WO1999007934A1 - Procede de production d'etoffes tissees et/ou tricotees utilisant un fil de fixation de la sericine et etoffe tissee et/ou tricotee ainsi obtenue - Google Patents

Procede de production d'etoffes tissees et/ou tricotees utilisant un fil de fixation de la sericine et etoffe tissee et/ou tricotee ainsi obtenue Download PDF

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Publication number
WO1999007934A1
WO1999007934A1 PCT/JP1997/002741 JP9702741W WO9907934A1 WO 1999007934 A1 WO1999007934 A1 WO 1999007934A1 JP 9702741 W JP9702741 W JP 9702741W WO 9907934 A1 WO9907934 A1 WO 9907934A1
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WO
WIPO (PCT)
Prior art keywords
woven
knitted fabric
producing
scouring
sericin
Prior art date
Application number
PCT/JP1997/002741
Other languages
English (en)
Japanese (ja)
Inventor
Keiichiro Kanehisa
Original Assignee
Kanehisa Inc.
Sumitomo Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanehisa Inc., Sumitomo Corporation filed Critical Kanehisa Inc.
Priority to JP10535548A priority Critical patent/JP3061420B2/ja
Priority to US09/194,716 priority patent/US6302922B1/en
Priority to EP97934712A priority patent/EP1004699A4/fr
Priority to AU37831/97A priority patent/AU3783197A/en
Priority to KR1020007001217A priority patent/KR100338235B1/ko
Priority to PCT/JP1997/002741 priority patent/WO1999007934A1/fr
Publication of WO1999007934A1 publication Critical patent/WO1999007934A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines

