PE6598A1 - Procedimiento para preparar perfluoropolioxialquilenos peroxidicos - Google Patents

Procedimiento para preparar perfluoropolioxialquilenos peroxidicos

Info

Publication number
PE6598A1
PE6598A1 PE1997000102A PE00010297A PE6598A1 PE 6598 A1 PE6598 A1 PE 6598A1 PE 1997000102 A PE1997000102 A PE 1997000102A PE 00010297 A PE00010297 A PE 00010297A PE 6598 A1 PE6598 A1 PE 6598A1
Authority
PE
Peru
Prior art keywords
peroxidic
value
products
procedure
cf2x
Prior art date
Application number
PE1997000102A
Other languages
English (en)
Inventor
Pier Antonio Guarda
Giuseppe Marchionni
Original Assignee
Ausimont Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ausimont Spa filed Critical Ausimont Spa
Publication of PE6598A1 publication Critical patent/PE6598A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C08G65/005Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
    • C08G65/007Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/223Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens
    • C08G65/226Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring containing halogens containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)
  • Hinges (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

SE REFIERE A UN PROCEDIMIENTO PARA OBTENER POLIMEROS PEROXIDICOS DE FORMULA A-O(CF2-CF2-O)p-(CF2-O)q-(O)r-B, DONDE LOS TERMINALES A Y B PUEDEN SER IGUALES O DIFERENTES ENTRE SI, Y COMPRENDEN -CF2X, -CF2-CF2X, EN DONDE X ES UN RADICAL QUE DERIVA DEL TIPO DE INICIADOR UTILIZADO, LOS SUBINDICES p,q Y r SON NUMEROS ENTEROS IGUALES O DIFERENTES, LA SUMA p+q ES UN VALOR ENTRE 2 Y 2000, LA PROPORCION p/q ES UN VALOR ENTRE 0,1 Y 40 Y LA PROPORCION r/(p+q) ES UN VALOR ENTRE 0,01 Y 0,3; QUE COMPRENDE: A) LA OXIDACION DE TETRAFLUOROETILENO A TEMPERATURAS ENTRE -100�C Y 40�C, CON PRESIONES RELATIVAS ENTRE 0 BAR Y 15 BAR, EN AUSENCIA DE RADIACIONES ULTRAVIOLETA (UV) ,EN PRESENCIA DE: 1) UN INICIADOR QUIMICO (IQ) QUE CONTIENE POR LO MENOS UNA LIGADURA F-X, EN DONDE X ES OXIGENO O HALOGENO, Y DICHO (IQ) ES SELECCIONADO DE FLUOR O HIPOFLUORITOS ALQUILICOS DE HASTA C3. 2) UN SOLVENTE QUE COMPRENDE UNA CANTIDAD DE COF2 SUPERIOR A 8% MOLAR, PREFERIBLEMENTE ENTRE 15% Y 60%, Y DICHO SOLVENTE SE SELECCIONA DE CFCl3, CF2Cl2, CF2HCl, CF3-CF2H, ENTRE OTROS. B)TRANSFORMACION DE LOS PERFLUOROPOLIETERES PEROXIDICOS A PRODUCTOS SIN OXIGENO PEROXIDICO MEDIANTE TRATAMIENTO TERMICO O RADIACION (UV) EN PRESENCIA O NO DE SOLVENTES, Y TALES PRODUCTOS SE SOMETEN A TRATAMIENTO DE FLUORACION, REDUCCION, ENTRE OTROS; PARA OBTENER PRODUCTOS FUNCIONALES
PE1997000102A 1996-02-14 1997-02-13 Procedimiento para preparar perfluoropolioxialquilenos peroxidicos PE6598A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT96MI000279A IT1282627B1 (it) 1996-02-14 1996-02-14 Procedimento per la preparazione di perfluoropoliossialchileni perossidici

Publications (1)

Publication Number Publication Date
PE6598A1 true PE6598A1 (es) 1998-03-03

Family

ID=11373268

Family Applications (1)

