WO2001013679A1 - Dispositif de chauffage en ceramique - Google Patents
Dispositif de chauffage en ceramique Download PDFInfo
- Publication number
- WO2001013679A1 WO2001013679A1 PCT/JP2000/005322 JP0005322W WO0113679A1 WO 2001013679 A1 WO2001013679 A1 WO 2001013679A1 JP 0005322 W JP0005322 W JP 0005322W WO 0113679 A1 WO0113679 A1 WO 0113679A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heating element
- resistance heating
- ceramic
- heater
- pattern
- Prior art date
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 123
- 238000010438 heat treatment Methods 0.000 claims abstract description 181
- 239000000758 substrate Substances 0.000 claims abstract description 31
- 150000004767 nitrides Chemical class 0.000 claims abstract description 26
- 230000002093 peripheral effect Effects 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 9
- 229910052575 non-oxide ceramic Inorganic materials 0.000 claims description 8
- 239000011225 non-oxide ceramic Substances 0.000 claims description 8
- 239000004065 semiconductor Substances 0.000 abstract description 24
- 235000012431 wafers Nutrition 0.000 description 36
- 239000004020 conductor Substances 0.000 description 35
- 229910052751 metal Inorganic materials 0.000 description 28
- 239000002184 metal Substances 0.000 description 28
- 239000002923 metal particle Substances 0.000 description 24
- 239000010410 layer Substances 0.000 description 21
- 239000002245 particle Substances 0.000 description 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 238000007639 printing Methods 0.000 description 13
- 239000000843 powder Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000011247 coating layer Substances 0.000 description 10
- 229910000679 solder Inorganic materials 0.000 description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 9
- 229910052709 silver Inorganic materials 0.000 description 9
- 239000004332 silver Substances 0.000 description 9
- 238000005245 sintering Methods 0.000 description 9
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 8
- 238000010304 firing Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- 239000011224 oxide ceramic Substances 0.000 description 8
- 229910052574 oxide ceramic Inorganic materials 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 238000009826 distribution Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 238000007650 screen-printing Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 229920005822 acrylic binder Polymers 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- LWUVWAREOOAHDW-UHFFFAOYSA-N lead silver Chemical compound [Ag].[Pb] LWUVWAREOOAHDW-UHFFFAOYSA-N 0.000 description 6
- 229910010271 silicon carbide Inorganic materials 0.000 description 6
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000005219 brazing Methods 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 229910052810 boron oxide Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 229910000833 kovar Inorganic materials 0.000 description 3
- 229910000464 lead oxide Inorganic materials 0.000 description 3
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 3
- 230000003252 repetitive effect Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007606 doctor blade method Methods 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229920006015 heat resistant resin Polymers 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 229910026551 ZrC Inorganic materials 0.000 description 1
- OTCHGXYCWNXDOA-UHFFFAOYSA-N [C].[Zr] Chemical compound [C].[Zr] OTCHGXYCWNXDOA-UHFFFAOYSA-N 0.000 description 1
- KZVBXDYTYQEHEW-UHFFFAOYSA-N [Pb].[Pb].[Ag] Chemical compound [Pb].[Pb].[Ag] KZVBXDYTYQEHEW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- JWVAUCBYEDDGAD-UHFFFAOYSA-N bismuth tin Chemical compound [Sn].[Bi] JWVAUCBYEDDGAD-UHFFFAOYSA-N 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- -1 for example Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/18—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being embedded in an insulating material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67098—Apparatus for thermal treatment
- H01L21/67103—Apparatus for thermal treatment mainly by conduction
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/141—Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds
- H05B3/143—Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds applied to semiconductors, e.g. wafers heating
Definitions
- the present invention relates to ceramic heaters used in the semiconductor industry. Background art
- Semiconductor products are manufactured through processes such as forming a photosensitive resin as an etching resist on a semiconductor wafer and etching the semiconductor wafer.
- This photosensitive resin is liquid and is applied to the surface of the semiconductor wafer using a spin coater or the like.After application, the resin must be dried to disperse the solvent, etc., and the applied semiconductor wafer is placed on a heater. It will be placed and heated.
- the thickness of the heater plate since it is made of metal, the thickness of the heater plate must be as thick as about 15 mm. This is because, in a thin metal plate, warpage, distortion, and the like are generated due to thermal expansion caused by heating, and the semiconductor wafer placed on the metal plate is damaged or tilted. However, when the thickness of the heater plate is increased, there is a problem that the weight of the heater increases and the heater becomes bulky.
- the heating temperature is controlled by changing the voltage or current applied to the resistance heating element.However, the thickness of the metal plate causes the temperature of the heater plate to quickly change with changes in voltage or current. There was also a problem that it was difficult to control the temperature without following.
- non-oxidized substrates having high thermal conductivity and high strength are used.
- a ceramic heater using aluminum nitride which is a material ceramic and having a resistance heating element formed on the surface or inside of the aluminum nitride substrate.
- FIG. 5 is a bottom view schematically showing a conventional ceramic heater.
- the resistance heating element 32 is provided on the bottom surface of the heater plate 31. As shown in FIG. 5, it is formed in a concentric pattern.
- Reference numeral 33 denotes an external terminal for connection to a power supply or the like connected to the end of the resistance heating element 32, and a surface for heating the semiconductor wafer (hereinafter, referred to as a wafer heating surface) is a resistance heating element 3 This is the side opposite to the side where 2 is provided. In some cases, the resistance heating element 32 may be formed in a spiral shape.
- the resistance heating element is formed in the same pattern and the same power is applied, it is considered that the temperature of the object to be heated becomes uneven.
- the present inventor has found that the temperature of the heater plate can be made uniform by making the heat transfer direction not only the diameter direction of the heater plate but also random.
- the resistance heating element is formed by printing, in a concentric circle or a spiral pattern, a part where the printing direction and the formation direction of the resistance heating element are substantially perpendicular and a part which is parallel are generated, and a part perpendicular to the printing direction is formed. It has been found that the unevenness of the thickness occurs in the parallel portion, the resistance value changes due to the unevenness, and the unevenness of the temperature also causes the above problem. For example, in the resistance heating element 42 shown in FIG.
- the thickness of the resistance heating element is large, while the printing direction and the resistance heating In the pattern of the region B in which the body formation direction is nearly parallel, the thickness of the resistance heating body tends to be thin.
- the resistance value is low in the region A and high in the region B.
- a resistance heating element is formed by combining a concentric or spiral pattern and a repetitive pattern of bent lines. Specifically, the inside of the disk-shaped ceramic substrate (the central portion) is formed. ), A resistive heating element having a concentric pattern or the like is formed as in the past, and a bent line-shaped resistance heating element different from the concentric shape is formed on the outer peripheral portion, thereby transferring heat.
