WO2004077536A1 - 空中配線の製造方法及びその空中配線の製造装置 - Google Patents
空中配線の製造方法及びその空中配線の製造装置 Download PDFInfo
- Publication number
- WO2004077536A1 WO2004077536A1 PCT/JP2004/001625 JP2004001625W WO2004077536A1 WO 2004077536 A1 WO2004077536 A1 WO 2004077536A1 JP 2004001625 W JP2004001625 W JP 2004001625W WO 2004077536 A1 WO2004077536 A1 WO 2004077536A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- aerial wiring
- manufacturing
- aerial
- gas
- wiring
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/047—Coating on selected surface areas, e.g. using masks using irradiation by energy or particles
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier
- H01L27/04—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having at least one potential-jump barrier or surface barrier; including integrated passive circuit elements with at least one potential-jump barrier or surface barrier the substrate being a semiconductor body
Definitions
- the present invention provides a method of growing a conductor from a substrate surface or a three-dimensional structure by using a beam excitation reaction such as a focused ion beam (FIB), and performing aerial wiring having a diameter on the order of nm and the aerial wiring.
- a beam excitation reaction such as a focused ion beam (FIB)
- FIB focused ion beam
- Non-Patent Document 3 Formation of columnar (villa) and wall structures using a focused ion beam and fabrication of field emitters and photonic crystal structures using an electron beam have been reported (Non-Patent Document 3). , 4). However, the technologies reported so far do not realize any three-dimensional structure.
- any arbitrary The present inventors have developed a technology for realizing a three-dimensional three-dimensional structure. 5).
- Non-Patent Document 3 (Non-Patent Document 3)
- Non-patent document 4 (Non-patent document 4)
- Non-Patent Document 5 (Non-Patent Document 5)
- aerial wiring on the order of ⁇ is indispensable for wiring such as microelectronic devices such as microcoils.
- An object of the present invention is to provide a method for manufacturing an aerial wiring capable of manufacturing an aerial wiring on the order of nm, and an apparatus for manufacturing the aerial wiring.
- a beam is radiated based on the three-dimensional position data previously stored in the computer pattern drawing device and the beam irradiation position, irradiation direction, and irradiation time, and the beam excitation reaction is used. Then, aerial wiring is manufactured by the CVD process.
- the beam excitation reaction is performed by a focused beam using a liquid metal ion source.
- the aerial wiring is characterized by producing an aerial wiring freely in a space.
- the CVD method is a focused ion beam-CVD method or an electron beam-CVD method.
- a micro three-dimensional structure, a reaction gas acting on a portion of the micro three-dimensional structure, a beam excitation reaction means, and a beam from the beam excitation reaction means are converted into three-dimensional position data. It is equipped with a computer pattern drawing device to be controlled in the evening, and is characterized in that previously designed aerial wiring is manufactured by a CVD process using a beam excitation reaction.
- FIG. 1 is a schematic view of an apparatus for manufacturing an aerial wiring using a focused ion beam according to a first embodiment of the present invention.
- FIG. 2 is a view showing a Fuwenantoren (C 14 H 1 ()) 3-dimensional example of manufacturing nano wires fabricated using a force one carbon single source (1).
- FIG. 3 is a diagram showing an example (part 2) of fabricating a three-dimensional nanowire fabricated using a carbon monoxide source of phenanthrene (C 14 H 1 () ).
- FIG. 4 is a diagram in which the branch portion of the wiring is observed by TEM.
- FIG. 5 is a diagram showing an example of a layout diagram of electrical characteristics of aerial wiring and an example of measured data.
- FIG. 6 is a schematic diagram of elemental analysis of aerial wiring and a characteristic diagram of EDX elemental analysis of a spectrum of an aerial wiring.
- FIG. 7 is a diagram showing the results of elemental analysis and electrical characteristics.
- FIG. 8 is a schematic view of an apparatus for manufacturing an aerial wiring using a focused ion beam, showing a first embodiment of the present invention.
- FIG. 9 is a SIM image of an aerial wiring grown in a mesh pattern showing an example of the present invention.
- FIG. 10 is a SIM image of a DLC aerial wiring manufactured in a ladder shape showing an example of the present invention.
