Classifications

• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C9/00—Alloys based on copper
  • C22C9/04—Alloys based on copper with zinc as the next major constituent
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
  • F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
  • F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
  • F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
  • F01L3/08—Valves guides; Sealing of valve stem, e.g. sealing by lubricant

Definitions

• the invention relates to a copper-zinc alloy that is particularly suited for use in a valve guide.
• Copper-zinc alloys or sintered steel alloys are used for a valve guide in an internal combustion engine.
• the properties of the Cu—Zn alloys no longer meet the demands imposed on a valve guide which is to be used in the new direct-injected FSI engines (FSI: fuel stratified injection).
• FSI direct-injected FSI engines
• the working temperature of the valve guides may reach and exceed 300° C.
• the copper-zinc alloys which are currently used soften at these temperatures.
• a similar disadvantageous effect is also observed in sintered steel alloys.
• Sintered steel alloys likewise soften at temperatures above 300° C., and in addition the hardness varies considerably.
• the outlay involved in producing sintered steel alloys is high, on account of the powder metallurgy production process.
• a valve guide that is formed of a specially formulated copper-zinc alloy.
• the alloy for the valve guide comprises 59 to 73% copper, 2.7 to 8.3% manganese, 1.5 to 6% aluminum, 0.2 to 4% silicon, 0.2 to 3% iron, 0 to 2% lead, 0 to 2% nickel, 0 to 0.2% tin, remainder zinc and inevitable impurities.
• % (percent) indications in this text refer to percent by weight (wt. %).
• the invention specifies a new use of a copper-zinc alloy.
• a similar alloy as described in the commonly assigned German patent DE 29 19 478 C2 (cf. GB 2 049 727 A) is used as a synchronizer ring alloy and has a high coefficient of friction. Hitherto, a high coefficient of friction has been considered an impediment to using a material as a valve guide, since this use requires the frictional stresses to be as low as possible.
• the copper-zinc alloy described has a surprisingly high hot strength, which in combination with its good wear resistance is the property which actually allows it to be used as a valve guide.
• This surprising combination of materials properties offers the option of using the known alloy in a new way as a valve guide.
• Use as a valve guide in modern engines requires a combination of a high thermal stability at over 300° C. and a good wear resistance, which is required on account of transverse forces acting on the valve tappets. On account of these otherwise excellent properties, the impact of the high coefficient of friction can be disregarded. Therefore, the invention overcomes a prejudice which has hitherto been commonly held in the specialist field.
• valve guides can be produced in rod form by semi-continuous or fully continuous casting, extrusion and drawing, i.e. by hot and cold forming.
• the alloy has a microstructure which includes an ⁇ solid solution component and a ⁇ solid solution component.
• the copper-zinc alloy for the use as a valve guide comprises 70 to 73% copper, 6 to 8% manganese, 4 to 6% aluminum, 1 to 4% silicon, 1 to 3% iron, 0.5 to 1.5% lead, 0 to 0.2% nickel, 0 to 0.2% tin, remainder zinc and inevitable impurities.
• the microstructure of the refined alloy produced in accordance with the above-noted German patent DE 29 19 478 C2 consists of an alpha and ⁇ solid solution matrix comprising up to 60 to 85% ⁇ phase, wherein the body centered cubic ⁇ phase represents the base matrix, in which the face centered cubic ⁇ phase is distributed predominantly in finely dispersed form.
• the microstructure may also contain hard intermetallic compounds, for example iron-manganese silicides.
• the alpha phase determines the stability of the alloy.
• Valve guides made from the novel alloy have a surprisingly high wear resistance, which is even higher than that of sintered steel.
• dry-friction wear in valve guides made from said alloy allows them to be used in engines which require “purer” fuels, i.e. lead-free of sulfur-free fuels (or ultra-low sulfur), since on account of the absence of these additives there is no need for an additional wear-reducing effect.
• This is particularly advantageous especially at temperatures around 300° C., the working temperature of the valve guides in FSI engines.
• a further advantage of the use of this alloy as a valve guide is that a stable hardness level is achieved in the desired working range above 300° C., since softening of the alloy only occurs at temperatures above 430° C., whereas the softening of copper-zinc alloys which have been used hitherto begins as early as 150° C. The associated drop in hardness occurs starting from 150° C., and the drop in hardness of sintered steel alloys commences from 300° C.
• the invention claims the use of a copper-zinc alloy, wherein the alloy comprises 69.5 to 71.5% copper, 6.5 to 8% manganese, 4.5 to 6% aluminum, 1 to 2.5% silicon, 1 to 2.5% iron, 0.5 to 1% lead, 0 to 0.2% nickel, 0 to 0.2% tin, remainder zinc and inevitable impurities.
• the microstructure of the alloy produced in the customary way includes an ⁇ and ⁇ solid solution matrix comprising up to 80% alpha phase distributed in finely dispersed form. It may also include hard intermetallic compounds, for example Fe—Mn silicides.
• valve guide is particularly advantageous since it has a hot tensile strength which is double that of conventional copper-zinc alloys which have hitherto been used as valve guides. Further advantageous properties include a high softening temperature, a high strength and a high wear resistance.
