WO1992021241A1 - Composition insecticide et bactericide utilisee en agriculture et en horticulture - Google Patents

Composition insecticide et bactericide utilisee en agriculture et en horticulture Download PDF

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Publication number
WO1992021241A1
WO1992021241A1 PCT/JP1992/000714 JP9200714W WO9221241A1 WO 1992021241 A1 WO1992021241 A1 WO 1992021241A1 JP 9200714 W JP9200714 W JP 9200714W WO 9221241 A1 WO9221241 A1 WO 9221241A1
Authority
WO
WIPO (PCT)
Prior art keywords
group
optionally substituted
insecticidal
cycloalkyl
pyridyl
Prior art date
Application number
PCT/JP1992/000714
Other languages
English (en)
Japanese (ja)
Inventor
Michihiko Matsuda
Nobuo Takakusa
Atsushi Yamamoto
Takao Iwasa
Sho Hashimoto
Original Assignee
Nippon Soda Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP3159690A external-priority patent/JP2990865B2/ja
Priority claimed from JP16742691A external-priority patent/JPH04368304A/ja
Application filed by Nippon Soda Co., Ltd. filed Critical Nippon Soda Co., Ltd.
Publication of WO1992021241A1 publication Critical patent/WO1992021241A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Definitions

  • the present invention relates to a novel insecticide for agricultural and horticultural use having an excellent insecticidal and fungicidal effect comprising a combination of an amide derivative of the following general formula [I] and an ergosterone cleaving inhibitor (hereinafter referred to as an EBI agent). Regarding the composition.
  • the present inventors have studied a more effective use of the amide derivative represented by the following formula I: and studied a combination with an EBI agent. It has been found that chestnuts are effective and fungicidal: ..
  • the present invention has the general formula (I): R ;
  • R represents an unsubstituted pyridyl group, a pyrazyl group or a thiazolyl group, excluding an unsubstituted 2-pidyl group
  • X represents an optionally substituted alkylene group or an alkylidene group
  • R represents an aryl group, R represents a hydrogen atom, an optionally substituted alkyl group or a cycloalkyl group, and R represents an optionally substituted alkyl group;
  • a toco group a fungicidal composition for agricultural and horticultural use containing the compound represented by or a salt thereof and EBI; j;
  • insecticidal / bactericidal composition for example, important insect pests of rice plants, leafhoppers, blasts, for example, aphids, two-naga, leaf snails, and udon, which are important pests such as fruit trees and vegetables.
  • Scab, scab important disease of wheat The effect on insect pests, aphids and powdery mildew, was greater than that of a single activated platform alone, indicating synergistic insecticidal and E-killing effects.
  • Tri-noremazole which inhibits the second cytochrome P—450
  • a halogen atom such as a chloro atom
  • a pyridyl group substituted with a cyano group or a lower alkyl group or a halogen atom such as a chloro atom.
  • X is a methylene group
  • R 2 is a hydrogen atom, a lower alkyl group, an alkyl group substituted with a cyano group, an aryl group, a propargyl group, a cyclopropyl group, a lower alkoxy group, a methoxymethyl group, a tylthiomethyl group, or a chloro atom.
  • Optionally substituted benzene a pyridylmethyl group substituted with a kappa atom, a pyridylethyl group substituted with a kappa atom, an acetyl group, or a benzoyl group substituted with a chloro atom.
  • R 3 are a hydrogen atom, a low-alkyl group or a cyclobucopyr group which may be substituted with a halogen atom such as a hydrogen atom or a fluorine atom, an R cyano group or two:
  • a halogen atom such as a hydrogen atom or a fluorine atom, an R cyano group or two:
  • Examples of amine derivatives of the formula: I, which are used in the active substance combination, include the compounds shown in Table 1 below: Preparation of the following amine derivatives or salts thereof Et insecticidal Qi is; use as i is described in WO 9 1 ZG 4 9 6 5 -
  • the EBI agents used in the present invention include: Amimehon, 'I, G :) Ajimehon, Bikorunoru, Funina'mo :, Holin, Pyriphenox, Block Koraz, Bewara No. 21 ', Hexaconazol, Mikrov'
  • the weight ratio of the active compounds of each group in the active substance is the same as that of the active substance group of the amide derivative of the general formula: 1: or a salt thereof; I! . ⁇ ; ⁇ M quantity part can be used
  • the active pesticidal composition according to the present invention exhibits excellent insecticidal and killing effects, foliage application, top dressing, underwater application, surface application ffi, soil surface application, soil admixture, planting hole ⁇ Seedling disinfection, seed disinfection, nursery box application, smoking, fumigation, etc.
  • the activated platform assembly according to the present invention is characterized in that each 'tongue' activated platform has a stronger insecticidal and fungicidal effect than the stand applied in Germany, and has no harm to crops.
  • the insecticidal fungicidal composition of the present invention has a base represented by the general formula: 1 or a salt thereof and an EBI agent as active ingredients, and can be used as a pure active ingredient compound.
  • Ordinary pesticides can take any form, that is, wettable powders, water solvents, water, emulsions, pills, flowables, smokers, fumigants, etc. Separately o You may use a mixture of the following:
  • U agent is huge, soybean flour, soybean flour, etc.
  • Gypsum Gypsum, talc,-,--, mineral and fine powders, organic and inorganic minerals such as sodium benzoate, urea and sodium sulfate are used ::
  • O Bodies that make the dosage form enormous include plants, ⁇ 3 ⁇ 4, kekosin, xylene and petroleum fractions such as' bonnen naphtha ', chikko' ⁇ xane, cyclohexanone, and dimethicone. ./ Reformami, Jimel's Fox, Trichosole, 'Reno,'
  • the above mixture is mixed and pulverized into fine powder, and diluted with water before use as a suspension.
  • Test example 1 Test for radish binker
  • a rice seedling 7 days after germination was transformed into a chemical solution of a composition diluted with water to a predetermined concentration according to the wettable powder shown in Example 1 of the above-mentioned drug and the formulation of Reference Example 1 or 2. It was immersed for 30 seconds. After air-drying, the treated seedlings were placed in a test tube, and 10 to 14 larvae of the third instar larvae of P. persica were inoculated. Cover with gauze, at a temperature of 25, S ⁇ ⁇ 5 5 5 5 Q Q 5 5 5 6 5