- FIG. 11 is a diagram showing an example of a parallel coil-shaped DLC aerial wiring according to an embodiment of the present invention.
- FIG. 1 is a schematic view of an apparatus for manufacturing an aerial wiring using a focused ion beam according to a first embodiment of the present invention.
- 1 is a Si substrate
- 2 is a DLC (Diamond Liquid Carbbon) pillar as a deposition structure
- 3 is an aerial wiring having a width connected to the DLC villa 1-2.
- No. 4 is a nozzle for sending out phenanthrene 'gas (melting point: 9.9 ° C, boiling point: 340 ° C) as a reaction gas
- 5 is phenanthrene' gas as a reaction gas
- 6 is a focused ion beam device
- 7 is A focused ion beam
- 8 is the scanning direction of the focused ion beam
- 9 is a computer pattern drawing device
- the computer pattern drawing device 9 has a CPU (central processing unit) 9A, interfaces 9B, 9D, It has a memory 9C, an input / output device 9E, and a display device 9F for storing three-dimensional position data, beam irradiation position, irradiation direction, and irradiation time.
- CPU central processing unit
- an air wiring 3 having a width was produced by an excitation reaction in a carbon-based gas (phenanthrene: C 14 H ⁇ ) gas phase.
- the deposited material was confirmed to be diamond-like force (DLC) by Raman spectroscopy.
- the energy of G a + ion is 30 keV, and the irradiation ion current is 1 pA ⁇ : about InA.
- this Ga + focused ion beam is irradiated to the Si substrate 1 in the atmosphere of the reaction gas 5, the reaction gas molecules adsorbed at the irradiation position are decomposed, and an amorphous carbon grows.
- the phenanthrene 5 used as the reaction gas has a melting point of 99. C, boiling point 3
- the focused ion beam uses Ga +
- the present invention is not limited to this. Any source of liquid metal ion, for example, Au + or Si + may be used.
- Chemical vapor deposition by focused ion beam irradiation proceeds by the decomposition and deposition of reactive gas molecules adsorbed on the substrate and the surface of the growing structure by secondary electrons.
- primary electrons are emitted in an elastic / inelastic scattering interaction process when primary ions penetrate into a substrate or a deposit.
- 30 keV G a + ion its range is about 20 nm.
- primary ions are scattered within a range of about 20 nm in radius from the ion beam irradiation position, and primary electrons are emitted from this scattering region.
- Secondary electrons with relatively low energy that jumped out to the substrate surface are quickly captured by the adsorbed gas molecules due to their large reaction cross-section, and the primary electrons are decomposed into the reactive gas molecules to form amorphous carbon. Grows.
- the ion beam irradiation position is fixed, pillars of amorphous carbon grow in the beam direction.
- the beam irradiation position is slightly shifted laterally, the secondary electron generation region is also shifted.
- the growth of secondary electrons on the pillar sidewall in the shifted direction starts the growth of laterally branched amorphous carbon.
- the scattered primary ions do not penetrate the overhanging branches of amorphous carbon.
- Fuenantoren Figure 2 an example of manufacturing a three-dimensional nano-wires fabricated by using carbon single source Ichisu of (CH 10) (L, C, R parallel circuit, growth time: 0 min), and FIG. 3 (L , C, R filter circuit, growth time: 11 minutes).
- Each wiring diameter is about 100 nm.
- TEM-EDX observations were made to examine the composition and structure of the fabricated 3D nanowires.
- Fig. 4 shows the TEM observation of the branching part of the wiring under 20 OkEV. From this observation, we were able to identify the distribution and position of Ga and C inside the three-dimensional nanowire. The analysis area had a diameter of 2 O nm or less.
- Fig. 5 shows an electrical characteristics evaluation layout of aerial wiring and an example of measurement data.
- a mixed gas in which tungsten carbonyl (W (CO) 6) gas, which is an organic metal gas, was supplied together with phenanthrene gas in order to reduce the wiring resistivity was used as a source gas.
