US20170015478A1 - Packaging - Google Patents

Packaging Download PDF

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Publication number
US20170015478A1
US20170015478A1 US15/264,916 US201615264916A US2017015478A1 US 20170015478 A1 US20170015478 A1 US 20170015478A1 US 201615264916 A US201615264916 A US 201615264916A US 2017015478 A1 US2017015478 A1 US 2017015478A1
Authority
US
United States
Prior art keywords
wrapper
polymeric film
type packaging
packaging
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US15/264,916
Other languages
English (en)
Inventor
Ingrid Sebald
Werner Schmidt
Felix Grimm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Loparex Germany GmbH and Co KG
Original Assignee
Infiana Germany GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102014010691.8A external-priority patent/DE102014010691A1/de
Priority claimed from DE102014010987.9A external-priority patent/DE102014010987A1/de
Application filed by Infiana Germany GmbH and Co KG filed Critical Infiana Germany GmbH and Co KG
Assigned to INFIANA GERMANY GMBH &CO. KG reassignment INFIANA GERMANY GMBH &CO. KG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SEBALD, Ingrid, GRIMM, FELIX, SCHMIDT, WERNER
Publication of US20170015478A1 publication Critical patent/US20170015478A1/en
Assigned to LOPAREX GERMANY GMBH & CO. KG reassignment LOPAREX GERMANY GMBH & CO. KG CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: INFIANA GERMANY GMBH & CO. KG
Abandoned legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/02Wrappers or flexible covers
    • B65D65/14Wrappers or flexible covers with areas coated with adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B29C47/0057
    • B29C47/0061
    • B29C47/06
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0018Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/002Combinations of extrusion moulding with other shaping operations combined with surface shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D31/00Bags or like containers made of paper and having structural provision for thickness of contents
    • B65D31/02Bags or like containers made of paper and having structural provision for thickness of contents with laminated walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00Details of, or accessories for, sacks or bags
    • B65D33/007Details of, or accessories for, sacks or bags for facilitating the separation of the two walls, e.g. walls of inequal height, tabs; for maintaining the mouth of the sack or bag open
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/52Details
    • B65D75/58Opening or contents-removing devices added or incorporated during package manufacture
    • B65D75/5805Opening or contents-removing devices added or incorporated during package manufacture for tearing a side strip parallel and next to the edge, e.g. by means of a line of weakness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00Use of unspecified macromolecular compounds as moulding material
    • B29K2101/12Thermoplastic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • B29L2031/7128Bags, sacks, sachets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B2037/148Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers whereby layers material is selected in order to facilitate recycling of the laminate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/242All polymers belonging to those covered by group B32B27/32
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514Oriented
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    • B32LAYERED PRODUCTS
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514Oriented
    • B32B2307/516Oriented mono-axially
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    • B32B2307/00Properties of the layers or laminate
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    • B32B2307/00Properties of the layers or laminate
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    • B32B37/04Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the partial melting of at least one layer
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    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing

Definitions

  • a wrapper-type packaging made of a flexible polymeric film in the form of a sack or bag and consisting of a front wall and a rear wall, which are located opposite one another and are sealed in each case by a side sealing seam to form a sack-like or bag-like tube, of which the opening is covered by a closure flap which is formed by a projection of the rear wall and is folded onto the front wall at least as far as, and preferably beyond, the opening and is closed by in each case longitudinal side sealing and, optionally, transverse sealing or adhesive bonding, and preferably having an opening aid, wherein the flexible polymeric film is oriented at least monoaxially and is optionally embossed and has a tear propagation resistance in machine direction which differs by at least 30% in relation to the tear propagation resistance in the direction transverse to the machine direction and the wrapper-type packaging is suitable in particular for optionally self-adhesive articles, preferably optionally self-adhesive hygiene articles, which are preferably provided for single use.
  • wrapper-type packagings made from flexible polymeric films are suitable for packaging a very wide variety of articles, especially articles for single use.
  • articles for single use In particular in the hygiene sector an increasing tendency to package hygiene articles for single use individually, in order to achieve the maximum protection and the maximum hygiene for the sensitive use of such products.
