio of 91: 9, dispersed and stirred to form a slurry.
- the amount of NMP was adjusted so that the slurry had an appropriate viscosity.
- This slurry was uniformly applied to one surface of a 10-m-thick copper foil to be the negative electrode plate 9 using a doctor blade. At the time of coating, a slightly uncoated portion (the portion where the copper foil was exposed) was formed into a streak shape.
- the aluminum foil coated with the slurry was vacuum dried at 100 ° C. for 2 hours.
- the applied thickness of the active material was adjusted so that the theoretical capacity per unit area of the negative electrode plate 9 and the theoretical capacity per unit area of the positive electrode plate 8 were 1: 1.
- the slurry was similarly applied to the other surface of the copper foil, and vacuum-dried.
- the positive electrode plate 8 and the negative electrode plate 9 produced as described above, and the separator 10 composed of a microporous sheet having a three-layer structure of the polypropylene layer Z polyethylene layer Z polypropylene layer were alternately laminated as shown in FIG. .
- the outermost electrode plate is made to be the negative electrode plate 9, and the separator 10 is set further outside the negative electrode plate 9. (That is, they were stacked in the order of separator Z negative electrode plate Z separator Z positive electrode plate Z separator ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ negative electrode plate ⁇ separator).
- the tab portion of the positive electrode plate 8 and the positive electrode lead terminal 3 made of an aluminum plate having a thickness of 0.1 mm were collectively ultrasonically welded to form a positive electrode current collector.
- the tab portion of the negative electrode plate 9 and the negative electrode lead terminal 4 having a thickness of 0.1 mm and having a nickel plate strength were collectively ultrasonically welded to form a negative electrode current collector.
- two exterior body films 2a and 2b which are aluminum laminate films having a four-layer structure of a nylon layer Z aluminum layer Z acid-modified polypropylene layer Z polypropylene layer, were used.
- the housing part 2al was formed by forming a concave part slightly larger than the battery element 5 in the exterior body film 2a by deep drawing so that the polypropylene layer side became concave.
- the battery element 5 is stacked on two battery films 2a and 2b so that only the positive electrode lead terminal 3 and the negative electrode lead terminal 4 protrude from the package films 2a and 2b. 5 was housed, and three sides around the exterior body films 2a and 2b were joined by heat fusion. Two opposing long sides adjacent to the side from which the lead terminal protrudes are heat-sealed using a heat-sealing device having a projecting portion on the surface of the heat-sealing head 7 as shown in FIG. By fusion, a joint having a groove 6 shown in the perspective view of FIG. 6 and the cross-sectional view of FIG. 8 was obtained.
- the electrolyte used was ImolZ liters of LiPF as a supporting salt, propylene carbonate and ethylene.
- the solvent used was a mixed solvent of carbonate (mass ratio 50:50). After injecting the electrolyte, the inside air is exhausted from the remaining one open side of the outer package films 2a and 2b, and the remaining
- Battery element 5 was sealed by heat-sealing one side.
- the bonding portion is bent substantially at right angles in the direction of the storage portion 2al so that the groove 6 becomes a corner, so that the lithium having the exterior body having a laminate film strength is formed.
- Film-covered battery 1 as a secondary battery was produced.
- a material using a laminated film of a metal thin film and a heat-fusible resin has a sufficient barrier property to seal a battery element.
- Other materials can be used.
- battery element a laminated type in which positive and negative electrode plates are alternately laminated has been described as an example, but the present invention can also be applied to a wound type.
- battery elements of other types of chemical batteries such as nickel-metal hydride batteries, nickel-cadmium batteries, lithium metal primary or secondary batteries, and lithium polymer batteries, have been described as examples of battery elements for lithium secondary batteries.
