WO2001013057A1 - Tube d'echange thermique et procede de recuperation de chaleur utilisant ce tube - Google Patents
Tube d'echange thermique et procede de recuperation de chaleur utilisant ce tube Download PDFInfo
- Publication number
- WO2001013057A1 WO2001013057A1 PCT/JP2000/005205 JP0005205W WO0113057A1 WO 2001013057 A1 WO2001013057 A1 WO 2001013057A1 JP 0005205 W JP0005205 W JP 0005205W WO 0113057 A1 WO0113057 A1 WO 0113057A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat
- tube
- composite material
- metal
- heat exchange
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D21/0001—Recuperative heat exchangers
- F28D21/0003—Recuperative heat exchangers the heat being recuperated from exhaust gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
- F28F19/02—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/04—Constructions of heat-exchange apparatus characterised by the selection of particular materials of ceramic; of concrete; of natural stone
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2255/00—Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes
- F28F2255/18—Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes sintered
Definitions
- the present invention relates to a heat exchange tube for recovering heat from high-temperature exhaust gas generated when incinerating municipal solid waste or the like, through water vapor, air, or the like. It relates to the heat recovery method using it.
- Background Discussion Currently, municipal solid waste, coal, sewage, «sludge, and other industries» The heat generated by burning 400-1200 exhaust gas generated from the combustion of materials such as steam, air, etc. As a result, the heat recovery system that recovers heat and uses it for power generation etc. has been enhanced.
- Japanese Patent Application Laid-Open No. 5-332508 discloses a ceramic heat source
- Japanese Patent Application Laid-Open No. 10-274401 discloses the following method.
- An object of the present invention is to provide a heat tube capable of performing stable heat recovery for a long time even at a height, and a heat recovery method using the same. This purpose is achieved by a heat tube made of a sintered body with a porosity of 2-60% or a heat tube made of a composite forest material with ceramics.
- FIG. 1 is a screen view of a heat tube according to the present invention.
- FIG. 2 is a longitudinal sectional view of a heat exchange tube which is another example of the present invention.
- FIG. 3 is a cross-sectional view of a heat tube according to another example of the present invention.
- FIG. 4 is a simplified view of a heat tube according to another example of the present invention.
- FIG. 5 is a cross-sectional view of the heat tube of FIG.
- FIG. 6 is a cross-sectional view of a heat tube of another example of the present invention.
- FIG. 7 is a cross-sectional view of a heat tube as another example of the present invention.
- FIG. 8 is a longitudinal sectional view of a heat exchange tube as another example of the present invention.
- FIG. 9 is a cross-sectional view of the heat exchange tube of FIG.
- FIG. 10 is a cross-sectional view of a heat tube according to another example of the present invention.
- FIG. 11 is a cross-sectional view of a heat tube of another example of the present invention.
- BEST MODE FOR CARRYING OUT THE INVENTION We studied heat exchange tubes that can be used for a long time under high-temperature rot from the viewpoints of preventing fly ash accumulation and cracking of ceramics itself.
- a heat exchange tube consisting of a sintered body of metal-ceramic with a porosity of 2-60%
- the heated fluid flowing through the heat exchange tube Part of the gas can be ejected from the pores, preventing the accumulation of other particles including ⁇ Sffi ⁇ .
- the porosity is set to 2 to 60%.
- the porosity When the porosity is set to 2% or more, there is no need to manufacture under a special high-temperature and high-pressure condition, and S3 ⁇ 4g cost is reduced. Then git to make the tube itself cool. Also, as a method of ejecting “" ”of the heat fluid from the pores, it is advisable to set the pressure of the heat fluid in the heat-building tube higher than the pressure of the atmosphere outside the heat exchange tube. If the heat tube made of this sintered body is made of a composite forest material of ceramics and metal, the ceramics will have excellent corrosion resistance, and the metal will also improve the brittleness of the ceramics itself, and will have excellent corrosion resistance and cracking. Difficult heat 3 ⁇ tube. On the other hand, for the prevention of cracking of the ceramic itself, the surface layer may be a heat tube formed of a ceramic / metal composite forest material for the reasons described above.
- any metal can be used as the metal in the composite material, but Al, Al-Si alloy, Al-Mg alloy, etc., which are excellent in terms of receptivity and cost effective, should be used. Good.
- A1 contained in the composite pillow is excellent in reciting as ceramics, 14 and is more preferable than A1N force, which is hard to adhere to. 13 ⁇ 4 ⁇ ⁇ is also convenient because it is only necessary to ⁇ the A1 in an N 2 atmosphere.
