WO1996027638A1 - Feine, feste teilchen enthaltende zusammensetzung - Google Patents
Feine, feste teilchen enthaltende zusammensetzung Download PDFInfo
- Publication number
- WO1996027638A1 WO1996027638A1 PCT/EP1996/000782 EP9600782W WO9627638A1 WO 1996027638 A1 WO1996027638 A1 WO 1996027638A1 EP 9600782 W EP9600782 W EP 9600782W WO 9627638 A1 WO9627638 A1 WO 9627638A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solid particles
- composition according
- cellulose
- particles
- composition
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
Definitions
- the invention relates to a composition
- a composition comprising fine, solid particles such as inorganic or organic pigments, synthetic polymers and the like. contains which are provided with a coating or are dispersed in a matrix, the coating or the matrix consisting of a homogeneous mixture of cellulose, tertiary amine oxide, water and possibly other constituents.
- Dispersions of solid particles such as pigments are required for a wide variety of applications.
- An important application is e.g. matting cellulosic threads.
- NMMO process a process in which cellulose in a mixture of N-methylmorpholine-N-oxide, water and optionally dissolved further components and further processed into threads in a manner known per se. If one tries to stir the pigments directly into the spinning mass, agglomerations occur, whereby spinning disturbances are automatically programmed. Furthermore, the uniformity of the threads obtained suffers.
- compositions which contain finely divided dispersed or dispersible solid particles which are stable, do not tend to separate, can be readily distributed in cellulosic compositions which are simple to produce, are versatile and which in the further processing of moldings, for example when washing cellulosic threads not as a result of washing out emulsifiers and the like. lead to problems when working up the washing water and the solvent, ie compositions which also meet the strict requirements of environmental protection in a satisfactory manner.
- compositions which contains fine, solid particles which are provided with a coating or are dispersed in a matrix and which are inert to the coating or matrix, the coating or the matrix consisting of a homogeneous mixture of cellulose , tertiary amine oxide, water and optionally other constituents and the composition consists of 0.5 to 10 wt% cellulose, 5 to 76 wt% solid particles and the remainder 100% of a mixture of tertiary amine oxide, water and optionally further constituents puts.
- the tertiary amine oxide is preferably N-methylmorpholine-N-oxide.
- the composition is composed of 40 to 50% by weight of solid particles, 1 to 2% by weight of cellulose (based on solid particles), 59 to 48% by weight of a mixture of tertiary amine oxide and water and optionally further constituents .
- the cellulose has advantageous a DP (average degree of polymerization) of 500 to 700.
- the tertiary amine oxide and water in the composition preferably have a weight ratio of from 75 to 90 to 25 to 10.
- the solid particles can be inorganic or organic in nature.
- the organic solid particles consist of synthetic polymers.
- the compositions preferably contain inorganic or organic pigments, in particular titanium dioxide or barium sulfate.
- compositions are preferably solid at room temperature. In a further embodiment of the invention, the compositions can also be liquid.
- the composition can also be in the form of solid discrete particles.
- the discrete particles can in particular have a powdery, granular or spherical shape.
- Another object of the invention is a process for the preparation of compositions which contain fine, solid particles which are inert to the coating or the matrix, which is characterized in that solid particles in a solution of cellulose, tertiary amine oxide , Water and optionally other constituents and the dispersion obtained, if appropriate, cooled and comminuted or excess solution is withdrawn from the dispersion obtained and optionally cooled and comminuted, 0.5 to 10% by weight of cellulose and 5 to 76% by weight of solid being used to prepare the composition Particles and remainder to 100 a mixture of tertiary amine oxide, water and optionally other ingredients used. It is advantageous to apply high shear forces when distributing the solid particles.
- the distribution of the solid particles in a solution having a viscosity of 5.0 to 100 mPas is preferably carried out, the viscosity being measured at 90.degree.
- the liquid, finely divided dispersion is advantageously poured into molds, cooled and comminuted.