  • the front wall and the rear wall for the formation of a sack-like or bag-like tube of a wrapper-type packaging are preferably not sealed longitudinally, but instead are joined longitudinally by a particular type, namely by crimping, in each case together with the closure flap folded over the front wall, whereby said closure flap is closed transversely. Therefore, there is no need to tear any seal seam for opening, which would be more difficult for the end user and, furthermore, would cause not only a fairly unpleasant noise, but also the risk of an unintended tearing of the packaging.
  • a wrapper-type packaging made of a flexible polymeric film in the form of a sack or bag and consisting of a front wall and a rear wall, which are located opposite one another and are sealed in each case by a side sealing seam to form a sack-like or bag-like tube, of which the opening is covered by a closure flap which is formed by a projection of the rear wall and is folded onto the front wall and is closed by in each case longitudinal side sealing and, optionally, transverse sealing or adhesive bonding, and preferably having an opening aid, characterized in that the flexible polymeric film is oriented at least monoaxially and is optionally embossed and has a tear propagation resistance in machine direction which differs by at least 30% in relation to the tear propagation resistance in the direction transverse to the machine direction.
  • the closure flap can be closed completely by longitudinal sealings at both sides and a transverse sealing or by the transverse adhesive bonding of the closure flap, against the front wall of the packaging, since by means of an opening aid, i.e. a marking in the form, for example, of a notch, the tearing direction for the opening of the packaging can be provided without any tearing of one of the seal seams.
  • This marked tearing direction marks the direction of relatively low tearing propagation resistance of the polymeric film used.
  • the inventive packaging is closed completely by means of the sealed closure flap the end user has a guaranty for retained hygiene requirements and that no unallowed access to the packaged product took place before its end use.
  • the polymeric film used according to the invention has at least a monoaxial orientation in the machine direction. This orientation is usually achieved by a difference in speed between its extrusion speed and takeoff speed during the film production.
  • the ratio of the speed i.e., the draw ratio
  • the ratio of the speed is preferably at least 1:30, preferably at least 1:50.
  • the multilayer polymeric film used according to the invention preferably comprises at least a three-layer sequence of
  • the layers of the polymeric film used according to the invention have preferably been prepared from thermoplastic polymers selected from the group comprising polyolefins, polyamides, polyesters, biodegradable polymers, copolymers of at least two monomers of the mentioned polymers and mixtures of at least two of the mentioned polymers.
  • the layers (a) and (e) and also, optionally, the layer (c) of the multilayer film used according the invention are based preferably in each case, identically or differently, on polyolefins and olefin copolymers of ⁇ , ⁇ -unsaturated olefins having 2-8, preferably 2-3, carbon atoms, which are preferably selected from the group comprising polyethylenes (PE)—especially polyethylenes of low density between 0.86 and 0.93 g/cm 3 (LDPE), linear polyethylenes of low density between 0.86 and 0.94 g/cm 3 (LLDPE) containing as comonomer one or more ⁇ -olefins having more than 2 carbon atoms, polyethylenes of medium density between 0.926 and 0.94 g/cm 3 (MDPE), polyethylenes of high density between 0.94 and 0.97 g/cm 3 (HDPE), copolymers of ethylene with an ⁇ -olefin having 4 or more carbon atoms (mPE);
  • At least the layer (e) as surface layer may be based on at least one polyester or at least one copolyester which is preferably selected from the group comprising polyethylene terephthalates (PET, c-PET, a-PET) and copolymers such as coPET, PBT and CoPBT).
  • PET polyethylene terephthalates
  • c-PET a-PET
  • a-PET amorphous PET
  • c-PET crystalline PET
  • PET refers to copolyesters which in addition to ethylene glycol and terephthalic acid can additionally contain further monomers, such as branched or aromatic diols, for example.
  • CoPBT refers to polybutylene terephthalates.
  • the polyester or copolyester used preferably has an intrinsic viscosity of preferably 0.1 to 2.0 dl/g, more preferably of 0.3 to 1.5 dl/g, more particularly of 0.6 to 1.0 dl/g, the methods for determining the intrinsic viscosity being known to the skilled person.
  • a comprehensive description of suitable PET and PBT is disclosed in Kunststoffhandbuch volume 3/1—technische Thermoplaste: Polycarbonate, Polyacetale, Polyester, Cellulosester; Carl Hanser Verlag, 1992, the content of which is hereby referenced in full.
