WO1997008361A1 - Appareil pour traitement de surface utilisant un jet de gaz - Google Patents
Appareil pour traitement de surface utilisant un jet de gaz Download PDFInfo
- Publication number
- WO1997008361A1 WO1997008361A1 PCT/JP1996/002401 JP9602401W WO9708361A1 WO 1997008361 A1 WO1997008361 A1 WO 1997008361A1 JP 9602401 W JP9602401 W JP 9602401W WO 9708361 A1 WO9708361 A1 WO 9708361A1
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- Prior art keywords
- gas
- nozzle
- plasma
- surface treatment
- supersonic
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/10—Heating of the reaction chamber or the substrate
- C30B25/105—Heating of the reaction chamber or the substrate by irradiation or electric discharge
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/513—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using plasma jets
Definitions
- the present invention relates to a gas treatment surface treatment apparatus that performs a surface treatment on a processing target by injecting a gas onto a surface of the processing target, and particularly relates to a case where a diamond thin film is formed on a tool chip or a semiconductor on a variety of substrates.
- the present invention relates to a surface treatment apparatus suitable for application in forming a thin film.
- the plasma is converted into a plasma by an induction plasma method or a DC plasma jet method, and the gas is activated so that the gas is activated and the reactivity with the surface to be processed is increased.
- the technique of performing surface treatment by spraying at high speed is already known, and is used for diamond film formation (diamond coating) and the like.
- JP-A-2-26695, JP-A-2-64097, JP-A-2-39421, JP-A-2-296976 For example, this type of technology is disclosed.
- the temperature of the gasified plasma is so high that when the gas is injected onto the object, the temperature must be reduced to a temperature that the object can withstand. If the injection is performed at a high temperature, the surface Film processing may be defective.
- the technology described in the above-mentioned Japanese Patent Application Laid-Open No. 2-296796 is not an adiabatic expansion process because the gas is converted into plasma and then further introduced downstream of the gas. That is, although the cooling is performed by the introduced gas, the flow velocity does not sufficiently increase, so that the above-described requirement of terminating the injection in a short time is not satisfied.
- the induction coil 5 for gas heating is arranged in the same vacuum chamber 8 (film formation chamber) as the object 15 (film formation target) 15. Have been. For this reason, when the source gas is filled in the film forming chamber, high vacuum cannot be maintained, and irregular discharge is likely to occur between the coil windings. When an illegal discharge occurs, a material component (for example, copper) of the wound coil is released as an impurity into the film forming chamber by a sputtering action. These impurities are incorporated as impurities into the thin film during the film formation process, and significantly reduce the performance of the thin film.
- the present invention has been made in view of such circumstances, and it is possible to improve the quality of an object to be processed by preventing an illegal discharge from occurring in an induction coil, and to supply stable power to plasma inside a nozzle. It is a primary object of the present invention to provide a device capable of performing such operations.
- the present invention has been made in view of such circumstances, and an apparatus capable of changing a plasma jet into a supersonic jet by adjusting the pressure, thereby improving the quality of a processing target. Its purpose is to provide it.
- the present invention has been made in view of such a situation, and is an apparatus capable of injecting additional energy into plasma, thereby increasing the speed of the plasma jet 7 and improving the quality of the object 15 to be processed.
- the third purpose is to provide
- the metal or metal compound does not turn into a gas, it cannot be injected as a gas onto the object 15 to be treated.
- the present invention provides an apparatus capable of injecting even a metal or a metal compound which cannot be a gas into an object to be processed, thereby forming a thin film of a metal or the like. That is the fourth purpose.
- the improvement in crystallinity is achieved by making the plasma particles regularly reach the surface of the object 15 to be treated.
- the present invention provides an apparatus capable of improving the crystallinity of the thin film of the object 15 by causing the plasma particles to regularly reach the surface of the object 15. This is the fifth purpose. Disclosure of the invention
- the pressure adjustment of the nozzle outlet surrounding the outlet of the supersonic nozzle 1 and the object 15 to be treated is performed.
- a chamber 18 for surrounding the induction coil 5 and a chamber 19 for pressure adjustment near the induction coil 5 are provided, and these chambers 18 and 19 are separated from each other.
- an outlet of the supersonic nozzle 1 and a chamber 18 for adjusting the pressure at the outlet of the nozzle surrounding the object 15 to be treated are provided, and the induction coil 5 is opened to the atmosphere.
