WO1998038977A1 - Kombination von erythrulose und einem reduzierenden zucker mit selbstbräunungseigenschaften - Google Patents
Kombination von erythrulose und einem reduzierenden zucker mit selbstbräunungseigenschaften Download PDFInfo
- Publication number
- WO1998038977A1 WO1998038977A1 PCT/CH1998/000083 CH9800083W WO9838977A1 WO 1998038977 A1 WO1998038977 A1 WO 1998038977A1 CH 9800083 W CH9800083 W CH 9800083W WO 9838977 A1 WO9838977 A1 WO 9838977A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- erythrulose
- self
- reducing sugar
- active ingredient
- tanning
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/04—Preparations for care of the skin for chemically tanning the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Definitions
- the present invention relates to a combination of erythrulose in D or L form or as a racemate and at least one further reducing sugar with self-tanning properties and to cosmetic compositions containing them for artificially tanning the skin.
- the cosmetic compositions bring about a more uniform and longer lasting coloring of the skin and reduce its drying out and irregular desquamation compared to known compositions, which e.g. Contain dihydroxyacetone alone.
- Hydroxyketones and hydroxyaldehydes are well-known active ingredients for self-tanners.
- the active ingredients usually processed in creams react with free amino groups of the stratum corneum and result in brownish-colored dyes which are bound to proteins of the stratum corneum.
- This reaction known as the Maillard reaction, of reducing sugars with amino acids, peptides or proteins leads to compounds having a carbonyl function which polymerize to brown melanoids.
- DHA dihydroxyacetone
- Erythrulose itself can also be used as the sole active ingredient for lightly tanning day creams.
- Erythrulose is a C4-keto sugar of the general structural formula 1, 3, 4-trihydroxy-butan-2-one, which occurs naturally or can be produced chemically or biotechnologically in a manner known per se. Erythrulose can be used in D or L form or as a racemate.
- DHA is a C3 keto sugar of the general structural formula 1, 3-dihydroxy-propan-2-one, which can be prepared in a manner known per se.
- reducing sugars with self-tanning properties that can be used in combination with erythrulose are e.g. Glucose, xylose, fructose, reose, ribose, arabinose, allose, tallose, old rose, mannose, galactose, lactose, sucrose, erythrose and glyceraldehyde.
- the combination of active ingredients contains a ratio between erythrulose and reducing sugar of approximately 10: 1 to 1 : 10, preferably about 1: 1 to 1: 3, particularly preferably 1: 2.
- erythrulose and about 1-15% reducing sugar preferably about 1.5% erythrulose and 3.5% reducing sugar, are used.
- the stability of erythrulose with a reducing sugar in a cosmetic formulation depends on many factors.
- the combination of active ingredients can be used both in 0 / W (e.g. cream or lotions) and W / O emulsions and other cosmetic formulation types (e.g. multiple emulsions, such as 0 / w / ⁇ or W / ⁇ / W emulsions, gels, ointments , Aerosols) are used.
- the stability of the active ingredients can be determined quantitatively by chromatography. For this purpose, the emulsion is diluted, membrane filtered and analyzed by means of HPLC.
- the oily phase in emulsions can e.g. KW oils such as paraffin oil or mineral oils, waxes such as beeswax or paraffin wax, silicone oils such as cyclomethicone or dimethicone, fatty alcohols such as stearyl alcohol or cetyl alcohol, natural oils such as jojoba oil, sesame oil or sunflower oil, fatty acid esters such as isopropyl myristate or glyceryl stearate or mono-glyceryl stearate or mono-glyceryl stearate or mono-glyceryl stearate or mono-glyceryl stearate or mono-glyceryl stearate or mono-glyceryl stearate or mono-glyceryl stearate or mono-glyceryl stearate or mono- , such as Caprylic / capric acid triglyceride.
- KW oils such as paraffin oil or mineral oils, waxes such as bees
- the oil phase preferably comprises 5-45% by weight, in particular approximately 10-30% by weight, of the total formulation.
