WO1982001993A1 - Use of polyethylene imine as absorbant for odorous substances - Google Patents

Use of polyethylene imine as absorbant for odorous substances Download PDF

Info

Publication number
WO1982001993A1
WO1982001993A1 PCT/DE1981/000226 DE8100226W WO8201993A1 WO 1982001993 A1 WO1982001993 A1 WO 1982001993A1 DE 8100226 W DE8100226 W DE 8100226W WO 8201993 A1 WO8201993 A1 WO 8201993A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyethyleneimine
polyethylene imine
odor
odorous substances
air
Prior art date
Application number
PCT/DE1981/000226
Other languages
German (de)
English (en)
French (fr)
Inventor
Holger Meyer
Original Assignee
Holger Meyer
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Holger Meyer filed Critical Holger Meyer
Priority to NL8120479A priority Critical patent/NL8120479A/nl
Priority to BR8108919A priority patent/BR8108919A/pt
Publication of WO1982001993A1 publication Critical patent/WO1982001993A1/en
Priority to DK360582A priority patent/DK360582A/da
Priority to FI822843A priority patent/FI76495C/fi
Priority to NO822800A priority patent/NO158281C/no

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/14Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/015Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/12Apparatus, e.g. holders, therefor
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00Anti-perspirants or body deodorants

Definitions

  • the invention relates to the use of polyethyleneimine for the absorption of odor-active substances.
  • polyethyleneimine is extremely suitable for forming stable absorption compounds with fatty acids, aldehydes and ketones and thus rendering them odorless.
  • the invention accordingly relates to the use of polyethyleneimine for the absorption of odor-active substances.
  • odor absorbent The most important requirements to be met by an odor absorbent are good effectiveness ibei lower Amount of use, value for money, odorlessness, toxicological harmlessness, compatibility with materials to be treated and biodegradability. These requirements are ideally met by polyethyleneimine.
  • Polyethyleneimine is made by polymerizing ethyleneimine.
  • the degree of polymerization of the polyethylene imine used according to the invention must be so high that the polyethyleneimine is toxicologically harmless. As the degree of polymerization increases, the water solubility of the polyethyleneimine decreases.
  • the degree of polymerization of the polyethyleneimine used according to the invention is not subject to any restrictions apart from the aforementioned minimum degree of polymerization, those polymeric ethyleneimines which still have sufficient water solubility are preferred for reasons of easier handling.
  • Such polyethyleneimines are commercially available and are known to the person skilled in the art with regard to their properties (cf. Ullmann's Encyclopedia of Industrial Chemistry, 3rd edition, 3rd volume, page 144, for example "Polymin P", trademark of BASF).
  • polyethyleneimine according to the invention can be carried out in various ways. Doing so the amount to be used is of course dependent on the concentration of the odor-active substances to be absorbed in the medium to be treated. Because of their ease of use, the use of aqueous polyethyleneimine solutions is appropriate. Although the polyethyleneimine concentration in these solutions is not of critical importance (good results are already achieved with polyethyleneimine concentrations in the range of 0.01%), a polyethyleneimine concentration of 0.1 to 10% and preferably 1 to 3% has been found, particularly from an economic point of view. proven.
  • Solutions of polyethyleneimine in water or other solvents and mixtures thereof are suitable for spraying or atomizing and are preferably used in this way.
  • Another preferred embodiment of the invention consists in impregnating materials which come into contact with odor-active substances with polyethyleneimine. So substances, substances, filters or filter masses and objects such as shoe insoles can be impregnated with polyethyleneimine,
  • polyethyleneimine in particular fatty acids, aldehydes and ketones
  • Absorp tion of amines and sulfides less pronounced, so that a longer contact is required for fully satisfactory results.
  • the polyethyleneimine used according to the invention together with other odor absorbents in order to ensure that compounds such as amines and sulfides are also completely absorbed with short contact times.
  • the polyethyleneimine can be used alone or together with other odor absorbents, depending on the application, together with other customary substances.