- the stagnation point pressure at the point where the gas 6 is supplied is set to P0, and the outlet of the supersonic nozzle 1 is When the pressure is P1, the Mach number at the exit surface of the supersonic nozzle 1 is M, and the specific heat ratio of the gas 6 is ⁇ , r-Y
- the above expression can be satisfied by controlling the flow rate of the gas 6 supplied into the supersonic nozzle 1.
- plasma is generated downstream of the inlet and outlet of the supersonic nozzle 1 respectively.
- the electrodes 28 and 20 are provided so as to be in contact with the gas 27 thus applied, and a predetermined voltage is applied between the electrodes 28 and 20.
- a driving means 29 for moving the electrode 28 at the inlet of the supersonic nozzle 1 in the flow direction of the plasma gas 27 and a detecting means 32 for detecting the plasma current are provided.
- the nozzle entrance electrode 28 can be moved by the driving means 29 so as to have the value of
- an electrode 20 is provided downstream of the outlet of the supersonic nozzle 1 so as to be in contact with the plasma gas 27, and a plasma is formed at the inlet of the supersonic nozzle 1.
- the electrodes 28 may be provided so as not to come into contact with the gas 27, and a predetermined voltage may be applied between the electrodes 28 and 20.
- raw materials to be attached to the surface of the object 15 The carrier gas 6 to be transported is supplied into the nozzle 1 from the inlet of the supersonic nozzle 1 or from a gas supply position upstream of the gas flow path from the position where the heating means 5 is provided, and the carrier gas 6 ′ is Downstream from the supply position, the two electrodes 36, 37 made of the above-mentioned raw materials are arranged, and discharge is performed between both electrodes 36, 37, and the raw materials discharged from both electrodes 36, 37 Is mixed into a carrier gas 6, and the carrier gas 6 mixed with the raw material is heated and turned into plasma by the heating means 5, and the heated and turned gas 7 is discharged from the nozzle outlet into the target 15.
- the driving means 39, 40 for moving the electrodes 36, 37 and the discharge voltage between the electrodes 36, 37 to change the distance d between the electrodes 36, 37. And the driving means 39 and 40 can move the electrodes 36 and 37 so that the discharge voltage becomes a desired value.
- FIG. 1 is a view showing a basic configuration of a surface treatment apparatus using gas injection according to the present invention.
- FIG. 2 is a diagram showing a configuration in which a nozzle outlet pressure adjusting device is added to the device shown in FIG.
- FIG. 3 is a diagram showing the configuration of the first embodiment device corresponding to the first invention.
- Figure 4 is a Draf showing Paschen's law.
- FIG. 5 is a diagram showing the configuration of the device of the second embodiment corresponding to the second invention.
- FIG. 6 is a diagram used to explain the second embodiment.
- FIGS. 7 (a) and 7 (b) are diagrams showing the configuration of a third embodiment device corresponding to the third invention.
- FIG. 8 is a diagram used to explain the third embodiment.
- FIG. 9 is a diagram used to explain the third embodiment.
- FIG. 10 is a diagram showing the configuration of the device of the fourth embodiment corresponding to the fourth invention.
- FIG. 11 is a diagram showing a configuration of a fifth embodiment device corresponding to the fifth invention.
- FIG. 1 is a diagram showing the basic configuration of the apparatus of the embodiment.
- the gas passing through the nozzle is adiabatically expanded and injected from the nozzle outlet 4a at a flow velocity u greater than the sonic velocity a.
- a supersonic nozzle a Lapearl nozzle (also called a Suehiro nozzle) 1, is configured.
- the Laval nozzle 1 is a medium-sized nozzle, and a gas 6 (for example, a mixed gas of C H4 and H 2) to be injected onto the surface of the object to be processed (for example, a cutting tool chip) 15 is introduced from the gas inlet 2 a.
- a gas inlet pipe 2 configured so that the cross-sectional area gradually decreases as the gas progresses; a throat section (throat) 3 having a minimum cross-sectional area A1 (diameter dl) of the entire nozzle; The cross-sectional area gradually expands at a predetermined divergence angle 0, and the gas 7 from the gas injection port 4a having the maximum cross-sectional area A2 (diameter d2) downstream from the slot.
- a gas injection pipe 4 from which the gas is injected.
- the Lapearl nozzle 1 is arranged such that the gas 7 injected from the injection port 4a is injected toward the surface of the processing target 15.