- A1N should be 1-90 wt. /.
- (A1 + A1) must be 50 wt% or more.
- A1ON of ceramics is further added to this composite forest material consisting of A1 and A1N, it will become more difficult to adhere the covertly.
- A1N is 1-90 wt. /.
- the power (A1 + A1N + A10N) more than 50 wt% '.
- the A10N, Al, O the total term for solid liquid N, A1 U 0 16 N, ⁇ 10 ⁇ , ⁇ ⁇ ⁇ ⁇ , A ⁇ 0 39 N, ⁇ 1 10 ⁇ 3 ⁇ 8, A, 0 3 N SiAl 7 0, N 7 SiaAl 3 represent like 0 45 N 5.
- such ceramics and metal composite pillow charges the surface of, BN, compound or SiC containing B (boric ⁇ such B 4 C, by coating or dipping a compound containing a C (charcoal ⁇ ) such as black ⁇ , such as 1- With a thickness of 400 m, adhesion of the compound can be substantially prevented, and if the compound is applied or immersed regularly, the heat tube can be stabilized for a longer time.
- the surface layer may be formed of such a composite material, and the inside may be formed of a conventional heat-resistant alloy tube, for example. Force to 12 mm is better.
- the base is made of a metal alloy tube and the details are made of such a composite forest material
- the outer surface of the metal tube can be covered with a composite material of ceramics and metal in a non-enclosed state. At least the heat of the forest material in the direction of the pipe Ifc ⁇ The strain due to the difference in the long rate can be overcome and the cracking and peeling of the composite material can be more reliably prevented.
- this meta-twisted alloy tube and this composite forest material If the interface is made at least as HTiri-fibre-structured, heat recovery can be performed with high heat without a significant decrease in tranquility.
- the ceramic-metal composite material contains 1-90 wt% of A1N and 50% or more of (A1 + A1N + A10N), and has a porosity of 2-60% for the reasons described above. ⁇ T that power is good.
- the sliding force between the metal alloy and the composite pillow will be smooth, and the difference in heat length ratio between the tubes will be smooth.
- the distortion due to is almost completely reduced.
- a metal alloy tube is used as the base and a part of the metal tube is made of such a composite material, the outer surface of the metal alloy tube is covered with a heat material and a composite material of ceramics and metal.
- the structure of the composite pillow may be at least at the interface between the slif material and the heat-expandable material and the composite pillow. In this case, the distortion due to the difference in the heat in the pipe diameter direction due to the difference of the Peng's tension ratio is also caused by the ⁇ bend material.
- the heat material it is possible to use fiber ridges mainly composed of B, C or A1, powder, film or tape.
- the composite material contains 1-90 wt% of A1N and 50 wt% or more of (A1 + A1N + A10N) and has a porosity of 2-60%.
- compounds containing B or C are likely to be ⁇ ffiT on the outer surface of the stranded metal tube.
- the length is less than 6 mm and the outer diameter is 20-200 mm. It is preferred that The cross-sectional shape may be circular or square, and there is no particular PI.
- a ceramic-metal composite material 1 having the cross-sectional shape and microstructure shown in Fig. 1.
- Single-layer heat 3 ⁇ tube No. 1 and the surface shape shown in Fig. 2 the first layer is an S-twisted metal tube 2
- the second layer is carbon fiber ⁇ 3
- the third layer is a surface layer
- the three-layered heat tube No. 2 whose part is a composite material 1 of ceramics and metal, and the heat exchange tube No. 3 with BN coating on the outer surface of the heat tube No. 2 were installed in a municipal solid waste incineration pilot plant. Heat recovery was performed according to the high-temperature exhaust gas of 750-950 ° C.
- Composite material of ceramics and metal A1 + A1N + A10N 90 wt% or more, thickness 4 mm, outer diameter: 40 mm
- Metal alloy tube SUS304, thickness 4 rmn, carbon fiber ⁇ : thickness 4 mm, composite material of ceramic and metal: A1 + A1N + A10N 90 wt% i3 ⁇ 4 ⁇ , thickness 10 mm, outer diameter: 40 mm
- the single-layer heat exchange tubes Nos. 4 and 5 made of a composite material 1 of ceramics and metal having a surface shape and having pores 4 shown in FIG.
- the pressure of the hot fluid was increased above the pressure of the exhaust gas atmosphere as in Example 1 and the hot fluid " ⁇ " was ejected from the pores.
