UY24459A1 - Procedimiento para preparar perfluoropolioxialquilenos peroxidicos - Google Patents
Procedimiento para preparar perfluoropolioxialquilenos peroxidicosInfo
- Publication number
- UY24459A1 UY24459A1 UY24459A UY24459A UY24459A1 UY 24459 A1 UY24459 A1 UY 24459A1 UY 24459 A UY24459 A UY 24459A UY 24459 A UY24459 A UY 24459A UY 24459 A1 UY24459 A1 UY 24459A1
- Authority
- UY
- Uruguay
- Prior art keywords
- peroxy
- solvent
- cf2x
- perfluoropolyoxyalkylenes
- cof2
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
- C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
- C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
- C08G65/223—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens
- C08G65/226—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyethers (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Hinges (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
La presente invención se refiere a un procedimiento para preparar perfluoropolioxialquilenos peroxídicos, usualmente denominados perfluoropoliéteres peroxídicos. Un proceso de oxidación de tetrafluoroetileno para la preparación de polímeros de perfluoropolioxialquilenos peroxídicos, a temperaturas entre -100ºC y -40ºC, en ausencia de radiaciones UV, el cual se lleva a cabo en presencia de un indicador químico que contiene al menos un enlace F-X, en el cual X es oxígeno o halógeno, a presiones totales de entre 0 y 15 bar relativas y en presencia de un solvente que comprende una cantidad de COF2 mayor que 8% molar de solvente total o en presencia de COF2 solamente. El indicador químico se elige entre flúor e hipofluoritos alquílicos que contienen hasta 3 átomos de carbono. El solvente se selecciona de compuestos fluorocarbonados lineales y cíclicos que contienen opcionalmente hidrógeno y/o cloro: perfluoropropano, perfluorociclobutano, perfluorociclohexano, cloropentafluoroetano, 1,1,2-tricloro-1,2,2-trifluoroetano, 1,2.diclorotetrafluoroetano; perfluoroaminas y perfluoroéteres y poliéteres, que contiene opcionalmente hidrógeno. Los polímeros peroxídicos obtenidos tiene la siguiente fórmula general: A-O-(CF2-CF2-O)p-(CF2-O)q-(O)r-B; en la que las termionales A y B pueden ser iguales o diferentes entre sí y comprende: CF2X, CF2-CF2X , en la que X indica un grupo radical derivado del tipo de iniciador utilizado; p, q y r, iguales o diferentes entre sí, son número enteros, la suma p+q es un númoer entero entre 2 y 1000, la relación p/q es de entre 0.1 y 40, la relación r/(p+q) es de entre 0.01 y 0.3.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT96MI000279A IT1282627B1 (it) | 1996-02-14 | 1996-02-14 | Procedimento per la preparazione di perfluoropoliossialchileni perossidici |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UY24459A1 true UY24459A1 (es) | 1997-08-05 |
Family
ID=11373268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UY24459A UY24459A1 (es) | 1996-02-14 | 1997-02-13 | Procedimiento para preparar perfluoropolioxialquilenos peroxidicos |
Country Status (28)
| Country | Link |
|---|---|
| US (1) | US5744651A (es) |
| EP (1) | EP0790269B1 (es) |
| JP (1) | JP3862339B2 (es) |
| KR (1) | KR100486125B1 (es) |
| CN (1) | CN1080276C (es) |
