WO1992020851A1 - Aiguille de machine a coudre et procede pour sa fabrication - Google Patents
Aiguille de machine a coudre et procede pour sa fabrication Download PDFInfo
- Publication number
- WO1992020851A1 WO1992020851A1 PCT/JP1992/000599 JP9200599W WO9220851A1 WO 1992020851 A1 WO1992020851 A1 WO 1992020851A1 JP 9200599 W JP9200599 W JP 9200599W WO 9220851 A1 WO9220851 A1 WO 9220851A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- needle
- stem
- degrees
- hole
- angle
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/13—Amines
- A61K31/155—Amidines (), e.g. guanidine (H2N—C(=NH)—NH2), isourea (N=C(OH)—NH2), isothiourea (—N=C(SH)—NH2)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/70—Carbohydrates; Sugars; Derivatives thereof
- A61K31/7004—Monosaccharides having only carbon, hydrogen and oxygen atoms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P1/00—Drugs for disorders of the alimentary tract or the digestive system
- A61P1/02—Stomatological preparations, e.g. drugs for caries, aphtae, periodontitis
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
- A61P31/04—Antibacterial agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21G—MAKING NEEDLES, PINS OR NAILS OF METAL
- B21G1/00—Making needles used for performing operations
- B21G1/02—Making needles used for performing operations of needles with eyes, e.g. sewing-needles, sewing-awls
- B21G1/04—Making needles used for performing operations of needles with eyes, e.g. sewing-needles, sewing-awls of needles specially adapted for use in machines or tools
-
- D—TEXTILES; PAPER
- D05—SEWING; EMBROIDERING; TUFTING
- D05B—SEWING
- D05B85/00—Needles
- D05B85/02—Needles with slotted eyes, i.e. with a slit leading to the eye for thread insertion
Definitions
- the present invention relates to a sewing needle and a method for manufacturing the same.
- the present invention has been made in view of the above-mentioned problems of the related art.
- an object of the present invention is to provide a high-quality sewing needle having sufficient buckling rigidity and hardly causing breakage accidents.
- Another object of the present invention is to provide a sewing needle which can secure a large gap between the needle stem and the sewing thread, stably perform sewing work, and can operate at high speed. is there.
- a further object of the present invention is to enable easy and inexpensive manufacture of high-quality sewing needles having sufficient strength and capable of stable sewing work and high-speed operation.
- An object of the present invention is to provide a method for manufacturing a sewing needle.
- the needle material has a cylindrical handle portion having a large diameter, a first needle stem having a small diameter at one end of the handle portion, and an end portion of the first needle stem having a small diameter.
- the second needle stem which has a small diameter, is formed by connecting it, and the second needle stem is formed with a thin part corresponding to the hole of the sewing needle, and the entire needle stem is die-less processed.
- a continuous groove extending from the handle to a point close to the tip of the second needle stem; a needle hole having a thin portion for the needle hole along the groove; and a hole formed by deforming the thin portion. It is characterized in that the groove is defined by an inner surface portion and an outer surface portion which are expanded at a predetermined angle by deforming the needle stem.
- a thin portion corresponding to the hollow portion of the finished machine needle is formed in advance on the second needle shaft, and the entire needle shaft is die-pressed.
- a hollow part with a sufficient depth is formed without causing burrs on the needle stem, and high-quality sewing needles with sufficient rigidity can be manufactured.
- a sewing needle according to the present invention comprises a cylindrical handle portion having a large diameter, a needle stem extending from the handle portion, and a sharp needle tip formed at the tip of the needle stem. It has a continuous concave thread groove extending from the handle portion to a point close to the tip, a needle hole formed along the thread groove, and a bore formed in the needle stem.
- the needle stem has a large-diameter first needle stem and a small-diameter second needle stem formed by two inclined portions formed at an interval on the opposite side of the thread groove.
- the needle stem is drawn in two stages of the first and second needle stems, and a constricted portion having a hollow portion with a sufficient depth is formed above the needle hole.