- the throat unit 3 is provided with an induction plasma device. That is, an induction coil 5 is wound around the outer periphery of the throat portion 3, and a high-frequency current can be supplied to the induction coil 5. Therefore, when the coil 5 is energized, an induced electromagnetic field is formed in the throat section 3, and the gas passing through the throat section 3 is heated and turned into plasma.
- the induction plasma device is an electrodeless plasma device using an induced electromagnetic field, and a plasma gas and an electrode come into direct contact like a DC plasma device, and as a result, the electrode is consumed as the electrode is consumed.
- the material tungsten or the like
- a high-density mixed gas 6 to be injected into the object 15 to be processed is supplied into the Laval nozzle 1 from the gas inlet 2a. Then, as described above, in the throat portion 3, since a high-frequency current is applied to the high-frequency induction coil 5, an induction electromagnetic field is generated in the pipe, and the energy of this field heats the high-density gas. It is turned into plasma.
- the heated, plasmaized high-density gas is expanded and accelerated due to the expansion of the nozzle by the downstream gas injection pipe 4, and is injected as a supersonic plasma jet 7 from the gas injection port 4a. .
- the ratio P 1Z P 0 between the stagnation pressure P 0 of the introduced gas 6 and the pressure P 1 downstream of the injection port 4a is about 0. 5 2 or less, the ratio of the cross-sectional area A1 of the throat section 3 to the cross-sectional area A2 of the injection port 4a (Suehiro ratio)
- the gas is adiabatically expanded, and the injection flow velocity is supersonic. That is, the flow velocity u is larger than the sound velocity a.
- the divergence angle ⁇ before and after the throat portion 3 must be an appropriate size, for example, about 15 °, because if it is too large, separation of the boundary layer occurs on the wall surface.
- the high-density gas heated and converted into plasma in the throat section 3 is excited by the heat into a highly reactive state, that is, a state in which the gas easily reacts on the processing target 15.
- this highly reactive gas has a very high temperature, and in some cases reaches as much as 10,000 degrees, if it is injected directly onto the object 15, the object 15 May not tolerate temperature.
- the Lapearl nozzle 1 since the Lapearl nozzle 1 is designed to be adiabatically expanded as described above, it is rapidly cooled in the adiabatic expansion process and reaches an appropriate temperature before reaching the injection target 15. Since the temperature at this time is determined by the divergent ratio A2 / A1, an arbitrary temperature can be obtained depending on the design conditions of the nozzle 1. As described above, the temperature of the gas 7 injected onto the processing target 15 can be adjusted to a temperature suitable for the processing, so that the quality of the film forming processing and the like can be improved.
- the highly reactive gas 7 travels at a supersonic velocity u, the time required to reach the target 15 is extremely short, and by the time the target reaches the target 15, the gas is excited by heating and plasma. The state does not return to the steady state (reaction hardly occurs). Thus, the temperature can be lowered to an appropriate temperature while the so-called excited state is frozen. Therefore, the adhesion between the object to be treated 15 and the reaction product is improved, and problems such as separation of the reaction product do not occur. Therefore, the quality of the film forming process and the like can be improved. In addition, since the injection is completed in a short time, the film forming speed is increased, and the working efficiency is also improved.
- T0 T + (1/2) ⁇ ⁇ (r— 1) / y-R ⁇ -(u) 2... (1)
- T Static temperature of the flow (so-called temperature)
- Equation (2) is obtained by rewriting equation (1) using Mach numbers (uZa, a: sound velocity). Also, the Mach number M is uniquely determined as a function of the Suehiro ratio A2ZA1.
- the value of the temperature ratio T0 / T increases in proportion to the square of the Mach number M.
- temperature ratio T0ZT 6.
- the plasma temperature ⁇ can be lowered to a temperature suitable for the object 15 by adiabatically expanding and accelerating the reactive plasma heated to a high temperature to a high Mach number using the rubber nozzle 1.
- the low-temperature and high-speed plasma flow 7 having high activity is supplied to the object 15 as a highly directional particle bundle, it also has a feature that the usage efficiency of the raw material gas is extremely high.
- a high-density, highly reactive gas containing extremely few impurities can be lowered to an arbitrary temperature and injected onto the object 15 to be processed.
- Efficiency can be dramatically improved and processing quality can be dramatically improved.
- the coil 5 is disposed in the throat section 3. It can be provided at any place of the nozzle 1 without being limited to.