  • the layer (a) and (e) are polymer components of the layer (a) and (e), respectively. It should preferably be ensured that the layer (a) can be bonded to the layer (e) by heat sealing, at least with respect to the two longitudinal side seal seams of the wrapper-type packaging.
  • the multilayer polymeric film used according to the invention has at least one layer (c) having a barrier effect.
  • a barrier effect more particularly against loss of gas or loss of aroma, against migration of low molecular mass components and/or against impairment of flavor and/or odor, or against moisture and/or against oils and fats.
  • the layer (c) with a barrier effect against gases, preferably against O 2 , (H 2 O—) vapor and/or gaseous flavors, against migration of low molecular mass organic compounds and/or against impairment of taste and/or odor is based on at least one thermoplastic polymer selected from the group comprising ethylene-vinyl alcohol copolymers, polyvinyl alcohols, polyvinylidene chlorides, vinylidene chloride copolymers, polyether-polyamide block copolymers and mixtures of the polymers with ethylene-vinyl acetate copolymers.
  • Preferred vinylidene chloride copolymers have a vinylidene chloride fraction of 80% or more.
  • Ethylene-vinyl alcohol copolymers are particularly preferred.
  • the layer (c) has a barrier effect against moisture and/or oils and fats which is based preferably on a thermoplastic, aliphatic or (partially) aromatic polyamide or copolyamide or mixtures thereof.
  • PA polyamides
  • copolyamides coPA
  • PA copolyamides
  • at least one layer (c) it is possible, for producing at least one layer (c), to use preferably aliphatic or (partially) aromatic polyamides, preferably having a melting point in the range from 160 to 240° C., more preferably from 170 to 220° C.
  • homopolyamides and/or copolyamides selected from the group comprising thermoplastic, aliphatic, partially aromatic and aromatic homopolyamides or copolyamides with isophorone diamine units.
  • These homopolyamides or copolyamides with isophorone diamine units can be composed of further aliphatic and/or cycloaliphatic diamines having 2-10 carbon atoms such as hexamethylene diamine and/or aromatic diamines having 6-10 carbon atoms such as p-phenylene diamine, and of aliphatic or aromatic dicarboxylic acids having 6-14 carbon atoms such as adipic acid, terephthalic acid or isophthalic acid.
  • copolyamides with isophorone diamine units can also comprise lactam units having 4-10 carbon atoms such as s-caprolactam, for example.
  • isophorone diamine can preferably be used as at least one diamine component that the homopolyamides and/or copolyamides which are preferably suitable for producing the layer (c) having units consisting of isophthalic acid or terephthalic acid and isophorone diamine.
  • Homopolyamides and/or copolyamides which are particularly preferably used according to the invention comprise units consisting of s-caprolactam, isophorone diamine and of an aromatic dicarboxylic acid, preferably isophthalic acid.
  • thermoplastic polyesters mentioned before useful for the production of the layer (e) can also be used for producing the layer (c).
  • composition of the layer (c) as barrier layer and with appropriate selection of suitable polymers it is possible to provide a multilayer polymeric film having also a DIN 53380-3 oxygen permeability which is significantly reduced which amounts up to 10.00 cm 3 /(m 2 ⁇ d ⁇ bar) at 23° C. and 50% rh.
  • the oxygen permeability of the multilayer polymeric film used according to the invention can be further reduced to at most 8 cm 3 /(m 2 ⁇ d ⁇ bar), preferably at most 7 or 6 cm 3 /(m 2 ⁇ d ⁇ bar), more preferably at most 5, 4 or 3 cm 3 /(m 2 ⁇ d ⁇ bar), even more preferably at most 2, 1 or 0.5 cm 3 /(m 2 ⁇ d ⁇ bar), most preferably at most 0.4, 0.3 or 0.2 cm 3 /(m 2 ⁇ d ⁇ bar), and more particularly at most 0.1, 0.09 or 0.08 cm 3 /(m 2 ⁇ d ⁇ bar) (in each case at 23° C. and 50% rh).
  • layer (c) functions as barrier layer (c), it is preferably connected to the adjacent layers via adhesion promoter layers (b) and (d).
  • maleic anhydride-modified PE PE modified with COOH groups
  • carboxyl group-modified copolymers of ethylene-vinyl acetate, or of ethylene(meth)acrylate or anhydride-modified ethylene-vinyl acetate copolymers and a polymer blend containing at least two of the mentioned polymers.
