US3911158A - Cheese flavoring - Google Patents
Cheese flavoring Download PDFInfo
- Publication number
- US3911158A US3911158A US514400A US51440074A US3911158A US 3911158 A US3911158 A US 3911158A US 514400 A US514400 A US 514400A US 51440074 A US51440074 A US 51440074A US 3911158 A US3911158 A US 3911158A
- Authority
- US
- United States
- Prior art keywords
- cheese
- composition
- weight
- ppm
- flavour
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000013351 cheese Nutrition 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 49
- 239000000796 flavoring agent Substances 0.000 claims abstract description 20
- 235000019634 flavors Nutrition 0.000 claims abstract description 19
- 235000013336 milk Nutrition 0.000 claims abstract description 16
- 239000008267 milk Substances 0.000 claims abstract description 16
- 210000004080 milk Anatomy 0.000 claims abstract description 16
- 241000283707 Capra Species 0.000 claims abstract description 15
- 235000013305 food Nutrition 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 19
- CETWDUZRCINIHU-UHFFFAOYSA-N 2-heptanol Chemical compound CCCCCC(C)O CETWDUZRCINIHU-UHFFFAOYSA-N 0.000 claims description 6
- NGDNVOAEIVQRFH-UHFFFAOYSA-N 2-nonanol Chemical compound CCCCCCCC(C)O NGDNVOAEIVQRFH-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 3
- VSMOENVRRABVKN-UHFFFAOYSA-N oct-1-en-3-ol Chemical compound CCCCCC(O)C=C VSMOENVRRABVKN-UHFFFAOYSA-N 0.000 claims 2
- VSMOENVRRABVKN-MRVPVSSYSA-N 1-Octen-3-ol Natural products CCCCC[C@H](O)C=C VSMOENVRRABVKN-MRVPVSSYSA-N 0.000 claims 1
- YDXQPTHHAPCTPP-UHFFFAOYSA-N 3-Octen-1-ol Natural products CCCCC=CCCO YDXQPTHHAPCTPP-UHFFFAOYSA-N 0.000 claims 1
- RGXWDWUGBIJHDO-UHFFFAOYSA-N ethyl decanoate Chemical compound CCCCCCCCCC(=O)OCC RGXWDWUGBIJHDO-UHFFFAOYSA-N 0.000 abstract description 32
- NUKZAGXMHTUAFE-UHFFFAOYSA-N methyl hexanoate Chemical compound CCCCCC(=O)OC NUKZAGXMHTUAFE-UHFFFAOYSA-N 0.000 abstract description 25
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract description 20
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 abstract description 20
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract description 20
- VKCYHJWLYTUGCC-UHFFFAOYSA-N nonan-2-one Chemical compound CCCCCCCC(C)=O VKCYHJWLYTUGCC-UHFFFAOYSA-N 0.000 abstract description 16
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 abstract description 13
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 abstract description 8
- 235000014059 processed cheese Nutrition 0.000 description 6
- -1 2-n0nanone Chemical compound 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000008447 perception Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical class CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 235000015067 sauces Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 101000635799 Homo sapiens Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Proteins 0.000 description 1
- 102220547770 Inducible T-cell costimulator_A23L_mutation Human genes 0.000 description 1
- 108091034117 Oligonucleotide Proteins 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 102100030852 Run domain Beclin-1-interacting and cysteine-rich domain-containing protein Human genes 0.000 description 1
- 235000019631 acid taste sensations Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000020251 goat milk Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019643 salty taste Nutrition 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/206—Dairy flavours
Definitions
- This invention relates to synthetic flavouring compositions and, more particularly, to a composition for providing food products with a flavour of the goats milk cheese type.
- compositions generally contain substances whose presence in the cheese aroma has been detected by analysis. These substances include certain methyl ketones such as Z-pentanone, 2-heptanone, 2-nonanone, certain fatty acids such as caprylic acid or butyric acid, certain lactones, and also phenol.
- these compositions generally have only a very vague aromatic note, in other words a note which is scarcely representative of the particular aroma of a certain type of cheese, and contain a large number of ingredients.
