WO1998050806A1 - Brightness enhancement article - Google Patents

Brightness enhancement article Download PDF

Info

Publication number
WO1998050806A1
WO1998050806A1 PCT/US1998/009278 US9809278W WO9850806A1 WO 1998050806 A1 WO1998050806 A1 WO 1998050806A1 US 9809278 W US9809278 W US 9809278W WO 9850806 A1 WO9850806 A1 WO 9850806A1
Authority
WO
WIPO (PCT)
Prior art keywords
brightness enhancement
cross
major surface
prisms
enhancement article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1998/009278
Other languages
English (en)
French (fr)
Inventor
Bettie C. Fong
Wade D. Kretman
Keith M. Kotchick
Sanford Cobb, Jr.
Richard A. Miller
Todd R. Williams
Kazuhiko Toyooka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Priority to KR1019997010317A priority Critical patent/KR100605430B1/ko
Priority to JP54847298A priority patent/JP2001524225A/ja
Priority to DE69804208T priority patent/DE69804208T2/de
Priority to EP98921006A priority patent/EP0980533B1/en
Priority to CA002288093A priority patent/CA2288093C/en
Priority to BR9808760-6A priority patent/BR9808760A/pt
Priority to AU73708/98A priority patent/AU735173B2/en
Publication of WO1998050806A1 publication Critical patent/WO1998050806A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/04—Prisms
    • G02B5/045—Prism arrays