Definitions

  • Silk is a protein from which sericin is removed, which is woven and knitted to produce a silk product.
  • fiproin which is a component of silk products, is presumed to have a plurality of fibrils in an ester bond, but has various problems due to weak bonding between the molecules of fipril.
  • Silk as a natural material cannot be said to have been completely elucidated scientifically, and there are many unknown fields. The same applies to cellulosic fibers (including cellulosic fiber yarns) produced from natural materials.
  • the present invention relates to a process for processing and processing raw silk, cellulosic fibers and their composite twisted yarns using a raw silk sericin fixing method, and forming a skeletal triazine in them to prevent shrinkage, shrinkage and form. It has improved stability. Hereinafter, weaving and knitting using these will be demonstrated.
  • sericin had a hard feel and was dull and shiny, and sericin was dissolved when dyed, making it difficult to use as a clothing fiber.
  • raw silk such as silk organza, siphon, sifted silk, and Fuji silk. It has a different look, feel, and performance from a woven or knitted fabric.
  • the sericin fixation method includes 1. Aldehydes
  • Chromium alum dichromate + reducing agent Alumina alum acrylyl aldehyde
  • formalins have a high risk to the human body and are not a preferred method due to their high risk.
  • the chromium salt method is not the best method, because the processing of epoxide resin is unstable due to various conditions such as industrial disposal and there is a concern that it may affect the human body such as skin disorders. .
  • the present invention is characterized in that a sericin fixing method based on a cyanuric chloride-based skeletal triazine which does not have such a problem is employed.
  • the invention described in Japanese Patent Publication No. 40-850 is a method of applying sericin to raw silk to prevent sericin from dissolving in ordinary refining (hot water), soap refining, and alkaline refining.
  • the patent invention of Japanese Patent No. 2559302 provides a method of processing five-in (silk) from which sericin has been removed.
  • Japanese Patent Publication No. 40-80050 describes a sericin fixing method using a reactive dye of cyanuric acid salt and a derivative thereof or a cyanuric acid derivative.
  • sericin is coated on the surface of silk fabric and silk fiber.
  • silk fabric that has not been subjected to sericin fixing sericin is dissolved by soap and alkali scouring.
  • the object is specified as a post-dyed silk product. In other words, it is a silk product having only a five-mouthed mouth.
  • the reason for avoiding the problems of the invention of Japanese Patent Publication No. 40-80050 and limiting it to post-dyed silk products is presumed to be as follows. In order to form skeletal triazine, 1% by weight of cyanuric chloride is applied to the weight of the thread, and sericin is fixed using ethylene tetrachloride as the medium.
  • the present invention solves and improves the above-mentioned problems of the prior art, and uses a sericin fixing method for raw silk to perform a skeletal triazine cross-linking reaction to modify a woven or knitted fabric, thereby improving shrink resistance and shrink resistance.
  • An object of the present invention is to provide a method for producing a woven or knitted fabric from which sericin has been removed by using special scouring after improving and improving the properties and morphological stability, and a woven or knitted fabric produced thereby. That is, it is impossible for a woven or knitted fabric modified by the sericin fixing method to dissolve 100% of sericin by ordinary scouring.
  • the swelling step which is an invention method developed by the inventor and already applied for a patent (Japanese Patent Application No. Hei 8-61825, PCT / JP96 / 011019).
  • a means to dissolve sericin in a special scouring method that includes an enzymatic scouring step Use a means to dissolve sericin in a special scouring method that includes an enzymatic scouring step.
  • the invention according to the first aspect of the present invention comprises a step of processing and treating raw silk and / or cellulosic fiber using a sericin fixing method for raw silk; and a step of processing and processing raw silk and / or cellulose fiber by a sericin fixing method. And woven and knitted using the ply-twisted yarn; swelling and swelling the woven and knitted fabric constituting the fabric by dipping in the tank; and swelling in the tank.
  • a process for enzymatic scouring of a woven or knitted material is provided, thereby providing a method for producing a woven or knitted material having a shrinkproof property, a shrinkproof property and a form stability of the woven or knitted material.
  • the raw silk is subjected to the sericin fixing method for the raw silk and Z or cellulosic fibers.
  • the yarn can be strongly twisted in the plying and twisting process, and the woven or knitted fabric has excellent shrinkage resistance, shrinkage resistance, and form stability.
  • sericin other than sericin in a part of the woven or knitted fabric is removed, and the fiber mouth is exposed to bring out the original characteristics of silk.
  • some sericin of the woven or knitted fabric remains around the fiber mouth to maintain the excellent shrinkproof property, shrinkproof property and form stability of the woven or knitted fabric.
  • the invention according to claim 2 is characterized in that the method further comprises, before the weaving and knitting step, a step of dyeing raw silk or cellulosic fiber.
  • the invention according to claim 3 is characterized in that the processing step using the sericin fixing method is carried out by using a reactive dye of cyanuric acid salt and a derivative thereof or a cyanuric acid derivative.