- the present inventors have found that semiconductor wafers and the like can be uniformly heated as a whole by randomly arranging the directions, and have completed the present invention.
- the ceramic heater of the present invention is a ceramic heater in which a resistance heating element is provided on the surface or inside of a disk-shaped ceramic substrate.
- the above-mentioned resistance heating element is characterized in that it is formed by mixing a concentric or spiral pattern and a resistance heating element having a pattern of bent lines or a pattern of repeated bent lines.
- a resistance heating element having a repetitive pattern of bent lines is formed on at least the outer peripheral portion of the disk-shaped ceramic substrate.
- FIG. 1 is a bottom view schematically showing one example of the ceramic heater of the present invention.
- FIG. 2 is a partially enlarged sectional view schematically showing a part of the ceramic heater shown in FIG.
- FIG. 3 is a partially enlarged cross-sectional view schematically showing a part of a ceramic heater according to the present invention in which a resistance heating element is formed inside a heater plate.
- FIG. 4 is a bottom view schematically showing another example of the resistance heating element pattern in the ceramic heater of the present invention.
- FIG. 5 is a bottom view schematically showing a conventional ceramic heater.
- FIG. 6 is a schematic diagram showing a state of heat conduction of a conventional ceramic heater.
- FIG. 7 is an explanatory diagram showing a state in which a pattern of a spiral resistance heating element is printed.
- FIG. 8 is an explanatory diagram showing a state in which a pattern of a bent resistance heating element is printed.
- FIG. 9 is a bottom view showing a pattern of a resistance heating element in which a partially bent pattern and a spiral pattern are mixed. Explanation of reference numerals
- the ceramic heater according to the present invention is a ceramic heater in which a resistance heating element is provided on the surface or inside of a disk-shaped ceramic substrate,
- the above-mentioned resistance heating element is characterized in that it is formed by mixing a concentric or spiral pattern and a resistance heating element having a pattern of bent lines or a pattern of repeated bent lines.
- the resistance heating element has a concentric shape or a vortex shape. Since a wound pattern and a resistive heating element composed of a bent line pattern or a repeating pattern of a bent line are formed in a hybrid manner, the concentric or spiral resistive heating element is formed over the entire ceramic substrate. As compared with the case where the surface is formed, a decrease in the temperature of the outer peripheral portion can be suppressed, and the temperature of the entire wafer heating surface becomes uniform, so that the semiconductor wafer and the like can be uniformly heated.
- FIG. 8 is a plan view schematically showing the resistance heating element 52 composed of a repeating pattern of a bent line.
- a bent portion is formed in the pattern composed of such a bent line or the repeated pattern of a bent line.
- a portion C where the printing direction is substantially perpendicular to the direction in which the resistance heating element is formed and a portion D where the direction is parallel are generated, so that the amount of generated heat is uniform as a whole. For this reason, the temperature variation generated due to the variation in the resistance value of the resistance heating element 52 can be reduced.
- the ceramic substrate constituting the ceramic heater of the present invention includes a force S composed of a non-oxide ceramic or an oxide ceramic such as a nitride ceramic or a carbide ceramic, and an oxide ceramic as an insulating layer on the surface of the non-oxide ceramic substrate. It can also be formed.
- Nitride ceramics have a tendency to decrease in volume resistance at high temperatures due to oxygen solid solution, etc.
- Carbide ceramics have conductivity unless particularly highly purified, and oxide ceramics should be formed as an insulating layer. Thereby, even at high temperatures or even when impurities are contained, short-circuiting between circuits can be prevented and temperature controllability can be ensured.
- Non-oxide ceramics are also advantageous because they have high thermal conductivity and can be quickly heated and cooled.
- non-oxide ceramics have a high thermal conductivity and are liable to vary in temperature due to the resistance heating element pattern. The effect of temperature equalization is greater than that of, and the configuration of the present invention is particularly advantageous.
- the surface roughness of the surface on the opposite side (bottom surface) of the heating surface of the ceramic substrate may be 0.0:! ⁇ 20 im for 13 ⁇ 4 &, and 0:! ⁇ 200 / im for 1111 &. desirable.
- nitride ceramic constituting the ceramic substrate examples include metal nitride ceramics, for example, aluminum nitride, silicon nitride, boron nitride, titanium nitride and the like.
- carbide ceramic examples include metal carbide ceramics, for example, silicon carbide, zirconium carbide, titanium carbide, tantalum carbide, tungsten carbide, and the like.
- an oxide ceramic may be used as the ceramic substrate, and alumina, silica, cordierite, mullite, zirconia, beryllia, and the like can be used.
- the nitride ceramic, carbide ceramic, and oxide ceramic may be used alone or in combination of two or more.
- nitride ceramics are preferred, and aluminum nitride is most preferred. This is because the thermal conductivity is as high as 18 O W / m ⁇ K.
- non-oxide ceramic substrates such as nitride ceramics and carbide ceramics described above have high thermal conductivity, so that the surface temperature of the heater plate can quickly follow the temperature change of the resistance heating element, and the wafer heating surface The temperature can be controlled well, and the mechanical strength is large, so that the heater plate does not warp and the semiconductor wafer placed thereon can be prevented from being damaged. .
- FIG. 1 is a bottom view schematically showing an example of the ceramic heater of the present invention
- FIG. 2 is a partially enlarged sectional view showing a part thereof.
- a heater plate 11 made of a ceramic substrate made of a nitride ceramic, a carbide ceramic, an oxide ceramic or the like (hereinafter, also referred to as a ceramic substrate made of a nitride or the like) is formed in a disk shape, and has a ceramic substrate (hereinafter referred to as a ceramic substrate).
- a ceramic substrate made of a nitride or the like
- the bottom of the heater plate 1 1a has a concentric pattern of resistance inside the bottom 1a.
- a heating element 12 a is formed.
- a resistance heating element 12 b having a repeating pattern of bent lines is formed on the outer peripheral portion of the heater plate 11.
- the inner resistance heating element 12a is connected to form a pair of double concentric circles close to each other so as to form a single wire, and external terminals 13 serving as input / output terminals are provided at both ends. They are connected via a metal coating layer 17. Further, a through hole 15 for inserting a support pin 16 for supporting the semiconductor wafer 19 is formed in a portion near the center, and a bottomed hole 14 for inserting a temperature measuring element. Are formed.
- the resistance heating element 12 is Although provided at the bottom of the heater plate 11, the resistance heating element 72 may be provided inside the heater plate 11 as shown in FIG.
- the pattern of the resistance heating element 12 is formed in the same manner as when the resistance heating element 12 is provided on the bottom surface.
- the external terminal 73 is connected via a through hole 76 and a brazing material (not shown).
