WO2003062478A1 - Procede de separation du zinc et d'un second metal en presence d'ions chlorures par mise en contact avec une resine echangeuse d’ions - Google Patents
Procede de separation du zinc et d'un second metal en presence d'ions chlorures par mise en contact avec une resine echangeuse d’ions Download PDFInfo
- Publication number
- WO2003062478A1 WO2003062478A1 PCT/FR2003/000212 FR0300212W WO03062478A1 WO 2003062478 A1 WO2003062478 A1 WO 2003062478A1 FR 0300212 W FR0300212 W FR 0300212W WO 03062478 A1 WO03062478 A1 WO 03062478A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- zinc
- metal
- zncl
- eluent
- chloride
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
- B01J49/57—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for anionic exchangers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/006—Compounds containing, besides zinc, two ore more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/04—Halides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/26—Refining solutions containing zinc values, e.g. obtained by leaching zinc ores
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the present invention relates to a process for the separation of zinc and a second metal which does not form a stable anionic complex in the presence of chloride ions.
- the present invention relates generally to the separation of zinc and a second metal having such a property in the presence of chloride ions, the description which follows will be more specifically illustrated by the process for the separation of zinc and nickel, without this in any way limiting the scope of the invention.
- the 5 metals found in 1 effluent, after treatment wet, are mainly zinc and nickel, in the form of chlorides ZnCl 2 and NiCl 2 .
- the present invention therefore aims to provide a process for effective separation of zinc and the second metal with the immediate advantage of providing recovery for each of the metals in their respective sectors.
- the present invention therefore relates to a process for the separation of zinc and a second metal which does not form an anionic complex in the presence of chloride ions, zinc and the second metal being present in an effluent in the form of ZnCl 2 and chloride of second metal.
- This process consists in forming and fixing the anionic complex ZnCl " 3 on a resin.
- this process is characterized in that the formation of the anionic complex is obtained by bringing the effluent into contact with the resin saturated in chloride ions, and in that the method further comprises the steps of: - extraction of the second metal chloride by means of a first eluent, then
- zinc has the particularity of forming an anionic complex ZnCl ⁇ in the presence of a suitable quantity or concentration of chloride ions, the second metal remaining in the form of non-ionic metal chloride, in these same conditions of quantity or particular concentration of chloride ions.
- the second metal can be a transition metal, preferably chosen from Cr, Cu, Ni, Fe.
- Nickel, iron, as well as any other second metal within the meaning of the present invention can then advantageously be recycled, directly or after a suitable treatment, and each valued in suitable sectors, in particular in the metallurgical industry. They can, for example, be reused in processes for the transformation of metals from ores. After extraction of the second metal in the form of chloride, it remains to proceed with the extraction of zinc at its degree of oxidation +11 for which several routes are proposed.
- a first way consists in extracting the Zn at the degree of oxidation +11 by means of a second eluent allowing the dilution of the chloride ion concentration, which has the effect of dissociating the ZnCl 3 ⁇ complex according to the reaction:
- a second way consists in carrying out a step of desorption of the zinc at its oxidation state +11 by transformation, by means of a reagent, of the ZnCl 3 " complex into a zinc complex more stable than the ZnCl 3 " complex, and not adsorbed by the resin.
- a third way consists in carrying out a step of electrolytic desorption of zinc at its degree of oxidation +11.
- composition of effluent 1 is in accordance with that indicated above, namely (in g / 1):
- This treatment is carried out in a tank 3 into which are introduced on the one hand the effluent 1 from the tank 2 and on the other hand a reagent 4 intended to allow the extraction of calcium.
- This reagent 4 can advantageously be sulfuric acid, added in stoichiometric amounts. After introduction, into a solid-liquid separator 5, of the mixture 6 constituted by the effluent 1 added with sulfuric acid 4, the precipitation of hydrated calcium sulphate CaSO 4 , xH 2 0, or gypsum 7, collected in the receptacle 8.
- the effluent 9 consisting of the initial calcium-free effluent, is introduced into a tank 10 for subsequent introduction into the separation column 11 with a capacity of 60 1, filled internally resin 12.
- the resin may be formed from a styrene-divinylbenzene copolymer backbone and from an N (CH 3 ) 3 + functional group in ionic form.
- the resin 12 used is a "He atitt" type resin.
- saturation of the resin 12 is carried out by introduction of a solution of hydrochloric acid HCl, or of sodium chloride NaCl, in order to create a medium concentrated in ions chlorides.
