US3127901A - Absorbing composition for tobacco smoke - Google Patents
Absorbing composition for tobacco smoke Download PDFInfo
- Publication number
- US3127901A US3127901A US102916A US10291661A US3127901A US 3127901 A US3127901 A US 3127901A US 102916 A US102916 A US 102916A US 10291661 A US10291661 A US 10291661A US 3127901 A US3127901 A US 3127901A
- Authority
- US
- United States
- Prior art keywords
- amine
- amines
- composition
- hydroxide
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 32
- 241000208125 Nicotiana Species 0.000 title description 8
- 235000002637 Nicotiana tabacum Nutrition 0.000 title description 8
- 239000000779 smoke Substances 0.000 title description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 23
- 150000003839 salts Chemical class 0.000 claims description 15
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 229960004887 ferric hydroxide Drugs 0.000 claims description 10
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 claims description 10
- 239000002250 absorbent Substances 0.000 claims description 9
- 230000002745 absorbent Effects 0.000 claims description 9
- 150000003973 alkyl amines Chemical class 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 8
- 235000019504 cigarettes Nutrition 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 8
- 230000001473 noxious effect Effects 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 description 40
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 5
- -1 hydroxy alkyl-amine Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 3
- 230000001476 alcoholic effect Effects 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 description 3
- 150000004692 metal hydroxides Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- QCOGKXLOEWLIDC-UHFFFAOYSA-N N-methylbutylamine Chemical compound CCCCNC QCOGKXLOEWLIDC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- XGGLLRJQCZROSE-UHFFFAOYSA-K ammonium iron(iii) sulfate Chemical compound [NH4+].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O XGGLLRJQCZROSE-UHFFFAOYSA-K 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 150000002505 iron Chemical class 0.000 description 2
- BMFVGAAISNGQNM-UHFFFAOYSA-N isopentylamine Chemical compound CC(C)CCN BMFVGAAISNGQNM-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- YOANQJMZPGJXJC-UHFFFAOYSA-N 1-aminononan-2-ol Chemical compound CCCCCCCC(O)CN YOANQJMZPGJXJC-UHFFFAOYSA-N 0.000 description 1
- MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 description 1
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical class CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
- 235000014548 Rubus moluccanus Nutrition 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940032296 ferric chloride Drugs 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- KAJZYANLDWUIES-UHFFFAOYSA-N heptadecan-1-amine Chemical class CCCCCCCCCCCCCCCCCN KAJZYANLDWUIES-UHFFFAOYSA-N 0.000 description 1
- QRYZBBMAFLIWPX-UHFFFAOYSA-N heptane-4,4-diamine Chemical class NC(CCC)(CCC)N QRYZBBMAFLIWPX-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- GNVRJGIVDSQCOP-UHFFFAOYSA-N n-ethyl-n-methylethanamine Chemical compound CCN(C)CC GNVRJGIVDSQCOP-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical class CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- GPCKFIWBUTWTDH-UHFFFAOYSA-N pentane-3,3-diamine Chemical class CCC(N)(N)CC GPCKFIWBUTWTDH-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
Definitions
- This invention relates to filters for absorbing noxious tobacco combustion products, said filters being either incorporated in cigarettes or separately suplied as an interchangeable cartridge in a suitable cigarette holder.
- the instant absorbent is of decidedly improved efficiency over preparations known heretofore.
- the absorbent comprises an alkyl-amine or a hydroxy alkyl-amine of a boiling point not lower than 60 C., preferably not lower than 90 C., a double salt of said amine with an inorganic salt (chloride, sulphate, alum) of a metal of the iron group, such as manganese, chromium, nickel or iron and a hydroxide of said metal in a colloidal state dispersed in the amine.
- Said components are thoroughly intermixed, the composition being employed in practice in a liquid carrier preferably selected from the group consisting of methyl alcohol, ethyl alcohol, sulphuric ether, methyl acetate and ethyl acetate.
- a liquid carrier preferably selected from the group consisting of methyl alcohol, ethyl alcohol, sulphuric ether, methyl acetate and ethyl acetate.
- other alcohols, ethers and esters can be employed by way of substitutes.
- the amines according to this invention can be normally in a liquid or solid condition.
- Aromatic and heterocyclic, amines, colored amines or odorous amines or amines generally of organoleptic characters which make them unsuitable for the purposes of this invention shall not be used.
- monoamines amyl amines, pentyl amines, hexyl. amines, methyl-diethylamine and the series ranging between octylamines and heptadecylamines, whether of a saturated, primary or secondary type are more particularly suitable.