- FIG. 2 shows a device equipped with a device capable of adjusting the outlet pressure P1 of the nozzle 1 to an arbitrary pressure and setting the pressure ratio P1 P0 to an arbitrary value with respect to the device of FIG. It shows a mashed configuration.
- a throat section 3 and a gas injection pipe 4 are provided in a vacuum chamber 8, and a support 14 for supporting an object 15 to be processed is provided in the chamber 8. .
- the air in the vacuum chamber 8 is exhausted by an exhaust pump 13.
- the amount of gas supplied to the gas introduction pipe 2 is adjusted by the gas supply amount adjustment valve 11 provided in the gas supply pipe 16, and the outlet pressure P1 of the injection gas 7 is adjusted by the P1 adjustment valve 12. Adjusted.
- the pressure P 0 in the gas inlet pipe 2 is detected by a P 0 measuring gauge 9, and the outlet pressure P 1 of the gas injection pipe 4 is detected by a P 1 measuring gauge 10. Adjustments 11 and 12 are made, and the pressure ratio P1ZP0 is set to a predetermined value.
- Reference numeral 17 denotes a high-frequency power supply that supplies a current to the high-frequency induction coil 5.
- the high-frequency induction coil 5 was supplied with a current of 13.56 MHz at 1 kW while cooling.
- the durability of the tool tip 15 has been dramatically improved by such a diamond thin film deposition (diamond coating).
- the following experimental results were obtained by using SiH4 or a mixed gas 6 of SiH4 and H2 as the raw material gas, subjecting the ceramic substrate 15 to the ejection target, and performing other conditions under the same conditions as those described above. Became.
- a high-density and highly reactive mixed gas containing Si was supplied onto the substrate 15, and an Si thin film was formed on the ceramic substrate 15.
- this Si thin film was evaluated by SEM observation and X-ray diffraction, it was found to be a dense polycrystalline film.
- the thickness of the Si thin film was about 60 / xm as a result of spraying (deposition) for 30 minutes.
- c-BN can be formed.
- various surface treatments such as etching, oxidation, and nitridation can be performed.
- the gas is heated and turned into plasma by the high-frequency induction coil 5, but other electrodeless plasma devices such as ECR plasma and helicon plasma may be used.
- a jet shield technology using an inert gas, a raw material gas, a diluent gas, or the like that is used in ordinary plasma spraying or plasma welding may be applied.
- all the gases 6 to be injected into the object 15 to be treated are introduced through the inlet 2 a (first embodiment), which is the inlet of the nozzle 1, or through the supply pipe 16.
- the gas 6 is supplied from 2a (the second embodiment), but the supply position of the gas 6 is higher than the position of the coil 5 where the gas 6 is heated and turned into plasma. It can be provided at any position on the side.
- a doping material for forming a semiconductor such as a p-type or an n-type
- a gas such as SiH4
- the mixed gas 6 is heated and turned into a plasma at the coil 5. What is necessary is just to supply it from the upstream position.
- the gas may be supplied from a position downstream of the position where the gas is heated and turned into plasma.
- the first embodiment device capable of achieving the first object of the present invention, the second embodiment device capable of achieving the second object, and the third object can be achieved.
- a third embodiment device, a fourth embodiment device capable of achieving the fourth object, and a fifth embodiment device capable of achieving the fifth object will be described. In each case, the basic configuration shown in Fig. 1 is assumed. The same reference numerals as those shown in FIGS. 1 and 2 represent the same functions.
- this apparatus is provided with a film forming chamber 18 so as to surround an outlet portion of the gas injection pipe 4 and a substrate 15 to be processed.
- a coil chamber 19 is provided so as to surround it.
- the film forming chamber 18 is a chamber for forming a semiconductor thin film on the substrate 15 to be processed, and is a chamber for adjusting the outlet pressure P 1 of the nozzle 1.
- the coil chamber 19 is a chamber for adjusting the pressure near the induction coil 5.
- the air inside the room is exhausted by the same vacuum pump as the exhaust pump 13 shown in Fig. 2, and the interior of the room is adjusted to a high vacuum by the same valve as the regulating valve 12. , Will be retained.
- 20 is a substrate holder for holding the substrate 15.
- the first embodiment has the following advantages as compared with the apparatus shown in FIG.
- the induction coil 5 for heating gas S is arranged in the same vacuum chamber 8 (film formation chamber) as the film formation target 15. Therefore, if the film forming chamber 8 is filled with the source gas, a high degree of vacuum cannot be maintained, and irregular discharge is likely to occur between the coil windings of the induction coil 5.