- the rigidity of the entire needle is sufficiently large, the gap between the needle stem and the sewing thread at the time of sewing can be increased, and the sewing operation can be performed stably.
- FIG. 1 is a side view of a needle material that has been subjected to two-stage wire drawing so as to be suitable for manufacturing a sewing needle according to the method of the present invention
- FIG. 2 is a view of the needle material shown in FIG.
- Fig. 3 is a side view of a part that has been subjected to plastic working to reduce the diameter of a part of the needle stem and is ready for the next working operation.
- Fig. 3 illustrates the state in which the needle material in Fig. 2 has been pressed.
- FIG. 4 is a cross-sectional view taken along line IV-IV in FIG. 3
- FIG. 5 is a cross-sectional view taken along line V--V in FIG. 3
- FIG. 7 is a cross-sectional view taken along line VI-VI, FIG.
- FIG. 7 is a partial side view showing an example of a sewing needle manufactured by the method of the present invention
- FIG. 8 is a sewing machine shown in FIG.
- Needle length 9 is a partial plan view showing the tip of the sewing machine needle
- FIG. 10 is a partial bottom view showing the tip of the sewing machine needle.
- FIG. 1 shows the shape of a needle material 10 after a two-stage drawing process suitable for manufacturing a machine needle according to the method of the present invention.
- a cylindrical handle portion 12 having a large diameter, and a cylindrical first needle stem portion having a smaller diameter than the handle portion 12 extending from the handle portion 12 via a tapered conical portion 18.
- 14 and a cylindrical second needle stem 16 having a smaller diameter than the first needle stem 14 extending toward the free end via a tapered conical portion 20.
- the needle material 10 shown in FIG. 2 is obtained by subjecting the needle material 10 shown in FIG. 1 to plastic working such as swaging or rolling or grinding, and forming the second needle shaft portion 16.
- a cylindrical slender portion 22 having a smaller diameter and tapered portions 24 and 26 connecting both ends thereof to the second needle stem portion 16 are formed.
- the slender portion 22 and both tapered portions 24 and 26 are provided at positions corresponding to the undercuts formed in the needle stem of the finished machine needle.
- the cross-sectional area of the narrow portion 22 is formed to be 60 to 70%, more preferably 65%, of the cross-sectional area of the second needle stem portion 16. If the cross-sectional area ratio is less than 60%, the machine needle after final finishing The cross-sectional area of the steel tends to be too small, resulting in insufficient strength and breakage. On the other hand, if it exceeds 70%, it becomes impossible to secure the necessary depth of the undercut for sewing.
- the needle material 10 having the slender portion 22 formed thereon is subjected to a diveless process to form a needle hole having a thread groove 28 and a thin portion 32 for a needle hole.
- Form part 30 As a result of this diveless processing, a continuous concave thread groove 28 extending in the length direction from the handle portion 12 to near the tip of the needle stem portion is formed in the needle material 10, and At the same time, the needle hole portion 30 having the thin portion 32 for the needle hole along the thread groove 28 in the second needle stem portion 16 and the thread groove 28 of the second needle stem portion 16 are on the opposite side.
- An undercut 40 is formed.
- the needle stem portions 14 and 16 in which the thread grooves 28 are formed have a substantially U-shaped or V-shaped cross-sectional shape as a whole, including the slender portion 22.
- the inner portion 34 and the outer portion 36 defining the groove 28 are each expanded at a predetermined angle.
- the U-shaped cross-sectional shape of the needle stem is smaller in the slender portion 22 than in the second needle stem 16. Deformed slender part
- 2 2 is the upper part of the needle hole 30 in the finished sewing machine needle.
- the opposite side of the thread groove 28 is recessed inward through the inclined portions 42 and 44 inclined at a predetermined angle with respect to the needle shaft. Are formed.
- the hole portion 40 is located on the opposite side to the thread groove 28, leaving a thin portion 32 for needle hole drilling
- a short groove 46 extending from the tip to the needle tip is formed.
