USRE39998E1 - Composite wear component - Google Patents
Composite wear component Download PDFInfo
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- USRE39998E1 USRE39998E1 US10/448,004 US44800497A USRE39998E US RE39998 E1 USRE39998 E1 US RE39998E1 US 44800497 A US44800497 A US 44800497A US RE39998 E USRE39998 E US RE39998E
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- United States
- Prior art keywords
- ceramic
- wear component
- composite wear
- component according
- pad
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- 239000002131 composite material Substances 0.000 title claims abstract description 46
- 239000000919 ceramic Substances 0.000 claims abstract description 63
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 27
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 23
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000005266 casting Methods 0.000 claims abstract description 14
- 239000011159 matrix material Substances 0.000 claims abstract description 14
- 229910001338 liquidmetal Inorganic materials 0.000 claims abstract description 12
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 11
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 10
- 239000000470 constituent Substances 0.000 claims abstract description 7
- 239000006104 solid solution Substances 0.000 claims abstract description 4
- 229910010293 ceramic material Inorganic materials 0.000 claims description 24
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 5
- 238000009750 centrifugal casting Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000010285 flame spraying Methods 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 3
- 238000005470 impregnation Methods 0.000 claims 2
- 239000000203 mixture Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- 238000005299 abrasion Methods 0.000 description 7
- 230000008595 infiltration Effects 0.000 description 6
- 238000001764 infiltration Methods 0.000 description 6
- 238000000227 grinding Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 5
- 229910001928 zirconium oxide Inorganic materials 0.000 description 5
- 229910000805 Pig iron Inorganic materials 0.000 description 4
- 238000005336 cracking Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229910016341 Al2O3 ZrO2 Inorganic materials 0.000 description 1
- 229910000617 Mangalloy Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000005495 investment casting Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005058 metal casting Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/08—Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C13/00—Disintegrating by mills having rotary beater elements ; Hammer mills
- B02C13/26—Details
- B02C13/28—Shape or construction of beater elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C15/00—Disintegrating by milling members in the form of rollers or balls co-operating with rings or discs
- B02C15/004—Shape or construction of rollers or balls
- B02C15/005—Rollers or balls of composite construction
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/02—Casting in, on, or around objects which form part of the product for making reinforced articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/06—Casting in, on, or around objects which form part of the product for manufacturing or repairing tools
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
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- C—CHEMISTRY; METALLURGY
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
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- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
- C04B35/62655—Drying, e.g. freeze-drying, spray-drying, microwave or supercritical drying
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/653—Processes involving a melting step
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C2210/00—Codes relating to different types of disintegrating devices
- B02C2210/02—Features for generally used wear parts on beaters, knives, rollers, anvils, linings and the like
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/12007—Component of composite having metal continuous phase interengaged with nonmetal continuous phase
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/22—Nonparticulate element embedded or inlaid in substrate and visible
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31678—Of metal
Definitions
- the present invention relates to a composite wear component produced by casting and consisting of a metal matrix whose wear face comprises inserts which have good wear resistance properties.
- the invention relates especially to wear components employed in plants for grinding, crushing and conveying various abrasive materials which are encountered in industries such as cement factories, mines, metallurgy, electricity generating stations or various quarries. These components are often subjected to high mechanical stresses in the bulk and to a high wear by abrasion at the working face. It is therefore desirable that these components should exhibit a high abrasion resistance and some ductility, to be able to withstand the mechanical stresses such as impacts and to be capable optionally of being mechanical.
- composite components which have a core made of relatively ductile alloy in which isolated inserts which have a good wear resistance are embedded.
- This well-known process employs wax models which must be melted to obtain the mould cavity which must be filled with metal; this mould itself is made of ceramic and not of a conventional sand.
- a ceramic pad (wafer core) is formed first, with a spongy structure which has a three-dimensional network of open pores all of which communicate with one another.
- This ceramic pad is formed by pouring grains of ceramic materials into an appropriate mould and, next, a liquid adhesive with a good fluidity, for example a liquid resin which, after curing, retains the grains to form the ceramic structure.
- the ceramic material may consist of aluminium oxide or of zirconium oxide.
- this pad is placed in a mould intended to produce the wax model of the component.
- the wax model is then case and, lastly, the ceramic mould is produced by dipping the wax model in a ceramic slurry.
- the ceramic mould containing the wax model is then heated so as to melt the wax model.
- the wax thus flows from the ceramic mould but the pads inserted beforehand in the wax model remain adhesively bonded to the walls of the ceramic mould.
- the latter is preheated to a temperature of the order of 1150° C., generally under vacuum.
- the component usually undergoes a subsequent heat treatment.
- the mechanical properties of the ceramic material should be adapted to those of the metal in order to produce a component whose properties correspond to the requirements of the specific application for which it is intended.
- the aim of the present invention is to provide a composite wear component with ceramic inserts satisfactorily corresponding to the requirements listed above.
- Another objective of the present invention is to solve this second problem by proposing specific geometries of the composite wear component.