- the resistivity of the wiring made only with the phenanthrene gas was 100 ⁇ cm, while the resistivity of the wiring made by supplying the tungsten carbonyl gas at the same time was 0.0. It could be reduced to 2 Qcm. That is, by supplying evening stainless steel gas, it is possible to manufacture a wiring having a variable range of resistivity up to 1/1000.
- Fig. 6 shows the SEM-EDX electron beam spot beam An experiment was carried out to determine the element content of. As a result of the measurement, it was clarified that increasing the gas density of tungsten carbonyl increased the contents of the metal elements Ga and W and reduced the resistivity of the three-dimensional nanowire.
- Fig. 7 shows the relationship between the resistivity measured by SEM-EDX and the W content.
- the source gas can be manufactured using a single source gas.
- a mixed gas with a different source gas is used as the source gas.
- FIG. 8 is a schematic view of an apparatus for manufacturing an aerial wiring using a focused ion beam according to a second embodiment of the present invention.
- 11 is a substrate
- 12 is an insulating plate
- 13 is an aerial wiring in the wiring
- 14 is a phenanthrene 'gas (melting point: 99 ° C, boiling point: 340 ° C) as a reaction gas.
- Nozzle 15 is a phenanthrene gas as a reaction gas-
- 16 is a focused ion beam device
- 17 is a focused ion beam
- 18 is the scanning direction of the focused ion beam
- 19 is a computer pattern drawing device Yes
- this computer pattern drawing device 19 has a CPU (Central Processing Unit) 19A, interfaces 19B, 19D, and stores in advance the three-dimensional position data and the beam irradiation position, irradiation direction, and irradiation time Memory 19 C :, an input / output device 19 E, and a display device 19 F. Therefore, as shown in FIG. 8, the aerial wiring 13 is composed of three-dimensional position data previously stored in the memory 19 c of the computer pattern drawing device 19 and the irradiation position, irradiation direction, and irradiation of the beam. Wired based on time.
- CPU Central Processing Unit
- FIG. 9 is a SIM (scanning ion microscopy) image (ion microscope image) of a mesh-shaped aerial wiring showing an embodiment of the present invention.
- a crossbar structure with a wiring diameter of 100 nm was fabricated by DLC wiring.
- the fabrication conditions were a beam current of 0.5 pA, a dose shift of 2.7 ms / nm, and an exposure time of 147 s.
- a metal wiring crossbar logic circuit can be formed by using an organic metal gas source as a reaction gas source.
- the wire diameter is 100 nm
- the fabrication time is 90 seconds
- the aerial wiring is formed
- the resistance, capacity, Inkkuta, etc. are freely created between the aerial wires Can also be configured.
- a gas source that can deposit metals such as Au, Pt, and W was used.
- a reactive gas source such as a P or N dopant during the production of the aerial torsion line
- local doping such as a PN junction is performed, and a three-dimensional information network with a mixture of electron and optical devices is constructed. can do.
- the fabrication conditions in this example are as follows: the beam current is 0.5 pA and the dose shift is 2.7 ms / nm.
- FIG. 10 is a SIM image of a DLC aerial wiring fabricated in a ladder shape showing an example of the present invention.
- the fabrication conditions were a beam current of 0.3 pA, a dose shift of 3.Oms / nm, and an exposure time of 107 s. is there.
- FIG. 11 is a SIM image of a parallel coiled DLC aerial wiring showing the embodiment of the present invention.
- the fabrication conditions were a beam current of 0.3 pA, a dose shift of 3.Oms / nm, and an exposure time of 166 s. is there.
- the beam diameter of the focused ion beam can be focused to about 5 nm, it is possible to obtain aerial wiring of several tens Onm level using three-dimensional data of a computer pattern drawing device.
- reaction gas By changing the reaction gas, it is possible to form three-dimensional wiring using various materials such as metals, semiconductors, and insulators. Of course, it is possible to form a composite three-dimensional aerial wiring that partially changes the material with one three-dimensional structure.
- local doping of a semiconductor material may be performed between the aerial wirings by focused ion beam implantation.
- local doping of a semiconductor material between the aerial wirings may be performed by irradiating an electron beam in a doping gas.
- a semiconductor device can be moved between the aerial wirings by a laser / electrostatic manipulator, and the semiconductor devices can be fixed between the aerial wirings by a CVD method. .
