Classifications

• • A—HUMAN NECESSITIES
  • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
  • A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
  • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
  • A23L27/40—Table salts; Dietetic salt substitutes
• • A—HUMAN NECESSITIES
  • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
  • A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
  • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
  • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
  • A23L33/16—Inorganic salts, minerals or trace elements
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F1/00—Treatment of water, waste water, or sewage
  • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
  • C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
  • C02F2103/08—Seawater, e.g. for desalination
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
  • Y02A20/00—Water conservation; Efficient water supply; Efficient water use
  • Y02A20/124—Water desalination

Definitions

• the present invention relates to a composition containing a low-sodium seawater mineral component derived from seawater, and a food and drink containing the same.
• ischemic heart disease develops due to an increased load on the heart.
• soft water water with a hardness of less than 100
• hard water water with a hardness of 100 or more
• Soft water does not contain enough mineral components, and minerals can be taken from soft water. And there is a limit: ⁇
• an electrodialysis method which is now widely used as a salt production process instead of the ancient salt field method, is widely used.
• seawater flows while the cation membrane and the anion membrane are alternately arranged, electrodes are placed at both ends, and a direct current is passed, so that substances that become ions in the liquid are removed.
• cations move to the cathode and anions move to the anode.
• cations can pass through the cation membrane, but anions cannot pass through the cation membrane.
• a concentration chamber and a dilution chamber are alternately formed in the membrane and the space between the membranes.
• seawater having a salt concentration 7 to 8 times that of seawater is formed.
• a membrane is selected that allows monovalent ions to pass through the exchange membrane but does not allow divalent ions to pass through, ions such as magnesium and calcium will not be able to enter the concentration chamber and will remain in the dilution chamber. Since this dilution water is rich in minerals, it can be used for mineral supplement beverages. Recently, the sale of mineral water using deep ocean water as raw water has also become commercially available. At present, it is common practice to select a membrane with high monovalent ion permeability as the ionic membrane and dialyze until the electrical conductivity of the mineral water becomes 10 to 12 mS / cm (sodium concentration: about 500 ⁇ ).
• monovalent cation exchange membranes (monovalent cation selective dialysis membranes) are used to remove monovalent cations contained in seawater. Move to the enrichment chamber side to leave divalent ions such as magnesium and calcium in the mineral chamber (dilution chamber mentioned above). At this time, the monovalent cations (mainly sodium) remaining in the mineral chamber side The lower the concentration of), the smaller the value of the flowing current and the lower the efficiency of electrodialysis.
• the mineral composition of seawater has a very high correlation with the mineral composition of human serum, and the composition ratio of magnesium is higher than that of land water. It is considered to be extremely useful as a source from which body constituent minerals can be taken.
• a mineral component containing divalent ions can be obtained without difficulty, the remaining large amount of sodium and the concentration of divalent ions vary, and furthermore, the electric conductivity is low. If electrodialysis is completed at a concentration of up to 10-12 mS / cm, the resulting seawater mineral-containing composition does not sufficiently remove sodium, so there is a limit to its intake for health and it is useful. Seawater minerals could not be used effectively enough.
• the present inventors have conducted intensive research on safe and excellent flavor seawater mineral components in order to use useful seawater mineral components widely in foods and drinks. As a result, the sodium concentration was low, and magnesium was low.
• the present invention has been completed by obtaining a mineral-containing composition having a high concentration and a stable mineral composition.
• the present invention relates to a seawater mineral component-containing composition obtained by subjecting seawater to electrodialysis treatment, wherein when adjusted to an aqueous solution having a hardness of 100 (EDTA method), the sodium concentration is 6 mg / L or less. It is a seawater mineral component-containing composition. Further, the present invention provides a seawater mineral component-containing composition having a sodium concentration of 6 mg / L or less when seawater is adjusted to an aqueous solution having a hardness of 100 (EDTA method) by electrodialysis. It is a characteristic food and drink.
• the present invention also provides a method for producing a seawater mineral component-containing composition by subjecting seawater to electrodialysis to obtain a seawater mineral component-containing composition, wherein the electrodialysis treatment uses a monovalent cation selective dialysis membrane.
• the present invention is a method for producing a seawater mineral component-containing composition for obtaining a seawater mineral component-containing composition by subjecting seawater to electrodialysis treatment, wherein the electrodialysis treatment is performed in a plurality of times.
• This is a method for producing a seawater mineral component-containing composition characterized by the following characteristics.
• the present invention is a method for producing a seawater mineral component-containing composition, wherein the concentration of sodium in the concentration chamber is kept low in the electrodialysis treatment.
• the seawater mineral component-containing composition of the present invention can be widely used as food or drink or an additive thereof, and may be used in the form of mineral water as it is, or in the form of a dried product, a concentrated product, a diluted product, etc. Furthermore, these may be used as a form in which additives such as vitamins, polyphenols, amino acids, peptides, proteins, sugars, fibers, organic acids and the like are added.
• the dried product can be produced by spray drying the mineral water or its concentrate by freeze-drying, evaporating to dryness, or inclusion in a powdered base material such as saccharides by a usual method.
• the seawater usable in the present invention includes surface water, middle water, deep water and the like. Of these, deep water, especially seawater 200 m or deeper, is less susceptible to environmental pollution and has a high level of cleanliness. Preferred for use in the invention.
• seawater mineral component of the present invention is extremely stable as a composition
• heating, cooling, freezing, etc. can be performed on the seawater mineral component-containing composition itself or in applying the seawater mineral component-containing composition to food or drink.