| AR (1) | AR005793A1 (es) |
| AT (1) | ATE194850T1 (es) |
| AU (1) | AU715369B2 (es) |
| BG (1) | BG62394B1 (es) |
| BR (1) | BR9700958A (es) |
| CA (1) | CA2197538C (es) |
| CZ (1) | CZ293428B6 (es) |
| DE (1) | DE69702550T2 (es) |
| ES (1) | ES2150155T3 (es) |
| HR (1) | HRP970079B1 (es) |
| HU (1) | HU220709B1 (es) |
| IL (1) | IL120220A (es) |
| IN (1) | IN190368B (es) |
| IT (1) | IT1282627B1 (es) |
| NO (1) | NO311693B1 (es) |
| NZ (1) | NZ314218A (es) |
| PE (1) | PE6598A1 (es) |
| PL (1) | PL318452A1 (es) |
| RO (1) | RO116894B1 (es) |
| RU (1) | RU2194725C2 (es) |
| TW (1) | TW442497B (es) |
| UY (1) | UY24459A1 (es) |
| ZA (1) | ZA971176B (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20011340A1 (it) * | 2001-06-26 | 2002-12-26 | Ausimont Spa | Pfpe aventi almeno un terminale alchiletereo e relativo processo dipreparazione |
| ITMI20030372A1 (it) | 2003-03-03 | 2004-09-04 | Solvay Solexis Spa | Perfluoropolieteri lineari aventi migliorata stabilita' termoossidativa. |
| ITMI20031915A1 (it) * | 2003-10-03 | 2005-04-04 | Solvay Solexis Spa | Processo per la preparazione di perfluoropolieteri. |
| ITMI20062308A1 (it) * | 2006-11-30 | 2008-06-01 | Solvay Solexis Spa | Additivi per alo-polimeri |
| ITMI20062306A1 (it) * | 2006-11-30 | 2008-06-01 | Solvay Solexis Spa | Lubrificanti fluorurati |
| EP2089443B1 (en) * | 2006-11-30 | 2010-07-21 | Solvay Solexis S.p.A. | Fluorinated lubricants |
| EP1980583A1 (en) * | 2007-04-10 | 2008-10-15 | Solvay Solexis S.p.A. | A method for preparing carbonylic perfluoropolyethers |
| WO2009019243A1 (en) * | 2007-08-07 | 2009-02-12 | Solvay Solexis S.P.A. | Modification of carbonaceous materials |
| EP2100909A1 (en) | 2008-03-14 | 2009-09-16 | Solvay Solexis S.p.A. | (Per)fluorinated addition products |
| US8536269B2 (en) * | 2008-08-15 | 2013-09-17 | Nova-Duct Technologies Pty Ltd | Peroxidic fluoropolyether and its use in emulsion polymerization of fluorin-containing monomer |
| EP2373720B1 (en) | 2008-12-05 | 2012-11-07 | Solvay Specialty Polymers Italy S.p.A. | Polyfunctional (per)fluoropolyethers |
| CN104125972B (zh) * | 2011-12-22 | 2017-09-05 | 索尔维特殊聚合物意大利有限公司 | 用于制造具有芳香族端基的(全)氟聚醚的方法 |
| CN103724559B (zh) * | 2013-12-17 | 2016-08-17 | 中昊晨光化工研究院有限公司 | 一种由全氟聚醚过氧化物合成全氟聚醚的方法 |
| JP2017105945A (ja) * | 2015-12-10 | 2017-06-15 | ダイキン工業株式会社 | 過酸化パーフルオロポリオキシアルキレン化合物の製造方法 |
| CN108440748B (zh) * | 2018-04-09 | 2020-06-16 | 浙江巨化技术中心有限公司 | 一种高分子量带有酰氟基团全氟聚醚过氧化物的合成方法 |
| KR102240973B1 (ko) * | 2019-06-13 | 2021-04-15 | 한국화학연구원 | 과산화 퍼플루오로폴리에테르의 과산화물 제거를 통한 퍼플루오로폴리에테르의 제조장치 및 제조방법 |
| CN114276532A (zh) * | 2021-12-29 | 2022-04-05 | 山东东岳高分子材料有限公司 | 一种过氧化全氟聚醚的制备方法及装置 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1745169B2 (de) * | 1967-02-09 | 1977-04-21 | Montecatini Edison S.P.A., Mailand (Italien) | Fluorierte lineare polyaether und verfahren zu ihrer herstellung |
| US4451646A (en) * | 1967-02-09 | 1984-05-29 | Montedison, S.P.A. | High molecular weight polymeric perfluorinated copolyethers and process for their preparation from tetrafluoroethylene |
| US3847978A (en) * | 1968-07-01 | 1974-11-12 | Montedison Spa | Perfluorinated linear polyethers having reactive terminal groups at both ends of the chain and process for the preparation thereof |
