UY33749A - ?un proceso para la producción de ácido metacrílico y sus derivados y los polímeros producidos a partir de los mismos - Google Patents

?un proceso para la producción de ácido metacrílico y sus derivados y los polímeros producidos a partir de los mismos

Info

Publication number
UY33749A
UY33749A UY0001033749A UY33749A UY33749A UY 33749 A UY33749 A UY 33749A UY 0001033749 A UY0001033749 A UY 0001033749A UY 33749 A UY33749 A UY 33749A UY 33749 A UY33749 A UY 33749A
Authority
UY
Uruguay
Prior art keywords
production
acid
derivatives
same
decarboxylation
Prior art date
Application number
UY0001033749A
Other languages
English (en)
Inventor
David William Johnson
Graham Ronald Eastham
Poliakoff Martyn
Thomas Andrew Huddle
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB1019915.6A external-priority patent/GB201019915D0/en
Priority claimed from GBGB1105467.3A external-priority patent/GB201105467D0/en
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of UY33749A publication Critical patent/UY33749A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C51/38Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by decarboxylation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04Acids, Metal salts or ammonium salts thereof
    • C08F20/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/12Esters of monohydric alcohols or phenols
    • C08F20/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un proceso para la producción de ácido metacrílico que comprende la descarboxilación catalizada básica de al menos uno o una mezcla de ácidos dicarboxílicos seleccionados de ácido itacónico, citracónico o mesacónico. La descarboxilación se lleva a cabo más de 240 hasta 275°C para proveer una alta selectividad. El producto de ácido metacrílico se puede esterificar. También se describe un método para preparar polímeros, copolímeros, o ésteres de ácido metacrílico. El proceso puede opcionalmente estar precedido por una descarboxilación y, en caso necesario, de una deshidratación en una fuente de preácido tal como ácido cítrico o ácido isocítrico.
UY0001033749A 2010-11-24 2011-11-23 ?un proceso para la producción de ácido metacrílico y sus derivados y los polímeros producidos a partir de los mismos UY33749A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1019915.6A GB201019915D0 (en) 2010-11-24 2010-11-24 A process for the production of methacrylic acid and its derivatives and polmers produced therefrom
GBGB1105467.3A GB201105467D0 (en) 2011-03-31 2011-03-31 A process for the production of methacrylic acid and its derivatives and polymers produced therefrom

Publications (1)

Publication Number Publication Date
UY33749A true UY33749A (es) 2012-06-29

Family

ID=45099138

Family Applications (1)

Application Number Title Priority Date Filing Date
UY0001033749A UY33749A (es) 2010-11-24 2011-11-23 ?un proceso para la producción de ácido metacrílico y sus derivados y los polímeros producidos a partir de los mismos

Country Status (20)

