UY23047A1 - Procedimiento para la preparación de 3-ciano-5-alcoxi-1-arilpirazoles plaguicidas.- - Google Patents

Procedimiento para la preparación de 3-ciano-5-alcoxi-1-arilpirazoles plaguicidas.-

Info

Publication number
UY23047A1
UY23047A1 UY23047A UY23047A UY23047A1 UY 23047 A1 UY23047 A1 UY 23047A1 UY 23047 A UY23047 A UY 23047A UY 23047 A UY23047 A UY 23047A UY 23047 A1 UY23047 A1 UY 23047A1
Authority
UY
Uruguay
Prior art keywords
arthropods
cyano
helminths
nematodes
protozoa
Prior art date
Application number
UY23047A
Other languages
English (en)
Inventor
Themistocles D'SILVA
Gail Scotton Powell
Philip Reid Timmons
Richard Glyn Pennicard
Original Assignee
Rhone Poulenc Agrochimie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Agrochimie filed Critical Rhone Poulenc Agrochimie
Publication of UY23047A1 publication Critical patent/UY23047A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/28—Two oxygen or sulfur atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
    • C07F9/6503—Five-membered rings
    • C07F9/65031—Five-membered rings having the nitrogen atoms in the positions 1 and 2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)

Abstract

Se describe un procedimiento que comprende la operación de: hacer reaccionar un compuesto de pirazolona con un cloruro de sulfenilo, que tiene la fórmula RSCl, en que R es como se define seguidamente, en el seno de un disolvente orgánico inerte a una temperatura en el intervalo de aproximadamente -20ºC a aproximadamente 100ºC, en presencia de una base de amina aromática o terciaria como aceptor de ácidos, para producir un compuesto intermedio derivado de éster de fórmula 5 (figura 1) en que: R2, R3, R5 y R6 son, individualmente, un átomo de hidrógeno o un átomo de halógeno. Como ejemplo no limitante: 1-(2,6-dicloro-4-trifluorometilfenil)-3-ciano-4-trifluorometilsulfenil-5-metoxipirazol. Los compuestos son utilizados en un método para la represión de artrópodos, nemátodos y plagas por helmintos y protozoos: en cultivos agrícolas y hortícolas donde las plagas de las plantas son por artrópodos o nemátodos; y en el sector de la medicina veterinaria contra artrópodos, helmintos y protozoos que parasitan interior o exteriormente sobre vertebrados de sangre caliente.
UY23047A 1989-03-02 1990-03-02 Procedimiento para la preparación de 3-ciano-5-alcoxi-1-arilpirazoles plaguicidas.- UY23047A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/317,722 US4918085A (en) 1989-03-02 1989-03-02 Pesticidal 3-cyano-5-alkoxy-1-arylpyrazoles, compositions and use

Publications (1)

Publication Number Publication Date
UY23047A1 true UY23047A1 (es) 1990-08-16

Family

ID=23234985

Family Applications (1)

Application Number Title Priority Date Filing Date
UY23047A UY23047A1 (es) 1989-03-02 1990-03-02 Procedimiento para la preparación de 3-ciano-5-alcoxi-1-arilpirazoles plaguicidas.-

Country Status (34)

Country Link
US (2) US4918085A (es)
EP (1) EP0385809B1 (es)
JP (1) JP2963484B2 (es)
KR (1) KR0161284B1 (es)
CN (1) CN1031238C (es)
AT (1) ATE124688T1 (es)
AU (1) AU631605B2 (es)
BG (1) BG60002B2 (es)
BR (1) BR9001053A (es)
CA (1) CA2010180C (es)
CZ (1) CZ285842B6 (es)
DD (1) DD299963A5 (es)
DE (1) DE69020600T2 (es)
DK (1) DK0385809T3 (es)
ES (1) ES2074120T3 (es)
FI (1) FI103110B1 (es)
GR (1) GR3017622T3 (es)
HU (1) HU209618B (es)
IE (1) IE67562B1 (es)
IL (1) IL93509A (es)
MA (1) MA21758A1 (es)
MX (1) MX9204661A (es)
MY (1) MY106224A (es)
NO (1) NO900941L (es)
NZ (1) NZ232762A (es)
OA (1) OA09549A (es)
PH (1) PH27053A (es)
PL (1) PL162501B1 (es)
PT (1) PT93312B (es)
RO (1) RO106561B1 (es)
RU (1) RU2037488C1 (es)
TR (1) TR24579A (es)
UY (1) UY23047A1 (es)
ZA (1) ZA901355B (es)