  • polyethyleneimine to absorb odor-active substances is practically possible wherever odor elimination is desired.
  • Preferred areas of application are cosmetics and body care, technical odor elimination and room air improvement.
  • polyethyleneimine can be used in body deodorants.
  • shoe insoles can be impregnated with polyethyleneimine.
  • polyethyleneimine for odor control in sewage treatment plants, in particular the waste air that accumulates in these.
  • the invention in particular gives the municipalities the possibility of freeing the residents of municipal sewage treatment plants from often very unpleasant odors in a simple and inexpensive manner.
  • Other areas of application that are suitable for odor elimination using polyethyleneimine include stables, animal processing plants, hospitals and chemical companies.
  • polyethyleneimine as an odor absorbent
  • Another focus of the use according to the invention of polyethyleneimine as an odor absorbent is in the field of indoor air improvement. So can in the air duct. Lines, ducts and shafts of air conditioning and air circulation systems are sprayed with polyethyleneimine solutions, which leads to a continuous elimination of unwanted and undesirable odors.
  • filters which are impregnated with polyethyleneimine can be used in the systems mentioned and in exhaust air purification systems. In this way, the required fresh air supply is reduced, which in turn leads to energy savings.
  • the use of polyethyleneimine solutions in the form of sprays to improve the odor in, for example, toilets and kitchens is particularly suitable.
  • the absorption of a number of odor-active substances was investigated with the help of polyethyleneimine.
  • polyethyleneimine For this purpose, about 50 g of gauze were impregnated with 100 ml of a 1.5% aqueous polyethyleneimine solution and then for 24 hours air dried.
  • the gauze impregnated in this way was introduced into a closed system with a volume of approximately 300 ml.
  • the air in the closed system was circulated by an integrated diaphragm pump. In each case 0.01 g of an odor-active substance was introduced into the circuit.
  • the action of the polyethyleneimine can be supported by adding other absorbents such as zinc sulfate, zinc ricinoleate, soda and zinc carbonate.
  • the exiting air mixture (see Example 1) is then free of all odor-active substances used.
  • a typical wording is as follows:
  • porous support materials such as cotton mats, felt mats, paper or plastic mats were treated with a 1.0 to 2.0% aqueous solution of polyethyleneimine and arranged in an air stream.
  • activated carbon was soaked or sprayed with a 1.0 to 2.0% polyethyleneimine solution and placed in a frame in an air stream.
  • a 0.1 to 2.0% aqueous solution of polyethyleneimine was atomized into an air circuit or an air outlet (e.g. air conditioning, Exhaust air) or atomized via clarifiers or introduced into their air suction.
  • Formulations for cosmetic purposes a) deodorant spray
  • composition is filled as a pump spray using a "press pack” system or with propellant.
  • compositions according to a) and b) are suitable as an additive in soap finishing, the amount of the additive preferably being about 1.0 to 2.0%.
  • Composition A was filled using a "press pack” system while Composition B was filled with a blowing agent in a weight ratio of 70:30.
  • polyethyleneimine "Polymin P” and “Polymin SK” (trademark of BASF) were used.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
PCT/DE1981/000226 1980-12-18 1981-12-16 Use of polyethylene imine as absorbant for odorous substances WO1982001993A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NL8120479A NL8120479A (nl) 1980-12-18 1981-12-16 Toepassing van polyethyleenimine voor het absorberen van geuraktieve stoffen.
BR8108919A BR8108919A (pt) 1980-12-18 1981-12-16 Utilizacao de polietilenimina para a absorcao de substancias de odoridade ativa
DK360582A DK360582A (da) 1980-12-18 1982-08-11 Anvendelse af polyethyleniaain til absorption af lugtaktive stoffer
FI822843A FI76495C (fi) 1980-12-18 1982-08-16 Anvaendning av polyetylenimin foer luktbekaempning.
NO822800A NO158281C (no) 1980-12-18 1982-08-17 Anvendelse av polyethyleniminloesninger ved luktbekjempelse

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3047774801218 1980-12-18
DE3047774A DE3047774C2 (de) 1980-12-18 1980-12-18 Verwendung von Polyethyleniminlösungen zur Geruchsbekämpfung

Publications (1)

Publication Number Publication Date
WO1982001993A1 true WO1982001993A1 (en) 1982-06-24

Family

ID=6119535

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE1981/000226 WO1982001993A1 (en) 1980-12-18 1981-12-16 Use of polyethylene imine as absorbant for odorous substances