- a through hole 75 is formed in the heater plate 11 so that the lifter pin 16 can be inserted, and a bottomed hole 74 for embedding a temperature measuring element such as a thermocouple is formed. Have been.
- a ceramic such as a nitride is used as a material of the heater plate. This is because the heater plate 11 can be made thin and light because it does not slip.
- the surface temperature of the heater plate 11 quickly follows the temperature change of the resistance heating element. That is, the surface temperature of the heater plate 11 can be satisfactorily controlled by changing the voltage and the current amount to change the temperature of the resistance heating element.
- the thickness of the heater plate 11 of the ceramic heater is preferably 0.5 to 5 mm. If the thickness is less than 0.5 mm, the strength is reduced and the material is easily broken. On the other hand, if the thickness is more than 5 mm, the heat does not easily propagate and the heating efficiency is reduced.
- a concentric resistance heating element 12a is formed inside, but the resistance heating element may be a spiral.
- the resistance heating element 12b having a repeating pattern of the bent lines is formed on the outer peripheral portion.
- the degree of the repeated bending of the bent lines may be large in number per unit length. That is, the resistance heating element 12b shown in FIG. 1 may be bent more frequently.
- the resistance heating element 12b formed of a bent line is formed so that a portion close to a straight line crosses a broken line A drawn on the outer periphery almost vertically.
- a large number of small bending lines such that a portion close to a straight line is substantially parallel to the broken line A may be formed in parallel with the circumferential direction.
- the inside refers to a circular portion extending from the center of the heater plate 11 to 1/3 of the radius, and the other portion is referred to as an outer peripheral portion.
- the resistance heating elements 22 a and 22 formed of an internal spiral pattern and a square or concentric pattern
- resistance heating elements 22 b and 22 d formed of a repeating pattern of bent lines between c.
- a resistance heating element 62 b composed of a repeating pattern of bent lines was sandwiched between resistance heating elements 62 a composed of concentric patterns on the outer peripheral portion of the bottom surface of the heater plate 61.
- a pattern may be formed, and concentric patterns 62c and 62d may be formed inside.
- the resistance heating element 12 formed on the surface or inside of a ceramic substrate such as a nitride is desirably divided into at least two or more circuits as shown in FIG. This is because, by dividing the circuit, the amount of heat generated can be changed by controlling the power supplied to each circuit, and the temperature of the heating surface of the semiconductor wafer can be adjusted.
- a conductive paste containing metal particles is applied to the surface of the heater plate 11 to form a conductor paste layer having a predetermined pattern. Is preferable, and metal particles are sintered on the surface of the heater plate 11. The sintering of the metal is sufficient if the metal particles and the metal particles and the ceramic are fused.
- the thickness of the resistance heating element is preferably 1 to 30 ⁇ , and more preferably 1 to 10 ⁇ .
- its thickness is preferably 1 to 50 x m.
- the width of the resistance heating element is preferably from 0 to 20 mm, and more preferably from 0.1 to 5 mm.
- the width of the resistance heating element is preferably 5 to 20 ⁇ .
- the resistance heating element 12 can change the resistance value depending on its width and thickness. The above range is the most practical. The resistance becomes thinner and thinner, and becomes larger. When the resistance heating element 12 is formed inside the heater plate 11, the thickness, Although the width increases, if the resistance heating element 12 is provided inside, the distance between the heating surface and the resistance heating element 12 is shortened, and the uniformity of the surface temperature is reduced. It is not necessary to expand it, and there is no need to consider the adhesion to ceramics such as nitrides to provide the resistance heating element 12 inside.Therefore, high melting point metals such as tungsten and molybdenum, Such a carbide can be used, and the resistance value can be increased. Therefore, the thickness itself may be increased for the purpose of preventing disconnection or the like. Therefore, it is desirable that the resistance heating element 12 has the above-described thickness and width.
- the resistance heating element 12 may have a rectangular or elliptical cross section, but is preferably flat. This is because the flattened surface tends to radiate heat toward the heated surface of the wafer, making it difficult to achieve a temperature distribution on the heated surface.
- the aspect ratio of the cross section (the width of the resistance heating element and the thickness of the resistance heating element) be 10 to 500.
- the resistance value of the resistance heating element 12 can be increased, and the uniformity of the temperature of the heating surface can be ensured.
- the thickness of the resistance heating element 12 is constant, if the aspect ratio is smaller than the above range, the amount of heat transmission of the heater plate 11 in the wafer heating direction becomes small, and the resistance heating element 12 Heat distribution similar to the pattern occurs on the heating surface. Conversely, if the aspect ratio is too large, the temperature just above the center of the resistance heating element 12 becomes high, resulting in the resistance heating element 1 A heat distribution similar to the pattern 2 occurs on the heated surface. Therefore, considering the temperature distribution, it is preferable that the aspect ratio of the cross section be 10 to 500.
- the aspect ratio is 10 to 20, and when the resistance heating element 12 is formed inside the heater plate 11, It is desirable to set the aspect ratio to 200 to 500.
- the resistance heating element 12 When the resistance heating element 12 is formed inside the heater plate 11, the aspect ratio becomes larger. However, when the resistance heating element 12 is provided inside, the heating surface and the resistance heating This is because the distance from the body 12 becomes shorter and the temperature uniformity of the surface decreases, and the resistance heating body 12 itself needs to be flattened. When the resistance heating element 12 is formed eccentrically inside the heater plate 11, the position should be close to the surface (bottom surface) facing the heating surface of the heater plate 11, It is desirable to set the position at more than 50% and up to 99% of the distance.
- the temperature distribution will be generated because it is too close to the heated surface, and if it is more than 99%, the heater plate 11 will be warped and the semiconductor wafer will be damaged. Because.
- the resistance heating element 12 When the resistance heating element 12 is formed inside the heater plate 11, a plurality of resistance heating element forming layers may be provided.
- the pattern of each layer is such that the resistance heating element 12 is formed in some layer so as to complement each other, and when viewed from above the wafer heating surface, the pattern is formed in any region. desirable.
- a structure for example, there is a structure in which the staggered arrangement is provided.
- resistance heating element 12 may be provided inside the heater plate 11 and the resistance heating element 12 may be partially exposed.
- the conductive paste is not particularly limited, but preferably contains not only metal particles or conductive ceramic for ensuring conductivity, but also a resin, a solvent, a thickener, and the like.
- metal particles for example, noble metals (gold, silver, platinum, palladium), lead, tungsten, molybdenum, nickel and the like are preferable. These may be used alone or in combination of two or more. This is because these metals are relatively hard to oxidize and have sufficient resistance to generate heat.
- the conductive ceramic examples include carbides of tungsten and molybdenum. These may be used alone or in combination of two or more.
