WO2003059073A1 - Procede destine a empecher les calmars ou les poulpes de devenir bruns ou noirs - Google Patents
Procede destine a empecher les calmars ou les poulpes de devenir bruns ou noirs Download PDFInfo
- Publication number
- WO2003059073A1 WO2003059073A1 PCT/JP2002/000192 JP0200192W WO03059073A1 WO 2003059073 A1 WO2003059073 A1 WO 2003059073A1 JP 0200192 W JP0200192 W JP 0200192W WO 03059073 A1 WO03059073 A1 WO 03059073A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- squid
- aqueous solution
- carbonate
- alkaline
- evening
- Prior art date
Links
- 241000238366 Cephalopoda Species 0.000 title claims abstract description 106
- 238000000034 method Methods 0.000 title claims abstract description 20
- 241000238413 Octopus Species 0.000 title abstract description 10
- 238000005406 washing Methods 0.000 claims abstract description 10
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 5
- 239000007864 aqueous solution Substances 0.000 claims description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 150000001720 carbohydrates Chemical class 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 4
- 239000001099 ammonium carbonate Substances 0.000 claims description 4
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
- 239000001095 magnesium carbonate Substances 0.000 claims description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 4
- 235000011181 potassium carbonates Nutrition 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 239000011736 potassium bicarbonate Substances 0.000 claims description 3
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 3
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 3
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 3
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- 239000012670 alkaline solution Substances 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229920002472 Starch Polymers 0.000 claims 2
- 239000008107 starch Substances 0.000 claims 2
- 235000019698 starch Nutrition 0.000 claims 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 239000007857 degradation product Substances 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000003513 alkali Substances 0.000 abstract description 11
- 230000008859 change Effects 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 8
- 241000209094 Oryza Species 0.000 description 7
- 235000007164 Oryza sativa Nutrition 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000006386 neutralization reaction Methods 0.000 description 7
- 235000009566 rice Nutrition 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 241000219109 Citrullus Species 0.000 description 6
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000003929 acidic solution Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 235000012255 calcium oxide Nutrition 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 235000019645 odor Nutrition 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000555825 Clupeidae Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 241001178520 Stomatepia mongo Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 235000019688 fish Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B4/00—General methods for preserving meat, sausages, fish or fish products
- A23B4/02—Preserving by means of inorganic salts
- A23B4/027—Preserving by means of inorganic salts by inorganic salts other than kitchen salt, or mixtures thereof with organic compounds, e.g. biochemical compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B4/00—General methods for preserving meat, sausages, fish or fish products
- A23B4/14—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
- A23B4/18—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
- A23B4/24—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Definitions
- the present invention relates to a method for preventing browning or blackening of raw rice or yellow rice, or to a method for preparing squid or yellow rice in which such browning or blackening is prevented.
- the present invention relates to a method for preparing a strength or a rice cake with improved storage stability and a method for preparing a strength or a rice grain with improved storage stability.
- the squid or evening squid captured at a fishing ground is then sold to a supermarket or a fish shop, etc.
- it is usually sterilized with sodium hypochlorite or treated with a chemical such as phosphate to improve water retention, and then wholesaled to restaurants and the like.
- the squid has a transparent color in the living state, causing a change in color for a protective color.
- the squid changes color from transparent to white and, over time, changes color from white to gray.
- the white part of the body surface on the side that is not visible and the cross section of the body part such as the amputated leg change to gray over time after death.
- This change in color is associated with a change or alteration in the material, producing an unpleasant odor from the body surface in response to a change in color from white to gray. This is thought to be caused by the degradation of proteins from the body surface by the bacteria attached to the surface of the captured squid or squid.
- these squids or evening squids need to be retailed or wholesaled as fresh as possible to maintain their freshness.
- an object of the present invention is to provide a squid or a squid having a fresh color at or near the time of capture, which effectively prevents browning or blackening. It is also an object of the present invention to prevent deterioration and to provide squid or squid with excellent storage stability.
- the present inventor has conducted intensive studies to solve the above-mentioned problems, and as a result, treating raw squid or squid with an alkaline aqueous solution, and then washing or neutralizing the alkaline aqueous solution, Have been found to be able to be effectively achieved, and have reached the present invention.
- squids such as hinika, mizuika, squid, kensekii power, koi squid, hoyu iri power, dos watermelon, daio squid, surumei power, sodii power, mongo squid and the like are preferably used.
- Various kinds of evening balls can be used without particular limitation.
- octopus, octopus, octopus, octopus and the like are preferably mentioned.
- the squid or squid to which the present invention is applied may be alive or dead. Especially when applied to dead squid or squid, it is very effective. If it is alive, it is unlikely that discoloration will occur, but if it is highly likely that it will die during transportation, it is appropriate to perform the above processing while alive. However, squid or squid may die during this process, but since the above process is performed, there is little problem with subsequent discoloration.