- the present invention relates to a flavouring of simple chemical composition whose aroma reproduces that of a cheese of the goats milk type particularly well. More particularly, the invention relates to a flavouring composition for providing food products with a cheese flavour of the goats milk type, containing at least the following substances whose respective quantities are expressed in parts by weight:
- hutanone 30 to 40 pentanone the butanone representing at least 30 and at most 50 7c by weight of these two ketones,
- the flavouring composition according to the invention can be incorporated in various food-grade products such as sauces, fatty emulsions such as mayonnaise, spreads or processed cheese. It can be incorporated directly in food-grade products containing fats in cases where these products are in liquid or pasty form either during their processing or in their final form.
- This composition can also be added in the form of a solution in an edible oil or, where thefood-grade product in question is low in fats, in the form of an aqueous emulsion which may, for example, be sprayed onto a powder-form product.
- composition according to the invention which has a high flavouring power, can be added to the food products which it is desired to flavour in quantities of from 50 to 500 ppm (by weight), according to the re quired flavouring intensity.
- the composition according to the invention is preferably added in quantities of from 200 to 400 ppm.
- the food product ultimately obtained has a perfectly stable cheese flavour of the goats milk cheese type whose nature and intensity persist for as long as the food product thus flavoured retains its own characteristics
- the n-heptanal, the methyl caproate and the ethyl caprate, substances whose presence in the aroma of cheese had not previously been detected, have proved to be constituents with a decisive role in the composition according to the invention, because organoleptic tests, which are described in detail hereinafter, have shown that a composition only containing known substances of the type normally used for preparing flavourings having a cheese aroma, namely butanone, 2- pentanone, Z-heptanone, 2-nonanone and caproic acid, only provides food products, such as a neutral tasting processesd cheese, with a cheese flavour of vague, indefinite character.
- this composition contains, in combination with the known substances, nheptanal, methyl caproate and ethyl caprate, it is able to provide food products with a highly specific flavour similar to that of a cheese of the goats milk type, especially if the quantity of ethyl caprate used represents at least 20 and at most 50 of the two esters methyl caproate and ethyl caprate, irrespective of the quantity of n-heptanal used (within the limits specified above).
- the composition according to the invention may contain, in addition to butanone, Z-pentanone, Z-heptanone and 2-nonanone, other methyl ketones such as Z-undecanone in quantities by weight up to 1.5 of the total weight of the composition.
- the composition according to the invention may also contain l-octen-3-ol in quantities by weight of up to 2 7: of the total weight, and Z-heptanol and/or 2-nonanol again in quantities by weight of up to 2
- the composition contains these two alcohols in similar quantities.
- composition according to the invention may be prepared very easily by mixing first of all the butanonc. Z-pentanone, Z-heptanone, 2-nonanone and the caproic acid and then the n-heptanol, methyl caproate and ethyl caprate in the proportions specified above.
- the mixing and dissolving temperature providing it is compatible with the stability of the constituents, is not a critical parameter in these operations.
- Mixing and dissolution can be carried out either at ambient temperature or at a slightly higher temperature, for example of the order of 50 to 60C, optionally with stirring in order to accelerate homogenization of the mixture.
- the caproic acid is added last of all.
- the mixture is preferably left standing for a few hours, for example for 10 to 12 hours, before being incorporated in the food product to be flavoured.
- the composition obtained is in the form of a colourless, oily liquid which is substantially insoluble in water and soluble in fats. It can be stored at ambient temperature for prolonged periods of the order of 12 months without losing its flavouring power.
- the perception threshold of the composition according to the invention i.e. the quantity by weight of the composition expressed in relation to the quantity of food product to which it is added, beyond which a cheese aroma of the goats milk cheese type is detected in the food product, was determined with samples of neutral tasting processed cheese containing predetermined quantities of the flavouring composition. These samples were presented to a jury of lO trained tasters in a tasting session of the triangular type in which each sample is presented to each of the tasters with two other samples, two of the three samples being similar.
- the samples were submitted to the jury of tasters.
- the perception threshold of a given composition was defined as the content by weight in the sample of flavouring composition, expressed in ppm, beyond which 8 out of 10 of the tasters resolved the triangle and detected an aroma of goat's milk cheese in the sample.
- the perception threshold thus defined and measured proved to be of the order of 50 ppm for each of the compositions tested.
- This cheese is then submitted to the jury of tasters. 8 out of these tasters considered the cheese to have a flavour characteristic of very ripe goats milk cheese.
- composition EXAMPLE 2 A flavouring composition containing the following substances is prepared:
- this composition When added to molten cheese of the kind described above in a proportion of 350 ppm, this composition provides the cheese with an aroma typical of strong or mature goats milk cheese.