- diamines propylene diamines, diamino pentanes, hexamethylendiamine, diamino-heptanes, -octanes, -nonanes and -decanes can usefully be employed.
- hydroxy alkyl-amines especially Water-soluble amines, such as ethanolamine, methylethanolamine, ethylethanolamine, heptylethanolamine, isopropylamines, isobutylamines and isoarnylamines can be usefully employed.
- ethanolamines also diamines and triamines can usefully be employed.
- the composition is hygroscopic in that it easily absorbs moisture from its environment. This circumstance is of basic importance for two reasons. Firstly, the absorbed moisture keeps the metal hydroxide colloidally dispersed in the amine, which is essential for the composition to fully develop its absorbing properties when incorporated by a cigarette tip or the like. Secondly, this moisture absorption should be taken care of in practice when the composition is employed for impregnating filters incorporated by cigarettes; generally, when the filter contains over about 20% composition, the absorbed moisture travels to the paper and tobacco and objectionably affects draught through the filter tip. Consequently, the proportion of composition retained by the filter should by no means exceed about 18-20%. On the other hand, this proportion is largely sufficient for practical purposes for, as was experimentally ascertained, proportions of about 1% already exhibit a certain activity, while proportions between about 10% and 15% are sufficient for practical purposes.
- the composition according to this invention seems to be simply a mixture of the various ingredients, which can be prepared by intermixing the amine, double salt and colloidal hydroxide, this was not found to be true. More particularly, the composition successfully acts to purify and absorb only when the double salt and colloidal hydroxide are generated in situ through suitable chemical reactions. Therefore, one feature of this invention resides in the method of preparing the absorbing composition described above, comprising reacting at elevated temperatures said inorganic salt with excess amine in the presence of water to form said double salt, interrupting the reaction by adding a substantial volume of the liquid carrier (alcohol, ether, ester), continuing heating of the reagents long enough to form the metal hydroxide, and removing the aqueous phase.
- the liquid carrier alcohol, ether, ester
- the remaining phase containing the amine, double salt and colloidal metal hydroxide in said carrier is employed for impregnating a given support of a porous character adapted to act as a filter.
- the nature of the support does not appear critical, so that all materials known for the purpose can be employed at will, such as cellulosic materials generally, compressed vegetable, mineral or synthetic fibres which may be scoured or otherwise pretreated to enhance their absorbing power, natural or synthetic sponges, various conglomerates etc.
- a filter paper web can be passed through a bath comprising the instant composition diluted with methyl alcohol, whereupon the excess alcohol is evaporated in vacuum leaving the web ready for preparing filters therefrom. Impregnation can be effected by means of a concentrated bath, or repeated several times till the desired composition content has been absorbed by the support.
- Example 1 100 grams of a mixture by equal parts of methylbutyl amine, isoamylamine or vinylamine are heated at about 100 C. with a solution of 12.5 grams ferric-chloride in 12.5 grams water in a closed container equipped with a reflux cooler. After half-an-hour 900 grams ethyl alcohol are added, heating being continued halfan-hour longer. The mixture is cooled, poured into a separating funnel, the aqueous phase being decanted from the alcoholic phase.
- the analysis shows grams starting amines, 4 grams double sulphate of iron and the amine and 3 grams colloidal ferric-hydroxide.
- the alcoholic phase is utilised for impregnating a porous support as described above, alcohol being subsequently recovered in vacuum.
- Example 2 grams triethanolamine (containing about 20% monoand di-ethanolamine) is heated at about 100 C. during one hour with 25 grams ferric-ammonium alum in a container equipped with a reflux cooler. The mixture is diluted with 900 grams ethyl alcohol and further heated during half-an-hour, thereupon cooled, the aqueous phase being decanted; the alcoholic phase contains 82 grams starting amines, 6 grams double sulphate of iron and the amine and 5 grams colloidal ferric-hydroxide.
- Example 3 Equal parts of glycerodiamine and hexamethylendiamine are heated at about 100 C. with a concentrated ferrous-sulphate solution by a ratio by weight of 20% ferrous salt to 80% amines. After about 3 hours 900 grams sulphuric ether are added, heating being continued during a further hour. Finally, the temperature is lowered beneath C., the mixture is filtered and the filtrate is conveyed over a dehydrating substance in order to absorb the water residues. The ethereal phase is found to contain 67 grams starting amines, grams double sulphate of iron and the amine and 3 grams colloidal ferric hydroxide.
- Absorbent composition for noxious tobacco-combustion products comprising an amine selected from the group consisting of alkyl-amines and hydroxyalkylamines of a boiling point of a least 60 C., a double salt of said amine and iron selected from the group consisting of sulfates and chlorides, and ferric-hydroxide colloidally dispersed in the amine.