  • Copolymers modified with maleic anhydride are particularly preferred.
  • the multilayer polymeric film used according to the invention comprises more than one layer (c) and comprises the following layer sequence:
  • the layers (c) are preferably based on homopolymers, copolymers or mixtures of polymers as described before, more preferably on copolyamides or ethylene-vinyl alcohol copolymers.
  • the other layers as well correspond preferably in their composition to the details given before in relation to these layers and have the mentioned property profile.
  • the layers of the multilayer polymeric film used according to the invention can in each case contain the same or different additives selected from the group encompassing antioxidants, antiblocking agents, antifog agents, antistats, active antimicrobial ingredients, light stabilizers, UV absorbers, UV filters, dyes, color pigments, stabilizers, preferably heat stabilizers, process stabilizers, and UV and/or light stabilizers, preferably based on at least one sterically hindered amine (HALS), process assistants, flame retardants, nucleating agents, crystallizing agents, preferably crystal seed formers, lubricants, optical brighteners, plasticizers, silanes, spacers, fillers, such as CaCO3, silicates, peel additives, seal additives, waxes, wetting agents, surface-active compounds, preferably surfactants, and dispersants.
  • HALS sterically hindered amine
  • the layers of the polymeric film can contain at least 0.01-30 wt %, preferably at least 0.1-20 wt %, in each case based on the total weight of an individual layer, of at least one of the before mentioned additives.
  • a tear propagation resistance in machine direction is obtained which differs by at least 30%, preferably up to 50%, from the tear propagation resistance transverse to the machine direction (measured according to DIN 53356-trouser leg).
  • an inventive packaging produced from such a preferably multilayer and monoaxially oriented polymeric films is easy to open outside any seal seam region and the optionally present adhesive seam regions, i.e., without the need of the end user for opening a seal seam or adhesive seam for this purpose.
  • the polymeric film used according to the invention can also be embossed.
  • at least a certain area of the surface layer (a) has an embossed structure, more preferably the entire surface of the layer (a), preferably with the exception of the seal seam regions.
  • This embossed structure of such release film used according to the invention is based preferably on a repeating, regularly or irregularly arranged pattern.
  • the embossed structure can be a continuous embossed structure such as a continuous groove structure, for example, or two or more, preferably repeating, individual embossed structures, or a regularly repeating but inherently random embossed structure, in each case corresponding to the embossing roll employed.
  • each embossed structure can be based on a multiplicity of preferably repeating individual embossed structures.
  • These respective individual embossed structures can be based preferably on a structure with embossment indentations (grooves), which have more or less pronounced embossment elevations such as ridges, for example, by which the embossed height of the embossed structure is defined.
  • grooves embossment indentations
  • a plan view may show a multiplicity of respectively different, preferably repeating, individual embossed structures such as, for example, preferably serpentine, sawtooth, hexagonal, diamond-shape, rhomboidal, parallelogrammatical, honeycomb, circular, dot-shaped, star-shaped, rope-shaped, reticular, polygonal, preferably triangular, tetragonal, more preferably rectangular and square, pentagonal, hexagonal, heptagonal, and octagonal, wire-shaped, ellipsoidal, oval, and lattice-shape-designed patterns, it also being possible for at least two patterns to be superimposed on one another.
  • individual embossed structures such as, for example, preferably serpentine, sawtooth, hexagonal, diamond-shape, rhomboidal, parallelogrammatical, honeycomb, circular, dot-shaped, star-shaped, rope-shaped, reticular, polygonal, preferably triangular, tetragonal, more preferably rectangular and square, pen
  • the embossment elevations may each preferably have a length in longitudinal direction of up to one centimeter, particular preference being given to a length of 0.001 mm to 10 mm.
  • the fraction of the elevations as a proportion of the total length of the structure with indentations can be preferably 75%, more preferably from 5% to 60%, and very preferably from 10% to 50%.
  • the elevations are arranged preferably at uniform or alternating repeating distances.
  • the elevations of the individual embossed structures may also preferably have a curvature, i.e., a convex or concave structure.
  • the embossed structure has repeating units of randomly arranged embossment indentations and embossment elevations.
  • the embossment elevations of the embossed structure are to amount preferably to ⁇ 75%, more preferably 50%, based on the overall embossed area of the polymeric film of the invention.