- a flat portion 48 protruding in the lateral direction is further formed on the free end side of the second needle stem portion 16 beyond the needle tip.
- an upper die 50 having a V-shaped convex portion 52 and a lower die 54 having a corresponding concave portion 56 are used.
- the needle stems 14 and 16 are pressed and deformed to allow the metal of the needle stem to flow into the gap between the two dies so that the thread groove 28 and the thread groove 28 are formed without forming burrs in the needle stem.
- a needle hole portion 30 is formed.
- the inner portion 34 and the outer portion 36 that define the thread groove 28 be widened at an angle of 10 to 28 degrees from the viewpoint of sewing and die pressing.
- the angle SM of the outer surface of the V-shaped convex portion 52 of the upper die 50 is less than 30 degrees or preferably 28 degrees at the needle stem portions 14 and 16 and the corresponding lower die 5
- the angle 0 2 1 of the inner surface of the concave portion 5 6 of 4 is preferably in the range of 20 to 28 degrees.
- the outer surface of the V-shaped projection 52 of the upper die 50 has an angle of 12 degrees of 25 degrees, which corresponds to the inner surface of the recess 56 of the lower die 54.
- the angle 0 22 in the range of 1 0-1 8 degrees, and preferred rather is about 1 4 degrees. That is, the recess 5 the angle 0 22 of the inner surface of the 6 Ri at Do rather sewing machine needle Na escape from the mold pressing is less than 1 0 degrees and the Ru exceed 1 8 degrees needle bore width standards exactly Therefore, the radius of the rounded corner at the bottom of the recess 56 becomes too small, and the bank of the short groove 46 becomes too thin to be formed.
- the angle range of the outer surface of the upper die 50 must be large enough to facilitate the threading at the time of sewing and increase the sewing speed. The decision was made in consideration of not increasing the size.
- a preformed slender portion 22 is used in order to prevent unnecessary bulging in the drawing portion 38 in the lateral direction during press working.
- the cross-sectional area of the squeezed portion 38 formed by the bore portion 40 force s of the sewing machine needle is about 65% of the cross-sectional area of the second needle stem 16.
- the shape of the tapered portions 24 and 26 provided at both ends of the slender portion 22 is such that the needle material extends in the needle axis direction at the time of pressing, so that it is set by the length of the inclined portion in the axial direction. It is better to set the tilt angle.
- the reason is that the distance between the upper end of the needle hole (with the sewing machine needle attached to the sewing machine) and the undercut 40 is as short as possible. This is because the flow toward the yarn groove 28 is achieved, and the desired shape of the needle hole portion 30 can be obtained.
- 2 6 inclination angle alpha iota and alpha 2 of about 1 8 degrees and about 1 3 times, respectively. These angles are approximately 9 degrees and approximately 6.5 degrees, respectively, when expressed as gradients with respect to the needle axis.
- the dimensional relationship between the slender portion 22 of the needle material 10 before dieless processing and the tapered portions 24 and 26 located at both ends thereof and the portion corresponding to these portions in the finished machine needle is It is preferable to do the following, but care should be taken to set the ratio appropriately according to the size of the finished sewing machine needle.
- H L 1 L, X 0.6. 6
- HL 3 ⁇ -(HL 1 + HL 2 ) one 0.1
- HL,, HL 2 and HL 3 are respectively die-pressed.
- the needle material 10 that has been subjected to the diveless process cuts the thin portion 32 for the needle hole along the thread groove 26 to form a needle hole 58.
- the flat portion 48 at the tip of the needle tip is fitted into the receiving portion formed on the punch die, and the needle material 10 is aligned and fixed to the die to make an accurate hole. Work is performed. Through this process, the tip of the needle stem is sharpened to form a needle tip 60, and the sewing machine needle 62 is completed.
- the sewing machine needle 62 completed in this way has a needle hole portion 30 above the needle hole portion 30 and a second needle stem portion 16 above the needle hole portion 30.
