Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
  • C08F8/00—Chemical modification by after-treatment
  • C08F8/14—Esterification

Definitions

• the lactic acid esterified polyvinyl alcohol is useful in films, moldings and adhesives.
• Polyvinyl alcohol is an article of commerce and useful in fibers, adhesives and textile and paper sizing.
• one of the drawbacks of polyvinyl alcohol is that it is not melt processible, or if modified to make it melt processible, it is often not soluble in cold water and not crystalline, which are desirable properties of this types of polymer.
• Example II which includes polyvinyl alcohol, polyethyleneimine, water and lactic acid.
• This prior art patent discloses a system in which the acid improves the properties of the adhesive described by inhibiting the crosslinking of the polyethyleneimine present.
• esterification of polyvinyl alcohol There is no disclosure in said patent of esterification of polyvinyl alcohol.
• This invention concerns a polymeric composition
• a polymeric composition comprising polyvinyl alcohol in which at least 1% of hydroxyl groups in said polyvinyl alcohol are esterified with lactic acid, and wherein each lactic acid ester group contains an average of 1.0 to about 3 lactic acid residues.
• This invention also concerns a process for
• esterifying polyvinyl alcohol with lactic acid comprising, dissolving polyvinyl alcohol and lactic acid in water, heating at a temperature of about 75°C to about 175°C to remove water by vaporization, to produce a lactic acid esterified polyvinyl alcohol.
• Polyvinyl alcohol has the repeat unit -CH 2 CH(OH)-, which when esterified by lactic acid in the instant invention is converted to the repeat unit
• m is, on average, 1.0 to about 3. It is believed that the variation in m makes lactic acid particularly effective in lowering the melting point of the polyvinyl alcohol. It is preferred if about 5 to about 50 percent, more preferably about 8 to about 20 percent, of the hydroxyl groups in the polyvinyl alcohol are esterified with lactic acid.
• m is an average of the number of monomeric lactic acid units per esterified polyvinyl alcohol hydroxyl group. It can be a fractional value because each esterified polyvinyl alcohol hydroxyl group may have a different number of lactic acid units attached, and m is an average value. However, m can never be less than 1.0, since each esterified hydroxyl group must be esterified by at least 1 lactic acid unit. As the ratio of lactic acid to polyvinyl alcohol in the initial reaction mixture increases, m will also increase.
• the process used to esterify the polyvinyl alcohol with lactic acid, as described herein, has several advantages.
• the only other ingredient is water, which is both cheap and nonflammable.
• the initial "molar" ratio of polyvinyl alcohol repeat unit: lactic acid in the esterification process will be about 100:1 to about 1:1.
• Lactic acid carboxyl groups should be free to esterify the hydroxyl groups of the polyvinyl alcohol, thus compounds which readily react with carboxyl groups to form other groupings should be avoided.
• the amount of water initially present in the reaction mixture will preferably be about the minimum needed to dissolve both the polyvinyl alcohol and lactic acid, or to achieve a low enough viscosity in the solution so that it may be transferred to another container, if needed (the viscosity will be most
• the solution is then heated to 75°C to 175°C, while simultaneously removing the water by vaporization.
• the process liquid may be sparged with the gas.
• the water that is removed is not only the water originally present, but also includes the water which is the byproduct of the esterification reaction.
• Volatilization of the water may also be aided by adding a compound which forms an azeotrope with water (see Example 1) . It is preferred that the temperature of the process liquid is about 90°C to about 130°C.
• the process be carried out in the absence of oxygen to avoid possible oxidation or other degradation of the process
• the starting polyvinyl alcohol have a relatively low ash content and that it contain a relatively low amount of inorganic salts (including metal carboxylates).
• the polymer may be purified by washing (see below).
• the lactic acid esterified polymer produced herein is useful as a molding resin, for films, for fibers and for adhesives, especially hot melt adhesives. It has the advantage of being fully or parLially soluble in cold water, being melt processible, and in some cases, also having a melting point, which indicates possibly higher use temperatures.
• the following abbreviations are used:
• Tg - glass transition temperature or point The polyvinyl alcohol beads used as a starting material in the Examples were purified by washing with a mixture of 80% methanol-20% water (v/v), the mixture being a nonsolvent for the polymer. Inorganic content, reported nominally as sodium acetate is given below:
• the polymer has a number average molecular weight of 50,000 to 70,000.
• the polymer was partly soluble in cold water.
• the degree of grafting determined by 13 C NMR (in d 5 -pyridine) was ca. 31%, and the average graft length was 1.3 lactic acid units per graft.
• DSC showed a T g around 43°C and no melting point.
• the polymer was partly soluble in cold water.
• the degree of grafting determined by 13 C NMR (in d 5 -pyridine) was ca. 29%, and the average graft length was 1.2 lactic acid units per graft.
• DSC showed a T g around 53°C and no melting point.
• the polymer was partly soluble in cold water.
• the degree of grafting determined by 13 C NMR (in ds-pyridine) was ca. 32 %, and the average graft length was 1.5 lactic acid units per graft.
• DSC showed a T g around 50°C and no melting point.
• the polymer was partly soluble in cold water. The degree of grafting could not be measured since the polymer was insoluble in the NMR solvent. DSC showed a T g around 50°C and a very broad melting point over the range 120-180°C. A polymer film was produced through compression molding at 170-180°C.
• the polymer was partly soluble in cold water. The degree of grafting could not be measured since the polymer was insoluble in the NMR solvent. DSC showed a T g around 54°C and a very broad melting point over the range 100-160°C. A polymer film was produced through compression molding at 170-180°C.
• the polymer was soluble in cold water.
• the degree of grafting determined by 13 C NMR (in ds-pyridine) was ca 14%, with the average graft length of 1.1 lactic acid units per graft.
• DSC shows a T g around 58°C and a weak and broad melting point in the range 100-150°C.
• a polymer film was produced through compression molding at 150-170°C, and the corresponding physico-mechanical properties compare well with those of a solvent cast, unmodified PVOH film: PVOH, cast film pressed

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• Chemical & Material Sciences (AREA)
• General Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
• Manufacture Of Macromolecular Shaped Articles (AREA)
• Polysaccharides And Polysaccharide Derivatives (AREA)
• Polyesters Or Polycarbonates (AREA)
• Biological Depolymerization Polymers (AREA)

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Publications (2)

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Cited By (2)

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• 1993
  • 1993-02-12 US US08/017,234 patent/US5331045A/en not_active Expired - Lifetime
• 1994
  • 1994-02-03 WO PCT/US1994/000936 patent/WO1994018243A2/en not_active Ceased
  • 1994-02-03 DK DK94906713.6T patent/DK0683794T3/da active
  • 1994-02-03 DE DE69403067T patent/DE69403067T2/de not_active Expired - Fee Related
  • 1994-02-03 ES ES94906713T patent/ES2101509T3/es not_active Expired - Lifetime
  • 1994-02-03 EP EP94906713A patent/EP0683794B1/en not_active Expired - Lifetime
  • 1994-02-03 JP JP51809294A patent/JP3430373B2/ja not_active Expired - Fee Related
  • 1994-02-03 AT AT94906713T patent/ATE152738T1/de not_active IP Right Cessation
  • 1994-02-03 CA CA002155115A patent/CA2155115C/en not_active Expired - Fee Related
• 1997
  • 1997-07-16 GR GR970401768T patent/GR3024118T3/el unknown

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