- Absorbent composition for noxious tobacco-combustion products comprising 80 to 93% by weight of an amine selected from the group consisting of alkyl-amines and hydroxyalkyl-amines of a boiling point of at least 60 C., 4 to 12% of a double salt of said amine and iron selected from the group consisting of sulfates and chlorides, and 3 to 9% of ferric-hydroxide colloidally dispersed in the amine.
- a cigarette tip incorporating a filtering material comprising a porous support having deposited thereon at least 1% by weight of an absorbent composition for noxious combustion products of tobacco, said composition comprising an amine selected from the group consisting of alkylamines and hydroxyalkyl-amines having a boiling point of at least 60 C., a double salt of said amine and iron selected from the group consisting of sulfates and chlorides, and ferric-hydroxide colloidally dispersed in the amine.
- a cigarette tip incorporating a filtering material comprising a porous support having deposited thereon at least 1% by Weight of an absorbent composition for noxious combustion products of tobacco, said composition comprising 80 to 93% of an amine selected from the group consisting of alkyl-amines and hydroxyalkyl-amines having a boiling point of at least 60 C., 4 to 12% of a double sulfate of said amine and iron, and 3 to 9% of ferric-hydroxide colloidally dispersed in the amine.
- a method of preparing an absorbent composition for noxious combustion products of tobacco comprising heating an inorganic iron salt selected from the group consisting of sulfates, chlorides and ferri-ammonium sulfate in the presence of Water, with an excess of an amine selected from the group consisting of alkylamines and hydroxyalkyl-amines having a boiling point of at least C.
- a method of preparing an absorbent composition for noxious combustion products of tobacco comprising heating ferri-ammonium alum in an excess of an amine selected from the group consisting of alkyl-amines and hydroxyalkyl-amines having a boiling point of at least 60 C.
- a liquid carrier selected from the group consisting of methyl alcohol, ethyl alcohol, sulfuric ether, methyl acetate and ethyl acetate, in order to interrupt the formation of said double salt; heating the reaction mass and the added carrier to form colloidal ferric-hydroxide in the mass, and evaporating the carrier.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1037260 | 1960-07-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3127901A true US3127901A (en) | 1964-04-07 |
Family
ID=11134068
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US102916A Expired - Lifetime US3127901A (en) | 1960-07-22 | 1961-04-14 | Absorbing composition for tobacco smoke |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3127901A (cg-RX-API-DMAC7.html) |
| BE (1) | BE606025A (cg-RX-API-DMAC7.html) |
| GB (1) | GB914355A (cg-RX-API-DMAC7.html) |
| NL (1) | NL267205A (cg-RX-API-DMAC7.html) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3410282A (en) * | 1967-03-13 | 1968-11-12 | Eastman Kodak Co | Filter medium for removing hydrogen cyanide from tobacco smoke |
| US3426765A (en) * | 1967-02-21 | 1969-02-11 | Celanese Corp | Tobacco smoke filters |
| US3429318A (en) * | 1967-09-07 | 1969-02-25 | Eastman Kodak Co | Selective filter medium |
| US3658070A (en) * | 1970-10-01 | 1972-04-25 | Nicholas R Diluzio | Tobacco smoke filters |
| US4149549A (en) * | 1976-05-17 | 1979-04-17 | Montclair Research Corporation | Cigarette and filter |
| US6769437B2 (en) | 2002-04-08 | 2004-08-03 | Philip Morris Incorporated | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
| US8701681B2 (en) | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US757514A (en) * | 1903-07-30 | 1904-04-19 | Hermann Otto Wendt | Process of providing cigars with smoke-improving portions at the pointed ends. |
| US1859379A (en) * | 1930-03-15 | 1932-05-24 | American Tobacco Co | Process of treating tobacco |
| US2815760A (en) * | 1951-12-24 | 1957-12-10 | Schreus Hans Theo | Tobacco smoke filter |
| US2832351A (en) * | 1950-06-26 | 1958-04-29 | Verdurin Company | Method of treating tobacco smoke |
| US2881772A (en) * | 1956-02-29 | 1959-04-14 | Eastman Kodak Co | Tobacco smoke filters |