- the CVD method may be a focusing beam-CVD method or an electron beam-CVD method. It should be noted that the present invention is not limited to the above embodiments, and various modifications are possible based on the spirit of the present invention, and these are not excluded from the scope of the present invention. As described above, according to the present invention, the following effects can be obtained.
- Aerial wiring of the order of ii m to n m can be manufactured in any size and shape, and a three-dimensional functional device can be manufactured.
- the method for manufacturing an aerial wiring and the apparatus for manufacturing an aerial wiring according to the present invention can be used for a microswitch, a sensor, a manifold for biotechnology, a microwave antenna, a quantum device, and the like.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020057016088A KR100749710B1 (ko) | 2003-02-28 | 2004-02-16 | 안테나의 제조방법 및 안테나의 제조디바이스 |
US10/546,989 US20070015335A1 (en) | 2003-02-28 | 2004-02-16 | Production method for antenna and production device for antenna |
EP04711480A EP1598857A4 (en) | 2003-02-28 | 2004-02-16 | MANUFACTURING METHOD FOR AN ANTENNA AND MANUFACTURING EQUIPMENT FOR AN ANTENNA |
CNA2004800081249A CN1765007A (zh) | 2003-02-28 | 2004-02-16 | 自由空间配线的制造方法及其制造装置 |
JP2005502830A JP4704911B2 (ja) | 2003-02-28 | 2004-02-16 | 空中配線の製造方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003/054362 | 2003-02-28 | ||
JP2003054362 | 2003-02-28 |
Publications (1)
Publication Number | Publication Date |
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WO2004077536A1 true WO2004077536A1 (ja) | 2004-09-10 |
Family
ID=32923460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/001625 WO2004077536A1 (ja) | 2003-02-28 | 2004-02-16 | 空中配線の製造方法及びその空中配線の製造装置 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20070015335A1 (ja) |
EP (1) | EP1598857A4 (ja) |
JP (1) | JP4704911B2 (ja) |
KR (1) | KR100749710B1 (ja) |
CN (1) | CN1765007A (ja) |
TW (1) | TW200424349A (ja) |
WO (1) | WO2004077536A1 (ja) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006123150A (ja) * | 2004-11-01 | 2006-05-18 | National Institute For Materials Science | 電子ビーム誘起蒸着法を用いたナノ構造作成制御方法 |
JP2006129977A (ja) * | 2004-11-04 | 2006-05-25 | Japan Science & Technology Agency | 神経再生電極装置の作製方法及びその神経再生電極装置 |
JP2007069329A (ja) * | 2005-09-08 | 2007-03-22 | Japan Science & Technology Agency | 微小立体構造操作具の作製方法及びそれによって作製される微小立体構造操作具 |
JP2007069325A (ja) * | 2005-09-08 | 2007-03-22 | Japan Science & Technology Agency | 微小電磁装置の作製方法及びそれによって作製される微小電磁装置 |
JP2007146224A (ja) * | 2005-11-28 | 2007-06-14 | Tdk Corp | 描画方法、読取り方法、描画装置、読取り装置および物体 |
JP2007149524A (ja) * | 2005-11-29 | 2007-06-14 | Japan Science & Technology Agency | 微小電子エミッタの作製方法及びそれを用いて作製される微小電子エミッタ |
JP2008226918A (ja) * | 2007-03-08 | 2008-09-25 | National Institute For Materials Science | 極微小ダイオード |
JP2008311620A (ja) * | 2007-05-15 | 2008-12-25 | Canon Inc | エッチングマスクの形成方法、3次元構造体の製造方法及び3次元フォトニック結晶レーザー素子の製造方法 |
JP2009250928A (ja) * | 2008-04-10 | 2009-10-29 | Nippon Hoso Kyokai <Nhk> | Mems型熱線式粒子速度検出素子及びその製造方法並びに音響センサ |