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US5232940A (en) * 1985-12-20 1993-08-03 Hatton Leslie R Derivatives of N-phenylpyrazoles
US6372774B1 (en) 1985-12-20 2002-04-16 Rhone-Poulenc Agriculture Ltd. Derivatives of N-phenylpyrazoles
GB8913866D0 (en) * 1989-06-16 1989-08-02 May & Baker Ltd New compositions of matter
NO179282C (no) * 1991-01-18 1996-09-11 Rhone Poulenc Agrochimie Nye 1-(2-pyridyl)pyrazolforbindelser til kontroll av skadeinsekter
US5405969A (en) * 1993-12-10 1995-04-11 Eastman Kodak Company Manufacture of thioether compounds
US5707551A (en) * 1994-12-22 1998-01-13 Rhone-Poulenc Inc. Nonaqueous suspension concentrates of highly water-soluble solids
US5906962A (en) * 1994-12-22 1999-05-25 Rhodia Inc. Non-aqueous suspension concentrates of highly water-soluble solids
US5801189A (en) * 1995-04-05 1998-09-01 Rhone-Poulenc Agriculture Limited Method for combating insects
US5629335A (en) * 1995-04-07 1997-05-13 Rhone-Poulenc Inc. Pesticidal 1-arylpyrazole-3-carboximidothioic acid esters
US5614182A (en) * 1995-04-10 1997-03-25 Rhone-Poulenc Inc. Methods of attracting and combatting insects
US5707934A (en) * 1995-04-28 1998-01-13 Rhone-Poulenc Inc. Plant growth regulation using 3-cyano-1-phenylpyrazoles such as fipronil
AUPN328395A0 (en) * 1995-05-31 1995-06-22 Rhone-Poulenc Rural Australia Pty Ltd Insecticide
US6060502A (en) * 1995-06-05 2000-05-09 Rhone-Poulenc Agrochimie Pesticidal sulfur compounds
US6060495A (en) * 1995-06-05 2000-05-09 Rhone-Poulenc Agrochimie Pesticidal sulfur compounds
US6136983A (en) * 1995-06-05 2000-10-24 Rhone-Poulenc Agrochimie Pesticidal sulfur compounds
US6261996B1 (en) * 1995-06-08 2001-07-17 Rhone-Poulenc Inc. Pregerminated rice seed
FR2739255B1 (fr) * 1995-09-29 1998-09-04 Rhone Merieux Composition antiparasitaire pour le traitement et la protection des animaux de compagnie
TW362952B (en) 1996-01-30 1999-07-01 Takeda Chemical Industries Ltd Arylpyrazole insecticides
AU724487B2 (en) * 1996-06-07 2000-09-21 Rhone-Poulenc Rural Australia Pty Ltd Method of treatment of sugar plant to improve the sugar content
US6524603B1 (en) 1996-07-23 2003-02-25 Rhone-Poulenc Agro Process and composition for the antiparasitic treatment of the surroundings of animals
CA2261264C (en) * 1996-07-23 2004-03-23 Merial Process and composition for the antiparasitic treatment of the surroundings of animals
JPH10143977A (ja) 1996-09-10 1998-05-29 Sony Corp ディスク装置およびそれを用いたビデオカメラ装置
EP0839809A1 (en) * 1996-11-01 1998-05-06 Rhone-Poulenc Agrochimie Pesticidal 1-arylpyrazole-5-sulfinilimine derivatives
EP0839810B1 (en) * 1996-11-04 2002-09-25 Aventis Cropscience S.A. Pesticidal 1-polyarylpyrazoles
EP0845211B1 (en) 1996-11-29 2003-10-01 Bayer CropScience S.A. Protection of buildings against termites by 1-Arylpyrazoles
US5929121A (en) * 1996-12-13 1999-07-27 Rhone-Poulenc Agro Protection of trees
US6350771B1 (en) 1996-12-24 2002-02-26 Rhone-Poulenc, Inc. Pesticidal 1-arylpyrazoles
ZA9711534B (en) 1996-12-24 1998-06-24 Rhone Poulenc Agrochimie Pesticidal 1-arylpyrazoles.
AU746514B2 (en) * 1996-12-24 2002-05-02 Merial, Inc. Pesticidal 1-arylpyrazoles
ZA981776B (en) * 1997-03-10 1998-09-03 Rhone Poulenc Agrochimie Pesticidal 1-arylpyrazoles
CO5060426A1 (es) * 1997-03-10 2001-07-30 Rhone Poulenc Agrochimie 1-aril-3-imidiopirazoles plaguicidas
US5907041A (en) * 1997-03-12 1999-05-25 Rhone-Poulenc Inc. Process for preparing pyrazole derivatives
US6057355A (en) * 1997-08-05 2000-05-02 Rhone-Poulenc Inc. Pesticidal combination
EP0898888A1 (en) 1997-08-29 1999-03-03 Rhone-Poulenc Agrochimie Device for the control of crawling social and/or congregating insects
EP0898886A1 (en) * 1997-08-29 1999-03-03 Rhone-Poulenc Agrochimie System for the protection of buildings against termites
EP0898885A1 (en) * 1997-08-29 1999-03-03 Rhone-Poulenc Agrochimie Protection system against subterranean termites
US5981565A (en) 1997-10-07 1999-11-09 Rhone-Poulenc Inc. Pyrazole pesticides
US6107314A (en) 1997-10-07 2000-08-22 Rhone-Poulenc Inc. Pesticides
BR9705278A (pt) * 1997-10-15 1999-05-25 Rhone Poulenc Agrochimie Composição método para controlar formigas cortadas de folha e produto comercial
BR9900235A (pt) * 1998-02-20 2000-04-25 Rhone Poulenc Agrochimie Método de sugação quìmica de uma árvore e método de proteção de duas ou mais árvoes.
US6149913A (en) * 1998-11-16 2000-11-21 Rhone-Poulenc Ag Company, Inc. Compositions and methods for controlling insects
US6524286B1 (en) * 1999-03-25 2003-02-25 Gordon O. Helms Medical application system for animals
US6156703A (en) * 1999-05-21 2000-12-05 Ijo Products, Llc Method of inhibiting fruit set on fruit producing plants using an aqueous emulsion of eicosenyl eicosenoate and docosenyl eicosenoate
JP2003516941A (ja) * 1999-12-02 2003-05-20 アベンティス クロップサイエンス ソシエテ アノニム 動物における節足動物の制御
WO2003022055A1 (en) * 2001-09-13 2003-03-20 Bayer Cropscience S.A. Pesticidal compositions
EP1699291B1 (en) * 2003-12-24 2009-09-02 Bayer CropScience AG Plant growth regulation
MX2011005184A (es) * 2008-11-19 2011-07-28 Merial Ltd Composiciones que comprenden un aril pirazol y/o una formamidina, metodos y usos de las mismas.
TWI579274B (zh) 2012-04-20 2017-04-21 龍馬躍公司 製備１－芳基－５－烷基吡唑化合物的改良方法