  • the invention according to claim 4 further comprises, after the enzyme scouring step, a finishing scouring step of washing out the enzyme adhering to the woven or knitted fabric, and in this finishing scouring step, the softening treatment and the water-repellent treatment are performed together. It is characterized by becoming.
  • the invention according to claim 5 further comprises the step of dyeing the scoured woven or knitted fabric after the enzyme scouring step. It is characterized by comprising a step of coloring.
  • a woven or knitted fabric manufactured by the method for manufacturing a woven or knitted fabric according to any one of the aforementioned items.
  • the invention according to the third aspect of the present invention is directed to the invention according to the first aspect of the present invention, wherein the yarn is processed and treated by using the sericin fixing method before weaving and knitting. It is characterized in that it is processed and processed using a sericin fixing method after it is made into a woven fabric.
  • the invention according to a fourth aspect of the present invention provides a woven or knitted fabric produced by the method for producing a woven or knitted fabric according to the third aspect of the present invention.
  • the invention according to the fifth aspect of the present invention relates to a composite twisted yarn of a raw yarn and a cellulosic fiber, while the above-described invention according to the first aspect of the present invention uses a raw yarn and a cellulose fiber. It is characterized in that it is used at least for warp or weft.
  • the invention according to a sixth aspect of the present invention provides a woven or knitted fabric produced by the method for producing a woven or knitted fabric according to the fifth aspect of the present invention.
  • FIG. 1 is a flowchart showing an embodiment of the method for producing a woven or knitted fabric according to the present invention.
  • FIG. 2 is a flowchart showing one embodiment of a method for producing a woven or knitted fabric according to another aspect of the present invention.
  • Fig. 3 shows the absolute value of the rust prevention test.
  • Fig. 4 shows changes in the time course of the soil prevention test.
  • Fig. 5 shows the absolute value of the rust prevention test.
  • Fig. 6 shows the change over time of the soil prevention test.
  • Fig. 7 shows the absolute value of the rust prevention test.
  • Fig. 8 shows the change over time of the rust prevention test.
  • Fig. 9 shows the absolute value of the rust prevention test.
  • FIG. 10 shows the change over time of the anti-shear test.
  • a method for producing a woven or knitted fabric having excellent shrinkage resistance, shrinkage resistance and form stability using a sericin-fixed yarn, a cellulosic fiber, or a composite twisted yarn thereof of raw silk according to the present invention, and a woven or knitted fabric produced thereby Will be described in detail.
  • the method for producing a woven or knitted fabric generally includes a yarn material preparation step (step 1), a processing / processing step using a sericin fixing method (step 2). ), A plying and twisting step (step 3), a weaving and knitting step (step 4), a swelling step of the woven and knitted article (step 5), and an enzymatic scouring step of the woven and knitted article (step 6). .
  • Raw yarn or cellulosic fiber or their composite twisted yarn is used as the yarn material. These yarn materials are processed and processed using the sericin fixing method.
  • the sericin fixing method is as described above.
  • the cyanuric acid salt and its derivative used in the invention according to Japanese Patent Publication No. 40-850 and the invention according to Patent No. 2559392, or cyanuric acid The method using a reactive dye of a derivative is preferred.
  • the raw silk and the fiber or cellulosic fiber processed and treated by the sericin fixing method are plied and twisted, for example, in the case of raw silk, sericin is wrapped around the fiber mouth.
  • the yarn can be strongly twisted because these yarns are fixed.They are woven and knitted using these twisted yarns as warp and / or weft yarns and picture yarns.
  • the knitting is therefore:
  • the shrink resistance has an anti-Shi Wa resistance and shape stability.
  • the woven or knitted fabric in this state has sericin settled on the fibroin surface and is rugged, without the luster and flexibility unique to silk. Therefore, in order to remove sericin, a special scouring method including a swelling step and an enzyme scouring step developed by the present inventor is performed to remove sericin other than sericin in a part of the woven or knitted fabric, thereby exposing the fibroid. On the other hand, some sericin of the woven or knitted fabric remains around the fiber mouth to maintain the excellent shrink-proof, shrink-proof and form stability of the woven or knitted fabric.
  • a dyeing step can be added simultaneously with the processing step using the sericin fixing method in step 2. Before sericin fixation, dyeing is uniformly and neatly finished. Alternatively, or after dyeing before the weaving and knitting process, and after the enzymatic scouring step of step 6, the scoured A dyeing step can be added. Sericin located on the front and back surfaces of the woven or knitted fabric is removed from around the fibroin, and thus has the advantage of dyeing the woven or knitted fabric neatly.
  • a finishing scouring step for washing out the enzyme attached to the woven or knitted fabric can be added.
  • the softening treatment and the water-repellent treatment are preferably performed together in the finishing scouring step.
  • the feature of the present invention is that, while the above-described invention according to the first aspect of the present invention processes and treats the yarn using the sericin fixing method before weaving and knitting, the yarn is woven and knitted into a woven or knitted fabric. The point is that it is later processed and processed using the sericin fixing method.