- the details of heat tubes Nos. 4 and 5 are as follows. Heat tube No. 4
- Composite material with ceramics A1 + A1N 90 wt% or more, thickness 6 mm, porosity 60%, outer diameter: 40 mm
- the dog has a longitudinal section shown in FIG. 4 and a cross section shown in FIG. 5, and the outer surface of the meta-combustion alloy tube 2 is covered with a ceramic and metal composite pillow 1 in a non-coated state, and The metal alloy tube 2 is in contact with the composite material dough 1 at least at its interface, so the heat tube No. 6-9 with a gap 5 is replaced by the same municipal waste pipe as in male example 1.
- the heat was recovered from the plant plant's high-temperature exhaust gas at 650-950 ° C.
- Metal alloy tube SUS304-15A, composite material of ceramics and metal: A1 + A1N + A10N 90 wt% or more, thickness 5-10 mm, porosity 40%
- Metal alloy tube SUS304-20A, composite material of ceramics and metal: A1 + A1N + A10N 9 0 wt. /. Above, thickness 6-8 mm, porosity 20%
- Biaxial alloy tube SUS304 "20A, outer surface BN coating, composite forest material of ceramics and metal: A1 + A1N + A1ON 90 wt% or more, thickness 6-8 mm, porosity 20%
- ⁇ Alloy Tube SUS304-20A, composite of ceramic and ⁇ S ⁇ : A1 2 0 3 80 ⁇ ⁇ % or more on the + AL thickness 2-4 mm, porosity of 30%
- the outlet can obtain 500 ⁇ C or more ata ata force, and the inlet heat can be 120-300 ° C. It was confirmed that when using a mixed gas of air of 1000-5000 mmAq and waste gas of 100-400 mmAq, it was possible to heat up to 800 ° C at the outlet. Difficult case 4
- Heat exchange tube No. 10 Details of heat tubes No. 10 and 11 are as follows. Heat exchange tube No. 10
- ⁇ Alloy Tube boiler ⁇ collars STBA28-20A, ceramic and metal composite materials: A 1 + A1N 90 wt% > Al 2 O 3 7wt%, thickness 6-7 mm, porosity 25%
- Meta-combustion alloy tube For boiler! ⁇ ff STBA28-20A, composite material of ceramics and metal: SiC 95 wt% or more + Mg, thickness 6-7 mm, porosity 2%
- the outer surface of the metamorphic alloy tube 2 of the same shape or U-shaped tube shape shown in Fig. 6 and Fig. 7 is non-bell-covered with the composite forest material 1 of ceramics and metal. 2 and 1 composite material, at least at the interface of which is marked with " ⁇ ", and therefore heat tube No. 12-14 with void 5 was placed in the coal, sewage cake, and the combustion gas of the furnace. Installed and heat recovered.
- Meta-combustion alloy tube Heat-resistant tube for boiler STBA28-40A and 65A, composite material of ceramics and metal: SiC 95 wt% or more + Mg, thickness about 7 mm, same shape (Fig. 6)
- ⁇ Alloy Tube ⁇ tube STBA28-20A and 50A boiler, ceramic and metal composite materials: A1 2 0 3 95 wt. /. + AL thickness about 3 mm, coaxial tube shape (Fig. 6)
- Meta-combustion alloy tube For boiler! ⁇ STBA28-15A and 20A, composite material of ceramic and metal: A1 + A1N 90 wt% or more, thickness 6-10 mm, U-tube shape (Fig. 7)
- coal and sewage mud burnt gas contains several hundred ppm of SOx power; These heat exchange tubes were not corroded, and were capable of recovering high-temperature high-efficiency 7K steam, achieving high power generation efficiency of 30% or more, and recovering high-temperature air and fine gas.
- the outer surface of the meta-twisted alloy tube 2 is successively covered in a non-crane state with a composite material of ⁇ ⁇ R I and ceramic and ⁇ .
- the metal alloy tube 2 and the ⁇ 6 material 6 and the Z or material 6 and the composite material 1 are at least partially in contact with each other at their interfaces, and therefore, the heat exchange tube No. 15 -18 was installed in high-temperature exhaust gas at 650-950 ° C in the same municipal solid waste pipe plant as in Example 1, and heat was recovered.
- Bi-twist alloy tube SUS304-15A
- heat return material A1 foil
- composite material of ceramics and metal A1 + A1 + A10N 90 wt ° /.