- This saturation step of the resin 12 is carried out by adding a solution of chlorides in the form of HCl, NaCl, KCl ... the equivalent concentration of chloride ions of which is greater than or equal to
- the effluent 9 is introduced, at a constant speed and at a rate of 2 1 / min, into the upper part of the column 11, the lower part of this column 11 being closed during this effluent introduction operation 9.
- the Zn at the degree of oxidation +11 is fixed on the resin 12 in the form of the anionic complex ZnCl 3 " .
- a possible alternative consists in introducing, directly into the tank 10 containing the effluent 9, a suitable quantity of chloride ions promoting the formation of the anionic complex ZnCl 3 " .
- the next step consists in extracting, by a first eluent 13, the nickel chloride NiCl 2 present in the effluent 9 and which has not been adsorbed by the resin 12.
- This first eluent 13 can be a solution of hydrochloric acid HCl or sodium chloride NaCl.
- this first eluent 13 has a concentration of chloride ions greater than or equal to about 0.7 mol / 1 and, preferably, between 1 and 1.3 mol / 1 approximately.
- concentration of chloride ions makes it possible in fact to maintain the zinc in its complexed form ZnCl 3 " and therefore adsorbed on the resin
- the elution product by means of this first eluent 13 is an effluent 14, collected from the lower part of the column 11 , opened during this elution step, and collected in the tank 15.
- the elution by means of this first eluent 13 is interrupted when the nickel concentration in the effluent 14 at the column outlet 11 becomes negligible.
- This effluent 14 therefore consists of a solution of pure nickel chloride NiCl 2 , in which the zinc is only present in a trace state, as will be verified later.
- the effluent 14 can then be implemented according to various treatments, including treatments aimed at developing the nickel proper.
- the NiCl 2 extracted with the first eluent 13 can be reacted, and therefore the Ni 2+ present in solution can be precipitated with a precipitation reagent 16.
- the effluent 14 is introduced into a precipitation 17 to which precipitation reagent 16 is added.
- the precipitation reagent 16 is an alkaline reagent, which makes it possible to form nickel hydroxide Ni (OH) 2 .
- alkaline reagent from soda, lime, potash.
- the precipitation reagent 16 is introduced until a pH of between 9.5 and 10.5 is obtained where the nickel hydroxide is at its minimum of solubility.
- the precipitation reagent 16 is introduced in quantities making it possible to reach the pH corresponding to the minimum solubility of the second metal cation precipitate.
- the effluent 14 was placed in the presence of 4 l of sodium hydroxide (10 M) in the precipitation tank 17.
- Nickel hydroxide Ni (OH) 2 is formed in accordance with the following chemical reaction: NiCl 2 + 2NaOH - ⁇ Ni (OH) 2 + 2NaCl
- a conventional coagulant and / or flocculant reagent can advantageously be added to the precipitation tank 17.
- the solid-liquid mixture 18 obtained in the precipitation tank 17 is then introduced and then separated by means of a filter press 19.
- the solid phase is then washed with 60 l of water in the filter press 19 and then the nickel hydroxide cake 20 is isolated.
- This hydroxide 20 after drying at 105 ° C to constant mass, has the following composition, in mass%:
- the step of extracting the zinc adsorbed on the resin 12 is carried out.
- the step of extracting the zinc to its degree d oxidation +11 is only carried out after complete extraction of NiCl 2 , in order to optimize, not only the selective separation of nickel, but also that of zinc.
- quantitative measurements carried out at the outlet of column 11 make it possible to define when all of the nickel present in the effluent 9 has been extracted and is found in the effluent 14.
- This zinc extraction step can be carried out according to several methods.
- a first way consists in dissociating the anionic complex ZnCl 3 " to form free ZnCl 2. This dissociation is carried out by means of a second eluent 21 allowing the dilution, and therefore the decrease, of the concentration of chloride ions in the medium contained in inside column 11.
- ZnCl 3 dissociates and causes the desorption of zinc in the form of ZnCl 2 which goes into solution.
- This second eluent 21 can be a solution of sodium chloride NaCl or water.
- the elution product obtained by means of this second eluent 21 is an effluent 22, collected from the lower part of the column 11, opened during this elution step, and collected in the tank 23.
- the elution by means of this second eluent 21 is interrupted when the zinc concentration in the effluent 22 at the outlet of column 11 is no longer detectable.