- the force or evening water applied to the present invention may be one obtained by freezing or thawing once frozen or chilled immediately after capture on a ship or the like. However, it is most preferable to apply immediately to those caught on board.
- squid or squid is first treated in an alkaline aqueous solution.
- This treatment can be performed, for example, by immersing in an alkaline aqueous solution or by spraying an alkaline aqueous solution.
- alkaline aqueous solution to be used for example, a solution in which an alkaline agent is dissolved in water can be used.
- an alkali agent various alkali agents can be used as long as they can impart alkalinity to the aqueous solution.
- examples of such an alkali agent include sodium hydroxide, potassium hydroxide, calcium hydroxide, disodium hydrogen phosphate, trisodium phosphate, dipotassium hydrogen phosphate, tripotassium phosphate, diammonium hydrogen phosphate, and sodium polyphosphate.
- the aqueous solution of sodium hydroxide, sodium hydroxide is an aqueous solution of an alkaline agent selected from the group consisting of calcium, calcium oxide, magnesium carbonate, ammonium carbonate, sodium carbonate, potassium carbonate, calcium carbonate, sodium bicarbonate and lithium bicarbonate.
- the squid or the squid may be frozen or frozen with the solution immersed in the solution.
- the subsequent washing or neutralization can be carried out by immersing in water or an acidic solution when thawing at a factory or the like after freezing or freezing and transporting.
- the pH of the alkaline aqueous solution may be greater than 7.0.
- a higher pH value is preferable.
- the pH value is usually 7.5 to 13.0, preferably 8.5 to 13.0, particularly preferably 9.5 to 12.0.
- the treatment time with the alkaline aqueous solution usually varies depending on the treatment temperature.
- the processing time is usually 1 minute to 24 hours, preferably 15 minutes to 1 hour.
- the processing temperature is usually 0 to 10 ° C, preferably 0 to 5 ° C. If the treatment temperature is lower than 0 ° C, the squid or squid is less likely to be contaminated by various bacteria, but the treatment time is longer. On the other hand, if the treatment temperature exceeds 10 ° C, the change or deterioration of the protein is accelerated, and there is a problem that the body is easily lost.
- saccharides or salts may be added to the alkaline aqueous solution in order to improve the permeability of the alkaline aqueous solution into the material.
- saccharide various saccharides can be used, and examples thereof include pudose sugar, reduced maltose, sorbitol, and sucrose.
- the washing time varies depending on the alkali treatment time, but is usually 1 minute to 24 hours, preferably 30 minutes to 3 hours. Washing can be performed with tap water or with salt water, for example, 1 to 6%, preferably 1 to 4%. In the latter case, the squid or squid to be treated is firm and preferable, and is also effective as a pretreatment for boiling.
- the neutralization treatment can be performed, for example, by spraying an acidic solution onto the alkali-treated material or by immersing it in an acidic solution.
- an aqueous solution of an inorganic acid such as hydrochloric acid, sulfuric acid, or nitric acid, or an organic acid such as acetic acid, sulfonic acid, or citric acid can be used.
- Preferred acids are, for example, acetic acid, citric acid and the like.
- the pH is usually between 4.0 and 6.6, preferably between 5.0 and 6.5.
- the pH of the acidic solution for immersion is, for example, 4.0 to 6.8, and preferably 5.5 to 6.5.
- Neutralization may be carried out acidic in salt water.
- the salt water concentration is, for example, 1 to 10% by mass, and preferably 3 to 8% by mass.
- the neutralization temperature is preferably, for example, in the range of about 5 to 15 ° C.
- the neutralization time can fluctuate depending on the alkali treatment time, but is usually from 10 minutes to 2 hours, preferably from 30 minutes to 1 hour. It may be weakly acidic, as measured by the force after neutralization or the pH of the water on the body surface of the rice.
- the squid or the squid that has been washed or neutralized in this way can then be packaged, and can be frozen or chilled in the packaged state.
- the squid or squid that has been washed or neutralized may be further boiled in salt water or the like.
- squid or evening squid is treated with an aqueous alkali solution, and then washed or neutralized, so that the squid or the squid can be browned or preserved even when stored for a long time in a frozen or chilled state. Blackening can be effectively prevented, and a squid or evening product having a color close to that at the time of fresh capture can be prepared.
- the above processing The boiled squid or the squid can retain the color after the treatment for a long period of time without causing browning or darkening even if boiled or dried in the sun.
- the squid or evening squid treated in this way has very little alteration, so that even when stored for a long period of time, the generation of offensive odors is reduced.
- the bacteria attached to the squid or the squid can be substantially killed. Therefore, the squid or the squid treated according to the present invention does not substantially lose its body during storage, or the time required for the squid or the squid to be treated is greatly extended. Even if the squid or squid can be easily transported to a distant place, and the treated squid or evening squid can be stored for a longer period of time, the yield is greatly improved and It will be possible to eat fresh food or dinner in a fresh form.