- the liquid dispersion is sprayed into solid particles.
- compositions according to the invention are advantageously used in pigmentation, in matting cellulose threads, films and membranes and in the production of cellulose threads, films and membranes stable against ultraviolet radiation.
- Inert to the coating or the matrix means that the solid particles which are used to build up the composition do not decompose the coating or the matrix under processing conditions.
- Non-inert compounds include copper oxide, iron-2 and iron-3-oxide, which in particular lead to a strong decomposition of N-methylmorpholine-N-oxide when they are heated with the amine oxide.
- Inert inorganic compounds in the context of the invention include titanium dioxide, barium sulfate, sodium carbonate, carbon black and the like.
- Correspondingly inert organic compounds include polymer powders such as PVC, polystyrene, thermoplastic starch and others.
- flame-retardant substances such as phosphorus or nitrogen compounds, silicates or porous particles, which subsequently with active substances such as fragrances, anti-insect agents and the like. can be loaded, can be incorporated as inert particles.
- Further constituents which may optionally be present in the composition are, above all, stabilizers such as propyl gallic acid, gallic acid, pyrogallol, ascorbic acid or dispersing agents (such as, for example, emulsifiers).
- the implementation of the method according to the invention can e.g. done in the following way.
- the solution must contain enough cellulose that when the solid particles are dispersed, the particles have at least one monomolecular layer of cellulose on the entire surface. It is advantageous if a multi-molecular layer envelops the dispersed particles in each case. It is very advantageous if the amount of solution is dimensioned such that the dispersed particles are embedded as in a matrix, the distance between the individual solid particles in the matrix is relatively large, e.g. is at least one particle diameter.
- the amounts of cellulose, based on the dispersed particles, can be varied within relatively wide limits, i.e. a considerable excess can also be used. If an excess is used, the solid particles are initially suspended in the solution; after the mixture has solidified, the finely dispersed particles are present as if embedded in a matrix.
- a matrix at room temperature is understood to mean a solid mass which essentially has a uniform, coherent structure in which the solid particles are finely divided, such as pigments in plastics.
- elevated temperatures e.g.> 90 ° C
- the matrix melts into a concentrated paste, with no flocculation of the particles.
- the minimum amount required can theoretically be determined from the specific surface of the solid particles e.g. of the pigments and the hydrodynamic volume of the cellulose in the solution. In practice, however, the procedure is first to start an experiment with an excess of cellulose solution and then to subject the liquid dispersion to ultrafiltration, in which only the solution passes, whereas the particles coated with a monomolecular layer remain.
- the required minimum amount can be calculated from the difference between the predetermined amount and the amount drawn off by ultrafiltration.
- the constituents intended for the matrix or the casing are heated until a solution or melt is formed, and then the previously comminuted solid particles are stirred in.
- the viscosity of the solution in which the solid particles are dispersed can be varied within relatively wide limits, it is expediently 0.5 to 200 mPa s, measured at 90 ° C.
- the viscosity depends to a large extent on the concentration and the DP of the cellulose used.
- the molecular weight of the cellulose used also has an influence on the dispersibility. It has DP from 600 to 700 proved to be particularly advantageous. In general, it can be said that the lower the DP, the better the cellulose is adsorbed on the dispersed particles.
- the amounts of the individual components of the composition and also the process conditions in the preparation of the composition such as temperature, viscosity and the like. can be varied within relatively wide limits and adapted to the respective application.
- the advantageous composition can easily be determined on the basis of simple preliminary tests.
- the composition contains the individual components in approximately the following amounts.
- Cellulose 0.5 to 10% by weight, solid particles 5 to 60% by weight and a mixture of tertiary amine oxide, water and optionally other constituents, the remainder 100%.
- the temperature at which the solid particles are distributed in the solution depends on the NMMO: water ratio.
