US20160311997A1 - A process for recovering polyester - Google Patents
A process for recovering polyester Download PDFInfo
- Publication number
- US20160311997A1 US20160311997A1 US15/102,053 US201415102053A US2016311997A1 US 20160311997 A1 US20160311997 A1 US 20160311997A1 US 201415102053 A US201415102053 A US 201415102053A US 2016311997 A1 US2016311997 A1 US 2016311997A1
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- US
- United States
- Prior art keywords
- polyester component
- polyester
- ranging
- pet
- article
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/105—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with enzymes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/14—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with steam or water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/16—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with inorganic material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/08—Cellulose derivatives
- C08J2401/22—Cellulose xanthate
- C08J2401/24—Viscose
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Definitions
- the present disclosure relates to a process for recovering polyester. Particularly, the present disclosure relates to a process for recovering polyester component and products of non-polyester component from an article comprising a polyester blend.
- Polyesters and its blends with various substances such as cotton, silk and viscose find applications in various articles such as apparel, home furnishings, upholstery, containers, carpets and the like owing to their flexibility and a range of desirable properties.
- Waste or used polyester is either burned or buried in landfills. These methods, although common in practice, are enormous detrimental to the environment. This is because the microorganisms present in the soil are unable to degrade the polyester which causes its accumulation in the soil. Such accumulated polyester mars the growth and development of the flora and fauna present in the sub-soil environment thereby disturbing the ecological balance.
- U.S. Pat. No. 5,236,959 discloses a process for recycling polyester/cotton blends by subjecting the blends to a first alcoholysis in a bath containing an alcohol and an effective catalyst such as sodium hydroxide and sodium carbonate at a suitable temperature until the polyester is depolymerized into a lower molecular weight polyester oligomer.
- Cotton fibers are removed from this alcoholic solution of oligomers and are further processed by pulping and acetylyzing processes to recover the cellulose acetate.
- the low molecular weight polyester oligomers are alcoholized yet again to produce the lower dialkyl ester of terephthalic acid.
- the present disclosure provides a process for recovering a polyester component and products of non-polyester component from an article comprising a polyester blend.
- the polyester blend comprises a polyester component and a non-polyester component and the polyester component is polyethylene terephthalate and the non-polyester component is at least one selected from the group consisting of cotton and viscose.
- the process comprises hydrolyzing the article using at least one hydrolyzing agent to obtain a first mixture comprising the polyester component, the non-polyester component, optionally, products of the non-polyester component and the hydrolyzing agent, followed by incubating the first mixture with at least one enzyme selected from the group consisting of cellulase and pectinase to further convert the non-polyester component into its products; thereby releasing the polyester component.
- the step of hydrolyzing the article is carried out at a temperature ranging from 90 to 160° C. for a time period ranging from 10 to 90 minutes and at a pressure ranging from 5 to 25 psi.
- the step of incubating is carried out in the presence of a buffer having strength ranging from 30 to 70 mM and pH ranging from 4.5 to 7.0 for an incubation period ranging from 20 to 50 hours at a temperature ranging from 40 to 60° C. and accompanied by stirring at a speed ranging from 150 to 250 rpm.
- the butler is sodium citrate.
- the present disclosure also provides a process for the removal of dye from the polyester blend.
- FIG. 1 illustrates Scanning Electron Microscopy images of PET/Cotton (65:35) fabric blend after undergoing the process as disclosed in Example 6, wherein
- FIG. 1A represents Control PET/Cotton (65:35) (untreated);
- FIG. 1B represents PET/Cotton (65:35) after treatment with 4% Na 2 CO 3 and 5 g/L of enzyme
- FIG. 1C represents PET/Cotton (65:35) after treatment with 4% Na 2 CO 3 and 10 g/L enzyme.
- FIG. 1D represents PET/Cotton (65:35) after treatment with 0.5% NaOH and 5 g/L enzyme.
- FIG. 1E represents PET/Cotton (65:35) after treatment with 0.5% NaOH and 10 g/L enzyme.