Definitions

  • This invention relates to enhancing the on-axis luminance (referred to here as "brightness") of a diffuse lighting device.
  • Displays used in devices such as computers feature a material such as a liquid crystal composition and a light source for back-lighting the material. Films disposed between the back light and the display have been used to enhance the brightness of the display by controlling the exit angles of light.
  • the invention features a brightness enhancement article that includes: (a) a transparent, flexible substrate; (b) a first major surface that includes an array of linear prisms having blunted or rounded peaks; and (c) a second major surface characterized by a plurality of light scattering protrusions. These protrusions imbue the surface with a matte appearance.
  • the peaks are characterized by a chord width, cross-sectional pitch width, and radius of curvature in which the chord width is equal to about 20-40% of the cross-sectional pitch width and the radius of curvature is equal to about 20-50% of the cross-sectional pitch width.
  • the article has a haze value between about 20-60% and a transmission value no greater than about 94% when measured under conditions in which the first surface has a substantially planar topography.
  • the prisms are preferably characterized by a root angle ranging from about 70E to about 110E, more preferably from about 85E to about 95E. Root angles of about 90E are particularly preferred.
  • the second major surface is integral with the substrate (e.g., the protrusions may be in the form of "bumps" made of the substrate material).
  • the second major surface is defined by a layer that includes a resin provided on the substrate.
  • the protrusions may be in the form of particles dispersed in the resin layer, or may be integral with the resin layer itself (e.g., they may be in the form of "bumps" made of the resin).
  • the first major surface of the article is integral with the substrate.
  • the haze and transmission values are measured by applying a material such as an index-matching oil to the first major surface to fill in the "valleys" between the blunted or rounded peaks to render the surface substantially planar.
  • the first major surface is defined by a separate layer that includes a resin provided with the above-described prisms.
  • the haze and transmission values are measured on the article prior to application of this resin layer.
  • the invention also features a method of enhancing the brightness of a uniform, diffusely-emitting, lighting device that includes placing the above- described brightness enhancement article substantially parallel to a light-emitting surface of the device.
  • the invention further features a uniform, diffusely-emitting, lighting device that includes the above-described brightness enhancement article.
  • Examples of preferred devices include back-lit displays such as back-lit liquid crystal displays.
  • the invention provides a brightness enhancement article having a matte appearance that exhibits good gain, wide viewing angles in both horizontal and vertical planes, soft cut-off, and good abrasion resistance.
  • the matte appearance also helps mask cosmetic imperfections in the article, as well as the device with which the article is used, such as scratches, white spots, and stains which may arise during manufacture or installation.
  • FIG. 1 is a cross-sectional view of a multi-layer brightness enhancement article.
  • FIG. 2 is a cross-sectional view of a monolithic brightness enhancement article. Description of the Preferred Embodiments
  • the brightness enhancement article features a flexible, transparent base layer and two distinct surfaces, each having a topography designed to act in concert to perform the function of controlling the exit angles of light emitted from a back- lit display where the article is placed substantially parallel to a light-emitting surface of the article.
  • the article may take several forms. Referring to FIG. 1 , there is shown a multi-layer brightness enhancement article 10.
  • Article 10 includes a flexible, transparent base layer 12 provided with two separate layers 14, 16 on opposite surfaces of layer 12.
  • Layer 12 is typically a thin, flexible, polymeric layer made of a material such as polyethylene terephthalate, polymethyl methacrylate, or polycarbonate.
  • the thickness of layer 12 preferably is in the range of about 25 to about 500 microns.
  • the thickness of layer 14 preferably is in the range of about 1 to about 50 microns.
  • the purpose of layer 14 is to provide a light-diffusing surface.
  • layer 14 includes a plurality of elements 18 protruding from the surface of layer 14. As shown in FIG. 1, these elements are preferably particles dispersed in a polymeric resin. Examples of suitable particles include silica, alumina, calcium carbonate, and glass and plastic beads.
  • the elements may also be in the form of "bumps" formed from the resin itself or from a different material and deposited on the surface of layer 14; an example of the former is commercially available from A.G. Bayer of Germany under the trade designation "Makr ⁇ fol.”
  • the size, size distribution, and loading of elements 18 are selected to provide a matte surface with light-diffusing ability, as indicated by the haze and percent transmission of article 10 measured in the absence of layer 16 according to ASTM D- 1003-95 using a Haze-Gard Plus haze meter commercially available from Byk-Gardner of Silver Spring, MD.
  • the haze is between about 20-60% and the percent transmission is not greater than about 94%.
  • Articles featuring a flexible, transparent base layer provided with a layer of resin having a series of particles protruding from its surface are commercially available from Tekra, Inc., New Berlin, WI, under the designation "MarnotTM XL Matte Melinex R Film” and "MarnotTM XL Matte Lexan R Film.”
  • the MarnotTM XL Matte Melinex R Film in grades 55 GU, 35 GU, and 20 GU have been found to be suitable.
  • the thickness of layer 16 preferably is in the range of about 10 to about
  • Layer 16 acts in concert with layer 14 to control the angles at which the light is emitted.
  • Layer 16 is preferably a layer of polymer resin provided with a topography designed to achieve this purpose. Suitable resins include the u.v.- polymerized products of acrylate and/or methacrylate monomers.
  • One particularly preferred resin is the u.v.-polymerized product of a brominated, alkyl-substituted phenyl acrylate or methacrylate (e.g., 4,6-dibromo-2-sec-butyl phenyl acrylate), a methyl styrene monomer, a brominated epoxy diacrylate, 2-phenoxyethyl acrylate, and a hexa-functional aromatic urethane acrylate oligomer, as described in Fong et al., U.S.S.N. , entitled "Chemical Composition and Polymers and Polymeric Material Derived Therefrom,” filed concurrently herewith, which is assigned to the same assignee as the present application and incorporated herein by reference.
  • a brominated, alkyl-substituted phenyl acrylate or methacrylate e.g., 4,6-dibromo-2-sec-butyl phenyl acryl
  • the topography of layer 16 is characterized by an array of linear prisms having blunted or rounded peaks 20 characterized by a chord width 22, cross- sectional pitch width 24, radius of curvature 26, and root angle 28 in which the chord width is equal to about 20-40% of the cross-sectional pitch width and the radius of curvature is equal to about 20-50% of the cross-sectional pitch width.