- the monohydrate of N-methylmorpholine-N-oxide has a melting point of about 72 ° C., so that a few degrees above it is sufficient to be able to produce a dispersion.
- very high concentrations of solid particles can be dispersed.
- the mass is generally solidified, for example by pouring it into a mold and cooling.
- the shaping can be comminuted without difficulty, for example by grinding.
- celluloses of the most varied of origins and with the most varied degrees of polymerization can be used to produce the casing or the matrix, such as cotton backs, cotton fibers, microcrystalline cellulose, cellulose obtained from wood, etc.
- the degrees of polymerization can easily be between 150 to 7000. Higher or lower values are not excluded. Mixtures of different degrees of polymerization can also be used.
- compositions obtained can be readily distributed in cellulosic spinning masses which contain tertiary amine oxides, water and possibly other additives.
- the particles are distributed very evenly very quickly.
- threads, films and membranes can be matted with titanium dioxide in a particularly advantageous manner.
- the production of barium sulfate-containing threads is also very simple, threads that have a particular stability against UV radiation.
- X-ray contrast fibers containing barium sulfate can also be produced particularly advantageously for medical purposes.
- compositions according to the invention can also be used in appropriate amounts in the preparation of the spinning mass. So you can mix and melt the composition with an NMMO / ⁇ O mixture and then add the cellulose, if necessary, excess water is removed.
- the distribution of synthetic polymers can also be carried out without any problems.
- dope can also be doped excellently.
- the liquid dispersion can also be deformed into discrete particles by spraying. Spraying can be done using conventional equipment. The size of the particles can be easily controlled by varying the spray speed, the length of the spray path and the conditions in the spray channel, such as temperature and pressure.
- Viscosity also plays a role; it is possible to adjust the viscosity, e.g. to control the shape of the discrete particles by varying the concentration or DP of the cellulose used.
- the shape of the particles obtained in the spraying process can also be influenced by other additives. In this way, discrete particles can be produced in powder form, with spherical, granular, rod-like shapes, etc.
- the degree of polymerization (DP) of cellulose was calculated in copper (II) ethylenediamine (Merck) by viscometric measurements of the intrinsic viscosity (ETA) according to the Staudinger equation:
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Paper (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8526571A JPH11501071A (ja) | 1995-03-04 | 1996-02-26 | 微細固体粒子を含有する組成物 |
PL96322109A PL322109A1 (en) | 1995-03-04 | 1996-02-26 | Composition containing fine solid particles |
EP96905800A EP0813573A1 (de) | 1995-03-04 | 1996-02-26 | Feine, feste teilchen enthaltende zusammensetzung |
AU49416/96A AU4941696A (en) | 1995-03-04 | 1996-02-26 | Composition containing fine solid particles |
US08/894,946 US5895795A (en) | 1995-03-04 | 1996-02-26 | Composition containing fine solid particles |
SK1153-97A SK115397A3 (en) | 1995-03-04 | 1996-02-26 | Composition containing fine solid particles, method of producing said composition and its use |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19507589.7 | 1995-03-04 | ||