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention se rapporte à une composition insecticide et bactéricide, utilisée en agriculture et en horticulture et comprenant un composé représenté par la formule générale (I), ou son sel et un inhibiteur de biosynthèse de l'ergostérol. Dans la formule (I), R1 représente pyridyle, pyrazyle ou thiazolyle qui sont éventuellement substitués exception faite du 2-pyridyle qui est insubstitué; X représente alkylène ou alkylidène éventuellement substitués; R2 représente hydrogène ou alkyle, alcényle, alcynyle, cycloalkyle, cycloalcényle ou aryle, qui sont éventuellement substitués, ou Y-R5; Y représente oxygène ou -CO-; R5 représente alkyle ou aryle éventuellement substitués; R3 représente hydrogène, ou alyle ou cycloalkyle éventuellement substitués; et R4 représente cyano ou nitro. Cette composition possède une action insecticide et bactéricide plus importante que celle d'un composé ayant uniquement un pouvoir insecticide et que celle d'un composé ayant uniquement un pouvoir bactéricide, respectivement, ce qui veut dire qu'elle a une action synergique.
PCT/JP1992/000714 1991-06-04 1992-06-02 Composition insecticide et bactericide utilisee en agriculture et en horticulture WO1992021241A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP3/159690 1991-06-04
JP3159690A JP2990865B2 (ja) 1991-06-04 1991-06-04 農園芸用殺虫殺菌組成物
JP3/167426 1991-06-13
JP16742691A JPH04368304A (ja) 1991-06-13 1991-06-13 農園芸用殺虫殺菌組成物

Publications (1)

Publication Number Publication Date
WO1992021241A1 true WO1992021241A1 (fr) 1992-12-10

Family

ID=26486407

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1992/000714 WO1992021241A1 (fr) 1991-06-04 1992-06-02 Composition insecticide et bactericide utilisee en agriculture et en horticulture

Country Status (1)