- thickness 4-10 mm porosity 40% heat exchange tube No. 16
- Bi-twisted alloy tube SUS304> 20A, mmm: carbon fiber ⁇ , thickness O.2-2 mm, composite forest material of ceramics and metal: A1 + A1N + A10N 90 wt 0 /. Above, thickness 3-8 mm, porosity 20% Heat exchange tube No. 17
- Metal alloy tube SUS30 20A
- heat I Coating material carbon H ⁇
- composite material of ceramics and metal ⁇ 3 80 wt% or more + ⁇ 1, thickness 2-4 mm
- composition of flue gas from the Municipal Garin Pilot Plant is 2-16% 0. , 200-600 pp m of HC1, max 300 ppm of SOx, 4-19% of CO 2, and the balance N 2.
- the age of using steam with the inlet ⁇ t of 280-400 ° C as the heat fluid is more than 540 at the outlet, and lOO ata can be obtained.
- a mixed gas of 1000-4000 mmAq of air and 50-400 mmAq of ⁇ fuel J3 ⁇ 4 ⁇ gas it was confirmed that heating up to 800 ° C was possible at the outlet.
- the outer surface of the metal alloy tube 2 is mm mm, and the ceramics and metal pipes are joined together by Nadarin Lin. , And the metal tube 2 and the heat ⁇ 1> material 6 and heat or heat>
- the H ⁇ impact material 6 and the composite forest material 1 are at least partially in contact at the interface, and thus the heat exchange tube Bu Nos. 19 and 20 were heated in a 700-1000 ° C exhaust gas atmosphere where municipal solid waste was partially oxidized by the same municipal solid waste pilot plant as in Example 1, and heat was recovered.
- Meta-combustion alloy tube Boiler meta-combustion tube STBA28-20A, heat Awakening material: carbon 80% or more fine pine, thickness 0.5-3 mm, composite material of ceramics and metal: A1 + A1N 86 wt%, A1, 0 3 6wt%, thickness 4-5mm, porosity 25%
- Kyo alloy tube Boiler tubing STBA28-20A, heat]
- Peng Yong-sheng material carbon 80 wt. /.
- Meta-combustion alloy tube Boiler meta-combustion tube STBA28-40A and 65A, heat]
- Awakening material Mixture of fine powder and fiber of 80 wt% or more carbon, thickness 0.2-4 mm, Composite material of ceramics and metal: SiC 95 wt % + Mg, thickness about 7 mm, same as above (Fig. 10)
- Twisted alloy tube Boiler for STBA28-15A and 20A, Heng Peng Yong-sheng material: carbon fiber 80wt% or more fine pine, thickness 0.4-1mm, ceramic and metal composite material: A1 + A1 90wt% or more , Thickness 6-8 mm, U ⁇ ⁇ ⁇ (Fig. 11)
- coal and sewage-burning fuel gas contain hundreds of ppm of SOx power, but none of the heat exchange tubes are corroded, and the high-temperature high temperature exceeding 30% is generated.
- Recovery of steam and recovery of hot air and column gas were the functions of the [ ⁇ ].
- the force 3 ⁇ 4 ⁇ is to allow more voids 5 to be present in the bent portion.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Laminated Bodies (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00949969A EP1122506A1 (fr) | 1999-08-12 | 2000-08-03 | Tube d'echange thermique et procede de recuperation de chaleur utilisant ce tube |
KR1020017002406A KR20010072966A (ko) | 1999-08-12 | 2000-08-03 | 열교환튜브 및 그것을 이용한 열회수방법 |
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11/228589 | 1999-08-12 | ||
JP22859099A JP3674401B2 (ja) | 1999-08-12 | 1999-08-12 | 熱交換用伝熱管 |
JP11/228590 | 1999-08-12 | ||
JP22858999A JP2001056195A (ja) | 1999-08-12 | 1999-08-12 | 熱交換用伝熱管 |
JP11/228592 | 1999-08-12 | ||
JP11228591A JP2001049379A (ja) | 1999-08-12 | 1999-08-12 | 熱交換用伝熱管 |
JP22859299A JP4016311B2 (ja) | 1999-08-12 | 1999-08-12 | 高温ガスからの熱回収方法 |
JP11/228591 | 1999-08-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001013057A1 true WO2001013057A1 (fr) | 2001-02-22 |