- a narrower portion 38 is formed which is narrower than the narrower portion 38, and two narrow portions 42 and 44 on the opposite side of the narrower portion 38 from the thread groove 28 retreat toward the center of the needle.
- a boring portion 40 is formed. Accordingly, the needle stem above the needle hole 58 is deflected inward by the undercut 40, so that a large gap between the sewing thread and the needle stem can be secured. It has become.
- the upper end and the lower end of the needle hole 58 (when the sewing machine needle 62 is attached to the sewing machine) have rounded curved edges 64 and 66, respectively.
- the needle stem is prevented from being drawn in two steps and the transverse width of the needle stem in the cross-sectional shape is prevented from becoming large, and the length is reduced in the vertical direction. It has a thicker shape, and the rigidity of the entire needle is sufficiently high. Therefore, breakage accidents during sewing work can be almost eliminated.
- a sufficiently deep undercut portion is formed, the gap between the needle stem and the sewing thread is increased, so that the sewing operation can be performed stably and high-speed operation is enabled.
- the needle surface is finished smoothly by pressing, and the formation of the constricted portion allows for improved penetration resistance and reduced needle heat.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Engineering & Computer Science (AREA)
- Epidemiology (AREA)
- General Chemical & Material Sciences (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Oncology (AREA)
- Dermatology (AREA)
- Communicable Diseases (AREA)
- Sewing Machines And Sewing (AREA)
- Cosmetics (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019930700055A KR950010719B1 (ko) | 1991-05-10 | 1992-05-11 | 재봉틀 바늘 및 그 제조방법 |
DE1992620550 DE69220550T3 (de) | 1991-05-10 | 1992-05-11 | Nähmaschinenadel und Herstellungsverfahren |
US07/966,145 US5392725A (en) | 1991-05-10 | 1992-05-11 | Sewing machine needle and method for manufacturing same |
EP92909648A EP0538486B2 (en) | 1991-05-10 | 1992-05-11 | Sewing machine needle and method of manufacturing same |
BR9205263A BR9205263A (pt) | 1991-05-10 | 1992-05-11 | Processo de fabricacao de uma agulha para maquina de costura e a respectiva agulha |
CZ9351A CZ282000B6 (cs) | 1991-05-10 | 1993-01-20 | Jehla do šicího stroje a způsob její výroby |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3/135954 | 1991-05-10 | ||
JP13595491 | 1991-05-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992020851A1 true WO1992020851A1 (fr) | 1992-11-26 |
Family
ID=15163729
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1992/000599 WO1992020851A1 (fr) | 1991-05-10 | 1992-05-11 | Aiguille de machine a coudre et procede pour sa fabrication |
Country Status (12)
Country | Link |
---|---|
US (1) | US5392725A (ja) |
EP (1) | EP0538486B2 (ja) |
JP (1) | JP2784960B2 (ja) |
KR (1) | KR950010719B1 (ja) |
AU (1) | AU1686692A (ja) |
BR (1) | BR9205263A (ja) |
CA (1) | CA2086763C (ja) |
CZ (1) | CZ282000B6 (ja) |
DE (1) | DE69220550T3 (ja) |
SG (1) | SG43109A1 (ja) |
TW (1) | TW222600B (ja) |