- the particle size of these metal particles or conductive ceramic particles is preferably from 0.1 to 100 ⁇ . If it is too fine, less than 0.1 // m, it is liable to be oxidized, while if it exceeds 100 / xm, sintering becomes difficult and the resistance value becomes large.
- the shape of the metal particles may be spherical or scaly. When these metal particles are used, they may be a mixture of the sphere and the flakes. When the metal particles are flakes or a mixture of spheres and flakes, the oxides between the metal particles can be easily retained, and the resistance heating element 12 and ceramics such as nitrides can be used. This is advantageous because it can ensure the adhesion to the metal and the like, and can increase the resistance value.
- Examples of the resin used for the conductor paste include an epoxy resin and a phenol resin.
- Examples of the solvent include isopropyl alcohol.
- Examples of the thickener include cellulose.
- the conductor paste is formed by adding an oxide to metal particles and sintering the metal particles and the oxide to the resistance heating element 12. In this way, by sintering the oxide together with the metal particles, it is possible to bring the ceramic such as a nitride, which is a heater plate, into close contact with the metal particles.
- oxides improves the adhesion with ceramics such as nitrides.However, the surface of metal particles and ceramics such as nitrides, especially the surface of non-oxide ceramics, is slightly oxidized. It is considered that the oxide film is formed by sintering and integrating the oxide films via the oxide, and the metal particles and the ceramic such as the nitride adhere to each other.
- oxide for example, lead oxide, zinc oxide, silica, boron oxide (B 2 0 3), alumina, at least one selected from the group consisting of yttria and titania is preferred.
- the lead oxide, zinc oxide, silica, boron oxide (B 2 0 3), alumina, Itsutori ⁇ the proportion of titania, when the 1 0 0 parts by weight of the total amount of the oxide, by weight, is oxidation of lead 1-10, silica 1-30, boron oxide 5-5, zinc oxide 20-70, alumina 1-10, yttria 1-50, titania :! It is desirable that the total amount be adjusted so as not to exceed 100 parts by weight. By adjusting the amounts of these oxides in these ranges, the adhesion to ceramics such as nitrides can be particularly improved.
- the amount of the oxide added to the metal particles is preferably 0.1% by weight or more and less than 10% by weight.
- the area resistivity when the resistance heating element 12 is formed using the conductor paste having such a configuration is preferably 1 to 45 ⁇ / port. If the sheet resistivity exceeds the 45 m QZ port, the amount of heat generated is too large for the applied voltage, and the amount of heat generated in the heater plate 11 with the resistance heating element 12 provided on the surface of the heater plate Is difficult to control. If the amount of the oxide is more than 10% by weight, the sheet resistivity exceeds 5 5 ⁇ / port, and the calorific value becomes too large, so that the temperature control becomes difficult, and the uniformity of the temperature distribution becomes uniform. Decrease.
- the resistance heating element 12 When the resistance heating element 12 is formed on the surface of the heater plate 11, it is desirable that a metal coating layer 17 be formed on the surface of the resistance heating element 12. This is to prevent the internal metal sintered body from being oxidized to change the resistance value.
- the thickness of the metal coating layer 17 to be formed is preferably from 0.1 to: ⁇ .
- the metal used for forming the metal coating layer 17 is not particularly limited as long as it is a non-oxidizing metal, and specific examples include gold, silver, palladium, platinum, nickel, and the like. . These may be used alone or in combination of two or more. Of these, nickel is preferred.
- the resistance heating element 12 needs a terminal to connect to the power supply, and this terminal is attached to the resistance heating element 12 via solder, but nickel prevents heat diffusion of the solder.
- Examples of the connection terminal include an external terminal 13 made of Kovar.
- the surface is not oxidized, so that the coating is unnecessary.
- a part of the resistance heating element may be exposed on the surface, and a through hole for connecting the resistance heating element 12 is provided in the terminal part. External terminals may be connected and fixed to the through holes.
- alloys such as silver-lead, tin-lead, and bismuth-tin can be used as the solder.
- the thickness of the solder layer is preferably 0.1 to 50 ⁇ . This is because the range is sufficient to secure connection by soldering.
- a through hole 15 is provided in the heater plate 11, and a lifter pin 16 is inserted into the through hole 15, so that the semiconductor wafer is not illustrated! / It can be delivered to a transfer machine or receive a semiconductor wafer from a transfer machine.
- thermocouple can be embedded in a ceramic substrate as needed. This is because the temperature of the resistance heating element can be measured with a thermocouple, and the temperature can be controlled by changing the voltage and current based on the data.
- the size of the joining part of the metal wires of the thermocouple is preferably equal to or larger than the wire diameter of each metal wire and 0.5 mm or less.
- thermocouples examples include K-type, R-type, B-type, S-type, E-type, J-type, and T-type thermocouples, as described in JIS-C-1602 (1980).
- the thickness of the heater plate in the present invention is preferably 5 Omm or less, particularly preferably 2 Omm or less. In particular, if the thickness of the heater plate exceeds 2 Omm, the heat capacity of the heater plate will increase, and if the temperature control means is provided for heating and cooling, the temperature tracking ability will decrease due to the large heat capacity. Because.
- the problem of non-uniform temperature solved by the present invention is because it is unlikely to occur with a heater plate having a thickness exceeding 2 Omm.
- the thickness is desirably 1 mm or more.
- the heater plate of the present invention preferably has a diameter of 20 Omm or more. In particular, it is desirable to be 12 inches (30 Omm) or more. This is because it will become the mainstream of next-generation silicon wafers. Further, the problem of non-uniform temperature solved by the present invention is because it is unlikely to occur with a heater plate having a diameter of 200 mm or less.
- the object to be heated may be placed directly on the heating surface, or may be heated at a distance of 5 to 5000 / zm.
- Sintering aid yttria (Y 2 0 3) and BC, etc. as necessary to ceramic powders such as nitrides such as nitride Aruminiumu Ya silicon carbide mentioned above, compounds containing Na, a C a,
- the slurry is formed into granules by a method such as spray drying, and the granules are placed in a mold or the like and pressed to be formed into a plate shape or the like. Is prepared.
- the formed body is heated, fired and sintered to produce a ceramic plate.
- the heater plate 11 is manufactured by processing into a predetermined shape, but may be a shape that can be used as it is after firing. By performing heating and firing while applying pressure, it is possible to manufacture a heater plate 11 having no pores. Heating and firing may be performed at a temperature equal to or higher than the sintering temperature, but in the case of nitride ceramics and carbide ceramics, the temperature is 100 to 250 ° C. In the case of oxide ceramics, the temperature is 150 ° C. to 200 ° C.
- the conductor paste is generally a high-viscosity fluid composed of metal particles, a resin, and a solvent.
- the conductor base is printed on a portion where the resistance heating element is to be provided by using screen printing or the like, thereby forming a conductor cost layer.