• the food or drink that can be treated with the seawater mineral component-containing composition of the present invention can be used without any particular limitation in the form of ordinary food and drink. For example, capsules, tablets, powders, jelly, etc.
• the seawater mineral component-containing composition of the present invention can be used in the form of liquor or normal food and drink, specifically fruit juice drinks, soft drinks, lactic acid drinks, carbonated drinks, coffee drinks, tea drinks, vegetable drinks, liquids, cocktails, shochu, Shochu High, Wine, Beer, Happoshu, Whiskey, Brande, Evening Bullet, Candy, Gummy, Cookies, Jelly, etc.
• the seawater mineral component-containing composition of the present invention has excellent flavor and extremely low sodium concentration, it can be used as a food and drink in a wide variety of products when applied to the above food and drink. It is possible to control the amount of mineral components such as magnesium and calcium in food and drink.
• the dose of the composition containing a seawater mineral component of the present invention can be set according to the shape of the food or drink to be provided. For example, it is possible to design a product using the intake of magnesium as an index. In this case, it may be possible to adjust the intake of magnesium from 1 mg to 700 mg per serving.
• the composition containing seawater mineral components of the present invention has a high ratio of mineral components having health effects such as magnesium and calcium, and has a low sodium concentration, and thus is suitable for foods and drinks such as reduced salt foods and health foods. It can be used for In the application of the seawater mineral component-containing composition of the present invention to foods and drinks, it may be applied in combination with other functional components, and other functional components are not particularly limited. As other functional components, vitamins, polyphenols, amino acids, peptides, proteins, sugars, fibers, organic acids, and the like can be applied.
• the seawater mineral component-containing composition of the present invention can be obtained by subjecting seawater to electrodialysis using a monovalent cation selective dialysis membrane and subjecting it to electrodialysis treatment.
• the electrodialysis treatment can be performed by using a normal electrodialysis machine.By adjusting the electric conductivity at the end of electrodialysis to a low conductivity of less than 10 mS / cm, the sodium concentration can be reduced, and By increasing the magnesium concentration, a seawater mineral component-containing composition having a stable mineral composition can be obtained.
• the low conductivity is preferably 8 mS / cm or less, particularly 6 mS / cm at the end of electrodialysis, taking into account the cost of water and power used.
• the sodium concentration is 4 mg / L or less and the magnesium concentration is 20 mg / L. L or more, and the weight ratio of magnesium to calcium is 4 or more.
• a minute composition can be obtained.
• AC 120 manufactured by Asahi Kasei Corporation
• AC 120 can be used as a monovalent cation selective dialysis membrane.
• the seawater mineral component-containing composition of the present invention may be one in which electrodialysis treatment is performed at least once to an electric conductivity of less than 10 mS / cm using a monovalent cation selective dialysis membrane.
• Mineral water obtained by treating to the electric conductivity (12 mS / cni) used in the salt production method can be concentrated and obtained again by multiple electrodialysis treatments with the same electric conductivity. it can.
• the concentration of sodium in the enrichment chamber is 20 mg / L or less, preferably 2 mg / L or less.
• Example 1 Method for producing secondary mineral water
• Example 2 sensory evaluation was performed on drinking water samples adjusted to hardness of 250, 300, 350, 500, and 1000. The evaluation was performed by six specialized panelists, who evaluated the overall evaluation to judge likes and dislikes and the five flavor characteristics on a five-point scale.
• the seawater mineral water having a low sodium concentration and a high magnesium concentration obtained in Example 2 has an excellent flavor as compared with the conventional mineral water derived from seawater, and has a wide variety of foods and drinks. Turned out to be applicable.
• Difficult to drink 4 4 Evaluation method Evaluation was carried out by six specialized panelists. The overall rating is 5 (like) ⁇ 4 (somewhat likes) ⁇ 3 (neither) ⁇ 2 (somewhat dislike) ⁇ 1 (dislike). Flavor rating: 4 (strongly feel) ⁇ 3 (feel) ⁇ 2 (somewhat feel) ⁇ 1
• Example 4 1000 ml of seawater mineral water obtained by electrodialysis until the electric conductivity became 6 mS / cm in Example 1 was evaporated to dryness in an oven to obtain 5.5 g of dried seawater mineral.
• Example 5 Method for producing a mineral-containing juice beverage
• a juice beverage was produced according to the following composition.
• composition (Blend%, weight)
• a soft drink was manufactured according to the following composition.
• composition (Blend%, weight)
• a whey beverage was manufactured according to the following composition.
• composition (Blend%, weight)
• a carbonated beverage was manufactured according to the following composition.
• composition (Blend%, weight)
• a coffee beverage was manufactured according to the following composition.
• composition (Blend%, weight)
• a tea beverage was produced according to the following composition.
• composition (Blend%, weight)
• a vegetable drink was manufactured according to the following composition.
• composition (Blend%, weight) Mixed vegetable juice 40. 0
• composition (Blend%, weight)
• Shochu high was manufactured with the following composition.
• composition (Blend%, weight)
• a tablet was produced according to the following composition.
• composition (Blend%, weight)
• a candy was manufactured according to the following composition.
• composition (Blend%, weight)
• Example 16 Method for producing gummy-containing gummy
• Gummies were produced according to the following composition.
• composition (Blend%, weight)
• Example 19 Method for producing mineral-containing cookie A cookie was produced according to the following composition.
• composition (Blending ratio, weight) Soft flour 32.0 Whole egg 16.0 Margarine 18.0 Kamikasu 25.5 Composition containing mineral components of seawater (* 13) 2.5 Baking powder 0.2 Water balance
• composition (Blending%, weight) Granulated sugar 15.0 Gelatin 5.0 Orange extract 5.0 Seawater mineral component-containing composition (* 14) 1.5 Peppermint powder 0.4 Pure water balance
• the seawater mineral component-containing composition of the present invention in which the ratio of mineral components having a health effect such as magnesium and calcium is increased and monovalent ions such as sodium and potassium are reduced, as a mineral composition derived from seawater, It can be widely applied to foods in which the amount of added sodium is a problem, such as reduced salt foods and health foods, and can solve the problem of sensual saltiness and unpleasant taste when processed into drinking water. Furthermore, in terms of health effects, the use of this mineral composition can provide many forms of foods and drinks that can be expected from the intake of magnesium and calcium and that are useful for preventing cardiovascular diseases and lifestyle-related diseases. it can.