- Emulsifiers known per se for oil-in-water and water-in-oil emulsions can be used as emulsifiers, such as, for example, silicones, sesquioleates, sorbitan esters, alkoxylated sorbitan and fatty acid esters, alkoxylated mono-, di- and triglycerides, optionally alkoxylated Polymers such as cross-polymers from ethylene oxide and Propylene oxide, optionally alkoxylated fatty alcohols, fatty acids, esters of natural oil derivatives, ethers such as polyethylene glycol (n) stearyl ether and polyethylene cetyl (n) stearyl ether.
- the emulsifiers are preferably used in amounts of 0.1-15% by weight, based on the overall formulation.
- the formulations according to the invention can also contain further auxiliaries, such as e.g. Stabilizers such as mannitol or cyclodextrin, humectants such as glycerin and propylene glycol, thickeners such as acrylic acid polymers or cellulose derivatives, antioxidants such as tocopheryl acetate, pH correcents such as sodium phosphate, film formers such as PVP, preservatives such as phenoxyethanol and paraben, dyes, fragrances, plasticizers, antiseptics, antiseptics Vitamins, pigments, propellants, as well as other compounds that are cosmetically or medically desirable. Examples of such other compounds can be found in the CTFA International Cosmetic Ingredient Dictionary, 6th Edition, The Cosmetic, Toiletry and Fragrance Association, Inc., Washington D.C., 1995.
- Lipophilic systems are generally more suitable for cosmetic formulations for self-tanners.
- tanning can be accelerated and the color intensity increased significantly.
- Dimethicone, cyclomethicone, propylene glycol dipelargonate, propylene glycol or ethoxydiglycol have proven to be suitable penetration accelerators.
- the measured color intensity was up to 55% higher for formulations containing penetration accelerators compared to the basic formulation without penetration accelerators.
- Synthetic oils such as Miglyol 812, isoppropyl palmitate and silicone oils and natural lipids such as jojoba oil and sesame oil go particularly well with the combination of active ingredients and are therefore preferred.
- Gels can also be used as the formulation basis for the compositions according to the invention. Carbomers, cellulose derivatives and other gel formers can be contained as gel-forming substances.
- the cosmetic formulation is to offer both a self-tanning effect and protection against the sun's rays
- the formulation can also be provided with one or more sun protection filters, such as e.g. Add octyl methoxy cinnamate and / or butyl methoxydibenzoyl methane.
- the active ingredients are only added at lower temperatures of around ⁇ 40 ° C and that the pH value 5 in the cosmetic formulations is not exceeded, which can be easily accomplished by buffering.
- the cosmetic formulations based thereon can be applied to human skin in the customary manner.
- a self-tanning body lotus is produced by using an oily phase made from 12.00% Cutina GMS (glyceryl stearate), 1.50% Eumulgin B1 (Ceteareth-12), 1.50% Eumulgin B2 (Ceteareth-20), 4 , 00% isopropyl myristate, 7.00% paraffin oil and 4.00 Miglyol 812 (caprylic / capric acid triglyceride) mixed together and heated to 70 ° C and an aqueous phase from 51.20% demineralized water, 0.50% phenonip and 3.00% glycerin mixed together and heated to 75 ° C.
- the aqueous phase is then stirred with the added oily phase and cooled to 50 ° C, homogenized and further cooled to 30 ° C and added to the mixture a further aqueous phase of 10.00% demineralized water, 1.50% erythrulose and 3.50% dihydroxyacetone and stirred cold. This creates a comfortable body lotus.
- a self-tanning white lotion is produced by using an oily phase made from 1.50% Arlatone 983 S (PEG-5 glyceryl stearate), 2.20% Arlatone 985 (PEG-5 glyceryl stearate), 1.50% Brij 76 ( Steareth-10), 5.00% Miglyol 812 (caprylic / capric acid triglyceride), 4.00% paraffin oil and 1.00% silicone oil AK 500 (Dimethicone) mixed and heated to 70 ° C and an aqueous phase from 59, 30% demineralized water, 0.50% phenonip and 10.00% propylene glycol are mixed together and heated to 75 ° C.