  • embossment elevation of the optionally uniform embossment elevations of the polymeric film used according to the invention amounts preferably to ⁇ 5 ⁇ m as measured according to DIN 53370 2006.
  • the embossment elevation of the embossed structure of the polymeric film used according to the invention is determined in accordance with DIN 53370 2006 by mechanical scanning of the surface. In this procedure, the embossment elevations are measured at not less than 10 locations, distributed uniformly in a line over the web width of the sample, it being necessary to ensure that the scanning device does not compress the embossed structure of the polymeric film, and the average of the measurements is formed, from which the thickness of the corresponding unembossed polymeric is subtracted.
  • the polymeric film used according to the invention has an asymmetric embossed structure, i.e., an embossed structure which is present consistently throughout the film and provides both the top face and the bottom face of the film with an embossment, meaning that these faces are no longer planar, but the extent of the embossment is different on the two faces of the film.
  • the top face of the film is identified as that film side on which the embossing tool acts or has acted.
  • the bottom face of the film accordingly, may have a weaker embossment (negative form).
  • the effect achieved by the embossment of the polymeric film used according to the invention is not only to obtain a release effect on the part of the polymeric film used according to the invention but also, surprisingly, to reduce the shrinkage of the oriented and optionally stretched polymeric film drastically, by more than 50% in comparison to a corresponding oriented and optionally stretched, unembossed polymeric film.
  • the oriented, optionally stretched and embossed polymeric film employed in accordance with the invention moreover, has excellent tensile strength, good to very good tear characteristics, and an excellent puncture resistance, which markedly improves the handling and the opening characteristics of the packaging according to the invention.
  • the multilayer polymeric film used according to the invention may also have a release coating on a surface layer, to improve its release effect, said surface layer being that which comes into contact with the packaged product in the context of the inventive wrapper-type packaging that is produced from the film.
  • the release coating is based preferably on a cured polysiloxane coating, with which the polymeric film employed in accordance with the invention may be furnished even prior to any occurring orientation or after this additional orientation.
  • the release coating that generates release effect is present over substantially the whole area, preferably except for at least one stripe which extends in machine direction, or over a partial area, preferably in the form of in-register transverse stripes with all of the seal seam regions of the packaging of the invention preferably not being furnished with a release coating.
  • polysiloxane in the sense of the present invention refers to compounds whose polymer chains are constructed alternately of silicon atoms and oxygen atoms.
  • a polysiloxane is based on n repeating siloxane units —[Si(R 2 )—O]—, which each independently of one another are disubstituted by two organic radicals R, with R preferably being in each case R 1 or OR 1 , and with R 1 in each case being an alkyl radical or an aryl radical.
  • the cured polysiloxane coating is preferably based on a repeating dialkylsiloxane unit or on a repeating alkylarylsiloxane unit.
  • the polysiloxane coating of the invention preferably has a crosslinked cyclic or catenated structure, more preferably a crosslinked catenated structure, which is linked by (D), (T) and/or (Q) units to form a two- or three-dimensional network.
  • the number n of the repeating siloxane units —[Si(R 2 )—O]— in the polysiloxane chain is termed the degree of polymerization of the polysiloxane.
  • the cured polysiloxane coating of the polymeric film employed in accordance with the invention is based preferably on at least one cured, i.e., crosslinked, polysiloxane selected from the group comprising addition-crosslinked, preferably addition-crosslinked with metal catalysis, condensation-crosslinked, radically crosslinked and/or cationically crosslinked polysiloxanes.
  • the polymeric film used according to the invention can be produced in principle by any known production methods, such as by extrusion or by coextrusion, for example.
  • both individual layers and all the layers of the polymeric film used according to the invention may be formed by extrusion, more particularly by blown film extrusion and/or flat film extrusion (cast extrusion), or preferably coextrusion, more particularly blown film coextrusion and/or flat film coextrusion (cast coextrusion), the latter being preferred.
  • these additives are employed by blending, where appropriate as a masterbatch, with the polymer component or components of the respective layer for processing. This blending may take place dry in pellet/powder form or pellet/pellet form.
  • An alternative possibility is for the additive to be added to the melted polymer component or components of the respective layer, preferably by metering in an extruder used for the extrusion of the layer in question.