Country Status (16)

Country Link
JP (1) JPS57501944A (it)
AU (1) AU550277B2 (it)
BR (1) BR8108919A (it)
CA (1) CA1173631A (it)
CH (1) CH658392A5 (it)
DE (1) DE3047774C2 (it)
ES (1) ES508649A0 (it)
FI (1) FI76495C (it)
FR (1) FR2497670B1 (it)
GB (1) GB2102292B (it)
GR (1) GR76970B (it)
IT (1) IT1142135B (it)
NL (1) NL8120479A (it)
PT (1) PT74148B (it)
SE (1) SE448148B (it)
WO (1) WO1982001993A1 (it)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0277398A1 (en) * 1985-10-31 1988-08-10 Aikoh Co. Ltd. A deodorant composition and use thereof
EP0858797A1 (fr) * 1997-02-14 1998-08-19 L'oreal Composition déodorante comprenant un dendrimère
WO2003088931A2 (en) * 2002-04-16 2003-10-30 Cosmetica, Inc. Polymeric odor absorption ingredients for personal care products
WO2005110502A1 (en) * 2004-04-30 2005-11-24 Kimberly-Clark Worldwide, Inc. Absorption of pain-causing agents
DE102009040089A1 (de) 2009-09-04 2011-07-21 Beiersdorf AG, 20253 Zubereitungen mit wasserunlöslichen polymeren Aminen zur Verminderung von Körpergeruch
WO2012175330A2 (en) 2011-06-20 2012-12-27 L'oreal Cosmetic use of a flocculant polymer as antiperspirant
KR20140040102A (ko) * 2011-02-11 2014-04-02 킴벌리-클라크 월드와이드, 인크. 살균 용액과 함께 사용하기 위한 와이프
US8778321B2 (en) 2007-10-01 2014-07-15 Nanotex Llc Modification of cellulosic substrates to control body odor
US9260817B2 (en) 2009-09-18 2016-02-16 The Procter & Gamble Company Freshening compositions comprising malodor binding polymers and malodor counteractants
US9273427B2 (en) 2009-09-18 2016-03-01 The Procter & Gamble Company Freshening compositions comprising malodor binding polymers
US9821081B2 (en) 2012-11-27 2017-11-21 The Procter & Gamble Company Perfume-free malodor reducing compositions
GB2570215A (en) * 2017-12-12 2019-07-17 Henkel Kgaa Polyethylene imine with low molecular weight as antiperspirant active substance in the form of a suspension

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2271716A (en) * 1992-10-26 1994-04-27 Unilever Plc Propellant-free deodorant composition
US6740713B1 (en) * 1999-07-08 2004-05-25 Procter & Gamble Company Process for producing particles of amine reaction products
US6764986B1 (en) * 1999-07-08 2004-07-20 Procter & Gamble Company Process for producing particles of amine reaction products
MXPA04011776A (es) * 2002-05-29 2005-03-31 Unilever Nv Control de olor en composiciones cosmeticas conteniendo sal de amina.
US8337596B2 (en) 2005-08-09 2012-12-25 Exxonmobil Research And Engineering Company Polyalkyleneacrylamide salt for acid gas scrubbing process
US20080164439A1 (en) * 2007-01-10 2008-07-10 Xinggao Fang Textiles treated with hyperbranched polyethyleneimine derivatives for odor control properties
US20090246258A1 (en) * 2008-03-28 2009-10-01 Piyush Shukla Antimicrobial and odor adsorbing textile
US20120183489A1 (en) * 2011-01-14 2012-07-19 Ricky Ah-Man Woo Compositions comprising metallated malodor control polymers
US9248209B2 (en) 2011-01-14 2016-02-02 The Procter & Gamble Company Compositions comprising hydrophobically modified malodor control polymers
WO2014085215A1 (en) * 2012-11-27 2014-06-05 The Procter & Gamble Company Perfume-free malodor reducing compositions
JP6635733B2 (ja) * 2015-09-14 2020-01-29 株式会社日本触媒 消臭剤
CN107955340B (zh) * 2017-11-02 2020-05-29 上海日之升科技有限公司 低散发汽车空调出风口叶片用pbt材料及其制备方法
US11299591B2 (en) 2018-10-18 2022-04-12 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US11518963B2 (en) 2018-10-18 2022-12-06 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US11466122B2 (en) 2018-10-18 2022-10-11 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof
US11732218B2 (en) 2018-10-18 2023-08-22 Milliken & Company Polyethyleneimine compounds containing N-halamine and derivatives thereof