- an oily phase made from 1.50% Arlatone 983 S (PEG-5 glyceryl stearate), 2.20% Arlatone 985 (PEG-5 glyceryl stearate), 1.50% Brij 76 ( Steareth-10), 5.00% Miglyol 812 (caprylic
- the aqueous phase is then added while stirring the oily phase and cooled to 50 ° C., homogenized and further cooled to 30 ° C., and the mixture is given a further aqueous phase composed of 10.00% demineralized water, 1.50% erythrulose and 3.50 % Dihydroxyacetone added and stirred cold.
- the result is a lottery that can be used comfortably.
- a self-tanning white lotus is produced analogously to Example 2, with the exception that 3.00% erythrulose and 2.00% DHA are used. As in Example 2, this creates a pleasantly usable lottery.
- a self-tanning cream is prepared by using an oily phase composed of 1.00% Cre ophor A6 (Ceteareth 6 and stearyl alcohol), 1.00% Cremophor A25 (Ceteareth 25), 3.00 % Cutina GMS (glyceryl stearate), 10.00% paraffin oil, 5.00% jojobaol and 1.00% cetyl alcohol mixed together and heated to 70 ° C and an aqueous phase from 48.50% demineralized water, 0.50% phenonip and 5.00% propylene glycol mixed together and heated to 75 ° C.
- an oily phase composed of 1.00% Cre ophor A6 (Ceteareth 6 and stearyl alcohol), 1.00% Cremophor A25 (Ceteareth 25), 3.00 % Cutina GMS (glyceryl stearate), 10.00% paraffin oil, 5.00% jojobaol and 1.00% cetyl alcohol mixed together and heated to 70
- the aqueous phase is then added while stirring the oily phase and cooled to 50 ° C., homogenized and further cooled to 30 ° C., and a further aqueous phase composed of 15.00% demineralized water, 5.00% cyclodextrin, 1 , 50% erythrulose and 3.50% dihydroxyacetone added and stirred cold. This creates a pleasantly usable cream.
- a self-tanning O / W cream with a sunscreen filter is produced by mixing an oily phase from 5.00% of a mixture of glyceryl stearate and PEG-100 stearate, 1.00% cetyl alcohol, 2.00% stearic acid, 4.00% Dimethicone, 2.00% cyclomethicone, 3.00% caprylic / capric acid triglyceride, 1.00% jojobaol, 4.00% isopropyl palmitate, 2.00% octyl methoxycinnamate and 1.00% butyl methoxydibenzoyl methane mixed together Heated to 75 ° C. and added to an aqueous phase heated to 80 ° C.
- a self-tanning W / ⁇ / W cream is made by mixing an aqueous solution of 2.00% poloxamer, 0.10% Phenonip, 16.02% demineralized water, 0.38% magnesium sulfate heptahydrate, 1.40% Xanthan gum, 0.10% Phenonip, and 20.00% demineralized water and 60.00% of a previously prepared W / ⁇ emulsion consisting of an oil phase with 3.30% of a mixture of sorbitan ester and polyglycerol ester, 3.00% polyglycerol ester, 15.00% isohexadecane , 14.00% caprylic / capric acid triglyceride and an aqueous phase with 55.50% demineralized water, 0.20% Phenonip, 0.70% magnesium sulfate heptahydrate, 2.50% erythrulose and 5.80% DHA added and homogenized.
- a self-tanning gel is prepared by mixing 1.00% PVM (copolymer of vinyl chloride and vinyl methyl ether) / MA decadiene crosspolymer, 0.50% phenonip and 83.50% demineralized water with sodium hydroxide solution to adjust the pH 3.7 and adds 15.00% to a mixture of 66.70% demineralized water, 10.00% erythrulose and 23.30% DHA.
- PVM copolymer of vinyl chloride and vinyl methyl ether
- MA decadiene crosspolymer 0.50% phenonip and 83.50% demineralized water with sodium hydroxide solution to adjust the pH 3.7 and adds 15.00% to a mixture of 66.70% demineralized water, 10.00% erythrulose and 23.30% DHA.