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• Life Sciences & Earth Sciences (AREA)
• Chemical & Material Sciences (AREA)
• Food Science & Technology (AREA)
• Polymers & Plastics (AREA)
• Health & Medical Sciences (AREA)
• Nutrition Science (AREA)
• Engineering & Computer Science (AREA)
• Mycology (AREA)
• Inorganic Chemistry (AREA)
• Non-Alcoholic Beverages (AREA)
• Coloring Foods And Improving Nutritive Qualities (AREA)
• Separation Using Semi-Permeable Membranes (AREA)
• Medicines Containing Material From Animals Or Micro-Organisms (AREA)
• Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
• Water Treatment By Electricity Or Magnetism (AREA)

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• 2002
  • 2002-08-09 JP JP2002232809A patent/JP2004065196A/ja active Pending
• 2003
  • 2003-08-08 KR KR1020057002234A patent/KR101002197B1/ko not_active Expired - Fee Related
  • 2003-08-08 US US10/523,805 patent/US20050281918A1/en not_active Abandoned
  • 2003-08-08 WO PCT/JP2003/010161 patent/WO2004014154A1/ja not_active Ceased
  • 2003-08-08 CN CNB038216809A patent/CN100355666C/zh not_active Expired - Fee Related
  • 2003-08-08 MY MYPI20033014A patent/MY146800A/en unknown
  • 2003-08-08 TW TW092121896A patent/TW200406160A/zh unknown

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