- this composition When added to the processed cheese described above in a proportion of 200 ppm, this composition butanone to pentanone the butanone representing at least 30 and at most by weight of these two ketones,
- 2-heptanone 2-nonanonc caproic acid 40 to distinguished by the fact that it contains, in combination with the aforementioned substances, from 5 to 9 parts by weight of n-heptanal and from 2 to 7 parts by weight of methyl caproate and ethyl caprate, the ethyl caprate representing at least 20 and at most 50 7: by weight of the two esters.
- composition of claim 1 for providing food products with a'goats milk cheese flavour containing additionally an effective amount up to 2 7cby weight of l-octen-3-ol and/or up to 2 by weight of 2- heptanol and/or 2-nonanol.
- Col. 1, line 36 change "l-heptanone" to read --2-heptanone-.
Landscapes
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Dairy Products (AREA)
- Seasonings (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1488573A CH578842A5 (enrdf_load_stackoverflow) | 1973-10-22 | 1973-10-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3911158A true US3911158A (en) | 1975-10-07 |
Family
ID=4404563
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US514400A Expired - Lifetime US3911158A (en) | 1973-10-22 | 1974-10-15 | Cheese flavoring |
Country Status (9)
Country | Link |
---|---|
US (1) | US3911158A (enrdf_load_stackoverflow) |
AR (1) | AR201885A1 (enrdf_load_stackoverflow) |
BE (1) | BE819693A (enrdf_load_stackoverflow) |
CA (1) | CA1014002A (enrdf_load_stackoverflow) |
CH (1) | CH578842A5 (enrdf_load_stackoverflow) |
DE (1) | DE2446330C3 (enrdf_load_stackoverflow) |
FR (1) | FR2247986B1 (enrdf_load_stackoverflow) |
GB (1) | GB1426410A (enrdf_load_stackoverflow) |
IT (1) | IT1032091B (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1166650A3 (de) * | 2000-06-07 | 2003-09-17 | Symrise GmbH & Co. KG | Käsearoma |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3034902A (en) * | 1960-10-19 | 1962-05-15 | Pfizer & Co C | Blue cheese flavoring composition |
US3635737A (en) * | 1969-04-25 | 1972-01-18 | Allen Baron | Particulate cheeselike compositions |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU62952A1 (enrdf_load_stackoverflow) * | 1971-04-08 | 1972-12-11 | ||
LU65039A1 (enrdf_load_stackoverflow) * | 1972-03-24 | 1973-09-26 |
-
1973
- 1973-10-22 CH CH1488573A patent/CH578842A5/xx not_active IP Right Cessation
-
1974
- 1974-08-21 CA CA207,614A patent/CA1014002A/fr not_active Expired
- 1974-09-09 BE BE148338A patent/BE819693A/xx not_active IP Right Cessation
- 1974-09-19 AR AR255663A patent/AR201885A1/es active
- 1974-09-24 FR FR7432189A patent/FR2247986B1/fr not_active Expired
- 1974-09-25 GB GB4166474A patent/GB1426410A/en not_active Expired
- 1974-09-27 IT IT53230/74A patent/IT1032091B/it active
- 1974-09-27 DE DE2446330A patent/DE2446330C3/de not_active Expired
- 1974-10-15 US US514400A patent/US3911158A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3034902A (en) * | 1960-10-19 | 1962-05-15 | Pfizer & Co C | Blue cheese flavoring composition |
US3635737A (en) * | 1969-04-25 | 1972-01-18 | Allen Baron | Particulate cheeselike compositions |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1166650A3 (de) * | 2000-06-07 | 2003-09-17 | Symrise GmbH & Co. KG | Käsearoma |
Also Published As
Publication number | Publication date |
---|---|
DE2446330C3 (de) | 1982-05-19 |
DE2446330A1 (de) | 1975-04-30 |
CH578842A5 (enrdf_load_stackoverflow) | 1976-08-31 |
FR2247986B1 (enrdf_load_stackoverflow) | 1978-11-03 |
AR201885A1 (es) | 1975-04-24 |
BE819693A (fr) | 1975-03-10 |
GB1426410A (en) | 1976-02-25 |
CA1014002A (fr) | 1977-07-19 |
IT1032091B (it) | 1979-05-30 |
FR2247986A1 (enrdf_load_stackoverflow) | 1975-05-16 |
DE2446330B2 (de) | 1976-10-28 |
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