- Effluent 22 consisting of a perfectly pure solution of zinc chloride ZnCl 2 , can then be implemented according to various treatments, including treatments aimed at enhancing the zinc proper. It is in particular possible to react the ZnCl 2 extracted with the second eluent 21, and therefore to precipitate the
- L 1 effluent 22 is introduced into a precipitation tank 25 in which is added the precipitation reagent 24.
- the precipitation reagent 24 is an alkaline reagent, which makes it possible to form zinc hydroxide Zn (OH) 2 .
- alkaline reagent from soda, lime, potash.
- a sulfide can also be used as a precipitation reagent 24, which allows the formation of zinc sulfide ZnS.
- the precipitation reagent can also be used as a precipitation reagent 24, which allows the formation of zinc sulfide ZnS.
- the effluent 22 was placed in the presence of 2 l of sodium hydroxide (10 M) in the precipitation tank 25.
- Zinc hydroxide Zn (OH) 2 is formed in accordance with the following chemical reaction:
- the subsequent filtration step it is possible to add a coagulating and / or flocculating reagent to the precipitation tank 25.
- the solid-liquid mixture 26 obtained in the precipitation tank 25 is then introduced and then separated by means of the filter press 19, which will have been emptied beforehand of the nickel hydroxide 20 collected during a previous step.
- the solid phase is then washed with 60 l of water in the filter press 19 and then the zinc hydroxide cake 27 is isolated.
- This hydroxide 27, after drying at 105 ° C to constant mass, has the following composition, in mass%:
- this zinc hydroxide 27 is of high purity and can validly be recovered through the zinc processing industries of the metallurgical industry.
- a second way allowing the extraction of zinc consists in carrying out, after the extraction step of NiCl 2 , a step of desorption of zinc at the degree of oxidation +11.
- This step aims to transform the anionic complex ZnCl 3 " adsorbed on the resin into a zinc complex which is more stable than the complex ZnCl 3 " and is not adsorbed on the resin 12.
- a quantitative desorption of the zinc is notably obtained when the desorption step is carried out with an ammonia solution.
- the complex formed in this case is Zn (NH 3 ) 4 2+ .
- a third way envisaged consists in carrying out, after the stage of extraction of NiCl 2 , a stage of electrolytic desorption of zinc at its degree of oxidation +11.
- the resin 12 on which the anionic complex ZnCl 3 " is formed is extracted from the column 11 and placed on a permeable membrane, this membrane itself being positioned between two electrodes. The application of a potential difference electric between these two electrodes allows the desorption, 1 electromigration and therefore the extraction, of zinc at the degree of oxidation +11.
- the installation shown in the appended figure will be validly completed by the installation of at least two columns 11 arranged in parallel, each containing the resin 12 for fixing the anionic complex ZnCl 3 " ; such columns 11 can then be successively used for the steps of the process for separating zinc and nickel, or iron respectively, according to the invention.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE60322179T DE60322179D1 (de) | 2002-01-23 | 2003-01-22 | Verfahren zur abtrennung von zink und nickel in gegenwart von chloridionen |
EP03715040A EP1468122B1 (fr) | 2002-01-23 | 2003-01-22 | Procédé de séparation du zinc et du nickel en présence d'ions chlorures |
US10/502,497 US20050211631A1 (en) | 2002-01-23 | 2003-01-22 | Method for the separation of zinc and a second metal which does not form an anionic complex in the presence of chloride ions |