- a self-tanning day cream is made by using 5.00% Arlacel 165 (glyceryl stearate, PEG-100 stearate, 1.00% cetyl alcohol, 2.00% stearic acid, 4.00% Dow Corning 200 silicone (dimethicone polymethylsiloxane), 2.00% Belsil CM 020 (cyclomethicone), 3.00% Miglyol 812 (caprylic / capric acid triglyceride), 1.00% jojobaol, 4.00% isopropyl palmitate, 2.00% Parsol MCX (octyl methoxycinnamate) and 1.00 % Butylmethoxydibenzoylmethan mixed together and this oily phase heated to 70 ° C.
- Arlacel 165 glyceryl stearate, PEG-100 stearate, 1.00% cetyl alcohol, 2.00% stearic acid, 4.00%
- Dow Corning 200 silicone diimethicone polymethyls
- the sun protection filters also protect the skin from the effects of harmful UV rays.
- Fields measuring 10 x 14 cm were marked on the backs of 4 female and 4 male subjects. The subjects were not allowed to sunbathe or visit a solarium during the entire test period.
- the subjects were 15 min before the measurements. Air-conditioned in a skin laboratory at 26-28 ° C and 40-50% humidity. Immediately after the initial value had been determined on day 0, the marked test fields were treated with 0.3 ml of the appropriate lotus with gentle rubbing. This process was repeated over the next 9 days. No lottery was applied after the 10th day.
- the skin moisture was determined with the Corneometer CM 820 (Courage and Khazaka).
- the skin color was measured with the Minolta Chromameter CR 300.
- the skin color was quantified with the "CIE L ab color system".
- the colors are defined in a three-dimensional color coordinate system. The a value corresponds to the red-green axis, the b value to the yellow-blue axis and the L * value to the light-dark axis. The smaller the L * value, the darker the color.
- the difference between two measuring points in this three-dimensional color coordinate system can be calculated from the absolute values using the following formula:
- the value calculated with this formula is a measure of the color change of the skin.
- FIG. 1 The different influence of the two formulations tested on the color intensity is shown in FIG. 1.
- the diagram shows the percentage color difference between the combination of erythrulose and DHA compared to DHA. DHA alone colors the skin faster in the first few days. However, from the 10th day onwards, the staining intensity of the combination erythrulose and DHA was greater. After the end of the application, the difference in the color intensity of the combination of erythrulose and DHA compared to DHA became more and more pronounced due to the delayed decrease in color. This shows that erythrulose produces a visible retard effect.
- the skin coloration produced with erythrulose and DHA shows no streaking and the skin no desquamation due to increased dehydration.
- the skin is measurably dried up to 30% less (Fig. 2).
- the skin feels less dry.
- the test subjects felt when using the combination tion of erythrulose and DHA in comparison to the DHA emulsion no tense feeling on the skin.
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- Veterinary Medicine (AREA)
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Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002282699A CA2282699C (en) | 1997-03-05 | 1998-02-27 | Combination of erythrulose and a reducing sugar with self-browning properties |
EP98903980A EP1014925B1 (de) | 1997-03-05 | 1998-02-27 | Kombination von erythrulose und einem reduzierenden zucker mit selbstbräunungseigenschaften |