Family
ID=27477332
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2000/005205 WO2001013057A1 (fr) | 1999-08-12 | 2000-08-03 | Tube d'echange thermique et procede de recuperation de chaleur utilisant ce tube |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1122506A1 (fr) |
KR (1) | KR20010072966A (fr) |
TW (1) | TW546454B (fr) |
WO (1) | WO2001013057A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003012155A1 (fr) * | 2001-07-30 | 2003-02-13 | Jfe Engineering Corporation | Matiere resistante a la corrosion par des sels fondus contenant du chlorure, tuyau en acier pour echangeur de chaleur revetu de cette matiere, et procede de production de cette matiere |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2224003T3 (es) * | 2002-07-31 | 2005-03-01 | Itn Nanovation Gmbh | Recubrimiento ceramico para calderas de combustion. |
US20090261289A1 (en) * | 2004-08-25 | 2009-10-22 | Yoon-Sik Ham | R502, R12 or R22 Substitute Mixed Refrigerant and Refrigeration System Using Thereof |
DE102006048445B4 (de) * | 2006-10-11 | 2016-09-08 | Udo Hellwig | Einrichtung zur Bereitstellung von Wärme, Verfahren zu deren Herstellung und Verfahren zur Übertragung von Wärme |
DE102013201465A1 (de) * | 2013-01-30 | 2014-07-31 | Eberspächer Exhaust Technology GmbH & Co. KG | Wärmetauscher einer Brennkraftmaschine |
DE102017217308A1 (de) * | 2017-09-28 | 2019-03-28 | Mahle International Gmbh | Wärmeübertrager |
Citations (7)
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JPS6183895A (ja) * | 1984-09-28 | 1986-04-28 | Hitachi Ltd | 伝熱面およびその製造方法 |
JPS61227036A (ja) * | 1985-04-02 | 1986-10-09 | 三菱重工業株式会社 | 耐食性にすぐれたセラミツクス被覆部材 |
JPS63140292A (ja) * | 1986-11-30 | 1988-06-11 | Chuo Denki Kogyo Kk | 多孔型放熱体 |
JPH01159596A (ja) * | 1987-09-09 | 1989-06-22 | Toshiba Corp | 蒸気発生器用伝熱管およびその製造方法 |
JPH04371800A (ja) * | 1991-06-19 | 1992-12-24 | Yoshida Kogyo Kk <Ykk> | 高性能伝熱体 |
JPH05180585A (ja) * | 1991-12-26 | 1993-07-23 | I N R Kenkyusho:Kk | 熱交換器 |
JPH06307791A (ja) * | 1993-04-26 | 1994-11-01 | Y K K Kk | 高性能伝熱体 |
-
2000
- 2000-08-03 KR KR1020017002406A patent/KR20010072966A/ko not_active Application Discontinuation
- 2000-08-03 WO PCT/JP2000/005205 patent/WO2001013057A1/fr not_active Application Discontinuation
- 2000-08-03 EP EP00949969A patent/EP1122506A1/fr not_active Withdrawn
- 2000-08-10 TW TW089116086A patent/TW546454B/zh active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6183895A (ja) * | 1984-09-28 | 1986-04-28 | Hitachi Ltd | 伝熱面およびその製造方法 |
JPS61227036A (ja) * | 1985-04-02 | 1986-10-09 | 三菱重工業株式会社 | 耐食性にすぐれたセラミツクス被覆部材 |
JPS63140292A (ja) * | 1986-11-30 | 1988-06-11 | Chuo Denki Kogyo Kk | 多孔型放熱体 |
JPH01159596A (ja) * | 1987-09-09 | 1989-06-22 | Toshiba Corp | 蒸気発生器用伝熱管およびその製造方法 |
JPH04371800A (ja) * | 1991-06-19 | 1992-12-24 | Yoshida Kogyo Kk <Ykk> | 高性能伝熱体 |
JPH05180585A (ja) * | 1991-12-26 | 1993-07-23 | I N R Kenkyusho:Kk | 熱交換器 |
JPH06307791A (ja) * | 1993-04-26 | 1994-11-01 | Y K K Kk | 高性能伝熱体 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003012155A1 (fr) * | 2001-07-30 | 2003-02-13 | Jfe Engineering Corporation | Matiere resistante a la corrosion par des sels fondus contenant du chlorure, tuyau en acier pour echangeur de chaleur revetu de cette matiere, et procede de production de cette matiere |
Also Published As
Publication number | Publication date |
---|---|
EP1122506A1 (fr) | 2001-08-08 |
TW546454B (en) | 2003-08-11 |
KR20010072966A (ko) | 2001-07-31 |
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