DE03715040T DE03715040T1 (de) | 2002-01-23 | 2003-01-22 | Verfahren zur trennung von zink und einem zweiten metall in gegenwart von chloridionen mittels eines ionenaustauschharzes |
JP2003562344A JP2005515302A (ja) | 2002-01-23 | 2003-01-22 | 亜鉛と塩化物イオンの存在下でアニオン錯体を形成しない第2金属とを分離する方法 |
KR10-2004-7011442A KR20040079948A (ko) | 2002-01-23 | 2003-01-22 | 아연 및 염화물 이온의 존재 하에서 음이온 착체를형성하지 않는 제 2 금속을 분리하는 방법 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR02/00816 | 2002-01-23 | ||
FR0200816A FR2834980B1 (fr) | 2002-01-23 | 2002-01-23 | Procede de separation du zinc et d'un second metal ne formant pas de complexe anionique en presence d'ions chlorures |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003062478A1 true WO2003062478A1 (fr) | 2003-07-31 |
Family
ID=27589566
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2003/000212 WO2003062478A1 (fr) | 2002-01-23 | 2003-01-22 | Procede de separation du zinc et d'un second metal en presence d'ions chlorures par mise en contact avec une resine echangeuse d’ions |
Country Status (12)
Country | Link |
---|---|
US (1) | US20050211631A1 (fr) |
EP (1) | EP1468122B1 (fr) |
JP (1) | JP2005515302A (fr) |
KR (1) | KR20040079948A (fr) |
CN (1) | CN1639360A (fr) |
AT (1) | ATE401427T1 (fr) |
DE (2) | DE60322179D1 (fr) |
ES (1) | ES2238203T1 (fr) |
FR (1) | FR2834980B1 (fr) |
PT (1) | PT1468122E (fr) |
TR (1) | TR200500468T3 (fr) |
WO (1) | WO2003062478A1 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101360501B1 (ko) * | 2012-08-20 | 2014-02-11 | 재단법인 포항산업과학연구원 | 니켈 습식 제련 공정 부산물로부터의 유가물 회수 설비 |
CN103695649A (zh) * | 2013-12-13 | 2014-04-02 | 来宾华锡冶炼有限公司 | 一种处理高浓度含氯废水的方法 |
US10099947B2 (en) | 2015-06-19 | 2018-10-16 | Earth Science Laboratories | Water treatment solution with chelating base product |
US10093564B2 (en) * | 2015-06-19 | 2018-10-09 | Earth Science Laboratories | Chelating base product for use in water-based system treatments |
CN108654684B (zh) * | 2017-03-29 | 2020-09-04 | 中国科学院大连化学物理研究所 | 一种b/l酸修饰的有机硅球催化剂及制备和其应用 |
FR3083224B1 (fr) | 2018-06-29 | 2023-01-06 | Centre Nat Rech Scient | Procede de decontamination de metaux lourds dans une solution aqueuse |
CN109929999B (zh) * | 2019-03-28 | 2020-09-22 | 中南大学 | 一种从氯化物混合液中选择性回收铜的方法 |
CN109897967B (zh) * | 2019-04-01 | 2020-04-21 | 中南大学 | 一种从复杂氯化物体系中分离回收锌的方法 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1583920A (fr) * | 1968-06-21 | 1969-12-05 | Le Nickel S.A | Procede de purification de solutions de nickel |
SU368186A1 (ru) * | 1970-09-24 | 1973-01-26 | Ордена Ленина комбинат Североникель имени В. И. Ленина | СПОСОБ ОЧИСТКИ РАСТВОРОВ ОТ ИОНОВ lOAliBirOI БИБЛ;-' |
DE2555813A1 (de) * | 1974-12-14 | 1976-06-16 | Auxiliar Ind Sa Empresa | Verfahren zur ausfaellung von zur elektrolyse geeignetem zinkoxydhydroxyd aus zinkchloridloesungen |
JPS5242420A (en) * | 1975-10-01 | 1977-04-02 | Toho Rayon Co Ltd | Process for recovering zinc of high purity |
JPS5270118A (en) * | 1975-12-04 | 1977-06-10 | Toho Rayon Co Ltd | Production of acrylonitrile polymer fibers |
US4123260A (en) * | 1977-02-25 | 1978-10-31 | Sherritt Gordon Mines Limited | Selective recovery of nickel and cobalt or copper and zinc from solution |
NL8403683A (nl) * | 1984-12-04 | 1986-07-01 | Tno | Werkwijze voor het verwijderen respektievelijk terugwinnen van een reeks zware metalen uit sedimenten c.q. secondaire slibben. |
JPH01194988A (ja) * | 1988-01-27 | 1989-08-04 | Sumitomo Metal Ind Ltd | 金属含有水の処理方法 |
US4883599A (en) * | 1986-10-16 | 1989-11-28 | Erik Lindahl | Method for cleansing metal-containing solutions |
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US2992894A (en) * | 1957-10-01 | 1961-07-18 | Kerr Mc Gee Oil Ind Inc | Process for concentrating copper and zinc values present in aqueous solution |