- the word ‘article’ besides having its standard meaning, includes any product made up of a polyester blend and is selected from the group consisting of apparel, home furnishings, upholstery, containers, carpets, tubes, stripes and pipes.
- the polyester blend is composed of a polyester component and a non-polyester component.
- the polyester component is polyethylene terephthalate (PET) and the non-polyester component is at least one selected from the group consisting of cotton and viscose.
- PET polyethylene terephthalate
- the article, before initiating the process described herein below, is optionally subjected to shredding.
- the article is first hydrolyzed at pre-determined temperature, pressure and time duration using at least one hydrolyzing agent to obtain a first mixture.
- the pre-determined temperature ranges from 90 to 160° C.
- the time period for hydrolysis ranges from 10 to 90 minutes
- the pre-determined pressure ranges from 5 to 25 psi.
- the amount of said article taken during the step of hydrolyzing ranges from 1 to 5% with respect to the total volume of the hydrolyzing agent.
- the hydrolyzing agent used is at least one alkali selected from the group consisting of sodium hydroxide, sodium carbonate, calcium hydroxide and calcium carbonate and has concentration ranging from 0.1 to 5%.
- the hydrolyzing agent used in the present process is water.
- the process of hydrolyzing is carried out in an autoclave.
- the first mixture that results from the step of hydrolyzing typically comprises a polyester component, a non-polyester component and the hydrolyzing agent.
- the mixture may also optionally contain products of the non-polyester component as a result of the step of hydrolysis.
- the first mixture is an eclectic mix which is a result of the reaction between the hydrolyzing agent and the non-polyester component.
- the first mixture is optionally neutralized to wash off the hydrolyzing agent.
- the present step of alkali hydrolysis may also be used to remove dye(s) when the non-polyester component of the article is dyed.
- removal of dye from the article is achieved.
- the first mixture is incubated with at least one enzyme selected from the group consisting of cellulase and pectinase to further separate the non-polyester component from the polyester component.
- at least one enzyme selected from the group consisting of cellulase and pectinase to further separate the non-polyester component from the polyester component. This is achieved by means of the afore-stated enzymes which convert the non-polyester component into its products—an act which releases the polyester component
- products of the non-polyester component includes the products or fragments of the non-polyester component obtained or left behind after the steps of alkali hydrolysis and/or enzyme treatment.
- ‘products of the non-polyester component’ are the disintegration products of the non-polyester component.
- the products of the non-polyester component of the present disclosure are carbohydrates.
- the step of incubation with enzyme(s) is carried out in the presence of a buffer which is sodium citrate.
- a buffer which is sodium citrate.
- the strength of the buffer ranges from 30 to 70 mM and has pH ranging from 4.5 to 7.0.
- the step of incubating is carried out for a time period ranging from 20 to 50 hours at a temperature ranging from 40 to 60° C., and is accompanied by stirring at a speed ranging from 150 to 250 rpm.
- the enzyme is selected from the group consisting of cellulase and a combination of cellulase and pectinase.
- the enzyme has a concentration ranging from 0.5 to 15 g/L.
- the enzymes after employment in the present process may be recycled up to 3 times without losing much of their activity.
- incubation with the afore-stated enzyme(s) results in further separation and release of the polyester component from the non-polyester component and both the, separated components are recovered and processed independently for re-use or for preparing value added products.
- a characteristic feature of the present disclosure is that separation of the non-polyester component from the polyester component is achieved twice, first chemically during the hydrolysis step and second biologically using the enzyme(s). This causes effective separation and maximum recovery of both the components. It is significant to note that during both the afore-stated steps, the non-polyester component gets reduced to derivatives/products which can be processed independently to obtain value added products.
- PET/Viscose (65:35) and PET/Cotton (80:20) fabrics were shredded finely.
- 0.1 g of shredded PET/Cotton was then autoclaved at 121° C. for 15 min with 40 ml of 4% NaOH solution.
- the alkali. treated PET/Cotton was neutralized.