DE19507589 | 1995-03-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996027638A1 true WO1996027638A1 (de) | 1996-09-12 |
Family
ID=7755632
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1996/000782 WO1996027638A1 (de) | 1995-03-04 | 1996-02-26 | Feine, feste teilchen enthaltende zusammensetzung |
Country Status (11)
Country | Link |
---|---|
US (1) | US5895795A (de) |
EP (1) | EP0813573A1 (de) |
JP (1) | JPH11501071A (de) |
KR (1) | KR19980701923A (de) |
CN (1) | CN1177364A (de) |
AU (1) | AU4941696A (de) |
CA (1) | CA2214402A1 (de) |
PL (1) | PL322109A1 (de) |
SK (1) | SK115397A3 (de) |
TW (1) | TW442525B (de) |
WO (1) | WO1996027638A1 (de) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998058015A1 (de) * | 1997-06-16 | 1998-12-23 | Lenzing Aktiengesellschaft | Zusammensetzung enthaltend feine feststoffteilchen |
WO2000014165A1 (de) * | 1998-09-02 | 2000-03-16 | Sachtleben Chemie Gmbh | Präparationsmittel |
WO2001011121A1 (de) * | 1999-08-10 | 2001-02-15 | Lenzing Aktiengesellschaft | Gefärbte cellulosische formkörper |
US6235392B1 (en) | 1996-08-23 | 2001-05-22 | Weyerhaeuser Company | Lyocell fibers and process for their preparation |
WO2004081267A1 (en) * | 2003-03-10 | 2004-09-23 | Politechnika Lódzka | The method of making modified cellulose fibers |
AT504005B1 (de) * | 2003-07-11 | 2008-03-15 | Thueringisches Inst Textil | Thermostabile form- oder spinnmasse |
US8367203B2 (en) | 2005-08-26 | 2013-02-05 | Lenzing Aktiengesellschaft | Cellulosic molded body, method for manufacturing it and use thereof |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1208382B1 (de) | 1999-08-17 | 2006-04-26 | Luminex Corporation | Verkapselung von fluoreszierenden partikeln |
DE102006033591B4 (de) * | 2006-07-18 | 2008-10-16 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Verfahren zur Stabilisierung der Spinnlösung bei der Herstellung von cellulosischen Verbundformkörpern |
NO20065147L (no) * | 2006-11-08 | 2008-05-09 | Ntnu Tech Transfer As | Nanokompositter basert på cellulosewhiskers og celluloseplast |
CN102704023B (zh) * | 2012-05-24 | 2014-04-16 | 恒天海龙股份有限公司 | 一种防x射线辐射纤维素纤维及其制备方法 |
US20230147314A1 (en) * | 2020-03-31 | 2023-05-11 | Aditya Birla Science and Technology Company Private Limited | A method of preparing dope dyed lyocell fibre |
EP4155438A1 (de) * | 2021-09-28 | 2023-03-29 | Lenzing Aktiengesellschaft | Lyocellfaser mit einem mattierungsmittel und verwendung zur herstellung eines textilen gewebes |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0047929A2 (de) * | 1980-09-13 | 1982-03-24 | Akzo GmbH | Cellulose-Form-und-Spinnmasse mit geringen Anteilen an niedermolekularen Abbauprodukten sowie Verfahren zur Herstellung und Verwendung zu Formkörpern |
DE4106029A1 (de) * | 1990-03-01 | 1991-11-07 | Chemiefaser Lenzing Ag | Stabile form- bzw. spinnmasse |
EP0553070A1 (de) * | 1992-01-23 | 1993-07-28 | Lenzing Aktiengesellschaft | Aminoxide |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3659660A (en) * | 1970-04-10 | 1972-05-02 | Dresser Ind | Large diameter bit for shallow angle holes |
AT399519B (de) * | 1993-09-14 | 1995-05-26 | Chemiefaser Lenzing Ag | Form- bzw. spinnmasse enthaltend cellulose und verfahren zur herstellung cellulosischer formkörper |
AT402410B (de) * | 1995-04-19 | 1997-05-26 | Chemiefaser Lenzing Ag | Verfahren zur herstellung einer cellulosesuspension |
-
1996
- 1996-02-26 KR KR1019970705320A patent/KR19980701923A/ko not_active Application Discontinuation
