US2181884A - Process of carroting - Google Patents

Process of carroting Download PDF

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Publication number
US2181884A
US2181884A US167856A US16785637A US2181884A US 2181884 A US2181884 A US 2181884A US 167856 A US167856 A US 167856A US 16785637 A US16785637 A US 16785637A US 2181884 A US2181884 A US 2181884A
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US
United States
Prior art keywords
acid
carroting
fur
hair
fibres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US167856A
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English (en)
Inventor
Giuliano Anthony Philip
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Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE436039D priority Critical patent/BE436039A/xx
Application filed by Individual filed Critical Individual
Priority to US167856A priority patent/US2181884A/en
Priority to GB23393/39A priority patent/GB524736A/en
Priority to FR859577D priority patent/FR859577A/fr
Application granted granted Critical
Publication of US2181884A publication Critical patent/US2181884A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01C—CHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C3/00—Treatment of animal material, e.g. chemical scouring of wool
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/14—Wool
    • D06P3/20—Wool using mordant dyes using metallisable dyes

Definitions

  • This invention relates to the treating of animal fibres and the like, such as fur or wool, and pertains particularly to the process of carroting the same, and the present application constitutes a-continuation in part of application Serial Number 34,299, filed August 1, 1935.
  • the present method used almost exclusively for the carroting of fur involves the use of the mercury salt, mercury nitrate.
  • This salt in solution is applied with a brush or by the use of a carroting machine to the fur or fur fibre while intact with the skin and these skins are dried eitherby heat or at normal'room temperature with a resultant volatilization of a certain amount of mercury.
  • a great health hazard exists for those persons who have to carry out the various steps or operations necessary in the felting of the fibreand the subsequent treatment of the same.
  • the present invention has for its primary object to provide a process for the carroting of animal fur fibre and the like, whereby'the same will be afiected in the same way as by the use of mercury nitrate solution so that the desired felting properties are imparted thereto, without using poisonous substances or substances which will have a detrimental effect upon persons required to handle or work with the felt or upon users of the felt material after the same is made up into hats or other bodies.
  • Another object of the invention is to impart to the fur and hair fibre the same properties that are characteristic of the "mercury carrot without the use of mercury nitrate.
  • a still further object of the invention is to provide a process which in addition to imparting the desired felting qualities to the fur, hair fibre or wool, will not cause the same to deteriorate after a long period of time; may be used upon white fur without causing the same to discolor; will facilitate the quick wetting down and fast shrinking of the fur and hair fibre in the starting of felting as well as in the sizing; will cause the fur and hair fibre'to take an even color without showing an underground or under cast when placed in a dye bath, and will cause the fur and hair fibre to form a stronger, tighter, and more even f lt than can be manufactured under present processes.
  • the protein coagulants which Ii have discovered to be entirely effective for carroting purposes and which avoid the objection to theuse of mercury nitrate and other mercury solutions, are phosphotuhgstic acid and phosphomolybdic acid, soluble salts and esters of the same, and derivatives thereof such as chloro-phosphotungstic and chloro phosphomolybdic acids, aceto-phosphotungstic and aceto-phosphomolybdie acids.
  • These products possess an enhanced felting action and are without poisonous properties and if left on fur or like fibre show no particular deteriorating action or any objectionable effect upon the health of the user. They also exceed mercuric nitrate in protein coagulating power.
  • the coagulants may be used either alone or in combination with one another, or in conjunction with hydrolytic agents such as inorganic acids having a pH value lower than 3.0 or a combination of organic acids and inorganic acids in which the pH of the mixture is lower than 3.0 and such a combination may be made up with such acids as citric acid, oxalic acid, tartaric acid, nitric acid, sulphuric acid, hydrochloric acid, hydrobromic acid and perchloric acid and these may be used with or without hydrogen peroxide or equivalent agents.
  • the method involves a simultaneous solubilization and hydrolysis of fur fibres with a protein coagulation action.
  • the h joint and paradoxical action sharpens and deunder the conditions of the carroting operation, pH values lower than 3.0 or higher than 13.0. This includes the acids named for the lower pH .range and the hydroxides of sodium or potasslum in the upper.
  • nitric acid 40 Baum or the same solution may be made substituting an equivalent amount of phosphomolybdic acid.
  • hydrochloric or sulphuric acids or some combination of the same may be substituted or the nitric acid may be partially replaced by some combination of the same, so long as the pH of the mixture is lower than 3.0.
  • HCl or H2804 may be used, with or without H202.
  • I may take 40 volumes of water in which is dissolved 3 ounces of sodium or potassium hydroxide, 1 ounce of either the tungsto or molybdo-phosphoric acid. and 1 fluid hum of hydrogen peroxide.
  • the deleterious effect of the caustic alkali maybe reduced or inhibited by the addition of ,1 fiuid ounces ofglycerine or diethylene glycol without affecting adversely the carroting action of the alkali.
  • the phosphotungstate ester of oleicacid may be given.
  • This ester is both Water and acid soluble and it may be substituted for the phosphotungstic acid given in the example set forth,
  • the phosphotungstate ester of oleic acid possesses the additional virtue of being a penetrating agent and in consequence P assures more rapid and complete penetration of an illustration, when lauryl alcohol, an example of an aliphatic alcohol, is treated with concentrated phosphoor phosphochloroor phosphoacetotungstic or molybdic acids, an ester results which possesses the same carroting potency as the unesterified acids. Those of the esters which are insoluble may be rendered soluble by esterifying in the presence of 98% sulphuric acid.
  • iIclhe sulpho ester of oleochlorphosphotungstic ac Aromatic alcohols, aldehydes or halides react with phospho derivatives in much the same way as the lauryl alcohol. The solubilization of the resultant esters frequently requires or necessitates a subsequent sulfonation operation. This may be accomplished by conventional sulfonation procedures.
  • tungsto-aceto-phosphoric acids in an amount suflicient to carrot the fibres, and a hydrolytic agent giving to the solution a pH value outside the limits 3.0 and 13.0.
  • the process of carroting animal hair for felt making which comprises treating the same with a solution containing phosphotungstic acid in an amount sufficient to carrot the hair, and a hydrolytic agent selected from the group consisting of nitric acid, perchloric acid, hydrochloric acid, sulphuric acid and hydrobromic acid, the hydrolytic agent being in an amount sumcient to yield in the solution a pH lower than 3.0.
  • the process of carroting animal hair for felt making which comprises treating the hair with the solution contaming phosphomolybdic acid in an amount sufflcient to carrot the hair, and nitric acid in an amount suflicient to yield in the solution a pH lower than 3.0.
  • the process of carroting animal hair for felt making which comprises treating the hair with a solution containing phosphomolybdic acid in an amount sufllcient to carrot the hair, nitric acid, and hydrogen peroxide, the nitric acid being in an amount sufilcient to yield in the solution a pH lower than 3.0.
  • the process of carroting animal hair for felt making which comprises treating the hair with, a solution containing a phosphotungstic acid in an amount suflicient to carrot the hair and nitric acid in an amount to yield in the solution a pH lower than 3.0.
  • the process of carroting animal hair to felt making which comprises treating the hair with a solution containing phosphotungstic acid in an amount suificient to carrot the hair, nitric acid, and hydrogen peroxide, the nitric acid being in an amount suflicient to yield in the solution a pH lower than 3.0.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Animal Husbandry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
US167856A 1937-10-07 1937-10-07 Process of carroting Expired - Lifetime US2181884A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE436039D BE436039A (enrdf_load_stackoverflow) 1937-10-07
US167856A US2181884A (en) 1937-10-07 1937-10-07 Process of carroting
GB23393/39A GB524736A (en) 1937-10-07 1939-08-14 Improvements in and relating to process of carroting
FR859577D FR859577A (fr) 1937-10-07 1939-08-29 Procédé de secrétage des fibres animales telles que les poils des peaux