- a material component for example, copper
- the wound coil is released as an impurity into the film forming chamber 8 by a sputtering action.
- impurities are taken into the thin film as impurities during the film formation process, and may significantly reduce the performance of the thin film. That is, impurities such as copper may adhere to the film formation target 15 which should be a semiconductor, and the quality may be degraded.
- the chamber 19 of the discharge coil 5 and the film forming chamber 18 are separated from each other and kept at a high vacuum separately, so that the induction coil is influenced by the source gas. (5) A situation in which the maintenance of high vacuum in the vicinity is hindered and illegal discharge occurs is avoided, the quality of the object to be treated is dramatically improved, and stable power can be supplied to the plasma inside the nozzle 1. Become.
- FIG. 4 is a graph showing Paschen's law, showing the relationship between gas pressure and dielectric breakdown voltage.
- the breakdown voltage increases not only on the low-voltage side ( ⁇ vacuum) than on the shaded area, but also on the high-pressure side than on the shaded area. Therefore, even if the vicinity of the induction coil 5 is set to a high pressure, illegal discharge can be prevented in the same manner as when a high vacuum is applied.
- the pressure in the film forming chamber 18 needs to be maintained at a vacuum pressure indicated by oblique lines.
- the film forming chamber 18 may be left as it is, the coil chamber 19 may be removed, and the induction coil 5 may be opened to the atmosphere. That is, the device configuration shown in FIGS. 5 and 6 may be used.
- the stagnation point pressure at the point where the introduced gas 6 is supplied is P 1
- the pressure at the outlet of the supersonic nozzle 1 (the pressure in the film forming chamber 18)
- the Mach number at the outlet surface of nozzle 1 is M and the specific heat ratio of gas 6 is T /
- the supersonic plasma jet 7 is ejected from nozzle 1 according to the principle of fluid dynamics as follows. 3) The formula needs to be satisfied.
- the apparatus of this embodiment is configured as shown in FIG. 5, and controls the pressure P0 so that the above equation (3) is satisfied.
- a pressure sensor 21 for detecting a stagnation point pressure P0 is provided inside the gas inlet pipe 2, and an outlet pressure of the supersonic nozzle 1 (film forming pressure) is provided inside the film forming chamber 18.
- a pressure sensor 22 for detecting the pressure of the chamber 18 is provided, and the outputs of the pressure sensors 21 and 22 are applied to a divider 23.
- the operation P1 / P0 is executed, and the operation result is applied to the positive terminal of the comparator 25.
- the function f (M) is added to the other negative terminal of the comparator 23 from the function generator 24.
- the comparator 23 outputs to the motor 26 a drive signal corresponding to the deviation P 1Z P0 ⁇ f (M), that is, a drive signal for satisfying the expression (3).
- the motor 26 drives the gas supply amount adjustment valve 11 provided in the gas supply pipe 16 in accordance with the above drive signal, adjusts the valve opening, and controls the amount of gas supplied to the gas supply pipe 2. .
- the stagnation point pressure P0 in the gas inlet pipe 2 is changed to a value that satisfies the above equation (3).
- thermal equilibrium plasma and non-equilibrium plasma can be generated as required.
- the stagnation point pressure P0 is set to a high pressure of about the atmospheric pressure, a thermal equilibrium plasma can be generated, and if it is set to a low pressure of several tens Torr or less, a non-equilibrium plasma can be generated. What is necessary is just to generate
- the stagnation point pressure P0 is controlled.However, the nozzle outlet pressure P1 may be controlled, or by controlling both the pressures P0 and PI, Equation (3) may be satisfied. '
- the plasma jet can be made into a supersonic jet by adjusting the pressures P0 and PI, thereby significantly improving the quality of the object to be processed. Can be done.
- the device shown in Fig. 7 (a) is a device that can increase the speed of the plasma jet 7 that is jetted to the processing target 15 to increase the reaction efficiency, thereby improving the quality of the processing target 15 more. Is shown.
- an electric bias is applied to the plasma using electrodes, and additional energy is injected into the plasma, thereby increasing the speed of the plasma jet 7.
- an electrode 28 is provided in the gas introduction pipe 2 of the supersonic horn 4 so as to be in contact with the plasma gas 27.
- the electrode 28 may be a flat plate or a rod.
- the substrate holder 20 is made of a material that also functions as an electrode, and the plasma current 27 flows through the substrate 15 that is ITO.