- the resistance heating element must be printed in a combination pattern of concentric circles and bent lines as shown in Fig. 1 because the temperature of the entire heater plate needs to be uniform.
- the conductor paste layer is desirably formed so that the cross section of the resistance heating element 12 after firing has a rectangular and flat shape.
- the conductor paste layer printed on the bottom surface of the heater plate 11 is heated and fired to remove the resin and the solvent, and the metal particles are sintered and baked on the bottom surface of the heater plate 11 to form a resistance heating element 12.
- the temperature of the heating and firing is preferably from 500 to 100 ° C. If the above-mentioned oxide is added to the conductor base, the metal particles, the heater plate and the oxide are sintered and integrated, so that the adhesion between the resistance heating element and the heater plate is improved. You.
- the metal coating layer 17 can be formed by electrolytic plating, electroless plating, sputtering, or the like, but in consideration of mass productivity, electroless plating is optimal.
- a terminal (external terminal 13) for connecting to the power supply is attached to the end of the pattern of the resistance heating element 12 by soldering.
- a thermocouple is fixed to the bottomed hole 14 with silver brazing, gold brazing, or the like, and sealed with a heat-resistant resin such as polyimide, and the production of the ceramic heater is completed.
- a method of manufacturing a ceramic heater in which the resistance heating element 72 is formed inside the heater plate 11 will be described.
- a ceramic powder such as a nitride is mixed with a binder, a solvent and the like to prepare a paste, and a green sheet is produced using the paste.
- the ceramic powder such as the nitride described above, aluminum nitride or the like can be used, and if necessary, a sintering aid such as yttria or a compound containing Na or Ca may be added. .
- binder at least one selected from an acrylic binder, ethyl cellulose, butyl cellulose solvent, and polyvinyl alcohol is desirable.
- solvent at least one selected from ⁇ -terbineol and dalicol is desirable.
- a paste obtained by mixing these is formed into a sheet by a doctor blade method to produce a green sheet.
- the thickness of the green sheet is preferably from 0.1 to 5 mm.
- a portion to be 74 and a portion to be a through hole 76 for connecting the resistance heating element to the external terminal 73 are formed.
- the above processing may be performed after forming a green sheet laminate described later.
- the printing pattern at this time is a combination pattern of concentric circles and bent lines as shown in FIG.
- These conductive pastes contain metal particles or conductive ceramic particles.
- the average particle size of the tungsten particles or molybdenum particles is preferably 0.1 to 5 ⁇ . If the average particle exceeds a force of 5 im, which is less than 0.1 ⁇ , it is difficult to print the conductive paste.
- a conductive paste for example, 85 to 87 parts by weight of metal particles or conductive ceramic particles; at least one kind of binder selected from acrylic, ethyl cellulose, butyl cellulose, and polyvinyl alcohol 1. 5 to 10 parts by weight; and a composition (paste) obtained by mixing 1.5 to 10 parts by weight with at least one solvent selected from ⁇ -terbineol and glycol.
- the number of green sheets stacked on the upper side is made larger than the number of green sheets stacked on the lower side, and the formation position of the resistance heating element is eccentric toward the bottom.
- the number of stacked green sheets on the upper side is preferably 20 to 50, and the number of stacked green sheets on the lower side is preferably 5 to 20.
- the green sheet laminate is heated and pressed to sinter the green sheet and the internal conductor paste.
- the heating temperature is preferably 100 to 200 ° C.
- the pressurizing pressure is preferably 100 to 200 kg Zcm 2. Heating is performed in an inert gas atmosphere.
- the inert gas for example, argon, nitrogen, or the like can be used.
- a bottomed hole for inserting a temperature measuring element may be provided.
- the bottomed hole can be formed by blasting sand blast or the like after surface polishing.
- an external terminal 73 is connected to a through hole 76 for connecting to an internal resistance heating element, and is heated and reflowed. Heating temperature is 200 ⁇ 5 0 ° C is preferred.
- thermocouple as a temperature measuring element is attached with silver brazing or gold brazing, etc., sealed with polyimide or other heat-resistant resin, and production of the ceramic heater is completed.
- the ceramic heater of the present invention can be used for an electrostatic chuck and a chuck top stage of a wafer prober.
- composition consisting of 100 parts by weight of aluminum nitride powder (average particle size: 1. l / m), 4 parts by weight of Italy (average particle size: 0.4 / zrn), 12 parts by weight of acrylic binder and alcohol The product was spray-dried to produce a granular powder.
- a disk having a diameter of 21 Omm was cut out from the plate to obtain a ceramic plate (heater plate 11).
- Drill the molded product to form a through hole 15 for inserting the support pins of a semiconductor wafer and a bottomed hole 14 for embedding a thermocouple (diameter: 1. lmm, depth: 2 mm) was formed.
- Conductive paste was printed on the heater plate 11 obtained in (3) by screen printing.
- the printing pattern was a pattern of a combination of concentric circles and bent lines as shown in Fig. 1. This may be a pattern like the ceramic heater 20 shown in FIG.
- Solvent PS 603D manufactured by Tokuka Chemical Laboratory, which is used to form through holes in printed wiring boards, was used.
- This conductive paste is a silver-lead paste, and based on 100 parts by weight of silver, lead oxide (5 wt./.), Zinc oxide (55 wt.%), Silica (10 wt.%), Boron oxide ( 25% by weight) and 7.5% by weight of an oxide consisting of alumina (5% by weight) Was something.
- the silver particles had an average particle size of 4.5 zm and were scaly.
- the heater plate 11 on which the conductor paste is printed is heated and baked at 780 ° C to sinter the silver and lead in the conductor paste and to bake them on the heater plate 11 to generate resistance heat.
- Body 12 was formed.
- the silver-lead resistance heating element had a thickness of 5 m, a width of 2.4 mm, and an area resistivity of 7.7 ⁇ . The thickness variation is ⁇ 0.4 m as a whole, but the variation is not localized.
- An electroless nickel plating bath consisting of an aqueous solution with a concentration of nickel sulfate 80 gZ1, sodium hypophosphite 24 g / 1, sodium acetate 12 gZ1, boric acid 8 g / 1, and ammonium chloride 6 gZ1. Then, the heater plate 11 prepared in the above (5) was immersed, and a 1 ⁇ m-thick metal coating layer (nickel layer) 17 was deposited on the surface of the silver-lead resistance heating element 12.
- a silver-lead solder paste (made by Tanaka Kikinzoku) was printed by screen printing on the portion where the external terminals 13 to secure the connection to the power supply were to be formed, forming a solder layer.
- the external terminal 13 made of Kovar was placed on the solder layer, heated and reflowed at 420 ° C., and the external terminal 13 was attached to the surface of the resistance heating element.