- capacitor element and the like the like.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04788392A EP1686636A4 (en) | 2003-10-07 | 2004-09-30 | FILTER-COATED BATTERY AND METHOD FOR MANUFACTURING FILTER-COATED BATTERY |
JP2005514556A JP4788889B2 (ja) | 2003-10-07 | 2004-09-30 | フィルム外装電池およびフィルム外装電池の製造方法 |
US10/574,562 US8697277B2 (en) | 2003-10-07 | 2004-09-30 | Film-clad battery and method of producing film-clad battery |
US14/198,875 US20140182119A1 (en) | 2003-10-07 | 2014-03-06 | Film-clad battery and method of producing a film-clad battery |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003348126 | 2003-10-07 | ||
JP2003-348126 | 2003-10-07 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/574,562 A-371-Of-International US8697277B2 (en) | 2003-10-07 | 2004-09-30 | Film-clad battery and method of producing film-clad battery |
US14/198,875 Division US20140182119A1 (en) | 2003-10-07 | 2014-03-06 | Film-clad battery and method of producing a film-clad battery |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005036674A1 true WO2005036674A1 (ja) | 2005-04-21 |
Family
ID=34430954
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/014364 WO2005036674A1 (ja) | 2003-10-07 | 2004-09-30 | フィルム外装電池およびフィルム外装電池の製造方法 |
Country Status (6)
Country | Link |
---|---|
US (2) | US8697277B2 (ja) |
EP (1) | EP1686636A4 (ja) |
JP (1) | JP4788889B2 (ja) |
KR (1) | KR100819977B1 (ja) |
CN (1) | CN1864284A (ja) |
WO (1) | WO2005036674A1 (ja) |
Cited By (9)
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JP2011216209A (ja) * | 2010-03-31 | 2011-10-27 | Hitachi Maxell Energy Ltd | ラミネート形電池およびその製造方法 |
JP2013157286A (ja) * | 2012-01-31 | 2013-08-15 | Toppan Printing Co Ltd | 蓄電デバイス |
WO2013191125A1 (ja) * | 2012-06-18 | 2013-12-27 | Necエナジーデバイス株式会社 | フィルム外装電池 |
US9083013B2 (en) | 2010-07-28 | 2015-07-14 | Tdk Corporation | Electrochemical device |
JP2017134962A (ja) * | 2016-01-27 | 2017-08-03 | Fdk株式会社 | ラミネート型蓄電素子の製造方法、ラミネート型蓄電素子 |
US10454129B2 (en) | 2014-03-31 | 2019-10-22 | Envision Aesc Energy Devices Ltd. | Secondary battery |
JP2021174629A (ja) * | 2020-04-22 | 2021-11-01 | Tdk株式会社 | 非水電解質二次電池及びその製造方法 |
WO2023022577A1 (ko) * | 2021-08-20 | 2023-02-23 | 주식회사 엘지에너지솔루션 | 파우치형 전지셀 및 파우치형 전지셀의 파우치날개 절곡 장치 |
JP7512989B2 (ja) | 2021-10-15 | 2024-07-09 | トヨタ自動車株式会社 | 電池の製造方法、電池の製造装置、および電池 |
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EP2312670B1 (en) | 2007-02-21 | 2016-08-10 | Nec Corporation | Packaged battery, stacked battery assembly, and film-covered battery |
JP4952658B2 (ja) * | 2008-06-02 | 2012-06-13 | ソニー株式会社 | 電池素子外装部材、及びこれを用いた非水電解質二次電池 |
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CN103066218B (zh) * | 2011-10-24 | 2016-01-20 | 索尼电子(无锡)有限公司 | 电池、电池芯容器形成方法以及电子设备 |
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TWI633693B (zh) * | 2013-10-22 | 2018-08-21 | 半導體能源研究所股份有限公司 | 二次電池及電子裝置 |
