WO2002012419A1 - Lubrifiant aqueux pour le travail au plastique d'un materiau metallique et procede d'elaboration d'un film lubrifiant - Google Patents

Lubrifiant aqueux pour le travail au plastique d'un materiau metallique et procede d'elaboration d'un film lubrifiant Download PDF

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Publication number
WO2002012419A1
WO2002012419A1 PCT/JP2001/003639 JP0103639W WO0212419A1 WO 2002012419 A1 WO2002012419 A1 WO 2002012419A1 JP 0103639 W JP0103639 W JP 0103639W WO 0212419 A1 WO0212419 A1 WO 0212419A1
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WO
WIPO (PCT)
Prior art keywords
lubricant
water
wax
metal material
plastic working
Prior art date
Application number
PCT/JP2001/003639
Other languages
English (en)
Japanese (ja)
Inventor
Yasuo Imai
Shuji Nagata
Masayuki Yoshida
Original Assignee
Nihon Parkerizing Co., Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Parkerizing Co., Ltd filed Critical Nihon Parkerizing Co., Ltd
Priority to JP2002517710A priority Critical patent/JP3984158B2/ja
Priority to CA2418942A priority patent/CA2418942C/fr
Priority to MXPA03000789A priority patent/MXPA03000789A/es
Priority to EP01925970.4A priority patent/EP1319702B1/fr
Priority to KR1020037001682A priority patent/KR100621693B1/ko
Publication of WO2002012419A1 publication Critical patent/WO2002012419A1/fr
Priority to US10/360,482 priority patent/US20030130137A1/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00—Cooling, heating or lubricating drawing material
    • B21C9/005—Cold application of the lubricant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C9/00—Cooling, heating or lubricating drawing material
    • B21C9/02—Selection of compositions therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J3/00—Lubricating during forging or pressing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/02—Carbon; Graphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/10—Metal oxides, hydroxides, carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/22—Compounds containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02—Natural products
    • C10M159/06—Waxes, e.g. ozocerite, ceresine, petrolatum, slack-wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/0413—Carbon; Graphite; Carbon black used as base material
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    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C10M2201/0663—Molybdenum sulfide used as base material
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
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    • C10M2201/0803—Inorganic acids or salts thereof used as base material
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    • C10M2201/081—Inorganic acids or salts thereof containing halogen
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    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
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    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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    • C10M2201/087—Boron oxides, acids or salts
    • C10M2201/0873—Boron oxides, acids or salts used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C—CHEMISTRY; METALLURGY
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    • C10M2201/102—Silicates
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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    • C10M2201/1023—Silicates used as base material
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
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    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)

Abstract

L'invention concerne un lubrifiant aqueux qui est utilisé dans le travail au plastique d'un matériau métallique et qui contient (A) un sel inorganique soluble dans l'eau, (B) un agent lubrifiant sélectionné parmi un bisulfure de molybdène et un graphite, et (C) une cire, les composés étant dissous ou dispersés dans l'eau, et un rapport de concentration solide (rapport pondéral) (B)/(A) étant compris entre 0,3 et 1,5 et (C)/(A) entre 0,1 et 1,0. Ladite invention concerne aussi un procédé de traitement d'un matériau métallique au moyen d'un film lubrifiant, caractérisé en ce qu'on forme un film lubrifiant en appliquant ledit lubrifiant aqueux, de préférence doté d'un poids sec compris entre 0,5 et 40g/m2, sur un matériau métallique clarifié, puis on le sèche. Le sel inorganique soluble dans l'eau (A) est, de préférence, sélectionné parmi un sulfate, un silicate, un borate, un molybdate et un tungstate. La cire (C) est, de préférence, une cire naturelle ou une cire synthétique dispersée dans l'eau et dont le point de fusion est compris entre 70 et 150°. On peut utiliser le lubrifiant aqueux pour facilement donner à la surface d'un métal ne possédant pas de film chimique, un excellent aspect lubrifié.
PCT/JP2001/003639 2000-08-07 2001-04-26 Lubrifiant aqueux pour le travail au plastique d'un materiau metallique et procede d'elaboration d'un film lubrifiant WO2002012419A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2002517710A JP3984158B2 (ja) 2000-08-07 2001-04-26 金属材料塑性加工用水系潤滑剤および潤滑皮膜の処理方法
CA2418942A CA2418942C (fr) 2000-08-07 2001-04-26 Lubrifiant aqueux utilise pour le travail au plastique de materiau metallique et methode de traitement d'un film lubrifiant
MXPA03000789A MXPA03000789A (es) 2000-08-07 2001-04-26 Lubricante acuoso usado para el trabajo plastico de material metalico, y metodo para el proceso de una pelicula lubricativa.
EP01925970.4A EP1319702B1 (fr) 2000-08-07 2001-04-26 Lubrifiant aqueux pour le travail plastique d'un materiau metallique et procede d'elaboration d'un film lubrifiant
KR1020037001682A KR100621693B1 (ko) 2000-08-07 2001-04-26 금속 재료의 소성 가공용 수성 윤활제 및 윤활피막의 처리방법
US10/360,482 US20030130137A1 (en) 2000-08-07 2003-02-07 Aqueous lubricant for plactic working of metallic material and method of lubricant film processing

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WO2013129268A1 (fr) * 2012-02-27 2013-09-06 株式会社神戸製鋼所 Agent lubrifiant soluble dans l'eau pour le travail des plastiques, matériau métallique destiné au travail des plastiques et article en métal travaillé
KR20180044997A (ko) 2015-09-30 2018-05-03 가부시키가이샤 고베 세이코쇼 내식성 및 가공 후의 외관이 우수한 강선재

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Publication number Priority date Publication date Assignee Title
WO2012133455A1 (fr) 2011-03-28 2012-10-04 日本パーカライジング株式会社 Agent de revêtement lubrifiant pour usinage plastique et son procédé de production
US9487732B2 (en) 2011-03-28 2016-11-08 Henkel Ag & Co. Kgaa Lubricating coating agent for plastic working and method for producing the same
WO2013129268A1 (fr) * 2012-02-27 2013-09-06 株式会社神戸製鋼所 Agent lubrifiant soluble dans l'eau pour le travail des plastiques, matériau métallique destiné au travail des plastiques et article en métal travaillé
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KR20180044997A (ko) 2015-09-30 2018-05-03 가부시키가이샤 고베 세이코쇼 내식성 및 가공 후의 외관이 우수한 강선재

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EP1319702A1 (fr) 2003-06-18
CA2418942A1 (fr) 2003-02-07
EP1319702B1 (fr) 2016-11-09
CN1468294A (zh) 2004-01-14
MXPA03000789A (es) 2004-11-01
CN1214095C (zh) 2005-08-10
JP3984158B2 (ja) 2007-10-03
KR20030027002A (ko) 2003-04-03
CA2418942C (fr) 2010-09-14
US20030130137A1 (en) 2003-07-10
KR100621693B1 (ko) 2006-09-08
EP1319702A4 (fr) 2004-08-11

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