  • the method for producing a woven or knitted fabric according to this embodiment generally includes a weaving or knitting process (step 11), a processing and treatment process using the sericin fixing method (step 12), and a swelling of the woven or knitted fabric.
  • a step (step 13) and an enzyme scouring step of the woven or knitted fabric (step 14) are provided.
  • Woven and knitted fabrics use raw yarns or cellulosic fibers, or their composite twisted yarns, to carry out known processes, such as soaking drying, spinning, priming, ply-twisting, and ply-twisting and setting. Weaving and knitting.
  • the woven or knitted fabric is processed using a sericin fixing method for raw silk. Processing using the sericin fixing method.
  • the processing step, the swelling step of the woven or knitted material, the enzyme scouring step, the dyeing step and the finishing scouring step can be the same as those in the first embodiment described above.
  • a raw yarn and a composite twisted yarn of raw yarn and cellulosic fiber were prepared (step 1).
  • the yarn was twisted and twisted while protecting the fiber mouth using the sericin fixing method (Step 3), and the high-speed weaving was performed while avoiding the thread (Step 4).
  • the sericin fixation method is performed, sericin cannot be dissolved by ordinary soap or alkaline scouring, so special techniques including a swelling process (step 5) and an enzyme scouring process (step 6) developed by the present inventor are proposed. Sericin was dissolved by a scouring method.
  • step 5 these fabrics were immersed in alkali potassium bicarbonate (hot water in which solvents such as Rasen Power I and II were dissolved) and swelled to increase the volume of the yarn.
  • step 6 sericin was dissolved using an auxiliary agent capable of degrading sericin, for example, alcalase, ceria-lase, and the like, and then finishing scouring was performed.
  • Table 1 shows the results of the shrinkage test conducted for the following fabrics at the Kyoto Prefectural Textile Guidance Center (Tanba, Minamiyama-cho, Nakafu-gun, Kyoto Prefecture) for the following fabrics. And changes over time. Each test was performed according to the method described below.
  • the woven or knitted fabric (sample C, D, E) produced by the method of the present invention has a lower shrinkage rate than a conventional post-dyed fabric (sample B) which has been subjected to ordinary soap and alkali scouring. Improved the anti-shear test. Improved. It was demonstrated that these effects were obtained only by applying the sericin fixing method to the weft yarn.
  • the fabric of the conventional method (sample A) using 31/2 pieces of warp and 31 knits of weft 31-6 yarns has a smaller shrinkage rate of the warp than the fabric of the conventional method (sample B). Is effective.
  • the sea recovery rate is significantly worse than B in Table 1.
  • Tables 1 and 2 show the results of the shrinkage test performed on each of the above cloths, and FIGS. 7 and 8 show the absolute value of the anti-shear test and changes over time.
  • plain plain crepe was woven using the following raw silk, and a sericin fixing method was tried on the woven fabric.
  • the ground of @ ⁇ produced in this way is plain weave, in the order of @ ® ⁇ ®, the ground and picture are rotated at 150 rpm, and Tango crepe is made by Dobby loom of Tsuda Koma Co., Ltd. (Originally plain crepe).
  • Table 4 shows the results of the shrinkage rate test performed on each of the above-mentioned cloths.
  • FIGS. 9 and 10 show the absolute value and the change over time of the anti-shear test.
  • the traditional plain crepe is manufactured through various traditional and complicated processes to produce flexible kimono with grain.
  • the traditional traditional textiles are soap and alkali scouring, which dissolves sericin, so the resilience and shrinkage of cedar have not been improved.
  • the product of the present invention in which sericin was fixed to the fabric had improved morphological stability in terms of both skin recovery and shrinkage resistance.
  • the fabric carried out by the sericin fixing method has improved the fastness several times more than the conventional fabric without deteriorating the characteristics of silk. * Improved, and the reactive dye is also applied to silk fabric. This has demonstrated further morphological stability.
  • the method for fixing sericin to raw silk comprises Improvement ⁇ I was able to prove that it was improved.
  • the cross-linking reaction to the skeletal triazine in the sericin fixing method of the present invention improves the shrinkage resistance, the anti-shrinkage property and the morphological stability of the new thread in cooperation with the special scouring, swelling and enzyme scouring according to the method of the present invention It has been demonstrated that the manufacturing method can be improved. Second, we demonstrated that this sericin fixation method could be applied to cellulosic fibers as well as silk, and improved and improved the properties of each other's fibers.
  • the processing of textiles of the new character includes epoxy resin and urethane resin processing. Furthermore, there are also memory-shaped fabrics using formalin, ammonia, and the like. However, these textile processing methods are not useful due to the effects on the human body, the global environment, and the destruction of the ozone layer. On the other hand, a skin patch test was performed on the woven fabric produced by the method of the present invention on 20 testers, and a semi-negative determination was obtained, indicating that there was no effect on the human body.
  • the sericin fixing method is useful for the industrial use of the present invention.
  • the use of dichlorotriazine.monochlorotriazine reactive dyes demonstrates the improvement and improvement of discoloration and discoloration and contamination. Is extremely high. table 1

