FR2938536B1 - Procede de fabrication d'un methacrylate de methyle derive de la biomasse - Google Patents

Procede de fabrication d'un methacrylate de methyle derive de la biomasse

Info

Publication number
FR2938536B1
FR2938536B1 FR0857812A FR0857812A FR2938536B1 FR 2938536 B1 FR2938536 B1 FR 2938536B1 FR 0857812 A FR0857812 A FR 0857812A FR 0857812 A FR0857812 A FR 0857812A FR 2938536 B1 FR2938536 B1 FR 2938536B1
Authority
FR
France
Prior art keywords
biomass
production
methyl methacrylate
methacrylate derived
derived
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0857812A
Other languages
English (en)
Other versions
FR2938536A1 (fr
Inventor
Jean Luc Dubois
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Trinseo Europe GmbH
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to FR0857812A priority Critical patent/FR2938536B1/fr
Priority to US13/129,714 priority patent/US20110287991A1/en
Priority to PCT/FR2009/052198 priority patent/WO2010058119A1/fr
Priority to EP09768204A priority patent/EP2361240A1/fr
Priority to BRPI0921466A priority patent/BRPI0921466A2/pt
Priority to CN200980154688.6A priority patent/CN102282121B/zh
Publication of FR2938536A1 publication Critical patent/FR2938536A1/fr
Application granted granted Critical
Publication of FR2938536B1 publication Critical patent/FR2938536B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C07C41/50—Preparation of compounds having groups by reactions producing groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/62—Carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
FR0857812A 2008-11-18 2008-11-18 Procede de fabrication d'un methacrylate de methyle derive de la biomasse Expired - Fee Related FR2938536B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR0857812A FR2938536B1 (fr) 2008-11-18 2008-11-18 Procede de fabrication d'un methacrylate de methyle derive de la biomasse
US13/129,714 US20110287991A1 (en) 2008-11-18 2009-11-17 Method for manufacturing a biomass-derived methyl methacrylate
PCT/FR2009/052198 WO2010058119A1 (fr) 2008-11-18 2009-11-17 Procede de fabrication d'un methylacrylate de methyle derive de la biomasse
EP09768204A EP2361240A1 (fr) 2008-11-18 2009-11-17 Procede de fabrication d'un methylacrylate de methyle derive de la biomasse
BRPI0921466A BRPI0921466A2 (pt) 2008-11-18 2009-11-17 processo para a fabricação de metacrilato de metila derivado de biomassa
CN200980154688.6A CN102282121B (zh) 2008-11-18 2009-11-17 制备生物质来源的甲基丙烯酸甲酯的方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0857812A FR2938536B1 (fr) 2008-11-18 2008-11-18 Procede de fabrication d'un methacrylate de methyle derive de la biomasse

Publications (2)

Publication Number Publication Date
FR2938536A1 FR2938536A1 (fr) 2010-05-21
FR2938536B1 true FR2938536B1 (fr) 2012-07-13

Family

ID=40786622

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0857812A Expired - Fee Related FR2938536B1 (fr) 2008-11-18 2008-11-18 Procede de fabrication d'un methacrylate de methyle derive de la biomasse

Country Status (6)