Country Link
WO (1) WO1992021241A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996003045A1 (fr) * 1994-07-28 1996-02-08 Bayer Aktiengesellschaft Pesticides
US5977148A (en) * 1995-04-11 1999-11-02 Nipppon Soda Co., Ltd. Termiticide
US6436976B1 (en) 1998-06-10 2002-08-20 Bayer Aktiengesellschaft Agents for combating plant pests
US6436968B1 (en) 1998-06-17 2002-08-20 Bayer Aktiengesellschaft Agents for controlling plant pests
EP2298076A1 (fr) 1998-06-10 2011-03-23 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
RU2431960C9 (ru) * 1994-07-28 2013-05-20 Байер Акциенгезелльшафт Синергетическое средство борьбы с насекомыми

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04154741A (ja) * 1989-10-06 1992-05-27 Nippon Soda Co Ltd アミン誘導体、その製造方法及び殺虫剤

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04154741A (ja) * 1989-10-06 1992-05-27 Nippon Soda Co Ltd アミン誘導体、その製造方法及び殺虫剤

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7008903B2 (en) 1994-07-28 2006-03-07 Bayer Aktiengesellschaft Pesticide
US6114362A (en) * 1994-07-28 2000-09-05 Bayer Aktiengesellschaft Compositions for the control of plant pests
US6297263B1 (en) 1994-07-28 2001-10-02 Bayer Aktiengesellschaft Pesticide
RU2431960C9 (ru) * 1994-07-28 2013-05-20 Байер Акциенгезелльшафт Синергетическое средство борьбы с насекомыми
US7884049B2 (en) 1994-07-28 2011-02-08 Bayer Cropscience Ag Compositions for the control of plant pests
KR100386956B1 (ko) * 1994-07-28 2003-08-25 바이엘 악티엔게젤샤프트 해충구제용 조성물
WO1996003045A1 (fr) * 1994-07-28 1996-02-08 Bayer Aktiengesellschaft Pesticides
EP1609361A3 (fr) * 1994-07-28 2010-01-06 Bayer CropScience Aktiengesellschaft Compositions pour lutter contre les parasites des plantes
US5977148A (en) * 1995-04-11 1999-11-02 Nipppon Soda Co., Ltd. Termiticide
US7696237B2 (en) 1998-06-10 2010-04-13 Bayer Cropscience Ag Agents for combating plant pests
EP2305034A1 (fr) 1998-06-10 2011-04-06 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
US7232840B2 (en) 1998-06-10 2007-06-19 Bayer Cropscience Ag Agents for combating plant pests
US9918474B2 (en) 1998-06-10 2018-03-20 Bayer Intellectual Property Gmbh Agents for combating plant pests
US9504254B2 (en) 1998-06-10 2016-11-29 Bayer Intellectual Property Gmbh Agents for combating plant pests
US6680325B2 (en) 1998-06-10 2004-01-20 Bayer Aktiengesellschaft Agents for combating plant pests
US7763266B2 (en) 1998-06-10 2010-07-27 Bayer Cropscience Ag Agents for combating plant pests
US8617581B2 (en) 1998-06-10 2013-12-31 Bayer Intellectual Property Gmbh Agents for combating plant pests
EP2298076A1 (fr) 1998-06-10 2011-03-23 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
EP2298077A1 (fr) 1998-06-10 2011-03-23 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
EP2301353A1 (fr) 1998-06-10 2011-03-30 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
US6436976B1 (en) 1998-06-10 2002-08-20 Bayer Aktiengesellschaft Agents for combating plant pests
EP2305031A1 (fr) 1998-06-10 2011-04-06 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
EP2305035A1 (fr) 1998-06-10 2011-04-06 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
EP2319314A1 (fr) 1998-06-10 2011-05-11 Bayer CropScience AG Agents pour lutter contre des parasites de végétaux
US8153665B2 (en) 1998-06-17 2012-04-10 Bayer Aktiengesellschaft Agents for controlling plant pests
US7179814B2 (en) 1998-06-17 2007-02-20 Bayer Aktiengesellschaft Agents for controlling plant pests
US6436968B1 (en) 1998-06-17 2002-08-20 Bayer Aktiengesellschaft Agents for controlling plant pests
US8853126B2 (en) 1998-06-17 2014-10-07 Bayer Aktiengesellschaft Agents for controlling plant pests
US6803377B2 (en) 1998-06-17 2004-10-12 Bayer Aktiengesellschaft Agents for controlling plant pests
US7361673B2 (en) 1998-06-17 2008-04-22 Bayer Aktiengesellschaft Agents for controlling plant pests

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