Application Number Title Priority Date Filing Date
PE1997000102A PE6598A1 (es) 1996-02-14 1997-02-13 Procedimiento para preparar perfluoropolioxialquilenos peroxidicos

Country Status (28)

Country Link
US (1) US5744651A (es)
EP (1) EP0790269B1 (es)
JP (1) JP3862339B2 (es)
KR (1) KR100486125B1 (es)
CN (1) CN1080276C (es)
AR (1) AR005793A1 (es)
AT (1) ATE194850T1 (es)
AU (1) AU715369B2 (es)
BG (1) BG62394B1 (es)
BR (1) BR9700958A (es)
CA (1) CA2197538C (es)
CZ (1) CZ293428B6 (es)
DE (1) DE69702550T2 (es)
ES (1) ES2150155T3 (es)
HR (1) HRP970079B1 (es)
HU (1) HU220709B1 (es)
IL (1) IL120220A (es)
IN (1) IN190368B (es)
IT (1) IT1282627B1 (es)
NO (1) NO311693B1 (es)
NZ (1) NZ314218A (es)
PE (1) PE6598A1 (es)
PL (1) PL318452A1 (es)
RO (1) RO116894B1 (es)
RU (1) RU2194725C2 (es)
TW (1) TW442497B (es)
UY (1) UY24459A1 (es)
ZA (1) ZA971176B (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20011340A1 (it) * 2001-06-26 2002-12-26 Ausimont Spa Pfpe aventi almeno un terminale alchiletereo e relativo processo dipreparazione
ITMI20030372A1 (it) * 2003-03-03 2004-09-04 Solvay Solexis Spa Perfluoropolieteri lineari aventi migliorata stabilita' termoossidativa.
ITMI20031915A1 (it) * 2003-10-03 2005-04-04 Solvay Solexis Spa Processo per la preparazione di perfluoropolieteri.
ITMI20062306A1 (it) * 2006-11-30 2008-06-01 Solvay Solexis Spa Lubrificanti fluorurati
US8258090B2 (en) * 2006-11-30 2012-09-04 Solvay Solexis S.P.A. Fluorinated lubricants
ITMI20062308A1 (it) * 2006-11-30 2008-06-01 Solvay Solexis Spa Additivi per alo-polimeri
EP1980583A1 (en) * 2007-04-10 2008-10-15 Solvay Solexis S.p.A. A method for preparing carbonylic perfluoropolyethers
WO2009019243A1 (en) * 2007-08-07 2009-02-12 Solvay Solexis S.P.A. Modification of carbonaceous materials
EP2100909A1 (en) 2008-03-14 2009-09-16 Solvay Solexis S.p.A. (Per)fluorinated addition products
WO2010017665A1 (zh) * 2008-08-15 2010-02-18 中昊晨光化工研究院 一种含氟聚醚过氧化物及其在含氟单体乳液聚合中的应用
JP5854840B2 (ja) 2008-12-05 2016-02-09 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア 多官能性(パー)フルオロポリエーテル
JP6227550B2 (ja) * 2011-12-22 2017-11-08 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. 芳香族末端基を有する(パー)フルオロポリエーテルの製造方法
CN103724559B (zh) * 2013-12-17 2016-08-17 中昊晨光化工研究院有限公司 一种由全氟聚醚过氧化物合成全氟聚醚的方法
JP2017105945A (ja) * 2015-12-10 2017-06-15 ダイキン工業株式会社 過酸化パーフルオロポリオキシアルキレン化合物の製造方法
CN108440748B (zh) * 2018-04-09 2020-06-16 浙江巨化技术中心有限公司 一种高分子量带有酰氟基团全氟聚醚过氧化物的合成方法
KR102240973B1 (ko) * 2019-06-13 2021-04-15 한국화학연구원 과산화 퍼플루오로폴리에테르의 과산화물 제거를 통한 퍼플루오로폴리에테르의 제조장치 및 제조방법
CN114276532A (zh) * 2021-12-29 2022-04-05 山东东岳高分子材料有限公司 一种过氧化全氟聚醚的制备方法及装置