JP6203123B2 (ja) * | 2014-05-30 | 2017-09-27 | 藤森工業株式会社 | 電池容器及びその製造方法、フィルム包装電池 |
JP6202753B2 (ja) * | 2014-07-01 | 2017-09-27 | 藤森工業株式会社 | 電池容器、フィルム包装電池及び電池容器の製造方法 |
KR101811837B1 (ko) | 2015-01-16 | 2017-12-22 | 주식회사 엘지화학 | 잉여 실링부를 포함하는 파우치형 전지셀 |
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KR102217451B1 (ko) | 2017-08-29 | 2021-02-22 | 주식회사 엘지화학 | 이차전지 및 그 제조방법과, 이차전지 제조용 가압블록 |
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KR102403858B1 (ko) * | 2019-09-30 | 2022-06-02 | 에스케이온 주식회사 | 배터리 셀의 파우치 케이스 폴딩 장치 및 방법 |
KR102216770B1 (ko) * | 2019-10-11 | 2021-02-17 | 주식회사 클레버 | 이차전지 파우치 폴딩용 실링부 포밍장치 |
WO2022261833A1 (zh) * | 2021-06-15 | 2022-12-22 | 宁德新能源科技有限公司 | 电化学装置及用电设备 |
KR102487120B1 (ko) * | 2021-08-13 | 2023-01-10 | 주식회사 클레버 | 3면 실링 파우치형 이차전지의 돌출부 성형장치 |
WO2024080741A1 (ko) * | 2022-10-11 | 2024-04-18 | 삼성전자 주식회사 | 프리 폴딩 라인을 포함하는 배터리 장치, 프리 폴딩 라인을 포함하는 배터리 장치의 실링 공정 및 실링 장치 |
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- 2004-09-30 CN CNA2004800295074A patent/CN1864284A/zh active Pending
- 2004-09-30 KR KR1020067007430A patent/KR100819977B1/ko not_active IP Right Cessation
- 2004-09-30 WO PCT/JP2004/014364 patent/WO2005036674A1/ja active Application Filing
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2014
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011216209A (ja) * | 2010-03-31 | 2011-10-27 | Hitachi Maxell Energy Ltd | ラミネート形電池およびその製造方法 |
US9083013B2 (en) | 2010-07-28 | 2015-07-14 | Tdk Corporation | Electrochemical device |
JP2013157286A (ja) * | 2012-01-31 | 2013-08-15 | Toppan Printing Co Ltd | 蓄電デバイス |
WO2013191125A1 (ja) * | 2012-06-18 | 2013-12-27 | Necエナジーデバイス株式会社 | フィルム外装電池 |
JPWO2013191125A1 (ja) * | 2012-06-18 | 2016-05-26 | Necエナジーデバイス株式会社 | フィルム外装電池 |
US9871231B2 (en) | 2012-06-18 | 2018-01-16 | Nec Energy Devices, Ltd. | Film-covered battery |
US10510997B2 (en) | 2012-06-18 | 2019-12-17 | Envision Aesc Energy Devices Ltd. | Film-covered battery |
US10454129B2 (en) | 2014-03-31 | 2019-10-22 | Envision Aesc Energy Devices Ltd. | Secondary battery |
JP2017134962A (ja) * | 2016-01-27 | 2017-08-03 | Fdk株式会社 | ラミネート型蓄電素子の製造方法、ラミネート型蓄電素子 |
JP2021174629A (ja) * | 2020-04-22 | 2021-11-01 | Tdk株式会社 | 非水電解質二次電池及びその製造方法 |
WO2023022577A1 (ko) * | 2021-08-20 | 2023-02-23 | 주식회사 엘지에너지솔루션 | 파우치형 전지셀 및 파우치형 전지셀의 파우치날개 절곡 장치 |
JP7512989B2 (ja) | 2021-10-15 | 2024-07-09 | トヨタ自動車株式会社 | 電池の製造方法、電池の製造装置、および電池 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2005036674A1 (ja) | 2006-12-28 |
EP1686636A1 (en) | 2006-08-02 |
JP4788889B2 (ja) | 2011-10-05 |
EP1686636A4 (en) | 2009-04-22 |
CN1864284A (zh) | 2006-11-15 |
KR100819977B1 (ko) | 2008-04-08 |
KR20060064686A (ko) | 2006-06-13 |
US8697277B2 (en) | 2014-04-15 |
US20140182119A1 (en) | 2014-07-03 |
US20070009795A1 (en) | 2007-01-11 |
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