- thermocouple for temperature control was inserted and filled with a ceramic adhesive (Alon Ceramic manufactured by Toa Gosei) to obtain a ceramic heater 10.
- Paste A 100 parts by weight of tungsten carbide particles having an average particle size of 1 / zm, 3.0 parts by weight of an acrylic binder, 3.5 parts by weight of a c-terbineol solvent, and 0.3 parts by weight of a dispersant are mixed together to form a conductor.
- Paste A was prepared.
- a conductive paste was prepared by mixing 100 parts by weight of tungsten particles having an average particle size of 3 ⁇ , 1.9 parts by weight of an acrylic binder, 3.7 parts by weight of an ⁇ -terbineol solvent, and 0.2 parts by weight of a dispersant.
- This conductor paste was printed by screen printing on a green sheet having a portion to be a via hole, thereby forming a conductor paste layer for a resistance heating element.
- the printing pattern was a spiral pattern as shown in Fig. 9 and a partially bent pattern.
- the width of the conductor paste layer was 10 mm, and its thickness was 12 m.
- the thickness variation is ⁇ 0.5 / im as a whole, but the variation is not localized.
- conductor paste A was printed by screen printing on a green sheet on which a portion to be a through hole was formed, to form a conductor paste layer for a conductor circuit.
- the shape of the print was band-shaped.
- the conductor paste B was filled into the via hole and the through hole.
- the obtained laminate was degreased in nitrogen gas at 600 ° C for 5 hours, and hot-pressed at 189 ° C and a pressure of 15 MPa for 10 hours to form a ceramic plate having a thickness of 3 mm.
- thermocouple for temperature control into the bottomed hole 74, fill with silica sol, 1 90.
- the mixture was cured and gelled for 2 hours to obtain a ceramic heater having a resistance heating element 72 and a through hole 76.
- a glass paste (G-5232N manufactured by Shoei Chemical Industry Co., Ltd.) is applied to the heater plate, and baked at 1000 ° C for 1 hour, and a 2 nm thick SiO 2 film is formed on the surface of a ceramic substrate made of SiC. Was formed.
- Drilling is performed on this molded product to form a part that becomes a through hole for inserting a lifter pin of a silicon wafer and a part that has a bottomed hole for embedding a thermocouple (diameter: 1. lmm, depth: 2 mm) did.
- Conductive paste was printed on the heater plate obtained in (3) by screen printing.
- the print pattern was a hybrid pattern consisting of repeated swirls and bent lines as shown in Fig. 1.
- the following composition was used as the conductor paste. 90 parts by weight of flaky silver (Ag-540 manufactured by Shoei Chemical Industry Co., Ltd.), 10 parts by weight of platinum in the form of acicular crystals (Pt-401 manufactured by Shoei Chemical Industry Co., Ltd.), 7.5 parts by weight of silica, and 1. It consisted of 5 parts by weight, 6 parts by weight of zinc oxide, and 30 parts by weight of cellulose acetate as an organic vehicle.
- the resistance heating element has a thickness of 5 / im, a width of 10mm, and a sheet resistivity of 0.1 3 ⁇ mouth.
- the thickness variation is ⁇ 0.5 ⁇ overall, but the variation is not localized.
- Electroless nickel plating consisting of an aqueous solution of nickel sulfate 80 g / sodium hypophosphite 24 g_ sodium acetate 12 g / boric acid 8 g / I and ammonium chloride 6 g / 1
- the substrate prepared in (5) above was immersed in the bath, and a 1 / zm-thick metal coating layer (nickel layer) 17 was deposited on the surface of the silver-lead lead resistance heating element 12.
- Silver-lead solder paste (made by Tanaka Kikinzoku) was printed by screen printing on the area where the terminals for securing the connection to the power supply were to be attached, forming a solder layer.
- Kovar terminal pins were placed on the solder layer, and heated and reflowed at 420 ° C., and the external terminals 13 were attached to the surface of the resistance heating element.
- thermocouple for temperature control was inserted into the bottomed hole, and a ceramic adhesive (Alon Ceramic manufactured by Toa Kasei) was embedded and fixed to obtain a ceramic heater.
- alumina powder 100 parts by weight of alumina powder (average particle size: 1.0 ⁇ ), 4 parts by weight of yttria (average particle size: 0.4 / zm), 12 parts by weight of acrylic binder and spray drying of a composition consisting of alcohol , And a ceramic heater was manufactured in the same manner as in Example 1 except that a granular powder was produced.
- a ceramic heater was manufactured in the same manner as in Example 1 except that the conductor paste was printed so that the pattern of the resistance heating element was the same as that of the ceramic heater 30 shown in FIG.
- the thickness was 6 / zm, but the variation was ⁇ 0.4 ⁇ .
- the thickness variation was thick in the direction perpendicular to the printing direction and thin in the direction parallel to the printing direction.
- the ceramic heaters obtained in Examples and Comparative Examples were energized to raise the temperature of the central portion to 200 ° C., and the central portion and the outer peripheral portion (of 20 mm from the outer peripheral end toward the center). ) was measured. Also, the time required to raise the temperature to 200 ° C. was measured.
- the heating time up to 200 ° C was 30 seconds (Example 1), 32 seconds (Example 2), 40 seconds (Example 3) and 5 minutes (Examples 1 to 3 and Test Examples). Example), but it was 30 seconds in Comparative Example 1.
- a heating element having a concentric or spiral pattern is formed at the center portion, while a heating element having a repeating pattern of bent lines is formed at the outer peripheral portion. Since it is formed, a decrease in the temperature of the outer peripheral portion on the wafer heating surface can be suppressed, and the entire semiconductor wafer to be heated can be uniformly heated.