| US2968306A (en) * | 1956-02-29 | 1961-01-17 | Eastman Kodak Co | Tobacco smoke filter capable of selective removal of aldehydes |
-
0
- NL NL267205D patent/NL267205A/xx unknown
-
1961
- 1961-04-14 US US102916A patent/US3127901A/en not_active Expired - Lifetime
- 1961-07-07 GB GB24688/61A patent/GB914355A/en not_active Expired
- 1961-07-12 BE BE606025A patent/BE606025A/fr unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US757514A (en) * | 1903-07-30 | 1904-04-19 | Hermann Otto Wendt | Process of providing cigars with smoke-improving portions at the pointed ends. |
| US1859379A (en) * | 1930-03-15 | 1932-05-24 | American Tobacco Co | Process of treating tobacco |
| US2832351A (en) * | 1950-06-26 | 1958-04-29 | Verdurin Company | Method of treating tobacco smoke |
| US2815760A (en) * | 1951-12-24 | 1957-12-10 | Schreus Hans Theo | Tobacco smoke filter |
| US2881772A (en) * | 1956-02-29 | 1959-04-14 | Eastman Kodak Co | Tobacco smoke filters |
| US2968306A (en) * | 1956-02-29 | 1961-01-17 | Eastman Kodak Co | Tobacco smoke filter capable of selective removal of aldehydes |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3426765A (en) * | 1967-02-21 | 1969-02-11 | Celanese Corp | Tobacco smoke filters |
| US3410282A (en) * | 1967-03-13 | 1968-11-12 | Eastman Kodak Co | Filter medium for removing hydrogen cyanide from tobacco smoke |
| US3429318A (en) * | 1967-09-07 | 1969-02-25 | Eastman Kodak Co | Selective filter medium |
| US3658070A (en) * | 1970-10-01 | 1972-04-25 | Nicholas R Diluzio | Tobacco smoke filters |
| US4149549A (en) * | 1976-05-17 | 1979-04-17 | Montclair Research Corporation | Cigarette and filter |
| US6769437B2 (en) | 2002-04-08 | 2004-08-03 | Philip Morris Incorporated | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
| US20040159328A1 (en) * | 2002-04-08 | 2004-08-19 | Mohammad Hajaligol | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
| US7228862B2 (en) | 2002-04-08 | 2007-06-12 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette |
| US8701681B2 (en) | 2003-10-27 | 2014-04-22 | Philip Morris Usa Inc. | Use of oxyhydroxide compounds in cigarette paper for reducing carbon monoxide in the mainstream smoke of a cigarette |
Also Published As
| Publication number | Publication date |
|---|---|
| GB914355A (en) | 1963-01-02 |
| BE606025A (fr) | 1961-11-03 |
| NL267205A (cg-RX-API-DMAC7.html) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3127901A (en) | Absorbing composition for tobacco smoke | |
| US3742059A (en) | Color-stabilized alkanolamines | |
| DE2320222A1 (de) | Verfahren zur aktivierung von isomerisierungskatalysatoren | |
| GB534900A (en) | Improvements in or relating to explosives | |
| US757514A (en) | Process of providing cigars with smoke-improving portions at the pointed ends. | |
| DE846276C (de) | Kernbindemittel | |
| US2922703A (en) | Incendiary fuels | |
| DE134222C (cg-RX-API-DMAC7.html) | ||
| Wilson | Soda lime as an absorbent for industrial purposes | |
| DE556608C (de) | Verfahren zur Herstellung von Gasabsorptionsmassen fuer Atemfilter | |
| DE513654C (de) | Verfahren zur Herstellung von Sprengstoffen unter Verwendung von Kalksalpeter | |
| DE882705C (de) | Verfahren zur Herstellung von neuen Amidderivaten | |
| AT284147B (de) | Verfahren zur Herstellung der neuen Verbindung 8{2-[N-(α-Methylphenäthyl)-methylamin]äthylamin}coffein | |
| US2692203A (en) | Softener and flame-resistant coating composition, method of its application to cellulosic materials and the article produced thereby | |
| US2140447A (en) | Explosive | |
| US2704243A (en) | Method of defoliation | |
| DE497212C (de) | Verfahren zur Herstellung sprengsalpeteraehnlicher Gemische | |
| RU1775667C (ru) | Состав дл приготовлени индикаторной бумаги дл определени нитратов | |
| SU817122A1 (ru) | Фильтровальный волокнистый материал | |
| US414351A (en) | Joseph warren wattles | |
| DE598531C (de) | Verfahren zum Herstellen von Sprengstoffen niedriger Ladedichte | |
| DE935164C (de) | Raeuchermittel zur Vernichtung schaedlicher Organismen | |
| DE965455C (de) | Verfahren zur Herstellung eines Kartons zur Erzeugung insekticiden Rauches | |
| AT145377B (de) | Verfahren zum Konservieren vorgetrockneter Früchte. | |
| DE511304C (de) | Fuellmasse fuer Acetylenflaschen |