- Electrodes 28 and 20 are connected to an AC power supply 33. Therefore, a predetermined voltage is applied between the electrodes 28 and 20 by the power supply 33. Further, the current can be adjusted by the variable resistor 34.
- DC power supply may be used instead of the AC power supply 33.
- the plasma current A flowing between the electrodes 28 and 20 is detected by the ammeter 32.
- the detection current A of the ammeter 32 is applied to the negative terminal of the comparator 30 via the current-to-voltage converter 31.
- a reference current value Aref (desired current value) is applied to the plus terminal of the comparator 30.
- the reference current value Aref is set according to a desired speed of the plasma jet 7.
- a driving signal corresponding to the deviation Aref—A that is, the plasma current A
- a drive signal for obtaining the desired current value Aref is output to the drive unit 29.
- the driving unit 29 is configured by a motor or the like that moves the electrode 28 in the flow direction of the plasma gas 27.
- the electrode 28 when the driving section 29 is driven in accordance with the drive signal, the electrode 28 is directed in the direction of arrow B (the direction in which the plasma current increases) or the gas upstream direction, which is the gas downstream direction according to the drive signal. It is moved in the direction of arrow B (the direction in which the plasma current decreases), and is finally positioned at a position where the plasma current reaches the desired value Aref.
- both the electrodes 28 and 20 are brought into contact with the plasma gas 27 and the voltage is applied to the plasma gas 27 by the power source 33.
- the electrode 28 may be drawn in the upstream direction B, and the plasma current may be set to a value equal to or less than the reference current value Aref.
- the electrode 28 is positioned at a position not in contact with the plasma gas 27 as shown in FIG.
- the plasma particles can be accelerated by an electric field generated by the power source 33, thereby improving the quality of the substrate 15 and providing a current to the substrate 15 The inconvenience due to the flow of the gas is eliminated.
- the flow of current into the substrate 15 may improve the quality of the film on the substrate 15 depending on the film forming conditions, but may adversely affect the film quality. Therefore, when the film quality is adversely affected, it is effective to apply the second control.
- the electrode 20 on the gas downstream side is also used as a substrate holder.
- the electrode 20 is different from the substrate holder 20.
- an annular electrode 35 may be provided.
- a thin film of a metal or a metal compound can be formed.
- a carrier gas 6 ′ for example, argon, hydrogen, oxygen
- a raw material for example, barium titanate
- the two electrodes 3 made of the above-mentioned raw material are supplied from the inlet of the supersonic nozzle 1 into the nozzle 1 and into the gas introduction pipe 2 of the supersonic nozzle 1 (downstream from the position where the carrier gas 6 is supplied). 6 and 3 7 are arranged.
- both electrodes 36 and 3 7 When a predetermined voltage is applied to both electrodes 36 and 37 by the power supply 41 and a discharge 38 (for example, arc discharge or glow discharge) is performed between these electrodes, both electrodes 36 and 3 7 The raw material is released as metal atoms and clusters from, and is mixed into the carrier gas 6 '. Then, the carrier gas 6 ′ into which the raw material is mixed is heated and turned into plasma in the throat section 3, and the heated and turned gas 7 is injected from the nozzle outlet toward the surface of the substrate 15.
- a discharge 38 for example, arc discharge or glow discharge
- the driving mechanisms 39, 40 for moving the electrodes 36, 37 are arranged such that the distance d, which changes due to the wear of the electrodes 36, 37, becomes a constant value dref, the electrodes 36, 3 7 respectively.
- a voltmeter 42 for detecting the discharge voltage V is provided.
- the output of voltmeter 42 is applied to the plus terminal of comparator 43.
- a reference voltage Vref corresponding to a desired discharge distance d ref is input to the minus terminal of the comparator 43. Therefore, the comparator 43 outputs a drive signal corresponding to the deviation V—Vref, that is, a drive signal for setting the discharge voltage to the desired value Vref, and drives the drive mechanisms 36 and 37 respectively.
- Motors 4 4 and 4 5 are added.
- the electrodes 36, 37 are moved in the direction C, which changes the discharge distance d, and the desired discharge distance d ref corresponding to the voltage Vref
- the electrodes 36 and 37 are positioned at the positions where is obtained.
- a metal or a metal compound that cannot be a gas can be jetted onto the substrate 15 and a metal thin film or the like can be formed.
- the improvement in crystallinity is achieved by making the plasma particles regularly reach the surface of the object 15 to be treated.