US3923615A (en) * | 1972-07-17 | 1975-12-02 | Deepsea Ventures Inc | Winning of metal values from ore utilizing recycled acid leaching agent |
DE2501284C3 (de) * | 1975-01-15 | 1980-06-12 | Duisburger Kupferhuette, 4100 Duisburg | Verfahren zur Aufarbeitung von Manganknollen und Gewinnung der in ihnen enthaltenen Wertstoffe |
-
2002
- 2002-01-23 FR FR0200816A patent/FR2834980B1/fr not_active Expired - Fee Related
-
2003
- 2003-01-22 EP EP03715040A patent/EP1468122B1/fr not_active Expired - Lifetime
- 2003-01-22 KR KR10-2004-7011442A patent/KR20040079948A/ko not_active Application Discontinuation
- 2003-01-22 AT AT03715040T patent/ATE401427T1/de not_active IP Right Cessation
- 2003-01-22 ES ES03715040T patent/ES2238203T1/es active Pending
- 2003-01-22 WO PCT/FR2003/000212 patent/WO2003062478A1/fr active IP Right Grant
- 2003-01-22 DE DE60322179T patent/DE60322179D1/de not_active Expired - Lifetime
- 2003-01-22 JP JP2003562344A patent/JP2005515302A/ja active Pending
- 2003-01-22 CN CNA038044889A patent/CN1639360A/zh active Pending
- 2003-01-22 DE DE03715040T patent/DE03715040T1/de active Pending
- 2003-01-22 US US10/502,497 patent/US20050211631A1/en not_active Abandoned
- 2003-01-22 TR TR2005/00468T patent/TR200500468T3/xx unknown
- 2003-01-22 PT PT03715040T patent/PT1468122E/pt unknown
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FR1583920A (fr) * | 1968-06-21 | 1969-12-05 | Le Nickel S.A | Procede de purification de solutions de nickel |
SU368186A1 (ru) * | 1970-09-24 | 1973-01-26 | Ордена Ленина комбинат Североникель имени В. И. Ленина | СПОСОБ ОЧИСТКИ РАСТВОРОВ ОТ ИОНОВ lOAliBirOI БИБЛ;-' |
DE2555813A1 (de) * | 1974-12-14 | 1976-06-16 | Auxiliar Ind Sa Empresa | Verfahren zur ausfaellung von zur elektrolyse geeignetem zinkoxydhydroxyd aus zinkchloridloesungen |
JPS5242420A (en) * | 1975-10-01 | 1977-04-02 | Toho Rayon Co Ltd | Process for recovering zinc of high purity |
JPS5270118A (en) * | 1975-12-04 | 1977-06-10 | Toho Rayon Co Ltd | Production of acrylonitrile polymer fibers |
US4123260A (en) * | 1977-02-25 | 1978-10-31 | Sherritt Gordon Mines Limited | Selective recovery of nickel and cobalt or copper and zinc from solution |
NL8403683A (nl) * | 1984-12-04 | 1986-07-01 | Tno | Werkwijze voor het verwijderen respektievelijk terugwinnen van een reeks zware metalen uit sedimenten c.q. secondaire slibben. |
US4883599A (en) * | 1986-10-16 | 1989-11-28 | Erik Lindahl | Method for cleansing metal-containing solutions |
JPH01194988A (ja) * | 1988-01-27 | 1989-08-04 | Sumitomo Metal Ind Ltd | 金属含有水の処理方法 |
Non-Patent Citations (5)
Title |
---|
DATABASE WPI Section Ch Derwent World Patents Index; Class E36, AN 1973-60927U, XP002215790 * |
DATABASE WPI Section Ch Week 197720, Derwent World Patents Index; Class M25, AN 1977-35053Y, XP002215789 * |
DATABASE WPI Section Ch Week 197730, Derwent World Patents Index; Class A14, AN 1977-52944Y, XP002215792 * |
DATABASE WPI Section Ch Week 198631, Derwent World Patents Index; Class D15, AN 1986-202748, XP002215791 * |
PATENT ABSTRACTS OF JAPAN vol. 013, no. 491 (C - 650) 7 November 1989 (1989-11-07) * |
Also Published As
Publication number | Publication date |
---|---|
EP1468122B1 (fr) | 2008-07-16 |
DE60322179D1 (de) | 2008-08-28 |
US20050211631A1 (en) | 2005-09-29 |
EP1468122A1 (fr) | 2004-10-20 |
DE03715040T1 (de) | 2005-06-23 |
JP2005515302A (ja) | 2005-05-26 |
ES2238203T1 (es) | 2005-09-01 |
CN1639360A (zh) | 2005-07-13 |
PT1468122E (pt) | 2008-08-04 |
TR200500468T3 (tr) | 2005-03-21 |
KR20040079948A (ko) | 2004-09-16 |
FR2834980A1 (fr) | 2003-07-25 |
ATE401427T1 (de) | 2008-08-15 |
FR2834980B1 (fr) | 2005-01-14 |
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