  • the root angle ranges from about 70-110E, preferably from about 85-95E, with root angles of about 90E being particularly preferred.
  • the placement of the prisms within the array is selected to maximize the desired optical performance.
  • the prisms may be arranged to form a plurality of alternating zones having peaks that are spaced at different distances from an arbitrarily selected, common reference plane, as described in Wortman et al., U.S.S.N.
  • the topography is preferably imparted onto the surface of the resin according to the processes described in Lu et al., U.S. Patent No. 5,175,030 and Lu, U.S. Patent No. 5,183,597. Specifically, the resin composition is contacted with a master bearing a negative of the desired topography. The resin composition is then cured, e.g., by exposure to ultraviolet radiation, while in contact with the master to impart the desired topography to the resin surface.
  • the brightness enhancement article may also be in the form of a monolithic article, as shown in FIG. 2.
  • brightness enhancement article 30 features a flexible, base layer 32 having a pair of opposed surfaces 34, 36, both of which are integrally formed with base layer 32.
  • Suitable materials for layer 32 are the same as those described above in the case of layer 12 of multi-layer article 10.
  • Surface 34 features a series of protruding light-diffusing elements 38. These elements may be in the form of "bumps" in the surface made of the same material as layer 32.
  • Surface 36 features an array of linear prisms having blunted or rounded peaks 40 integrally formed with base layer 32.
  • these peaks are characterized by a chord width 42, cross-sectional pitch width 44, radius of curvature 46, and root angle 48 in which the chord width is equal to about 20- 40% of the cross-sectional pitch width and the radius of curvature is equal to about 20-50% of the cross-sectional pitch width.
  • the root angle ranges from about 70- 110E, preferably from about 85-95E, with root angles of about 90E being particularly preferred.
  • the placement of the prisms within the array is selected to maximize the desired optical performance.
  • topography characterizing surface 36 is not critical.
  • One useful molding process is described in Benson et al., U.S.S.N. 08/472,444, filed June 7, 1995, entitled “Ultra-Flexible Retroreflective Cube Corner Composite Sheetings and Methods of Manufacture," which is assigned to the same assignee as the present application and hereby incorporated by reference.
  • the haze and transmission values are measured by applying a material such as an index-matching oil to the peak-bearing surface to fill in the "valleys" between the blunted or rounded peaks and thereby render the surface substantially planar.
  • Suitable oils have a refractive index substantially equal to the refractive index of the surface. The haze and transmission measurements are then made in accordance with ASTM D- 1003-95 using the Haze-Gard Plus haze meter.
  • a photopolymerizable resin was prepared combining a brominated epoxy acrylate (available from UCB-Radcure of Smyrna, GA under the designation “RDX 51027”) (52 parts) and 2-phenoxy-ethyl acrylate (available from Henkel Corp., Ambler, PA, under the designation "Photomer 4035”) (9 parts), and heating at 100EC to soften the brominated epoxy acrylate, after which the two components were mixed until fluid.
  • RDX 51027 2-phenoxy-ethyl acrylate
  • methyl styrene available from Monomer-Polymer & Dajac Laboratories, Inc., Feasterville, PA as a 70:30 mixture of meta- and para- isomers
  • 4,6-dibromo-2-sec-butyl phenyl acrylate prepared as described in Olson, U.S.S.N.
  • MarnotTM XL Matte Melinex R 55 GU film available from Tekra Corp., New Berlin, WI
  • a knife coater to yield a resin coating having a thickness of 25 microns.
  • the coated film was then placed in contact with a master bearing a micro-fine prismatic pattern.
  • the master and film were heated to 130EF, and then passed under an ultraviolet lamp (300 watts/in 2 ) at a speed of 20-25 ft/min. to cure the resin and simultaneously replicate the prismatic pattern of the master on the resin surface.
  • chord width 16.8 microns radius 14.8 microns root angle 90 degree pitch 50 microns chord width/pitch 33.6%
  • “Gain” refers to the ratio of the brightness of a backlit display equipped with a brightness enhancing film to the brightness of the display in the absence of the film.
  • the "viewing angle” is the angle at which the on-axis brightness drops by 50%. It is measured in both the horizontal plane (i.e., in a plane parallel to the long axis of the prisms forming one surface of the brightness enhancement film) and the vertical plane (i.e., in a plane perpendicular to the long axis of the prisms).
  • the gain and viewing angles of the film were measured using an Eldim EZ Contrast Conoscopic Measurement Device (available from Eldim Co. of Caen, France) equipped with a Sharp STN backlight model C12P (available from Sharp Co. of Tokyo, Japan) as the backlighting source.
  • the Conoscopic Measurement Device provides a plot of gain versus viewing angle in both the vertical and horizontal planes. The maximum slope of the curve provides a measure of the "softness" of the brightness cut-off, with smaller slopes being desirable. The results are as follows: Gain 1.30
  • a film was prepared according to Example 1 except that the film was a Tekra MarnotTM XL Matte Melinex R 20 GU film. Following cure, the film was separated from the master to yield a product having a surface characterized as follows: chord width : 10.4 microns radius : 10.5 microns root angle 90 degree pitch 50 microns chord width/pitch 20.8%
  • the article may feature a base in which the blunted or rounded peaks are integrally formed with the base and the matte surface is provided in the form of a separate resin layer on the base.
  • the matte surface may be integrally formed with the base and the peak-bearing surface provided in the form of a resin layer.
  • the brightness enhancement article may be combined with one or more additional brightness enhancement articles.
  • additional articles may be the same or different from the original article.
  • the article may be combined with a second brightness enhancement article having prisms terminating in pointed peaks, rather than a rounded or blunt peaks.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Non-Portable Lighting Devices Or Systems Thereof (AREA)
PCT/US1998/009278 1997-05-09 1998-05-06 Brightness enhancement article Ceased WO1998050806A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
KR1019997010317A KR100605430B1 (ko) 1997-05-09 1998-05-06 휘도 향상 물품, 휘도 향상 방법, 및 상기 물품을 포함하는 장치
JP54847298A JP2001524225A (ja) 1997-05-09 1998-05-06 輝度向上物品
DE69804208T DE69804208T2 (de) 1997-05-09 1998-05-06 Helligkeitssteigerer
EP98921006A EP0980533B1 (en) 1997-05-09 1998-05-06 Brightness enhancement article
CA002288093A CA2288093C (en) 1997-05-09 1998-05-06 Brightness enhancement article
BR9808760-6A BR9808760A (pt) 1997-05-09 1998-05-06 Artigo de realce de brilho, processo para realçar o brilho de um dispositivo de iluminação uniforme, e, dispositivo
AU73708/98A AU735173B2 (en) 1997-05-09 1998-05-06 Brightness enhancement article