  • the melts corresponding to the individual layers of the polymeric film used according to the invention are coextruded simultaneously and jointly through a round die or a flat die, the resulting polymeric film is taken off for orienting and solidification on one or more rolls, at a rate conforming to the before mentioned removal ratio of at least 1:30, in such a way that the ratio of removal is greater than the rate of extrusion and the film oriented in this way is heat-set.
  • Subsequent monoaxial or biaxial stretching may be carried out sequentially or simultaneously.
  • Sequential stretching is generally carried out successively, with preference being given to the successive biaxial stretching, where stretching is performed first longitudinally (in machine direction) and transversely (perpendicularly to the machine direction).
  • the polymer or the polymer mixture of the individual layers is compressed in an extruder and fluidized, it being possible for any additives added to be already present in the polymer or polymer mixture.
  • the melts are then pressed simultaneously through a flat die (slot die) and the multilayer film extruded is taken off on one or more take-off rolls at a temperature of 10 to 100° C., preferably 10 to 50° C., with the rate of removal being necessarily greater than the rate of extrusion in order to achieve the before mentioned removal ratio, and it cools and solidifies.
  • the multilayer polymeric film used according to the invention can then optionally oriented either only longitudinally, or longitudinally and transversely to the extrusion direction, leading to further orientation of the molecule chains.
  • Longitudinal orientation is carried out preferably at a temperature of 70 to 130° C., preferably 80 to 110° C., usefully with the aid of two rolls which run at different speeds in line with the target draw ratio, and the additional transverse orientation, when practiced, is carried out preferably at a temperature of 120 to 180° C. by means of a corresponding tenter frame.
  • the desired transverse orientation ratios can be set at this point.
  • Orientation is preferably orientation in machine direction in accordance with the invention.
  • any orientation taking place of the polymeric film used according to with the invention is followed preferably by its heat-setting (heat treatment) where the film is held for about 0.1 to 10 s at a temperature of 100 to 160° C. Subsequently, where appropriate after interim storage, the polymeric film of the invention may be furnished with any release coating present. It is also possible for the extruded multilayer stretched polymeric film used according to the invention to be provided with any release coating even prior to orientation.
  • the flexible multilayer polymeric films used according to the invention can be transparent, transparently colored, opaque or non transparent.
  • the film can have a printing on the outer side facing away from the packaged product.
  • FIG. 1 shows an inventive wrapper-type packing in plan view.
  • FIG. 2 shows a plan view of the wrapper-type packaging of FIG. 1 in the opened condition.
  • FIG. 3 shows a further embodiment of the inventive wrapper-type packaging in plan view.
  • FIG. 4 shows a plan view of the wrapper-type packaging of FIG. 3 in the opened condition.
  • FIG. 5 shows a further embodiment of the inventive wrapper-type packaging in plan view.
  • FIG. 6 shows a plan view of the wrapper-type packaging of FIG. 5 in the opened condition.
  • FIG. 7 shows a further embodiment of the inventive wrapper-type packaging in accordance with FIG. 1 , without transverse sealing of the closure tab, in plan view.
  • FIG. 8 shows a plan view of the wrapper-type packaging of FIG. 7 in the opened condition.
  • FIG. 9 shows a further embodiment of the inventive wrapper-type packaging in accordance with FIG. 3 , without transverse sealing of the closure tab, in plan view.
  • FIG. 10 shows a plan view of the FIG. 9 in the opened condition.
  • FIG. 1 shows an embodiment of the inventive wrapper-type packaging ( 1 ), produced from a single film web of the before described multilayer film used according to the invention.
  • the wrapper-type packaging comprises a bag with an opening ( 7 ) from which the packaged product can be removed after opening.
  • the bag is formed from a front wall ( 2 ) and a rear wall ( 3 ) by folding the film along the folding line ( 6 ).
  • the wrapper-type packaging is closed completely by means of the closure flap ( 8 ) by longitudinal sealing ( 9 , 10 ) and transverse sealing ( 11 ) of the inner layer of the closure flap ( 8 ) against the outer layer of the front wall ( 2 ).
  • the transverse seal seam ( 11 ) is placed at a distance from the edge of the packaging flap.
  • the closure flap ( 8 ) can also be bonded to the front wall ( 2 ) by means of a strip of an adhesive, which runs transversely on the inside of the closure flap, in which case the bond strength of the adhesive, should correspond to the seal strength of a seal seam that is ponding the parts, which is preferably greater than the tear propagation resistance of the inventive wrapper-type packaging in the direction of the marking for the opening of the packaging.