JP53802898A JP4065571B2 (ja) | 1997-03-05 | 1998-02-27 | エリトルロースと自己褐変性を有する還元糖との組合せ物 |
AT98903980T ATE304838T1 (de) | 1997-03-05 | 1998-02-27 | Kombination von erythrulose und einem reduzierenden zucker mit selbstbräunungseigenschaften |
DE59813071T DE59813071D1 (de) | 1997-03-05 | 1998-02-27 | Kombination von erythrulose und einem reduzierenden zucker mit selbstbräunungseigenschaften |
AU62033/98A AU737402B2 (en) | 1997-03-05 | 1998-02-27 | Combination of erythrulose and a reducing sugar with self-tanning properties |
US09/380,651 US6451293B1 (en) | 1997-03-05 | 1998-02-27 | Combination of erythrulose and a reducing sugar with self-tanning properties |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH51897 | 1997-03-05 | ||
CH518/97 | 1997-03-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998038977A1 true WO1998038977A1 (de) | 1998-09-11 |
Family
ID=4188843
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CH1998/000083 WO1998038977A1 (de) | 1997-03-05 | 1998-02-27 | Kombination von erythrulose und einem reduzierenden zucker mit selbstbräunungseigenschaften |
Country Status (11)
Country | Link |
---|---|
US (1) | US6451293B1 (de) |
EP (1) | EP1014925B1 (de) |
JP (1) | JP4065571B2 (de) |
KR (1) | KR20000075690A (de) |
AT (1) | ATE304838T1 (de) |
AU (1) | AU737402B2 (de) |
CA (1) | CA2282699C (de) |
CZ (1) | CZ298916B6 (de) |
DE (1) | DE59813071D1 (de) |
ES (1) | ES2248890T3 (de) |
WO (1) | WO1998038977A1 (de) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19857010A1 (de) * | 1998-12-10 | 2000-06-21 | Cognis Deutschland Gmbh | Selbstbräunungsmittel |
EP1060736A3 (de) * | 1999-06-15 | 2002-11-20 | Neutrogena Corporation | Selbstbräununsschaum |
WO2007093830A1 (en) * | 2006-02-17 | 2007-08-23 | Dermasalve Limited | Skin application |
DE102007041475A1 (de) * | 2007-08-31 | 2009-03-05 | Beiersdorf Ag | Wirkstoffkombination aus Glycyrrhetinsäure und Erythrulose und kosmetische oder dermatologische Zubereitungen, diese Wirkstoffkombination enthaltend |
WO2009103573A1 (en) * | 2008-02-18 | 2009-08-27 | Unilever Plc | Glow and sunless tanning via a heated flowable cosmetic transferred onto skin |
DE102010026776A1 (de) | 2010-07-10 | 2012-01-12 | Merck Patent Gmbh | Bräunungsverstärker |
FR3102929A1 (fr) * | 2019-11-08 | 2021-05-14 | L V M H Recherche | Composition contenant de la DHA |
CN115461331A (zh) * | 2020-04-29 | 2022-12-09 | 花王株式会社 | 含有芳香族磺酸盐的自助美黑组合物及其方法 |
EP4143135A4 (de) * | 2020-04-29 | 2024-06-05 | Kao Corporation | Selbstbräunende zusammensetzungen enthaltend ein alkylsulfonat und verfahren dafür |
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JP2002528400A (ja) * | 1998-10-26 | 2002-09-03 | ユニバーシティー オブ マサチューセッツ | アデノシンまたはアデノシン類似体を用いた皮膚の治療 |
US20040228810A1 (en) * | 2003-05-13 | 2004-11-18 | Starr Hamson | Sprayable sunless tanning solution with sunscreen protection |
EP1648395A1 (de) * | 2003-07-10 | 2006-04-26 | Beiersdorf AG | Hauttönungsprodukt enthaltend selbstbräuner zur farbangleichung unterschiedlich pigmentierter hautstellen |
US20050100516A1 (en) * | 2003-11-07 | 2005-05-12 | Formulated Solutions, Llc | Hydroalcohol based self-tanning composition |
BR0308051A (pt) * | 2003-12-15 | 2005-09-06 | Natura Cosmeticos Sa | Composição base para preparação de formulações multifuncionais para o cuidado e proteção da pele e cabelo |