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

On reforme des étoffes tissées et/ou tricotées au moyen d'une réaction de réticulation de la triazine du squelette en faisant appel à la méthode de fixation de la séricine de la soie brute et ce, afin de renforcer l'irrétrécissabilité, l'auto-défroissabilité et la stabilité des formes de l'étoffe. L'opération achevée, on retire la séricine grâce à un raffinage spécifique. Le procédé de production de ces étoffes tissées et/ou tricotées consiste à transformer et à traiter la soie brute et/ou la fibre cellulosique en faisant intervenir la méthode de fixation précitée, à doubler et à torsader la soie brute et/ou la fibre cellulosique ainsi transformées et traitées à l'aide de la méthode de fixation, à tisser et à tricoter l'étoffe avec les fils ainsi doublés et torsadés, à faire gonfler l'étoffe tissée et/ou tricotée constituant une pièce de vêtement en l'immergeant dans une cuve et, enfin, à procéder à un raffinage enzymatique de l'étoffe dans la cuve. Ce procédé confère à l'étoffe tissée et/ou tricotée des qualités d'irrétrécissabilité, d'auto-défroissabilité et de stabilité des formes.
PCT/JP1997/002741 1996-02-23 1997-08-07 Procede de production d'etoffes tissees et/ou tricotees utilisant un fil de fixation de la sericine et etoffe tissee et/ou tricotee ainsi obtenue WO1999007934A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP10535548A JP3061420B2 (ja) 1997-08-07 1997-08-07 生糸のセリシン定着糸を用いた織編物の製造方法
US09/194,716 US6302922B1 (en) 1996-02-23 1997-08-07 Process for manufacturing woven or knit fabrics having excellent shrink and crease resistance and shape stability by using sericin fixed yarns of raw silks and the woven or knit fabrics manufactured by the same process
EP97934712A EP1004699A4 (fr) 1997-08-07 1997-08-07 Procede de production d'etoffes tissees et/ou tricotees utilisant un fil de fixation de la sericine et etoffe tissee et/ou tricotee ainsi obtenue
AU37831/97A AU3783197A (en) 1997-08-07 1997-08-07 Method of production of woven/knitted fabrics using sericin fixation yarn and woven/knitted fabric produced by the method
KR1020007001217A KR100338235B1 (ko) 1997-08-07 1997-08-07 세리신이 정착된 생사를 이용한 제직물 또는 편성물의제조 방법 및 이 방법으로 제조된 제직물 또는 편성물
PCT/JP1997/002741 WO1999007934A1 (fr) 1997-08-07 1997-08-07 Procede de production d'etoffes tissees et/ou tricotees utilisant un fil de fixation de la sericine et etoffe tissee et/ou tricotee ainsi obtenue

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1997/002741 WO1999007934A1 (fr) 1997-08-07 1997-08-07 Procede de production d'etoffes tissees et/ou tricotees utilisant un fil de fixation de la sericine et etoffe tissee et/ou tricotee ainsi obtenue

Publications (1)

Publication Number Publication Date
WO1999007934A1 true WO1999007934A1 (fr) 1999-02-18