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Surface Heating Bodies (AREA)
- Resistance Heating (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020017004473A KR20010083893A (ko) | 1999-08-10 | 2000-08-09 | 세라믹 히터 |
EP00951906A EP1120997A1 (en) | 1999-08-10 | 2000-08-09 | Ceramic heater |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22676999 | 1999-08-10 | ||
JP11/226769 | 1999-08-10 | ||
JP2000/238779 | 2000-08-07 | ||
JP2000238779A JP3381909B2 (ja) | 1999-08-10 | 2000-08-07 | 半導体製造・検査装置用セラミックヒータ |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09806478 A-371-Of-International | 2001-07-26 | ||
US10/766,027 Continuation US20040155025A1 (en) | 1999-08-10 | 2004-01-29 | Ceramic heater |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001013679A1 true WO2001013679A1 (fr) | 2001-02-22 |
Family
ID=26527346
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2000/005322 WO2001013679A1 (fr) | 1999-08-10 | 2000-08-09 | Dispositif de chauffage en ceramique |
Country Status (7)
Country | Link |
---|---|
US (1) | US20040155025A1 (ja) |
EP (1) | EP1120997A1 (ja) |
JP (1) | JP3381909B2 (ja) |
KR (1) | KR20010083893A (ja) |
CN (2) | CN1169404C (ja) |
TW (1) | TW465254B (ja) |
WO (1) | WO2001013679A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1249858A2 (en) * | 2001-04-11 | 2002-10-16 | Sumitomo Electric Industries, Ltd. | Heater member for mounting heating object and substrate processing apparatus using the same |
JP2015520010A (ja) * | 2012-03-26 | 2015-07-16 | ヘレーウス ノーブルライト ゲゼルシャフト ミット ベシュレンクテルハフツングHeraeus Noblelight GmbH | 基板照射装置 |
CN114959204A (zh) * | 2022-04-25 | 2022-08-30 | 中国航发成都发动机有限公司 | 一种局部热处理电阻加热元件及其固定工装 |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1249433A4 (en) * | 1999-09-06 | 2005-01-05 | Ibiden Co Ltd | BRIQUETTE AND CERAMIC SINTERED CARBON ALUMINUM NITRIDE SUBSTRATE FOR SEMICONDUCTOR MANUFACTURING OR VERIFICATION EQUIPMENT |
WO2001062686A1 (fr) * | 2000-02-24 | 2001-08-30 | Ibiden Co., Ltd. | Piece frittee en nitrure d'aluminium, substrat en ceramique, corps chauffant en ceramique et mandrin electrostatique |
JP2001247382A (ja) * | 2000-03-06 | 2001-09-11 | Ibiden Co Ltd | セラミック基板 |
EP1233651A1 (en) * | 2000-04-07 | 2002-08-21 | Ibiden Co., Ltd. | Ceramic heater |
JP3565496B2 (ja) * | 2000-04-13 | 2004-09-15 | イビデン株式会社 | セラミックヒータ、静電チャックおよびウエハプローバ |
JP3516392B2 (ja) * | 2000-06-16 | 2004-04-05 | イビデン株式会社 | 半導体製造・検査装置用ホットプレート |
WO2002003435A1 (fr) * | 2000-07-04 | 2002-01-10 | Ibiden Co., Ltd. | Plaque chaude destinee a la fabrication et aux essais de semiconducteurs |
WO2002009171A1 (fr) * | 2000-07-25 | 2002-01-31 | Ibiden Co., Ltd. | Substrat ceramique pour appareil de fabrication/inspection de semi-conducteurs, element chauffant en ceramique, dispositif de retenue electrostatique sans attache et substrat pour testeur de tranches |
JP4325902B2 (ja) * | 2002-03-20 | 2009-09-02 | 京セラ株式会社 | ウエハ加熱装置 |
JP2003317906A (ja) | 2002-04-24 | 2003-11-07 | Sumitomo Electric Ind Ltd | セラミックスヒータ |
WO2006004045A1 (ja) * | 2004-07-05 | 2006-01-12 | Tokyo Electron Limited | 処理装置及びヒーターユニット |
US20060088692A1 (en) * | 2004-10-22 | 2006-04-27 | Ibiden Co., Ltd. | Ceramic plate for a semiconductor producing/examining device |
FR2890824B1 (fr) * | 2005-09-15 | 2007-11-23 | Commissariat Energie Atomique | Four de fusion a dispositif inducteur a une seule spire compose d'une pluralite de conducteurs |
JP5683063B2 (ja) * | 2007-09-05 | 2015-03-11 | アプライド マテリアルズ インコーポレイテッドApplied Materials,Incorporated | 窒化アルミニウム又は酸化ベリリウムのセラミックカバーウェハ |
ATE492140T1 (de) * | 2008-06-09 | 2011-01-15 | Leister Process Tech | Elektrisches widerstandsheizelement für eine heizeinrichtung zum erhitzen eines strömenden gasförmigen mediums |
TWI477252B (zh) * | 2009-11-03 | 2015-03-21 | Ind Tech Res Inst | 加熱保溫承載器 |
JP5341049B2 (ja) * | 2010-10-29 | 2013-11-13 | 日本発條株式会社 | セラミックス焼結体の製造方法、セラミックス焼結体およびセラミックスヒータ |
KR101343556B1 (ko) | 2012-05-18 | 2013-12-19 | 주식회사 케이에스엠컴포넌트 | 2차원적으로 배선된 열선을 포함하는 세라믹 히터 |
US20150016083A1 (en) * | 2013-07-05 | 2015-01-15 | Stephen P. Nootens | Thermocompression bonding apparatus and method |
JP6804828B2 (ja) * | 2015-04-20 | 2020-12-23 | 日本特殊陶業株式会社 | セラミックヒータ及び静電チャック |
KR20180130535A (ko) * | 2016-04-07 | 2018-12-07 | 마테리온 코포레이션 | 산화 베릴륨 일체형 저항 히터 |
US10679873B2 (en) * | 2016-09-30 | 2020-06-09 | Ngk Spark Plug Co., Ltd. | Ceramic heater |
KR102110417B1 (ko) * | 2018-08-21 | 2020-05-13 | 엘지전자 주식회사 | 전기 히터 |
JP6840349B2 (ja) * | 2019-02-22 | 2021-03-10 | 住友電気工業株式会社 | ヒータ |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1174064A (ja) * | 1997-08-29 | 1999-03-16 | Kyocera Corp | ウエハ加熱装置 |
JPH11251040A (ja) * | 1998-02-27 | 1999-09-17 | Kyocera Corp | セラミックヒータ及びその製造方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2409244A (en) * | 1943-11-05 | 1946-10-15 | Bilan John | Glass electric hot plate |
US4002883A (en) * | 1975-07-23 | 1977-01-11 | General Electric Company | Glass-ceramic plate with multiple coil film heaters |
AT376540B (de) * | 1983-01-05 | 1984-11-26 | Electrovac | Vorrichtung zur regelung bzw. begrenzung wenigstens eines temperaturwertes bzw. eines temperaturbereiches von strahlungs- bzw. kontaktheizkoerpern von elektrischen kochgeraeten |
DE3406604C1 (de) * | 1984-02-23 | 1985-07-25 | Bosch-Siemens Hausgeräte GmbH, 7000 Stuttgart | Heizeinrichtung fuer Strahlungsheizstellen mit elektrischen Strahlungsheizelementen |