US20050238680A1 (en) * | 2004-04-21 | 2005-10-27 | Qing Stella | Personal care compositions that deposit hydrophilic benefit agents |
US20050238595A1 (en) * | 2004-04-21 | 2005-10-27 | Qing Stella | Personal care compositions that deposit sunless tanning benefit agents |
US20050239670A1 (en) * | 2004-04-21 | 2005-10-27 | Qing Stella | Personal care compositions that deposit hydrophilic benefit agents |
JP4231469B2 (ja) * | 2004-08-27 | 2009-02-25 | 花王株式会社 | 擬似眉形成化粧料 |
DE102007010986A1 (de) * | 2007-03-05 | 2008-09-11 | Merck Patent Gmbh | Übergangsmetallhaltige Effektpigmente |
US20090197819A1 (en) * | 2007-03-20 | 2009-08-06 | Clarence Albert Johnson | Compositions for improving and repairing skin |
US20080312169A1 (en) * | 2007-03-20 | 2008-12-18 | Clarence Albert Johnson | Cosmetic use of D-ribose |
US20090063334A1 (en) * | 2007-08-28 | 2009-03-05 | Alistair Duncan | Business-to-business transaction processing utilizing electronic payment network |
DE102007041472A1 (de) * | 2007-08-31 | 2009-03-05 | Beiersdorf Ag | Wirkstoffkombinationen aus Glycyrrhetinsäure und Dihydroxyaceton und kosmetische oder dermatologische Zubereitungen, diese Wirkstoffkombination enthaltend |
US20090187060A1 (en) | 2008-01-22 | 2009-07-23 | E-Z-Em, Inc. | Method and Formulation for Neutralizing Toxic Chemicals and Materials |
US20090232750A1 (en) * | 2008-03-13 | 2009-09-17 | St Cyr John A | Compositions for indoor tanning |
US20120128602A1 (en) | 2010-11-19 | 2012-05-24 | Kao Corporation | Skin compositions containing low levels of colorants |
US8747818B1 (en) * | 2011-02-07 | 2014-06-10 | Dennis Gross | Self-tanning compositions |
FR2999912B1 (fr) * | 2012-12-21 | 2015-02-13 | Clarins Lab | Composition concentree en dihydroxyyacetone |
JP6813165B2 (ja) * | 2016-07-26 | 2021-01-13 | ピアス株式会社 | 擬似眉形成化粧料 |
KR20180036113A (ko) * | 2016-09-30 | 2018-04-09 | (주)아모레퍼시픽 | 피부 착색용 화장료 조성물 |
JP6195402B1 (ja) * | 2017-03-17 | 2017-09-13 | ウィントレーディング株式会社 | まゆ形成方法 |
BR112020000035B1 (pt) * | 2017-07-06 | 2023-03-14 | Dsm Ip Assets B.V. | Composição tópica compreendendo eritrulose e caprilato de glicerila, usos de eritrulose e caprilato de glicerila e método de extermínio e/ou inibição de crescimento de p. acnes e c. albicans |
WO2020179457A1 (ja) * | 2019-03-04 | 2020-09-10 | 株式会社 資生堂 | セルフタニング用乳化化粧料 |
US20220296480A1 (en) * | 2019-05-10 | 2022-09-22 | Dsm Ip Assets B.V. | Topical compositions |
EP4059489A1 (de) | 2021-03-19 | 2022-09-21 | IONIQ Skincare GmbH & Co. KG | Elektrostatisch sprühbare bräunungsformulierung |
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WO1995022960A1 (en) * | 1994-02-28 | 1995-08-31 | Estee Lauder, Inc. | Skin tanning compositions and methods for their preparation and use |
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FR2653334B1 (fr) * | 1989-10-19 | 1991-12-20 | Erphar Ste Civile | Preparation cosmetique de bronzage. |
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DE4318576A1 (de) * | 1993-06-04 | 1994-12-08 | Merck Patent Gmbh | Hautfärbende Zubereitung |
FR2732680B1 (fr) * | 1995-04-05 | 1997-05-09 | Oreal | Composes de type ceramides, leur procede de preparation et leur utilisation |
US5922333A (en) * | 1997-02-28 | 1999-07-13 | Laughlin Products, Inc. | System for automatically coating the human body |
FR2772268B1 (fr) * | 1997-12-15 | 2000-03-03 | Clarins | Nouvelle composition cosmetique autobronzante et antideshydratante |
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1998