Citations (10)

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Publication number Priority date Publication date Assignee Title
JPS4833118A (it) * 1971-06-02 1973-05-08
FR2164801A1 (it) * 1971-12-22 1973-08-03 Gillette Co
US3939099A (en) * 1974-12-26 1976-02-17 Chesebrough-Pond's, Inc. Fragrance composition
DE2623652A1 (de) * 1975-05-30 1976-12-09 Procter & Gamble Unterwaescheartikel und verfahren zu deren herstellung
FR2310800A1 (fr) * 1975-05-16 1976-12-10 Japan Synthetic Rubber Co Ltd Parfum-deodorant a base d'hydrogel
JPS534783A (en) * 1976-07-02 1978-01-17 Japan Synthetic Rubber Co Ltd Gel hydrate and gel hydrate deodorant
FR2368509A1 (fr) * 1976-10-20 1978-05-19 Oreal Nouveaux deodorants ou desodorisants et compositions les contenant
DE2737070A1 (de) * 1977-08-17 1979-03-08 Vulich Verfahren zur reinigung von gasen
FR2455068A1 (fr) * 1979-04-26 1980-11-21 Kuraray Co Gel aqueux a base de derives ammoniacaux de copolymeres de l'anhydride maleique et de polyamines et leurs utilisations
US4252789A (en) * 1979-08-01 1981-02-24 The Gillette Company Deodorant stick

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JPS503396B2 (it) * 1971-12-06 1975-02-04
SE7607100L (sv) * 1975-07-02 1977-01-03 Rohm & Haas Absorbermedel

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Publication number Priority date Publication date Assignee Title
JPS4833118A (it) * 1971-06-02 1973-05-08
FR2164801A1 (it) * 1971-12-22 1973-08-03 Gillette Co
US3939099A (en) * 1974-12-26 1976-02-17 Chesebrough-Pond's, Inc. Fragrance composition
FR2310800A1 (fr) * 1975-05-16 1976-12-10 Japan Synthetic Rubber Co Ltd Parfum-deodorant a base d'hydrogel
DE2623652A1 (de) * 1975-05-30 1976-12-09 Procter & Gamble Unterwaescheartikel und verfahren zu deren herstellung
JPS534783A (en) * 1976-07-02 1978-01-17 Japan Synthetic Rubber Co Ltd Gel hydrate and gel hydrate deodorant
FR2368509A1 (fr) * 1976-10-20 1978-05-19 Oreal Nouveaux deodorants ou desodorisants et compositions les contenant
DE2737070A1 (de) * 1977-08-17 1979-03-08 Vulich Verfahren zur reinigung von gasen
FR2455068A1 (fr) * 1979-04-26 1980-11-21 Kuraray Co Gel aqueux a base de derives ammoniacaux de copolymeres de l'anhydride maleique et de polyamines et leurs utilisations
US4252789A (en) * 1979-08-01 1981-02-24 The Gillette Company Deodorant stick

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Title
Chemical Abstracts, Vol. 79, No. 10, published on 10 September 1973, (Columbus Ohio, USA) page 75, column 1, abstract 54766d; & JP-A-48 033 118, published on 8 May 1973 (KANEBO CO. LTD) *
Chemical Abstracts, Vol. 89, No. 2, published on 10 July 1978 (Columbus Ohio USA) page 359, column 2, abstract 11983m; & JP-A-53 004 783, published on 17 January 1978 (JAPAN SYNTHETIC RUBBER CO.) *
Chemical Abstracts, Vol. 89, No. 4, published on 24 July 1978, (Columbus, Ohio, USA) F. Woeller et al: "Sythesis of porous polyaromatic column packings for GC analysis of extraterrestrial atmospheres" page 784, column 2, abstract 35900h; & J.Chromatrogr.Sci. 1978, 16(4), 137-40 *