Country Link
US (1) US9174913B2 (es)
EP (1) EP2643283B1 (es)
JP (1) JP5857064B2 (es)
KR (1) KR20130129977A (es)
CN (1) CN103228606B (es)
AR (1) AR083970A1 (es)
AU (1) AU2011333557A1 (es)
BR (1) BR112013012861B1 (es)
CA (1) CA2817641C (es)
EA (1) EA201390751A1 (es)
ES (1) ES2552981T3 (es)
MX (1) MX2013005510A (es)
MY (1) MY179932A (es)
NZ (1) NZ611514A (es)
SG (1) SG190294A1 (es)
TW (1) TW201229025A (es)
UA (1) UA110121C2 (es)
UY (1) UY33749A (es)
WO (1) WO2012069813A1 (es)
ZA (1) ZA201303625B (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR085338A1 (es) 2011-02-09 2013-09-25 Lucite Int Uk Ltd Un proceso para la produccion de acido (met)acrilico y derivados y polimeros producidos a partir del mismo
GB201207388D0 (en) * 2012-04-27 2012-06-13 Lucite Int Uk Ltd A process for the production of methacrylic acid and its derivatives and polymers produced therefrom
TW201508064A (zh) * 2013-08-02 2015-03-01 Lucite Int Uk Ltd 製造甲基丙烯酸及其衍生物之方法
CN105579429B (zh) * 2013-08-26 2018-11-20 瓦赫宁根研究基金会 甲基丙烯酸的生产方法
CA2861524A1 (en) * 2013-09-16 2014-11-03 Armstrong World Industries, Inc. Methods for preparing methacrylic acid from biobased starting materials
MY198780A (en) 2015-05-19 2023-09-27 Mitsubishi Chemical Uk Ltd Process for the biological production of methacrylic acid and derivatives thereof
CN106060964A (zh) * 2016-07-01 2016-10-26 惠州市德赛西威汽车电子有限公司 一种车载蓝牙电话系统中快速自动连接手机的方法及装置
GB201707034D0 (en) 2017-05-03 2017-06-14 Gradley Michell Lorraine Modified microorganisms and methods for production of useful products
EP3553045A1 (en) 2018-04-09 2019-10-16 Kemijski Institut Process and catalysts to produce methacrylic acid monomer from biomass-derived carboxylic acids
GB2621337A (en) 2022-08-08 2024-02-14 Mitsubishi Chemical Uk Ltd Process for the biological production of methacrylic acid and derivatives thereof

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE550710A (es) *
US2504049A (en) 1946-03-04 1950-04-11 Du Pont Preparation of polymethacrylic acid and of polymeric products containing polymethacrylic acid
DE2323328C2 (de) 1973-05-09 1982-04-01 Basf Ag, 6700 Ludwigshafen Verfahren zur Abtrennung von Acrylsäure aus einer angesäuerten wäßrigen Butanol-Acrylsäure-Veresterungsablauge
JPS57168906A (en) 1981-04-13 1982-10-18 Kao Corp Maleic acid/(meth)acrylic acid copolymer
DE4443557A1 (de) 1994-12-07 1996-06-13 Roehm Gmbh Hochwärmeformbeständige, spannungsrißbeständige Polymethacrylat-Formmassen
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
DE10203565C1 (de) 2002-01-29 2003-07-10 Roehm Gmbh Verfahren zur Herstellung eines schlagzähen Polymethylmethacrylat- Formkörpers und Verwendung des so hergestellten Kunststoffformkörpers
EP2085376B1 (en) * 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
FR2938536B1 (fr) 2008-11-18 2012-07-13 Arkema France Procede de fabrication d'un methacrylate de methyle derive de la biomasse
GB0922255D0 (en) 2009-12-21 2010-02-03 Lucite Int Uk Ltd Method of producing acrylic and methacrylic acid

Also Published As

Publication number Publication date
MY179932A (en) 2020-11-19
KR20130129977A (ko) 2013-11-29
CA2817641C (en) 2018-08-21
EP2643283B1 (en) 2015-08-12
WO2012069813A1 (en) 2012-05-31
AR083970A1 (es) 2013-04-10
CN103228606B (zh) 2016-11-09
NZ611514A (en) 2015-04-24
CN103228606A (zh) 2013-07-31
BR112013012861A2 (pt) 2016-08-23
BR112013012861B1 (pt) 2019-10-08
UA110121C2 (uk) 2015-11-25
ZA201303625B (en) 2014-06-25
EA201390751A1 (ru) 2013-11-29
ES2552981T3 (es) 2015-12-03
JP5857064B2 (ja) 2016-02-10
MX2013005510A (es) 2013-12-16
JP2014505668A (ja) 2014-03-06
US20130303713A1 (en) 2013-11-14
AU2011333557A1 (en) 2013-06-27
US9174913B2 (en) 2015-11-03
EP2643283A1 (en) 2013-10-02
CA2817641A1 (en) 2012-05-31
SG190294A1 (en) 2013-06-28
TW201229025A (en) 2012-07-16

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Effective date: 20200121