- 1998-02-27 AT AT98903980T patent/ATE304838T1/de not_active IP Right Cessation
- 1998-02-27 US US09/380,651 patent/US6451293B1/en not_active Expired - Lifetime
- 1998-02-27 EP EP98903980A patent/EP1014925B1/de not_active Expired - Lifetime
- 1998-02-27 KR KR1019997007757A patent/KR20000075690A/ko not_active Application Discontinuation
- 1998-02-27 CA CA002282699A patent/CA2282699C/en not_active Expired - Lifetime
- 1998-02-27 JP JP53802898A patent/JP4065571B2/ja not_active Expired - Lifetime
- 1998-02-27 AU AU62033/98A patent/AU737402B2/en not_active Expired
- 1998-02-27 CZ CZ0308399A patent/CZ298916B6/cs not_active IP Right Cessation
- 1998-02-27 ES ES98903980T patent/ES2248890T3/es not_active Expired - Lifetime
- 1998-02-27 WO PCT/CH1998/000083 patent/WO1998038977A1/de active IP Right Grant
- 1998-02-27 DE DE59813071T patent/DE59813071D1/de not_active Expired - Lifetime
Patent Citations (3)
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FR1307259A (fr) * | 1960-07-25 | 1962-10-26 | Oreal | Produit pour le brunissage artificiel de la peau |
EP0576189A1 (de) * | 1992-06-17 | 1993-12-29 | Unilever Plc | Selbstbräunende kosmetische Mittel |
WO1995022960A1 (en) * | 1994-02-28 | 1995-08-31 | Estee Lauder, Inc. | Skin tanning compositions and methods for their preparation and use |
Non-Patent Citations (1)
Title |
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"Simulated sun - taking the heat out ot tanning", MANUFACTURING CHEMIST, vol. 63, no. 7, 1992, WOOLWICH, LONDON (GB), pages 18 - 21, XP000290706 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19857010A1 (de) * | 1998-12-10 | 2000-06-21 | Cognis Deutschland Gmbh | Selbstbräunungsmittel |
EP1060736A3 (de) * | 1999-06-15 | 2002-11-20 | Neutrogena Corporation | Selbstbräununsschaum |
WO2007093830A1 (en) * | 2006-02-17 | 2007-08-23 | Dermasalve Limited | Skin application |
DE102007041475A1 (de) * | 2007-08-31 | 2009-03-05 | Beiersdorf Ag | Wirkstoffkombination aus Glycyrrhetinsäure und Erythrulose und kosmetische oder dermatologische Zubereitungen, diese Wirkstoffkombination enthaltend |
WO2009103573A1 (en) * | 2008-02-18 | 2009-08-27 | Unilever Plc | Glow and sunless tanning via a heated flowable cosmetic transferred onto skin |
DE102010026776A1 (de) | 2010-07-10 | 2012-01-12 | Merck Patent Gmbh | Bräunungsverstärker |
WO2012007095A2 (de) | 2010-07-10 | 2012-01-19 | Merck Patent Gmbh | Bräunungsverstärker und selbstbräunungssubstanzen |
FR3102929A1 (fr) * | 2019-11-08 | 2021-05-14 | L V M H Recherche | Composition contenant de la DHA |
CN115461331A (zh) * | 2020-04-29 | 2022-12-09 | 花王株式会社 | 含有芳香族磺酸盐的自助美黑组合物及其方法 |
EP4143135A4 (de) * | 2020-04-29 | 2024-06-05 | Kao Corporation | Selbstbräunende zusammensetzungen enthaltend ein alkylsulfonat und verfahren dafür |
Also Published As
Publication number | Publication date |
---|---|
AU6203398A (en) | 1998-09-22 |
KR20000075690A (ko) | 2000-12-26 |
EP1014925B1 (de) | 2005-09-21 |
JP2001513780A (ja) | 2001-09-04 |
AU737402B2 (en) | 2001-08-16 |
US6451293B1 (en) | 2002-09-17 |
CA2282699C (en) | 2007-09-18 |
JP4065571B2 (ja) | 2008-03-26 |
CZ298916B6 (cs) | 2008-03-12 |
DE59813071D1 (de) | 2005-10-27 |
EP1014925A1 (de) | 2000-07-05 |
ES2248890T3 (es) | 2006-03-16 |
US20020031482A1 (en) | 2002-03-14 |
CA2282699A1 (en) | 1998-09-11 |
ATE304838T1 (de) | 2005-10-15 |
CZ308399A3 (cs) | 2000-02-16 |
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