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0354281A1 (en) * 1985-10-31 1990-02-14 Aikoh Co. Ltd. A deodorant composition and use thereof
AT395534B (de) * 1985-10-31 1993-01-25 Aikoh Co Desodorierende zusammensetzung
AT398901B (de) * 1985-10-31 1995-02-27 Aikoh & Co Ltd Desodorierende zusammensetzung
EP0277398A1 (en) * 1985-10-31 1988-08-10 Aikoh Co. Ltd. A deodorant composition and use thereof
EP0858797A1 (fr) * 1997-02-14 1998-08-19 L'oreal Composition déodorante comprenant un dendrimère
FR2759582A1 (fr) * 1997-02-14 1998-08-21 Oreal Composition deodorante
US6001342A (en) * 1997-02-14 1999-12-14 L'oreal Deodorant composition and use thereof
WO2003088931A2 (en) * 2002-04-16 2003-10-30 Cosmetica, Inc. Polymeric odor absorption ingredients for personal care products
WO2003088931A3 (en) * 2002-04-16 2004-04-29 Cosmetica Inc Polymeric odor absorption ingredients for personal care products
WO2005110502A1 (en) * 2004-04-30 2005-11-24 Kimberly-Clark Worldwide, Inc. Absorption of pain-causing agents
US8778321B2 (en) 2007-10-01 2014-07-15 Nanotex Llc Modification of cellulosic substrates to control body odor
DE102009040089A1 (de) 2009-09-04 2011-07-21 Beiersdorf AG, 20253 Zubereitungen mit wasserunlöslichen polymeren Aminen zur Verminderung von Körpergeruch
US9260817B2 (en) 2009-09-18 2016-02-16 The Procter & Gamble Company Freshening compositions comprising malodor binding polymers and malodor counteractants
US9273427B2 (en) 2009-09-18 2016-03-01 The Procter & Gamble Company Freshening compositions comprising malodor binding polymers
KR20140040102A (ko) * 2011-02-11 2014-04-02 킴벌리-클라크 월드와이드, 인크. 살균 용액과 함께 사용하기 위한 와이프
EP2672873A4 (en) * 2011-02-11 2015-10-07 Kimberly Clark Co WIPE CLOTH FOR USE WITH A DEVOTIVE SOLUTION
KR101968771B1 (ko) * 2011-02-11 2019-04-12 킴벌리-클라크 월드와이드, 인크. 살균 용액과 함께 사용하기 위한 와이프
WO2012175330A2 (en) 2011-06-20 2012-12-27 L'oreal Cosmetic use of a flocculant polymer as antiperspirant
US9821081B2 (en) 2012-11-27 2017-11-21 The Procter & Gamble Company Perfume-free malodor reducing compositions
GB2570215A (en) * 2017-12-12 2019-07-17 Henkel Kgaa Polyethylene imine with low molecular weight as antiperspirant active substance in the form of a suspension
GB2570215B (en) * 2017-12-12 2020-03-25 Henkel Kgaa Polyethylene imine with low molecular weight as antiperspirant active substance in the form of a suspension

Also Published As

Publication number Publication date
ES8405276A1 (es) 1984-06-16
PT74148B (en) 1986-01-24
CH658392A5 (de) 1986-11-14
SE8204681D0 (sv) 1982-08-13
PT74148A (en) 1982-01-01
AU550277B2 (en) 1986-03-13
DE3047774C2 (de) 1986-10-30
FI76495B (fi) 1988-07-29
ES508649A0 (es) 1984-06-16
CA1173631A (en) 1984-09-04
BR8108919A (pt) 1982-11-30
FI822843L (fi) 1982-08-16
NL8120479A (nl) 1982-11-01
GR76970B (it) 1984-09-04
AU7934582A (en) 1982-07-01
IT1142135B (it) 1986-10-08
FI822843A0 (fi) 1982-08-16
GB2102292A (en) 1983-02-02
IT8125684A0 (it) 1981-12-18
DE3047774A1 (de) 1982-07-01
FR2497670B1 (fr) 1986-04-18
FI76495C (fi) 1988-11-10
FR2497670A1 (fr) 1982-07-16
GB2102292B (en) 1984-05-16
SE448148B (sv) 1987-01-26
SE8204681L (sv) 1982-08-13
JPS57501944A (it) 1982-11-04

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