Country Link
US (1) US20110287991A1 (fr)
EP (1) EP2361240A1 (fr)
CN (1) CN102282121B (fr)
BR (1) BRPI0921466A2 (fr)
FR (1) FR2938536B1 (fr)
WO (1) WO2010058119A1 (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0922255D0 (en) 2009-12-21 2010-02-03 Lucite Int Uk Ltd Method of producing acrylic and methacrylic acid
JP5857064B2 (ja) 2010-11-24 2016-02-10 ルーサイト インターナショナル ユーケー リミテッド メタクリル酸およびその誘導体を製造するための方法ならびにこれを用いて製造されるポリマー
UY33901A (es) 2011-02-09 2012-09-28 Lucite Int Uk Ltd Un proceso para la producción de ácido (met)acrílico y derivados y polímeros producidos a partir del mismo
GB201207388D0 (en) * 2012-04-27 2012-06-13 Lucite Int Uk Ltd A process for the production of methacrylic acid and its derivatives and polymers produced therefrom
US9382491B2 (en) 2012-07-03 2016-07-05 Sartec Corporation Hydrocarbon synthesis methods, apparatus, and systems
WO2014008355A1 (fr) 2012-07-03 2014-01-09 Mcneff Clayton V Procédés, appareil et systèmes de synthèse d'hydrocarbures
CN102962062B (zh) * 2012-12-11 2014-09-17 西南化工研究设计院有限公司 一种由甲醛与丙酸甲酯合成甲基丙烯酸甲酯的催化剂及其制备方法
CA2922180C (fr) 2013-08-26 2020-04-14 Stichting Dienst Landbouwkundig Onderzoek Procede de production d'acide methacrylique
CN104725225B (zh) * 2013-12-23 2017-01-18 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法
BR112017019379A2 (pt) * 2015-04-16 2018-06-05 Anellotech Inc intermediários químicos derivados de biomassa
EP3419958B1 (fr) 2016-02-25 2020-04-29 3M Innovative Properties Company Procédés de fabrication d'esters (alk)acryliques dans des réacteurs à écoulement
US10239812B2 (en) 2017-04-27 2019-03-26 Sartec Corporation Systems and methods for synthesis of phenolics and ketones
CN107337600A (zh) * 2017-07-04 2017-11-10 湖北三里枫香科技有限公司 一种甲醇和醋酸甲酯生产甲基丙烯酸甲酯的方法及工艺装置
US10696923B2 (en) 2018-02-07 2020-06-30 Sartec Corporation Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids
US10544381B2 (en) 2018-02-07 2020-01-28 Sartec Corporation Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid
WO2022067134A1 (fr) * 2020-09-25 2022-03-31 Carbon Technology Holdings, LLC Bioréduction de minerais métalliques intégrés à la pyrolyse de biomasse
CN112851505B (zh) * 2021-01-08 2022-04-26 西南化工研究设计院有限公司 一种丙烯酸甲酯连续气相加氢制丙酸甲酯工艺
CN112851507A (zh) * 2021-01-25 2021-05-28 西南化工研究设计院有限公司 一种乙醇合成甲基丙烯酸甲酯的工艺

Family Cites Families (13)

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Publication number Priority date Publication date Assignee Title
US3701798A (en) 1965-12-03 1972-10-31 Eastman Kodak Co Synthesis of unsaturated compounds
US3933888A (en) 1972-10-06 1976-01-20 Rohm And Haas Company Production of unsaturated acids, esters and nitriles, and catalyst therefor
DE2733496A1 (de) * 1977-07-25 1979-02-15 Roehm Gmbh Verfahren zur herstellung von methacrylsaeure sowie estern und dem nitril dieser saeure
GB1491183A (en) 1976-04-06 1977-11-09 Roehm Gmbh Preparation of methacrylic acid esters and nitrile
US4118588A (en) 1976-04-10 1978-10-03 Basf Aktiengesellschaft Manufacture of methacrylic acid and methyl methacrylate
DE2702187A1 (de) 1977-01-20 1978-07-27 Roehm Gmbh Verfahren zur herstellung von methacrylsaeure, dem nitril und estern dieser saeure
DE3712835A1 (de) * 1987-04-15 1988-11-03 Ruhrchemie Ag Verfahren zur herstellung von carbonsaeuremethylestern
SE470515B (sv) 1992-11-02 1994-06-27 Chemrec Ab Förfarande för framställning av väteperoxid
SE0004185D0 (sv) 2000-11-15 2000-11-15 Nykomb Synergetics B V New process
US20050059839A1 (en) * 2003-09-15 2005-03-17 The Regents Of The University Of California Process and catalysts for the oxidation of methanol and/or ethanol
EP1732874A1 (fr) * 2004-04-02 2006-12-20 Ciba Speciality Chemicals Water Treatments Limited Preparation de derives d'acide acrylique a partir d'acides carboxyliques alpha- ou beta-hydroxy
FR2884818B1 (fr) * 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
BRPI0605173A (pt) * 2006-12-05 2008-07-22 Braskem Sa processo de produção de uma ou mais olefinas, olefina, e, polìmero

Also Published As

Publication number Publication date
CN102282121A (zh) 2011-12-14
WO2010058119A1 (fr) 2010-05-27
EP2361240A1 (fr) 2011-08-31
US20110287991A1 (en) 2011-11-24
FR2938536A1 (fr) 2010-05-21
CN102282121B (zh) 2016-08-24
BRPI0921466A2 (pt) 2016-01-12

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