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US167856A US2181884A (en) 1937-10-07 1937-10-07 Process of carroting
GB23393/39A GB524736A (en) 1937-10-07 1939-08-14 Improvements in and relating to process of carroting

Publications (1)

Publication Number Publication Date
US2181884A true US2181884A (en) 1939-12-05

Family

ID=26256485

Family Applications (1)

Application Number Title Priority Date Filing Date
US167856A Expired - Lifetime US2181884A (en) 1937-10-07 1937-10-07 Process of carroting

Country Status (4)

Country Link
US (1) US2181884A (enrdf_load_stackoverflow)
BE (1) BE436039A (enrdf_load_stackoverflow)
FR (1) FR859577A (enrdf_load_stackoverflow)
GB (1) GB524736A (enrdf_load_stackoverflow)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2582086A (en) * 1949-12-23 1952-01-08 Frank H Lee Company Composition for carroting fur and the like
US2944939A (en) * 1957-02-06 1960-07-12 Merck & Co Inc Water-insoluble molybdenum salts of neomycin and process of using same in the purification of neomycin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2582086A (en) * 1949-12-23 1952-01-08 Frank H Lee Company Composition for carroting fur and the like
US2944939A (en) * 1957-02-06 1960-07-12 Merck & Co Inc Water-insoluble molybdenum salts of neomycin and process of using same in the purification of neomycin

Also Published As

Publication number Publication date
GB524736A (en) 1940-08-13
BE436039A (enrdf_load_stackoverflow)
FR859577A (fr) 1940-12-21

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