- 1996-02-26 WO PCT/EP1996/000782 patent/WO1996027638A1/de not_active Application Discontinuation
- 1996-02-26 CA CA002214402A patent/CA2214402A1/en not_active Abandoned
- 1996-02-26 US US08/894,946 patent/US5895795A/en not_active Expired - Fee Related
- 1996-02-26 AU AU49416/96A patent/AU4941696A/en not_active Abandoned
- 1996-02-26 PL PL96322109A patent/PL322109A1/xx unknown
- 1996-02-26 SK SK1153-97A patent/SK115397A3/sk unknown
- 1996-02-26 EP EP96905800A patent/EP0813573A1/de not_active Withdrawn
- 1996-02-26 JP JP8526571A patent/JPH11501071A/ja active Pending
- 1996-02-26 CN CN96192352A patent/CN1177364A/zh active Pending
- 1996-03-04 TW TW085102627A patent/TW442525B/zh not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0047929A2 (de) * | 1980-09-13 | 1982-03-24 | Akzo GmbH | Cellulose-Form-und-Spinnmasse mit geringen Anteilen an niedermolekularen Abbauprodukten sowie Verfahren zur Herstellung und Verwendung zu Formkörpern |
DE4106029A1 (de) * | 1990-03-01 | 1991-11-07 | Chemiefaser Lenzing Ag | Stabile form- bzw. spinnmasse |
EP0553070A1 (de) * | 1992-01-23 | 1993-07-28 | Lenzing Aktiengesellschaft | Aminoxide |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6235392B1 (en) | 1996-08-23 | 2001-05-22 | Weyerhaeuser Company | Lyocell fibers and process for their preparation |
US6488876B1 (en) | 1997-06-16 | 2002-12-03 | Lenzing Aktiengesellschaft | Composition containing fine solid particles |
AT404846B (de) * | 1997-06-16 | 1999-03-25 | Chemiefaser Lenzing Ag | Zusammensetzung enthaltend feine feststoffteilchen |
AU734982B2 (en) * | 1997-06-16 | 2001-06-28 | Lenzing Aktiengesellschaft | Composition containing fine solid particles |
WO1998058015A1 (de) * | 1997-06-16 | 1998-12-23 | Lenzing Aktiengesellschaft | Zusammensetzung enthaltend feine feststoffteilchen |
WO2000014165A1 (de) * | 1998-09-02 | 2000-03-16 | Sachtleben Chemie Gmbh | Präparationsmittel |
US6635694B1 (en) | 1998-09-02 | 2003-10-21 | Sachtleben Chemie Gmbh | Preparation agents |
AT407997B (de) * | 1999-08-10 | 2001-07-25 | Chemiefaser Lenzing Ag | Gefärbte cellulosische formkörper |
WO2001011121A1 (de) * | 1999-08-10 | 2001-02-15 | Lenzing Aktiengesellschaft | Gefärbte cellulosische formkörper |
US6793689B2 (en) | 1999-08-10 | 2004-09-21 | Lenzing Aktiengesellschaft | Dyed cellulosic moulded bodies |
BG65520B1 (bg) * | 1999-08-10 | 2008-10-31 | Lenzing Aktiengesellschaft | Оцветени целулозни формовани тела |
CZ304940B6 (cs) * | 1999-08-10 | 2015-02-04 | Lenzing Aktiengesellschaft | Obarvené celulózové tvarované těleso |
WO2004081267A1 (en) * | 2003-03-10 | 2004-09-23 | Politechnika Lódzka | The method of making modified cellulose fibers |
AT504005B1 (de) * | 2003-07-11 | 2008-03-15 | Thueringisches Inst Textil | Thermostabile form- oder spinnmasse |
US8367203B2 (en) | 2005-08-26 | 2013-02-05 | Lenzing Aktiengesellschaft | Cellulosic molded body, method for manufacturing it and use thereof |
Also Published As
Publication number | Publication date |
---|---|
TW442525B (en) | 2001-06-23 |
CN1177364A (zh) | 1998-03-25 |
EP0813573A1 (de) | 1997-12-29 |
JPH11501071A (ja) | 1999-01-26 |
CA2214402A1 (en) | 1996-09-12 |
SK115397A3 (en) | 1998-02-04 |
AU4941696A (en) | 1996-09-23 |
PL322109A1 (en) | 1998-01-05 |
US5895795A (en) | 1999-04-20 |
KR19980701923A (ko) | 1998-06-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0356419B1 (de) | Verfahren zur Herstellung von Lösungen von Cellulose | |
AT402410B (de) | Verfahren zur herstellung einer cellulosesuspension | |