JP2010225533A (ja) * | 2009-03-25 | 2010-10-07 | Japan Fine Ceramics Center | 緊張化した空中配線の形成方法、荷電粒子線プリズムとその製造方法、荷電粒子線の干渉縞を用いた観察方法、電子顕微鏡および電子顕微鏡における干渉縞の形成方法 |
Families Citing this family (3)
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US8277691B2 (en) * | 2008-05-05 | 2012-10-02 | Ada Technologies, Inc. | High performance carbon nanocomposites for ultracapacitors |
US20140042390A1 (en) * | 2011-02-16 | 2014-02-13 | The Regents Of University Of California | Interpenetrating networks of carbon nanostructures and nano-scale electroactive materials |
CN112072319B (zh) * | 2020-08-31 | 2022-03-01 | 泉州师范学院 | 一种金属等离激元纳米光学天线的制备方法 |
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- 2004-02-16 EP EP04711480A patent/EP1598857A4/en not_active Withdrawn
- 2004-02-16 US US10/546,989 patent/US20070015335A1/en not_active Abandoned
- 2004-02-16 WO PCT/JP2004/001625 patent/WO2004077536A1/ja active Application Filing
- 2004-02-16 CN CNA2004800081249A patent/CN1765007A/zh active Pending
- 2004-02-16 KR KR1020057016088A patent/KR100749710B1/ko not_active IP Right Cessation
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- 2004-02-18 TW TW093103843A patent/TW200424349A/zh unknown
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2006123150A (ja) * | 2004-11-01 | 2006-05-18 | National Institute For Materials Science | 電子ビーム誘起蒸着法を用いたナノ構造作成制御方法 |
JP2006129977A (ja) * | 2004-11-04 | 2006-05-25 | Japan Science & Technology Agency | 神経再生電極装置の作製方法及びその神経再生電極装置 |
JP4485323B2 (ja) * | 2004-11-04 | 2010-06-23 | 独立行政法人科学技術振興機構 | 神経再生電極装置の作製方法及びその神経再生電極装置 |
JP2007069329A (ja) * | 2005-09-08 | 2007-03-22 | Japan Science & Technology Agency | 微小立体構造操作具の作製方法及びそれによって作製される微小立体構造操作具 |
JP2007069325A (ja) * | 2005-09-08 | 2007-03-22 | Japan Science & Technology Agency | 微小電磁装置の作製方法及びそれによって作製される微小電磁装置 |
JP2007146224A (ja) * | 2005-11-28 | 2007-06-14 | Tdk Corp | 描画方法、読取り方法、描画装置、読取り装置および物体 |
JP2007149524A (ja) * | 2005-11-29 | 2007-06-14 | Japan Science & Technology Agency | 微小電子エミッタの作製方法及びそれを用いて作製される微小電子エミッタ |
JP4672534B2 (ja) * | 2005-11-29 | 2011-04-20 | 独立行政法人科学技術振興機構 | 微小電子エミッタの作製方法及びそれを用いて作製される微小電子エミッタ |
JP2008226918A (ja) * | 2007-03-08 | 2008-09-25 | National Institute For Materials Science | 極微小ダイオード |
JP2008311620A (ja) * | 2007-05-15 | 2008-12-25 | Canon Inc | エッチングマスクの形成方法、3次元構造体の製造方法及び3次元フォトニック結晶レーザー素子の製造方法 |
JP2009250928A (ja) * | 2008-04-10 | 2009-10-29 | Nippon Hoso Kyokai <Nhk> | Mems型熱線式粒子速度検出素子及びその製造方法並びに音響センサ |
JP2010225533A (ja) * | 2009-03-25 | 2010-10-07 | Japan Fine Ceramics Center | 緊張化した空中配線の形成方法、荷電粒子線プリズムとその製造方法、荷電粒子線の干渉縞を用いた観察方法、電子顕微鏡および電子顕微鏡における干渉縞の形成方法 |
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JP4704911B2 (ja) | 2011-06-22 |
TW200424349A (en) | 2004-11-16 |
KR100749710B1 (ko) | 2007-08-16 |
JPWO2004077536A1 (ja) | 2006-06-08 |
EP1598857A1 (en) | 2005-11-23 |
US20070015335A1 (en) | 2007-01-18 |
KR20050106058A (ko) | 2005-11-08 |
EP1598857A4 (en) | 2008-11-26 |
CN1765007A (zh) | 2006-04-26 |
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