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US4134987A (en) * 1976-01-14 1979-01-16 Huppatz John L Compounds and compositions
GB8531485D0 (en) * 1985-12-20 1986-02-05 May & Baker Ltd Compositions of matter
DE3617554A1 (de) * 1986-05-24 1987-11-26 Bayer Ag 5-oxy(thio)-pyrazol-derivate
DE3625686A1 (de) * 1986-07-30 1988-02-04 Bayer Ag 4-cyano(nitro)-5-oxy(thio)-pyrazol-derivate

Also Published As

Publication number Publication date
HU901255D0 (en) 1990-05-28
CN1031238C (zh) 1996-03-13
DE69020600T2 (de) 1995-12-14
US4918085A (en) 1990-04-17
MX9204661A (es) 1994-02-28
NO900941D0 (no) 1990-02-28
ATE124688T1 (de) 1995-07-15
PT93312B (pt) 1996-01-31
CA2010180C (en) 2000-04-18
KR0161284B1 (ko) 1998-12-01
PL162501B1 (pl) 1993-12-31
FI103110B (fi) 1999-04-30
MY106224A (en) 1995-04-29
DD299963A5 (de) 1992-05-14
TR24579A (tr) 1992-01-01
RO106561B1 (ro) 1993-05-31
CZ95690A3 (cs) 1999-07-14
NZ232762A (en) 1992-04-28
IE67562B1 (en) 1996-04-17
DE69020600D1 (de) 1995-08-10
CA2010180A1 (en) 1990-09-02
IL93509A0 (en) 1990-11-29
KR900014331A (ko) 1990-10-23
NO900941L (no) 1990-09-03
DK0385809T3 (da) 1995-08-21
EP0385809A1 (en) 1990-09-05
PH27053A (en) 1993-02-01
IE900518L (en) 1990-09-02
CZ285842B6 (cs) 1999-11-17
JPH02282366A (ja) 1990-11-19
US5047550A (en) 1991-09-10
PT93312A (pt) 1990-11-07
HU209618B (en) 1994-09-28
ES2074120T3 (es) 1995-09-01
IL93509A (en) 1994-04-12
JP2963484B2 (ja) 1999-10-18
MA21758A1 (fr) 1990-10-01
GR3017622T3 (en) 1996-01-31
BG60002B2 (en) 1993-06-30
HUT53493A (en) 1990-11-28
FI901056A0 (fi) 1990-03-01
OA09549A (fr) 1993-01-31
CN1045262A (zh) 1990-09-12
ZA901355B (en) 1991-04-24
RU2037488C1 (ru) 1995-06-19
FI103110B1 (fi) 1999-04-30
AU631605B2 (en) 1992-12-03
EP0385809B1 (en) 1995-07-05
BR9001053A (pt) 1991-02-26
AU5063890A (en) 1990-09-06

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Legal Events

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Effective date: 20100302