US5264681A (en) * | 1991-02-14 | 1993-11-23 | Ngk Spark Plug Co., Ltd. | Ceramic heater |
US5294778A (en) * | 1991-09-11 | 1994-03-15 | Lam Research Corporation | CVD platen heater system utilizing concentric electric heating elements |
JPH05326112A (ja) * | 1992-05-21 | 1993-12-10 | Shin Etsu Chem Co Ltd | 複層セラミックスヒーター |
JP2647799B2 (ja) * | 1994-02-04 | 1997-08-27 | 日本碍子株式会社 | セラミックスヒーター及びその製造方法 |
JP3477062B2 (ja) * | 1997-12-26 | 2003-12-10 | 京セラ株式会社 | ウエハ加熱装置 |
JPH11204238A (ja) * | 1998-01-08 | 1999-07-30 | Ngk Insulators Ltd | セラミックスヒーター |
US6967313B1 (en) * | 1999-05-07 | 2005-11-22 | Ibiden Company, Ltd. | Hot plate and method of producing the same |
JP2001118664A (ja) * | 1999-08-09 | 2001-04-27 | Ibiden Co Ltd | セラミックヒータ |
DE60021848T2 (de) * | 1999-11-19 | 2006-06-08 | Ibiden Co., Ltd. | Keramisches heizgerät |
JP2001297857A (ja) * | 1999-11-24 | 2001-10-26 | Ibiden Co Ltd | 半導体製造・検査装置用セラミックヒータ |
EP1137321A1 (en) * | 1999-11-30 | 2001-09-26 | Ibiden Co., Ltd. | Ceramic heater |
US20040222211A1 (en) * | 1999-12-28 | 2004-11-11 | Ibiden Co., Ltd. | Carbon-containing aluminum nitride sintered body, and ceramic substrate for a semiconductor producing/examining device |
JP3228923B2 (ja) * | 2000-01-18 | 2001-11-12 | イビデン株式会社 | 半導体製造・検査装置用セラミックヒータ |
JP3228924B2 (ja) * | 2000-01-21 | 2001-11-12 | イビデン株式会社 | 半導体製造・検査装置用セラミックヒータ |
JP2001244320A (ja) * | 2000-02-25 | 2001-09-07 | Ibiden Co Ltd | セラミック基板およびその製造方法 |
US20040035846A1 (en) * | 2000-09-13 | 2004-02-26 | Yasuji Hiramatsu | Ceramic heater for semiconductor manufacturing and inspecting equipment |
-
2000
- 2000-08-07 JP JP2000238779A patent/JP3381909B2/ja not_active Ceased
- 2000-08-09 CN CNB008016534A patent/CN1169404C/zh not_active Expired - Lifetime
- 2000-08-09 EP EP00951906A patent/EP1120997A1/en not_active Withdrawn
- 2000-08-09 WO PCT/JP2000/005322 patent/WO2001013679A1/ja not_active Application Discontinuation
- 2000-08-09 CN CNA2003101028186A patent/CN1533218A/zh active Pending
- 2000-08-09 KR KR1020017004473A patent/KR20010083893A/ko not_active Application Discontinuation
- 2000-08-10 TW TW089116058A patent/TW465254B/zh active
-
2004
- 2004-01-29 US US10/766,027 patent/US20040155025A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1174064A (ja) * | 1997-08-29 | 1999-03-16 | Kyocera Corp | ウエハ加熱装置 |
JPH11251040A (ja) * | 1998-02-27 | 1999-09-17 | Kyocera Corp | セラミックヒータ及びその製造方法 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1249858A2 (en) * | 2001-04-11 | 2002-10-16 | Sumitomo Electric Industries, Ltd. | Heater member for mounting heating object and substrate processing apparatus using the same |
EP1249858A3 (en) * | 2001-04-11 | 2009-05-13 | Sumitomo Electric Industries, Ltd. | Heater member for mounting heating object and substrate processing apparatus using the same |
JP2015520010A (ja) * | 2012-03-26 | 2015-07-16 | ヘレーウス ノーブルライト ゲゼルシャフト ミット ベシュレンクテルハフツングHeraeus Noblelight GmbH | 基板照射装置 |
CN114959204A (zh) * | 2022-04-25 | 2022-08-30 | 中国航发成都发动机有限公司 | 一种局部热处理电阻加热元件及其固定工装 |
Also Published As
Publication number | Publication date |
---|---|
JP3381909B2 (ja) | 2003-03-04 |
TW465254B (en) | 2001-11-21 |
JP2001135464A (ja) | 2001-05-18 |
CN1533218A (zh) | 2004-09-29 |
KR20010083893A (ko) | 2001-09-03 |
CN1169404C (zh) | 2004-09-29 |
EP1120997A1 (en) | 2001-08-01 |
CN1320351A (zh) | 2001-10-31 |
US20040155025A1 (en) | 2004-08-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2001013679A1 (fr) | Dispositif de chauffage en ceramique | |
WO2001084886A1 (fr) | Dispositif de chauffage en ceramique | |
WO2003007661A1 (fr) | Appareil de chauffage en ceramique et article en ceramique soude | |
KR100615443B1 (ko) | 세라믹 히터 | |
WO2001078454A1 (fr) | Dispositif chauffant ceramique | |
WO2002003434A1 (fr) | Radiateur ceramique pour appareil de fabrication ou de test de semi-conducteurs | |
WO2001078456A1 (fr) | Element ceramique chauffant | |
WO2001078455A1 (fr) | Plaque ceramique | |
JP3729785B2 (ja) | セラミックヒータ | |
WO2002045138A1 (fr) | Dispositif ceramique chauffant permettant la production de semi-conducteurs et dispositifs d'inspection | |
WO2001084885A1 (fr) | Element chauffant en ceramique | |
JP2002334820A (ja) | 半導体ウエハまたは液晶基板加熱用セラミックヒータ | |
JP3625046B2 (ja) | 半導体製造・検査装置用セラミックヒータ | |
JP2002334828A (ja) | ホットプレートユニット | |
JP2004303736A (ja) | セラミックヒータ | |
JP2001085144A (ja) | セラミックヒータ | |
JP3186750B2 (ja) | 半導体製造・検査装置用セラミック板 | |
JP2002141257A (ja) | 半導体製造・検査装置用セラミックヒータ | |
JP2001338747A (ja) | 半導体製造・検査装置用セラミックヒータ | |
JP2006024433A (ja) | セラミックヒータ | |
JP2001358205A (ja) | 半導体製造・検査装置 | |
JP2002319525A (ja) | 半導体製造・検査装置用セラミックヒータ | |
JP2002246286A (ja) | セラミックヒータ | |
JP2003234165A (ja) | セラミックヒータ | |
JP2002319526A (ja) | 半導体製造・検査装置用セラミックヒータ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 00801653.4 Country of ref document: CN |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): CN KR US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020017004473 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2000951906 Country of ref document: EP |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 09806478 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 2000951906 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1020017004473 Country of ref document: KR |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2000951906 Country of ref document: EP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 1020017004473 Country of ref document: KR |