- Raw watermelon (from Sanin Senzaki) (body color: transparent) was purchased at a supermarket and immediately immersed in the above alkaline aqueous solution at about 5 ° C for 1 hour with appropriate stirring. Next, take out the immersed watermelon, wash it once with running water, and then It was immersed in water at about 5 ° C for 30 minutes and washed with water. The water-washed watermelon is then drained, put in a polypropylene bag, evacuated, closed the opening, refrigerated at 5 to 10 ° C (Case A 1), and 26 to At room temperature at 33 ° C (case B 1), changes in body color and degree of deterioration were observed.
- a comparative watermelon product was prepared and placed in a polypropylene bag in the same manner as in Example 1 except that the above-mentioned aqueous solution treatment and the washing or neutralization treatment were not performed, and the product was evacuated. After that, close the opening and perform refrigerated storage at 5 to 10 ° C (Case AC1) and normal temperature storage at 26 to 33 ° C (Case BC1). Similarly, the degree of color change and deterioration was observed.
- Case BC 1 the color of the storage was slightly yellowish at the beginning of storage, and as the storage period elapsed, yellow gradually turned gray and its size began to expand. In the first year, the whole became gray. In addition, fine bubbles are generated from the beginning of storage, the size of the bubbles increases with time, the amount of gas gradually increases, and on the 5th day, the gas in the bag is about twice the thickness of the squid. On the ninth day, the amount of gas became 3 to 4 times the thickness of the squid. Furthermore, in this case, after the fifth day, the squid It broke out and grew, and when I pressed it with my finger, I collapsed.
- Example 1 was repeated except that raw Kensakii power (from Hakodate) (the body color was transparent) was used.
- a comparative Kensaki force was prepared by treating in the same manner as in Example 2 except that the alkali treatment and the water washing treatment were not performed.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Meat, Egg Or Seafood Products (AREA)
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2002219618A AU2002219618A1 (en) | 2002-01-15 | 2002-01-15 | Method for preventing squid or octopus from becoming brown or black |
CN02826915.2A CN1279830C (zh) | 2002-01-15 | 2002-01-15 | 防止乌贼或章鱼褐变或者黑化的方法 |
PCT/JP2002/000192 WO2003059073A1 (fr) | 2002-01-15 | 2002-01-15 | Procede destine a empecher les calmars ou les poulpes de devenir bruns ou noirs |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2002/000192 WO2003059073A1 (fr) | 2002-01-15 | 2002-01-15 | Procede destine a empecher les calmars ou les poulpes de devenir bruns ou noirs |
Publications (1)
Publication Number | Publication Date |
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WO2003059073A1 true WO2003059073A1 (fr) | 2003-07-24 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2002/000192 WO2003059073A1 (fr) | 2002-01-15 | 2002-01-15 | Procede destine a empecher les calmars ou les poulpes de devenir bruns ou noirs |
Country Status (3)
Country | Link |
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CN (1) | CN1279830C (fr) |
AU (1) | AU2002219618A1 (fr) |
WO (1) | WO2003059073A1 (fr) |
Families Citing this family (1)
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CN114982818A (zh) * | 2022-03-28 | 2022-09-02 | 广西农业职业技术大学 | 一种香蕉果肉褐变抑制方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH067075A (ja) * | 1992-06-27 | 1994-01-18 | Soushiyou:Kk | 甲殻類その他魚介類の発色方法 |
JP2000106849A (ja) * | 1998-10-06 | 2000-04-18 | Ueda Oils & Fats Mfg Co Ltd | 貝類の乾燥前の処理方法 |
JP2000287617A (ja) * | 1999-04-30 | 2000-10-17 | Japan Techno:Kk | 魚の褐変若しくは黒化防止方法 |
-
2002
- 2002-01-15 CN CN02826915.2A patent/CN1279830C/zh not_active Expired - Fee Related
- 2002-01-15 WO PCT/JP2002/000192 patent/WO2003059073A1/fr active Application Filing
- 2002-01-15 AU AU2002219618A patent/AU2002219618A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH067075A (ja) * | 1992-06-27 | 1994-01-18 | Soushiyou:Kk | 甲殻類その他魚介類の発色方法 |
JP2000106849A (ja) * | 1998-10-06 | 2000-04-18 | Ueda Oils & Fats Mfg Co Ltd | 貝類の乾燥前の処理方法 |
JP2000287617A (ja) * | 1999-04-30 | 2000-10-17 | Japan Techno:Kk | 魚の褐変若しくは黒化防止方法 |
Also Published As
Publication number | Publication date |
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CN1612692A (zh) | 2005-05-04 |
CN1279830C (zh) | 2006-10-18 |
AU2002219618A1 (en) | 2003-07-30 |
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