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4451646A (en) * 1967-02-09 1984-05-29 Montedison, S.P.A. High molecular weight polymeric perfluorinated copolyethers and process for their preparation from tetrafluoroethylene
DE1745169B2 (de) * 1967-02-09 1977-04-21 Montecatini Edison S.P.A., Mailand (Italien) Fluorierte lineare polyaether und verfahren zu ihrer herstellung
US3847978A (en) * 1968-07-01 1974-11-12 Montedison Spa Perfluorinated linear polyethers having reactive terminal groups at both ends of the chain and process for the preparation thereof
IT1229845B (it) * 1989-04-20 1991-09-13 Ausimont Srl Procedimento per la preparazione di perfluoropolieteri perossidici.
IT1249319B (it) * 1991-04-26 1995-02-22 Ausimont Spa Perfluoropolieteri ad elevata viscosita' e basso contenuto di ossigeno perossidico, e procedimento per la loro preparazione
US5182342A (en) * 1992-02-28 1993-01-26 E. I. Du Pont De Nemours And Company Hydrofluorocarbon solvents for fluoromonomer polymerization
IT1264977B1 (it) * 1993-11-17 1996-10-17 Ausimont Spa Processo per preparare perfluoropolietri
US5658962A (en) * 1994-05-20 1997-08-19 Minnesota Mining And Manufacturing Company Omega-hydrofluoroalkyl ethers, precursor carboxylic acids and derivatives thereof, and their preparation and application
WO1995032173A1 (fr) * 1994-05-24 1995-11-30 Eisai Co., Ltd. Compose porteur de deux groupes 2,6-diiodophenol-4-yl et medicament de diagnostic de l'allergie a l'iode
IT1274591B (it) * 1994-08-05 1997-07-18 Ausimont Spa Processo per la preparazione di poliossiperfluoroalcani idrogeno terminati

Also Published As

Publication number Publication date
AR005793A1 (es) 1999-07-14
BG101229A (en) 1997-08-29
HRP970079B1 (en) 2001-06-30
CN1080276C (zh) 2002-03-06
HUP9700438A3 (en) 1998-12-28
PL318452A1 (en) 1997-08-18
EP0790269A3 (en) 1998-10-07
IT1282627B1 (it) 1998-03-31
CA2197538C (en) 2005-06-21
ITMI960279A0 (es) 1996-02-14
ATE194850T1 (de) 2000-08-15
CZ293428B6 (cs) 2004-04-14
CA2197538A1 (en) 1997-08-15
BG62394B1 (bg) 1999-10-29
US5744651A (en) 1998-04-28
IL120220A (en) 2001-01-11
TW442497B (en) 2001-06-23
DE69702550D1 (de) 2000-08-24
HU9700438D0 (en) 1997-04-28
EP0790269B1 (en) 2000-07-19
HUP9700438A2 (hu) 1998-03-02
HU220709B1 (hu) 2002-04-29
BR9700958A (pt) 1998-09-01
JPH09227506A (ja) 1997-09-02
RO116894B1 (ro) 2001-07-30
NZ314218A (en) 1998-08-26
KR100486125B1 (ko) 2005-10-27
CZ43497A3 (cs) 1998-03-18
DE69702550T2 (de) 2001-03-15
AU1268397A (en) 1997-08-21
RU2194725C2 (ru) 2002-12-20
NO970668D0 (no) 1997-02-13
NO311693B1 (no) 2002-01-07
ITMI960279A1 (it) 1997-08-14
EP0790269A2 (en) 1997-08-20
HRP970079A2 (en) 1998-04-30
IL120220A0 (en) 1997-06-10
KR970061935A (ko) 1997-09-12
IN190368B (es) 2003-07-19
CN1167124A (zh) 1997-12-10
UY24459A1 (es) 1997-08-05
JP3862339B2 (ja) 2006-12-27
ES2150155T3 (es) 2000-11-16
ZA971176B (en) 1997-08-25
AU715369B2 (en) 2000-02-03
NO970668L (no) 1997-08-15

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Legal Events

Date Code Title Description
FG Grant, registration
FD Application declared void or lapsed