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/853,261 US6280063B1 (en) 1997-05-09 1997-05-09 Brightness enhancement article
US08/853,261 1997-05-09

Publications (1)

Publication Number Publication Date
WO1998050806A1 true WO1998050806A1 (en) 1998-11-12

Family

ID=25315531

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/009278 Ceased WO1998050806A1 (en) 1997-05-09 1998-05-06 Brightness enhancement article

Country Status (10)

Country Link
US (1) US6280063B1 (enExample)
EP (1) EP0980533B1 (enExample)
JP (1) JP2001524225A (enExample)
KR (1) KR100605430B1 (enExample)
CN (1) CN1144068C (enExample)
AU (1) AU735173B2 (enExample)
BR (1) BR9808760A (enExample)
CA (1) CA2288093C (enExample)
DE (1) DE69804208T2 (enExample)
WO (1) WO1998050806A1 (enExample)

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KR100605430B1 (ko) 2006-07-28
CN1144068C (zh) 2004-03-31
DE69804208D1 (de) 2002-04-18
AU7370898A (en) 1998-11-27
DE69804208T2 (de) 2002-07-18
CN1255202A (zh) 2000-05-31
CA2288093A1 (en) 1998-11-12
AU735173B2 (en) 2001-07-05
EP0980533A1 (en) 2000-02-23
US6280063B1 (en) 2001-08-28
KR20010012365A (ko) 2001-02-15
BR9808760A (pt) 2000-07-11
JP2001524225A (ja) 2001-11-27
CA2288093C (en) 2002-10-08
EP0980533B1 (en) 2002-03-13

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