  • Suitable commercial adhesives suitable are known to the person skilled in the art.
  • FIG. 2 shows a plan view of the inventive wrapper-type packaging in accordance with FIG. 1 , in which a part ( 14 ) of the packaging, which is already torn away from the packaging to a predominant extent, starting from the notch ( 13 ), via the opening ( 7 ) with the packaged product (not shown). Furthermore, on the front wall ( 2 ) of the inventive packaging, the side seal seams ( 11 ) which extend longitudinally, and the seal seams placed transversely for the closing of the closure flap ( 8 ), can be seen to be intact, and so the packaged product can be removed without effort and destruction of the rest of the packaging.
  • FIG. 3 shows a further embodiment of the inventive wrapper-type packaging, which differs from the packaging shown in FIG. 1 in that the marking ( 13 ) of the direction of opening is located on the folding line ( 12 ) of the closure flap.
  • This notch could also be replaced by a barcode (not shown) or could be located in the edge region of the closure flap ( 8 ) beneath the transverse seal seam ( 11 ) and at right angles to the seal seam ( 11 ).
  • FIG. 4 shows a plan view of the wrapper-type packaging according to FIG. 3 in the predominantly open condition, and without the packaged product, which has already been removed. Again, on the front wall of the wrapper-type packaging, the transverse seal seam ( 11 ) of the closure flap and also the seal seams extending at the sides longitudinally can be seen to be intact.
  • FIG. 5 Shown in FIG. 5 is a further preferred embodiment of the inventive wrapper-type packaging.
  • the closure tab ( 8 ) is joined to the front wall ( 2 ) directly at the level of the opening ( 7 ) of the bag, with the edge region of the closure flap being connected to the opening edge region of the front wall by means of a transverse seal seam, formed as so called fin seam.
  • This fin seam has a notch ( 13 ) for marking the direction of opening.
  • FIG. 6 shows a plan view of the inventive wrapper-type packaging as per FIG. 5 , in the partly opened condition and after removal of the packaged product; again, the seal seams extending at the sides longitudinally, and the fin seam extending transversely can be seen to be intact, apart from the tearing along the notch.
  • FIG. 7 and FIG. 8 correspond to FIG. 1 and FIG. 2 , with the exception that the wrapper-type packaging has no transverse seal seam for the closing of the closure flap. Since, however, the seams ( 9 ) and ( 10 ) extending at the sides longitudinally are seal seams, and the packaging has a notch as opening aid, the consumer is able to remove the packaged product without effort and without any need for side seal seams to be torn open, in order to get to the packaged product. In spite of the effortless opening of the wrapper-type packaging according to FIG. 7 , this wrapper-type packaging ensures a better security during transport and storage than corresponding packaging with less secure side seams for closure.
  • FIG. 9 and FIG. 10 correspond to FIG. 3 and FIG. 4 , with the exception of a transverse seal seam for closing the closure flap, for these embodiments of the invention the same explanations as mentioned in relation to FIG. 7 and FIG. 8 are of relevance.
  • the inventive packagings can be opened easily, without the possibility of an unallowed access to the packaged product before the intended opening for removing the packaged product and the therefore partial destruction of the wrapper-type packaging takes place.
  • the inventive wrapper-type packaging is easy to open.
  • the inventive wrapper-type packaging can be produced according to known, conventional techniques; whereby during production the difference in tear propagation resistance of the film and the related opening behavior of the packaging produced therefrom, has to be taken into account.
  • the inventive wrapper-type packaging is especially suitable for the packaging of articles which are intended for single use, preferably hygiene articles intended for single use, more particularly sanitary towels, tampons, panty liners or incontinence articles that are intended for single use.
  • inventive wrapper-type packaging is suitable as individual packaging for adhesive articles of any kind, more particularly as individual packaging for self-adhesive articles intended for single use, more preferably for self-adhesive hygiene articles intended for single use.
  • inventive wrapper-type packaging is suitable for the packaging of self-adhesive panty liners, self-adhesive sanitary towels or self-adhesive incontinence articles which are intended for single use and are packaged preferably in the folded shape.

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  • Laminated Bodies (AREA)
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DE102014010987.9A DE102014010987A1 (de) 2014-03-21 2014-07-29 Verpackung
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