- the crystallinity of the thin film of the substrate 15 is improved by causing the plasma particles to regularly reach the surface of the object 15 to be processed.
- the magnetic force lines 47 a parallel to each other along the flow direction of the plasmatized gas 7. , 47 b, 47 c... Are formed, the magnetic field generating coils 46 are arranged.
- the plasma particles move along the magnetic field lines, if the magnetic field lines 47 a, 47 b, 47 c ... are parallel to each other, the plasma particles will move in an orderly parallel motion, and the substrate 1 5 To reach the surface. As a result, the crystallinity of the thin film is improved.
- the movement of the plasma particles can be adapted to the lattice constant of the thin film crystal by changing the magnitude of the magnetic field intensity (line of magnetic force) applied by the magnetic field generating coil 46 as required. Therefore, crystallization can be optimized by changing the magnetic field strength according to the type of the thin film (according to the magnitude of the lattice constant).
- first to fifth embodiments described above can be appropriately combined.
- first embodiment or the second embodiment or the third embodiment is combined with the third embodiment
- first embodiment or the second embodiment is combined with the fifth embodiment.
- a combination of the third embodiment or the fourth embodiment is possible.
- the quality of the object to be processed can be improved, and stable power is supplied to the plasma inside the nozzle. Will be able to
- the pressure of the inlet or outlet of the nozzle is adjusted to make the plasma jet a supersonic jet, so that the quality of the object to be processed can be improved.
- the quality of the object to be processed can be improved.
- a metal or a metal compound that cannot be a gas can be jetted to an object to be processed, so that a thin film of a metal or a metal compound can be formed.
- the plasma particles are made to regularly reach the surface of the object to be processed, so that the crystallinity of the thin film to be processed can be improved.
- the present invention is applicable not only to the case of forming a thin film but also to any surface treatment performed by gas injection.
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Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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EP96928669A EP0851040A4 (en) | 1995-08-29 | 1996-08-28 | SURFACE TREATMENT DEVICE WITH GASJET |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22049795A JPH0967191A (ja) | 1995-08-29 | 1995-08-29 | ガス噴射による表面処理装置 |
JP7/220497 | 1995-08-29 |
Publications (1)
Publication Number | Publication Date |
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WO1997008361A1 true WO1997008361A1 (fr) | 1997-03-06 |
Family
ID=16751980
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1996/002401 WO1997008361A1 (fr) | 1995-08-29 | 1996-08-28 | Appareil pour traitement de surface utilisant un jet de gaz |
Country Status (3)
Country | Link |
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EP (1) | EP0851040A4 (ja) |
JP (1) | JPH0967191A (ja) |
WO (1) | WO1997008361A1 (ja) |
Cited By (1)
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CN114051306A (zh) * | 2021-11-15 | 2022-02-15 | 安徽工业大学 | 一种束流直径可调的大气压等离子体射流发生器及使用方法 |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1050622A (ja) * | 1996-08-05 | 1998-02-20 | Komatsu Ltd | 表面処理装置用ノズル、表面処理装置およびこれを用いた表面処理方法 |
DE10104615A1 (de) * | 2001-02-02 | 2002-08-14 | Bosch Gmbh Robert | Verfahren zur Erzeugung einer Funktionsbeschichtung mit einer HF-ICP-Plasmastrahlquelle |
DE10145131B4 (de) * | 2001-09-07 | 2004-07-08 | Pva Tepla Ag | Vorrichtung zum Erzeugen eines Aktivgasstrahls |