WO (1) | WO1992020851A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016123789A (ja) * | 2015-01-07 | 2016-07-11 | 福井鋲螺株式会社 | 障害釘、弾球遊技機及び障害釘の製造方法 |
JP2018535720A (ja) * | 2015-10-08 | 2018-12-06 | グロッツ−ベッケルト・カーゲー | ミシン針、ミシン針の製造方法及び縫製方法 |
US10638750B2 (en) | 2004-05-20 | 2020-05-05 | Eden Research Plc | Compositions containing a hollow glucan particle or a cell wall particle encapsulating a terpene component, methods of making and using them |
US10667512B2 (en) | 2005-11-30 | 2020-06-02 | Eden Research Plc | Terpene-containing compositions and methods of making and using them |
US10729130B2 (en) | 2004-01-23 | 2020-08-04 | Eden Research Plc | Nematicidal compositions and methods of using them |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5553477A (en) * | 1994-10-07 | 1996-09-10 | United States Surgical Corporation | Progressive die apparatus and method for forming surgical incision members |
JP3524012B2 (ja) | 1999-04-05 | 2004-04-26 | オルガン針株式会社 | ミシン針のプレス装置、及びミシン針のプレス方法 |
DE19932288C2 (de) * | 1999-07-10 | 2001-11-29 | Groz Beckert Kg | Nähmaschinennadel mit verbesserter Schlingenbildung |
JP2004141468A (ja) * | 2002-10-25 | 2004-05-20 | Organ Needle Co Ltd | ミシン針 |
IL163209A (en) * | 2004-07-26 | 2009-08-03 | Yair Eilam | A sewing machine needle for sewing with a complex thread |
JP6027718B2 (ja) * | 2005-11-30 | 2016-11-16 | エーデン リサーチ ピーエルシー | チモール、オイゲノール、ゲラニオール、シトラール、及びl−カルボンから選択されたテルペン又はテルペン混合物を含む組成物及び方法 |
CN102205383B (zh) * | 2010-03-31 | 2014-04-09 | 京达医材科技股份有限公司 | 针灸针的制造方法及其构造 |
JP5748626B2 (ja) * | 2011-09-21 | 2015-07-15 | サンスター株式会社 | 口腔用組成物 |
GB201220940D0 (en) | 2012-11-21 | 2013-01-02 | Eden Research Plc | Method P |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3986468A (en) * | 1975-11-17 | 1976-10-19 | Union Special Corporation | Sewing machine needle |
JPS5637512Y2 (ja) * | 1977-09-30 | 1981-09-02 | ||
JPS60134489U (ja) * | 1984-02-20 | 1985-09-07 | オルガン針株式会社 | タフト針 |
JPS6129813B2 (ja) * | 1976-07-16 | 1986-07-09 | Singer Co | |
JPS6140440B2 (ja) * | 1976-07-16 | 1986-09-09 | Singer Co |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1057860A (en) † | 1911-05-22 | 1913-04-01 | Willis Q Sampson | Method of forming needles. |
US1949349A (en) † | 1933-01-12 | 1934-02-27 | Torrington Co | Sewing machine needle |
US1949350A (en) * | 1933-01-12 | 1934-02-27 | Torrington Co | Method of making sewing machine needles |
GB734656A (en) * | 1953-09-16 | 1955-08-03 | Emilio Penci | Improved needles for sewing machines of the household and of the industrial type, and their system of manufacture |
US3589428A (en) * | 1969-11-05 | 1971-06-29 | Sho Masujima | Process for producing needles for sewing machines |
JPS5637512U (ja) * | 1979-08-29 | 1981-04-09 | ||
US4329693A (en) * | 1979-09-04 | 1982-05-11 | Kaye Instruments, Inc. | Method of and apparatus for data recording and the like |
DE3027534A1 (de) † | 1980-07-21 | 1982-02-18 | Josef 5100 Aachen Zocher | Naehmaschinen-nadel |
US4524815A (en) * | 1981-03-25 | 1985-06-25 | Rhein-Nadel Maschinennadel Gesellschaft mit beschraHaftung | Method of producing sewing machine needles |
US4458614A (en) * | 1982-01-08 | 1984-07-10 | Organ Needle Co. Ltd. | Sewing machine needle |