| IT1229845B (it) * | 1989-04-20 | 1991-09-13 | Ausimont Srl | Procedimento per la preparazione di perfluoropolieteri perossidici. |
| IT1249319B (it) * | 1991-04-26 | 1995-02-22 | Ausimont Spa | Perfluoropolieteri ad elevata viscosita' e basso contenuto di ossigeno perossidico, e procedimento per la loro preparazione |
| US5182342A (en) * | 1992-02-28 | 1993-01-26 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon solvents for fluoromonomer polymerization |
| IT1264977B1 (it) * | 1993-11-17 | 1996-10-17 | Ausimont Spa | Processo per preparare perfluoropolietri |
| US5658962A (en) * | 1994-05-20 | 1997-08-19 | Minnesota Mining And Manufacturing Company | Omega-hydrofluoroalkyl ethers, precursor carboxylic acids and derivatives thereof, and their preparation and application |
| JP3349513B2 (ja) * | 1994-05-24 | 2002-11-25 | エーザイ株式会社 | ２，６−ジ−ヨードフェノール−４−イルを少なくとも２ケ含む化合物とヨードアレルギー診断薬 |
| IT1274591B (it) * | 1994-08-05 | 1997-07-18 | Ausimont Spa | Processo per la preparazione di poliossiperfluoroalcani idrogeno terminati |
-
1996
- 1996-02-14 IT IT96MI000279A patent/IT1282627B1/it active IP Right Grant
-
1997
- 1997-02-11 AT AT97102123T patent/ATE194850T1/de not_active IP Right Cessation
- 1997-02-11 EP EP97102123A patent/EP0790269B1/en not_active Expired - Lifetime
- 1997-02-11 ES ES97102123T patent/ES2150155T3/es not_active Expired - Lifetime
- 1997-02-11 DE DE69702550T patent/DE69702550T2/de not_active Expired - Lifetime
- 1997-02-12 ZA ZA9701176A patent/ZA971176B/xx unknown
- 1997-02-12 JP JP02763897A patent/JP3862339B2/ja not_active Expired - Fee Related
- 1997-02-12 HR HR970079A patent/HRP970079B1/xx not_active IP Right Cessation
- 1997-02-12 NZ NZ314218A patent/NZ314218A/en unknown
- 1997-02-12 CZ CZ1997434A patent/CZ293428B6/cs not_active IP Right Cessation
- 1997-02-12 AR ARP970100544A patent/AR005793A1/es unknown
- 1997-02-13 TW TW086101634A patent/TW442497B/zh not_active IP Right Cessation
- 1997-02-13 NO NO19970668A patent/NO311693B1/no not_active IP Right Cessation
- 1997-02-13 UY UY24459A patent/UY24459A1/es not_active IP Right Cessation
- 1997-02-13 IL IL12022097A patent/IL120220A/xx not_active IP Right Cessation
- 1997-02-13 KR KR1019970004275A patent/KR100486125B1/ko not_active IP Right Cessation
- 1997-02-13 HU HU9700438A patent/HU220709B1/hu not_active IP Right Cessation
- 1997-02-13 RU RU97102618/04A patent/RU2194725C2/ru active
- 1997-02-13 CA CA002197538A patent/CA2197538C/en not_active Expired - Fee Related
- 1997-02-13 RO RO97-00284A patent/RO116894B1/ro unknown
- 1997-02-13 PE PE1997000102A patent/PE6598A1/es not_active Application Discontinuation
- 1997-02-13 BG BG101229A patent/BG62394B1/bg unknown
- 1997-02-13 US US08/800,022 patent/US5744651A/en not_active Expired - Lifetime
- 1997-02-13 PL PL97318452A patent/PL318452A1/xx unknown
- 1997-02-13 AU AU12683/97A patent/AU715369B2/en not_active Ceased
- 1997-02-13 BR BR9700958A patent/BR9700958A/pt not_active IP Right Cessation
- 1997-02-13 IN IN244CA1997 patent/IN190368B/en unknown
- 1997-02-14 CN CN97111640A patent/CN1080276C/zh not_active Expired - Lifetime
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| VENC | Patent expired |
Effective date: 20170213 |