DE10223865B4 (de) * | 2002-05-29 | 2007-08-16 | Plasmatreat Gmbh | Verfahren zur Plasmabeschichtung von Werkstücken |
DE102005004242B4 (de) * | 2005-01-29 | 2008-11-27 | Mtu Aero Engines Gmbh | Verfahren zur Herstellung von Triebwerkteilen |
SE529053C2 (sv) | 2005-07-08 | 2007-04-17 | Plasma Surgical Invest Ltd | Plasmaalstrande anordning, plasmakirurgisk anordning och användning av en plasmakirurgisk anordning |
SE529058C2 (sv) | 2005-07-08 | 2007-04-17 | Plasma Surgical Invest Ltd | Plasmaalstrande anordning, plasmakirurgisk anordning, användning av en plasmakirurgisk anordning och förfarande för att bilda ett plasma |
SE529056C2 (sv) | 2005-07-08 | 2007-04-17 | Plasma Surgical Invest Ltd | Plasmaalstrande anordning, plasmakirurgisk anordning och användning av en plasmakirurgisk anordning |
US7928338B2 (en) | 2007-02-02 | 2011-04-19 | Plasma Surgical Investments Ltd. | Plasma spraying device and method |
US7589473B2 (en) | 2007-08-06 | 2009-09-15 | Plasma Surgical Investments, Ltd. | Pulsed plasma device and method for generating pulsed plasma |
US8735766B2 (en) | 2007-08-06 | 2014-05-27 | Plasma Surgical Investments Limited | Cathode assembly and method for pulsed plasma generation |
ITMI20092107A1 (it) * | 2009-11-30 | 2011-06-01 | Milano Politecnico | Metodo e apparato per la deposizione di strati sottili nanostrutturati con morfologia e nanostruttura controllata |
US8613742B2 (en) | 2010-01-29 | 2013-12-24 | Plasma Surgical Investments Limited | Methods of sealing vessels using plasma |
US9089319B2 (en) | 2010-07-22 | 2015-07-28 | Plasma Surgical Investments Limited | Volumetrically oscillating plasma flows |
CN107267918A (zh) * | 2017-05-17 | 2017-10-20 | 深圳市航盛新材料技术有限公司 | 制备纳米薄膜的系统及方法 |
FI129719B (en) * | 2019-06-25 | 2022-07-29 | Picosun Oy | PLASMA IN SUBSTRATE PROCESSING EQUIPMENT |
EP4205515A2 (en) | 2020-08-28 | 2023-07-05 | Plasma Surgical Investments Limited | Systems, methods, and devices for generating predominantly radially expanded plasma flow |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5244174A (en) * | 1975-10-06 | 1977-04-06 | Hitachi Ltd | Plasma treatment device |
JPS6316043A (ja) * | 1986-07-08 | 1988-01-23 | Canon Inc | 微粒子の捕集方法 |
JPH04116172A (ja) * | 1990-08-31 | 1992-04-16 | Energy Conversion Devices Inc | 高速で薄膜を形成する方法および薄膜形成装置 |
JPH04180221A (ja) * | 1990-11-14 | 1992-06-26 | Kobe Steel Ltd | プラズマ処理方法 |
JPH05171427A (ja) * | 1991-04-22 | 1993-07-09 | Multi Arc Scient Coatings | プラズマ強化装置と電気アーク蒸着法 |
JPH08990A (ja) * | 1994-06-16 | 1996-01-09 | Komatsu Ltd | ガス噴射による表面処理方法および表面処理装置 |
-
1995
- 1995-08-29 JP JP22049795A patent/JPH0967191A/ja active Pending
-
1996
- 1996-08-28 WO PCT/JP1996/002401 patent/WO1997008361A1/ja not_active Application Discontinuation
- 1996-08-28 EP EP96928669A patent/EP0851040A4/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5244174A (en) * | 1975-10-06 | 1977-04-06 | Hitachi Ltd | Plasma treatment device |
JPS6316043A (ja) * | 1986-07-08 | 1988-01-23 | Canon Inc | 微粒子の捕集方法 |
JPH04116172A (ja) * | 1990-08-31 | 1992-04-16 | Energy Conversion Devices Inc | 高速で薄膜を形成する方法および薄膜形成装置 |
JPH04180221A (ja) * | 1990-11-14 | 1992-06-26 | Kobe Steel Ltd | プラズマ処理方法 |
JPH05171427A (ja) * | 1991-04-22 | 1993-07-09 | Multi Arc Scient Coatings | プラズマ強化装置と電気アーク蒸着法 |
JPH08990A (ja) * | 1994-06-16 | 1996-01-09 | Komatsu Ltd | ガス噴射による表面処理方法および表面処理装置 |
Non-Patent Citations (1)
Title |
---|
See also references of EP0851040A4 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114051306A (zh) * | 2021-11-15 | 2022-02-15 | 安徽工业大学 | 一种束流直径可调的大气压等离子体射流发生器及使用方法 |
CN114051306B (zh) * | 2021-11-15 | 2024-02-06 | 安徽工业大学 | 一种束流直径可调的大气压等离子体射流发生器及使用方法 |
Also Published As
Publication number | Publication date |
---|---|
EP0851040A1 (en) | 1998-07-01 |
JPH0967191A (ja) | 1997-03-11 |
EP0851040A4 (en) | 2000-09-06 |
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