JPS60134489A (ja) * | 1983-12-23 | 1985-07-17 | Hitachi Ltd | 半導体レ−ザ装置 |
JPS6129813A (ja) * | 1984-07-20 | 1986-02-10 | Olympus Optical Co Ltd | 合焦検出装置におけるサンプリング補正装置 |
JPS6140440A (ja) * | 1984-08-01 | 1986-02-26 | Toyota Motor Corp | 内燃機関の燃料噴射量制御装置 |
US4598753A (en) * | 1984-10-09 | 1986-07-08 | The Singer Company | Method for pressing finless sewing machine needles |
-
1992
- 1992-05-11 AU AU16866/92A patent/AU1686692A/en not_active Abandoned
- 1992-05-11 JP JP4509025A patent/JP2784960B2/ja not_active Expired - Fee Related
- 1992-05-11 BR BR9205263A patent/BR9205263A/pt not_active IP Right Cessation
- 1992-05-11 DE DE1992620550 patent/DE69220550T3/de not_active Expired - Fee Related
- 1992-05-11 US US07/966,145 patent/US5392725A/en not_active Expired - Lifetime
- 1992-05-11 EP EP92909648A patent/EP0538486B2/en not_active Expired - Lifetime
- 1992-05-11 CA CA002086763A patent/CA2086763C/en not_active Expired - Fee Related
- 1992-05-11 WO PCT/JP1992/000599 patent/WO1992020851A1/ja active IP Right Grant
- 1992-05-11 KR KR1019930700055A patent/KR950010719B1/ko not_active IP Right Cessation
- 1992-05-25 TW TW081104067A patent/TW222600B/zh active
-
1993
- 1993-01-20 CZ CZ9351A patent/CZ282000B6/cs not_active IP Right Cessation
-
1996
- 1996-12-28 SG SG1996003787A patent/SG43109A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3986468A (en) * | 1975-11-17 | 1976-10-19 | Union Special Corporation | Sewing machine needle |
JPS6129813B2 (ja) * | 1976-07-16 | 1986-07-09 | Singer Co | |
JPS6140440B2 (ja) * | 1976-07-16 | 1986-09-09 | Singer Co | |
JPS5637512Y2 (ja) * | 1977-09-30 | 1981-09-02 | ||
JPS60134489U (ja) * | 1984-02-20 | 1985-09-07 | オルガン針株式会社 | タフト針 |
Non-Patent Citations (1)
Title |
---|
See also references of EP0538486A4 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10729130B2 (en) | 2004-01-23 | 2020-08-04 | Eden Research Plc | Nematicidal compositions and methods of using them |
US10638750B2 (en) | 2004-05-20 | 2020-05-05 | Eden Research Plc | Compositions containing a hollow glucan particle or a cell wall particle encapsulating a terpene component, methods of making and using them |
US10667512B2 (en) | 2005-11-30 | 2020-06-02 | Eden Research Plc | Terpene-containing compositions and methods of making and using them |
JP2016123789A (ja) * | 2015-01-07 | 2016-07-11 | 福井鋲螺株式会社 | 障害釘、弾球遊技機及び障害釘の製造方法 |
JP2018535720A (ja) * | 2015-10-08 | 2018-12-06 | グロッツ−ベッケルト・カーゲー | ミシン針、ミシン針の製造方法及び縫製方法 |
Also Published As
Publication number | Publication date |
---|---|
DE69220550T3 (de) | 2004-11-18 |
CZ5193A3 (en) | 1993-06-16 |
DE69220550D1 (de) | 1997-07-31 |
JP2784960B2 (ja) | 1998-08-13 |
JPH07501327A (ja) | 1995-02-09 |
BR9205263A (pt) | 1993-07-20 |
TW222600B (ja) | 1994-04-21 |
US5392725A (en) | 1995-02-28 |
CA2086763C (en) | 1996-09-17 |
EP0538486B2 (en) | 2004-03-31 |
CZ282000B6 (cs) | 1997-04-16 |
EP0538486A4 (en) | 1993-12-01 |
SG43109A1 (en) | 1997-10-17 |
DE69220550T2 (de) | 1998-02-05 |
AU1686692A (en) | 1992-12-30 |
EP0538486B1 (en) | 1997-06-25 |
KR950010719B1 (ko) | 1995-09-22 |
EP0538486A1 (en) | 1993-04-28 |
CA2086763A1 (en) | 1992-11-11 |
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