- the invention proposes a composite wear component produced by conventional or centrifugal casting. It consists of a metal matrix whose wear surface comprises inserts which have good abrasion resistance properties, these inserts being made of a ceramic material, itself composite, consisting of a solid solution or homogeneous phase of 20 to 80% of Al 2 O 3 and 80 to 20% or ZrO 2 , the percentages being expressed by weights of constituents.
- the ceramic material may additionally contain other oxides whose proportion by weight does not exceed 3 to 4%.
- the composition of the ceramic material consists of the following:
- the composition of the ceramic material consists of the following:
- the content of ceramic materials in the insert is between 35 and 80% by weight volume, preferably between 40 to 60% and advantageously of the order of 50%.
- This composite ceramic material is produced from an aggregate of ceramic grains which have a particle size within the range F6 to F22 according to the FEPA standard, that is to say a diameter of between approximately 0.7 mm and 5.5 mm. These ceramic grains are manufactured in a conventional way, by electrofusion, by sintering, by flame spraying or by any other process allowing the two constituents to fuse.
- the ceramic grains are aggregated with the aid of an adhesive, the proportion of which does not exceed 4% by weight relative to the total weight of the pad and is preferably between 2 and 3% by weight.
- This adhesive may be inorganic or organic.
- An adhesive based on a silicate or an adhesive which is in the form of epoxy resin may be mentioned by way of example.
- the invention is based on the finding that aluminium oxide (corundum) and zirconium oxide have relatively different properties and this makes it possible, by a judicious choice within the abovementioned ranges, to adjust the hardness, the toughness and the thermal expansion coefficient of the ceramic composite so as to combine a good hardness and a good toughness; and to make it compatible with the precise application for which the component is intended, on the one hand, and to obtain, on the other hand, an expansion coefficient of the composite ceramic which is close to that of the casting metal chosen, that is to say of the pig iron or of the steel which has an expansion coefficient of between 10 ⁇ 10 ⁇ 6 and 11 ⁇ 10 ⁇ 6 .
- Zirconium oxide has the advantage of having an expansion coefficient which is close to that of the metal. In addition, it contributes to good toughness, that is to say that it reduces the risks of breakage.
- Aluminium oxide for its part, contributes to good hardness. Within the pads the zirconium particles present in the alumina make it possible to increase the resistance of the latter to cracking and thus to obtain a toughness greater than that of each of the components considered in isolation, namely ZrO 2 or Al 2 O 3 .
- the wear components which are subjected to strong abrasion it is advantageous to increase the proportion of aluminium oxide, not exceeding, however, a certain limit beyond which the abrasion resistance and the toughness begin to decrease.
- the second range is rather chosen for the ceramic composition.
- the choice of the proportions of the constituents of the composite ceramic insert may, of course, also take into account the composition of the casting metal with a view to the properties required by the application for which the component is intended. Similarly, the choice of the composition of the casting metal may be adapted to the nature of the composite insert.
- the pad rather in the form of a “honeycomb” structure which includes various elementary cells exhibiting a polygonal or circular shape within the ceramic phase.
- the thickness of the walls of the various cells constituting the ceramic phase preferably varies between 5 and 25 mm.
- this embodiment makes it possible to increase the quantity of the ceramic phase without, however, risking the problem of poor infiltration of the liquid metal in the case of a component whose wear takes place more particularly in depth.
- the advantage lies in the fact that the walls do not exceed the limiting thickness for infiltration of the liquid metal, which is approximately 25 mm, but with a height that is practically equal to the height of the composite component.
- the improvement in the grinding process is observed.
- hollow pits are created in the cellular metal part, which then fill with material to be ground and thus ensure that they play a part in self-protection against wear.
- This profile advantageously makes it possible to avoid the creation of preferential wear paths by the ground material, reflected in a drop in output rate in the case of the mills.
- this structure in the “honeycomb” form according to the second preferred embodiment makes it possible to reduce the risk of propagation of the cracks that could develop in the infiltrated pad during the production of the component.
- the splits which might be formed are then closed onto themselves and do not propagate within the whole component.
- FIG. 1 describes a composite wear component according to a first preferred embodiment of the present inventionwith FIG. 1 being a sectional view.
- FIGS. 2A and 2B describe a composite wear component according to a second embodiment of the present invention with FIG. 2B being a sectional view taken along line 2 B— 2 B ⁇ 21 — 21 of FIG. 2 A.
- FIG. 3 describes a particular application for a composite wear component according to the present invention.
- a mixture of 75% of Al 2 O 3 and 23% of ZrO 2 is made up, the two constituents of which are fused by electrofusion to form composite grains of a particle size included in the categories F6 to F20 of the FEPA standard. These grains are then poured into a mould of appropriate shape with a liquid adhesive which, after curing, holds the grains together to form a ceramic pad.