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PCT/JP1997/002741 WO1999007934A1 (fr) 1996-02-23 1997-08-07 Procede de production d'etoffes tissees et/ou tricotees utilisant un fil de fixation de la sericine et etoffe tissee et/ou tricotee ainsi obtenue

Country Status (5)

Country Link
EP (1) EP1004699A4 (fr)
JP (1) JP3061420B2 (fr)
KR (1) KR100338235B1 (fr)
AU (1) AU3783197A (fr)
WO (1) WO1999007934A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055756A (zh) * 2019-05-07 2019-07-26 四川丝玛帛科技有限公司 蚕丝的多维交联固胶方法
CN114622412A (zh) * 2022-03-02 2022-06-14 杭州路先非织造股份有限公司 一种热粘合制备丝胶整理水刺非织造布的方法

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Publication number Priority date Publication date Assignee Title
GB0126118D0 (en) 2001-10-31 2002-01-02 Vollrath Friedrich W L Precursor feedstock for forming filaments
KR100443462B1 (ko) * 2002-02-28 2004-08-09 성광물산(주) 티셔츠의 에리 형태안정화 가공방법
KR100693384B1 (ko) * 2005-06-24 2007-03-09 한양대학교 산학협력단 폴리락틱애시드 섬유의 정련방법
NZ592338A (en) 2008-09-26 2012-11-30 Oncomed Pharm Inc Frizzled-binding agents and uses thereof
KR100933549B1 (ko) 2009-05-07 2009-12-23 정은주 실크생사를 이용한 편직용 실크사 및 그 실크사에 의한 실크원단과 실크편직제품

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JPS50126909A (fr) * 1974-03-29 1975-10-06
JPS5520034B2 (fr) * 1972-04-18 1980-05-30
JPS63126910A (ja) * 1986-11-11 1988-05-30 Satoshi Aoki 絹繊維の再生方法
JPH0411084A (ja) * 1990-04-28 1992-01-16 Kanebo Ltd 特殊表面絹布およびその製造方法
JPH0995865A (ja) * 1995-09-27 1997-04-08 Heian Yushi Kagaku Kogyo Kk セリシン定着繭及びセリシン定着糸
JPH09119033A (ja) * 1995-10-27 1997-05-06 Matsuoka Kigyo Kk 潜在捲縮性生糸およびその製造方法、ならびにその潜在捲縮性生糸から得られる捲縮性絹糸

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JPS5520034B2 (fr) * 1972-04-18 1980-05-30
JPS50126909A (fr) * 1974-03-29 1975-10-06
JPS63126910A (ja) * 1986-11-11 1988-05-30 Satoshi Aoki 絹繊維の再生方法
JPH0411084A (ja) * 1990-04-28 1992-01-16 Kanebo Ltd 特殊表面絹布およびその製造方法
JPH0995865A (ja) * 1995-09-27 1997-04-08 Heian Yushi Kagaku Kogyo Kk セリシン定着繭及びセリシン定着糸
JPH09119033A (ja) * 1995-10-27 1997-05-06 Matsuoka Kigyo Kk 潜在捲縮性生糸およびその製造方法、ならびにその潜在捲縮性生糸から得られる捲縮性絹糸

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Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110055756A (zh) * 2019-05-07 2019-07-26 四川丝玛帛科技有限公司 蚕丝的多维交联固胶方法
CN114622412A (zh) * 2022-03-02 2022-06-14 杭州路先非织造股份有限公司 一种热粘合制备丝胶整理水刺非织造布的方法
CN114622412B (zh) * 2022-03-02 2023-08-01 杭州路先非织造股份有限公司 一种热粘合制备丝胶整理水刺非织造布的方法

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AU3783197A (en) 1999-03-01
KR20010022623A (ko) 2001-03-26
JP3061420B2 (ja) 2000-07-10
KR100338235B1 (ko) 2002-05-27
EP1004699A4 (fr) 2000-11-08
EP1004699A1 (fr) 2000-05-31

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