EP1943296B1 (de) | Verfahren zur herstellung von ultrafeinen pulvern auf basis von polyamiden, ultrafeinen polyamidpulvern sowie deren verwendung | |
DE2822148C2 (de) | Verfahren zur Herstellung eines pulverförmigen, füllstoffhaltigen Kautschuks | |
WO1996027638A1 (de) | Feine, feste teilchen enthaltende zusammensetzung | |
DE2356727A1 (de) | Verfahren zum digerieren von normalerweise festen, in wasser und alkalien unloeslichen additionspolymeren | |
EP1483336B2 (de) | Verfahren zur herstellung von gecoateten, feinteiligen, anorganischen festk rpern und deren verwendung | |
EP2141124B1 (de) | Verfahren zur Herstellung von grob- und/oder nanoskaligen, gecoateten, desagglomerierten Magnesiumhydroxidpartikeln | |
EP0918815B1 (de) | Zusammensetzung enthaltend feine feststoffteilchen | |
EP2154177B1 (de) | Herstellungsverfahren von thermoplastischen Polymeren enthaltend grobskalige und/oder nanoskalige, gecoatete, dessagglomerierte Magnesiumhydroxidpartikel und eine Vorrichtung hierzu | |
DE1916267C3 (de) | Verfahren zum Einbringen von Zusatzstoffen in thermoplastische Kunststoffe | |
DE2247695A1 (de) | Verfahren zur herstellung von pulverfarbe | |
EP1109868B1 (de) | Präparationsmittel | |
DE3689500T2 (de) | Verfahren zur Herstellung von koagulierten kolloidalen Teilchen. | |
DE1467418A1 (de) | Verfahren zur Herstellung von hochkonzentrierten Russaufschlaemmungen | |
DE2257182C3 (de) | Verfahren zur Herstellung von Gemischen von Vinylchloridpolymeren und deren Verwendung zur Herstellung von Plastisolen und Organosolen | |
DE1604349B2 (de) | Granuliertes polytetraaethylenpulver, verfahren zu dessen herstellung und dessen verwendung | |
DE4041382A1 (de) | Verfahren zur herstellung chlorierter polyolefine | |
WO2002031042A2 (de) | Verfahren zur zugabe von anorganischen additiven zu fertigen polymerschmelzen | |
DE2507339A1 (de) | Verfahren zur herstellung von kleinen, kugelfoermigen polypropylenteilchen | |
DE1807891C3 (de) | Verfahren zur Herstellung stabiler Bleichromat-Pigmentprodukte | |
DE19526742A1 (de) | Antistatikadditiv | |
DE1160610B (de) | Verfahren zur Herstellung von Polyaethylenpulver oder von waesserigen Dispersionen von Polyaethylen | |
DE2749241A1 (de) | Verfahren zur herstellung von gefaerbten, stranggepressten produkten | |
WO2000050504A1 (de) | Metalloxide enthaltende kunststoffkomposite |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 96192352.0 Country of ref document: CN |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AL AM AU BB BG BR CA CN CZ EE FI GE HU IS JP KG KP KR LK LR LT LV MD MG MK MN MX NO NZ PL RO SG SI SK TR TT UA US UZ VN AZ BY KG KZ MD RU TJ TM |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1019970705320 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 115397 Country of ref document: SK |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1996905800 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2214402 Country of ref document: CA Ref document number: 2214402 Country of ref document: CA Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 1996 526571 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 08894946 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 1996905800 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1019970705320 Country of ref document: KR |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 1996905800 Country of ref document: EP |
|
WWR | Wipo information: refused in national office |
Ref document number: 1019970705320 Country of ref document: KR |