- FIG. 1 it is recommended to employ the configuration shown in FIG. 1 , which takes two ceramic pads 1 which are superposed and leaving a 10 mm gap between them. These Ceramic pads 1 are placed in an appropriate mould, preferably made of sand, into which is next cast a liquid pig iron 2 including 3% or carbon, 26% of chromium and other conventional elements in a small proportion which is always encountered in alloys of this type. A wear component is thus produced with ceramic inserts 1 with a hardness of the order of 1600 Hv with an expansion coefficient close to 8 ⁇ 10 ⁇ 6 , held in a pig iron matrix 2 with a hardness close to 750 Hv.
- the ceramic material is prepared as in Example 1 but this time choosing a composition which gives preference to the expansion coefficient at the expense of hardness, that is to say by taking 40% of ZrO 2 and 60% of Al 2 O 3 .
- a “honeycomb” form configuration is employed, as shown in FIG. 2 , which is formed of ceramic inserts 1 and cast metal 2 .
- the structure is in the form of a “honeycomb” whose cells have walls the thickness of which is approximately 20 mm and the height of which is practically equal to the height of the composite component.
- This structure is produced with the aid of a manganese steel with a composition of 1% of carbon, 14% of manganese and 1.5% of molybdenum.
- a composite component is thus produced with a hardness of approximately 1350 Hv with an expansion coefficient close to 9 ⁇ 10 ⁇ 6 .
- the objective here is to decrease the risk of splits in the component because of the high impact level to which this type of component is subjected.
- FIG. 3 shows an example of a ceramic pad employed for an application in beaters, which allows the three wear phases of the beater to be strengthened.
- the ceramic pad 1 is a single component situated within the metal phase 2 .
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- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Food Science & Technology (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Reinforced Plastic Materials (AREA)
- Ceramic Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
- Dental Preparations (AREA)
- Materials For Medical Uses (AREA)
- Semiconductor Lasers (AREA)
- Rolls And Other Rotary Bodies (AREA)
- Silicon Polymers (AREA)
- Magnetic Heads (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96202741A EP0838288A1 (fr) | 1996-10-01 | 1996-10-01 | Pièce d'usure composite |
EP97870099 | 1997-07-04 | ||
PCT/EP1997/004762 WO1998015373A1 (fr) | 1996-10-01 | 1997-08-27 | Piece d'usure composite |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/269,723 Reissue US6399176B1 (en) | 1996-10-01 | 1997-08-27 | Composite wear component |
Publications (1)
Publication Number | Publication Date |
---|---|
USRE39998E1 true USRE39998E1 (en) | 2008-01-08 |
Family
ID=26143214
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/269,723 Ceased US6399176B1 (en) | 1996-10-01 | 1997-08-27 | Composite wear component |
US10/448,004 Expired - Lifetime USRE39998E1 (en) | 1996-10-01 | 1997-08-27 | Composite wear component |
US10/152,569 Expired - Fee Related US6520241B2 (en) | 1996-10-01 | 2002-05-23 | Composite wear component |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/269,723 Ceased US6399176B1 (en) | 1996-10-01 | 1997-08-27 | Composite wear component |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/152,569 Expired - Fee Related US6520241B2 (en) | 1996-10-01 | 2002-05-23 | Composite wear component |
Country Status (23)
Country | Link |
---|---|
US (3) | US6399176B1 (xx) |
EP (1) | EP0930948B1 (xx) |
JP (1) | JP2001504036A (xx) |
KR (2) | KR20060013699A (xx) |
CN (1) | CN1114513C (xx) |
AT (1) | ATE195895T1 (xx) |
AU (1) | AU723329B2 (xx) |
BR (1) | BR9712188A (xx) |
CA (1) | CA2266475A1 (xx) |
CZ (1) | CZ294041B6 (xx) |
DE (1) | DE69702988T2 (xx) |
EE (1) | EE9900139A (xx) |
ES (1) | ES2150278T3 (xx) |
HU (1) | HU224208B1 (xx) |
ID (1) | ID17782A (xx) |
MY (1) | MY128314A (xx) |
PL (1) | PL189446B1 (xx) |
PT (1) | PT930948E (xx) |
RU (1) | RU2177389C2 (xx) |
SK (1) | SK284900B6 (xx) |
TR (1) | TR199900645T2 (xx) |
UA (1) | UA46124C2 (xx) |
WO (1) | WO1998015373A1 (xx) |
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WO1998045486A1 (en) | 1997-04-04 | 1998-10-15 | Smith And Stout Research And Development, Inc. | Wear resistant, high-impact, iron alloy member and method of making the same |
US6221184B1 (en) | 1998-01-19 | 2001-04-24 | Magotteaux International S.A. | Process of the production of high-carbon cast steels intended for wearing parts |
WO1999047264A1 (fr) | 1998-03-17 | 1999-09-23 | Magotteaux International S.A. | Ejecteur a une ou plusieurs poches |
EP1530965A1 (en) | 2003-11-11 | 2005-05-18 | Mattern, Udo | Controlled release delivery system of sexual hormones for nasal application |
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