• a copper-zinc alloy wherein the alloy comprises 60 to 61.5% copper, 3 to 4% manganese, 2 to 3% aluminum, 0.3 to 1% silicon, 0.2 to 1% iron, 0 to 0.5% lead, 0.3 to 1% nickel, 0 to 0.2% tin, remainder zinc and inevitable impurities.
• the microstructure of said alloy includes a base mass of ⁇ solid solution, in which ⁇ precipitations in needle and ribbon form are embedded.
• the microstructure may also include randomly dispersed manganese-iron silicides.
• Valve guides made from this alloy have a high wear resistance which is even significantly higher than that of sintered steel.
• dry-friction wear in valve guides made from said alloy allows them to be used in engines which require “purer” fuels, i.e. lead-free or sulfur-free fuels, since the absence of these additives means that there is no need for an additional wear-reducing effect. This is particularly advantageous especially at temperatures around 300° C., the working temperature of the valve guides in FSI engines.
• Further properties of said alloy which are advantageous for its use as a valve guide include a high softening temperature and a high hot tensile strength.
• a copper-zinc alloy which additionally comprises up to 0.1% of at least one of the elements chromium, vanadium, titanium or zirconium is used for valve guides.
• the copper-zinc alloy as used for a valve guide may additionally comprise at least one of the following elements in the concentration of ⁇ 0.0005% boron, ⁇ 0.03% antimony, ⁇ 0.03% phosphorus, ⁇ 0.03% cadmium, ⁇ 0.05% chromium, ⁇ 0.05% titanium, ⁇ 0.05% zirconium, ⁇ 0.05% cobalt.
• sintered steel and copper-zinc alloys having approximately the following composition: 56 to 60% copper, 0.3 to 1% lead, 0.2 to 1.2% iron, 0 to 0.2% tin, 0.7 to 2% aluminum, 1 to 2.5% manganese, 0.4 to 1% silicon, remainder zinc and inevitable impurities, are used as material for valve guides which are subject to relatively low thermal stresses.
• an alloy of this type is referred to as a standard alloy. Alloy 1 corresponds to a first embodiment of the alloy according to the invention (cf. claims 2 - 4 ), and alloy 2 corresponds to a second embodiment of the novel alloy (cf. claims 5 , 6 ).
• alloy 1 When compared with standard alloy, the hardnesses of alloy 2 are always well above those of the standard alloy. By contrast, alloy 1 has a significant increase in hardness, from 224 to 280 HV50, as the temperature rises up to 350° C. Compared to the sintered steel, alloy 1 has a hardness which is higher by 140 HV50. Therefore, the hardness maximum of alloy 1 lies at the temperatures which correspond to the working temperature of valve guides in FSI engines.
• alloys 1 and 2 compared to the materials which are customarily used is attributable on the one hard to the higher starting hardness and on the other hand to further hardening effects.
• the electrical conductivity can be used as a measure of the thermal conductivity.
• a high value represents good thermal conductivity.
• the electrical conductivity of the standard alloy is 11 m/ ⁇ mm 2 .
• Alloy 2 has good electrical conductivity of 7.5 m/ ⁇ mm 2 , which is only about a quarter lower than that of the standard alloy.
• the electrical conductivity of alloy 1 is 4.6 m/ ⁇ mm 2 . This represents an electrical conductivity or heat dissipation which is approximately 48% higher than that of sintered steel (3.1 m/ ⁇ mm 2 ). Therefore, the dissipation of heat of alloys 1 and 2 is significantly better than that of sintered steel.
• Alloy 1 likewise has an excellent wear resistance of 1470 km/g, which is higher by more than a factor of 10 than the wear resistance of the standard alloy, at 126 km/g.
• the wear resistance of alloy 2 with lubricant is of a similar order of magnitude (94 km/g).
• alloys 1 and 2 have significant advantages over sintered steel and the standard alloy.
• Sintered steel has a wear of 312 km/g, which approximately corresponds to the wear properties of the standard alloy, at 357 km/g.
• the dry wear properties of alloy 2, at 417 km/g, are significantly better than those of the standard alloy and sintered steel. In other words, the wear is significantly lower.
• alloy 1 even has a wear resistance which is twice as high as that of sintered steel.
• the low dry-friction wear makes alloys 1 and 2 of particular interest, since on account of the increasing purity of the fuels, i.e. their freedom from lead or sulfur, imposed by the engine, the wear-reducing effect of what is known as the “blow by”, i.e. the lubrication provided by the fuel itself, in which in future the additive levels will be reduced, is absent.
• the hot tensile strength was determined using tensile tests at 350° C.
• the hot tensile strength of the standard alloy is 180 N/mm 2 .
• that of alloy 1 is twice as high (384 N/mm 2 ).
• Alloy 2 has a hot tensile strength which is approximately 35% higher than that of the standard alloy, at 243 N/mm 2 .
• Alloy 1 and alloy 2 can preferably be produced by semi-continuous or fully continuous casting, extrusion, drawing and straightening.
• Alloy 2 and in particular alloy 1 have clear advantages over the previous standard alloy used as a valve guide alloy and also compared to sintered steel. These advantages relate to the hot tensile strength, the softening temperature, the strength and the wear resistance. Furthermore, the conductivity is also sufficient, and consequently alloys 1 and 2 represent a considerable improvement for use as a valve guide, since these alloys satisfy the demands imposed on the material at the high operating temperatures used in the new generation of engines.
• Table 1 shows the material properties of a standard Cu—Zn alloy, a sintered steel alloy (standard alloy), in comparison with the novel alloy 1 and the novel alloy 2.

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