- Shredded PET/Viscose was autoclaved under similar conditions but in water. Both the samples were subjected to incubation using 5 g/L (6.4 FPU/40 ml) of cellulase (SacchariSEB C6) and 5 g/L of pectinase (Advanced Enzymes Pvt. Ltd.
- PET/Viscose (65:35) and PET/Cotton (80:20) were cut into pieces weighing 0.1 g each.
- PET/Cotton was autoclaved with 40 ml of 4% NaOH solution for 15 min at 121° C.
- PET/Viscose was autoclaved under similar conditions but with water. Both the samples were then subjected to incubation using varying concentrations (0.5-5.0 g/L) of the enzymes cellulase (SacchariSEB C6) and pectinase (Advanced Enzymes Pvt Ltd. India) in the presence of 10 ml of 50 mM Na-citrate buffer (pH 4.8) for 48 hours at 50° C., 200 rpm.
- the enzymes cellulase SachariSEB C6
- pectinase Advanced Enzymes Pvt Ltd. India
- PET/Cotton fabric (65: 35) was cut into small pieces and pretreated with 4% NaOH and autoclaved at 121° C. for 15 min. Different fabric loads in the range of 0.1 g to 2.0 g per 40 ml of alkali were used. After autoclaving, the fabric was separated from the alkali solution using a fine nylon strainer. The separated fabric was washed thoroughly for neutralizing the alkali. This was followed by incubating using 5 g/L (800 FPU/L) of the enzyme cellulase (CodeXyme4) from Codexis Inc, USA. The incubation was carried out in 40 ml of 50 mM Na-citrate buffer (pH 4.8) for 24-48 hours, at 50° C. 200 rpm.
- 50 mM Na-citrate buffer pH 4.8
- PET/Cotton fabric (65:35) was autoclaved at 121° C. for 15 min with different alkalis having 4% w/v concentration.
- the alkalis used were sodium hydroxide (NaOH), sodium carbonate (Na 2 CO 3 ), calcium carbonate (CaCO 3 ) and calcium hydroxide (Ca(OH) 2 ).
- Fabric loading of 0.5 g in 40 ml (1.25% w/v) of alkali was used. This was followed by incubation using the enzymes cellulase (CodeXyme 4) and pectinase at 5 g/L each for 48 hours at 50° C., 200 rpm.
- 40 ml of 50 m141: Na-citrate buffer having a pH of 4.8 was used.
- PET/Cotton 0.5 g was autoclaved at 121° C. for 15 min with 40 ml of 0.5% NaOH and 4% Na 2 CO 3 . This was followed by incubation using cellulase (CodeXyme4) at varying concentrations: 1 to 15 g/L (6.4 FPU-96 FPU). 40 ml of 50 mM Na-citrate buffer having pH 4.8 was used and the incubation period was 48 hours, at 50° C., 200 rpm.
- PET/Cotton 0.5 g of PET/Cotton (65:35) was autoclaved with 40 ml of either 0.5% NaOH or 4% Na 2 CO 3 at 121° C. for 15 min. This was followed by incubation using the enzyme cellulase (CodeXyme4) at 5 and 10 g/L concentrations for 48 hours; at 50° C., 200 rpm. 40 ml of 50 mM Na-citrate buffer having pH 4.8 was used.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Sustainable Development (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN4133/MUM/2013 | 2013-12-31 | ||
IN4133MU2013 | 2014-01-06 | ||
PCT/IN2014/000806 WO2015111071A2 (en) | 2013-12-31 | 2014-12-30 | A process for recovering polyester |
Publications (1)
Publication Number | Publication Date |
---|---|
US20160311997A1 true US20160311997A1 (en) | 2016-10-27 |
Family
ID=53493353
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/102,053 Abandoned US20160311997A1 (en) | 2013-12-31 | 2014-12-30 | A process for recovering polyester |
US15/102,004 Expired - Fee Related US9932456B2 (en) | 2014-01-06 | 2015-01-06 | Process for recovering polyester from polyester/wool blend |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/102,004 Expired - Fee Related US9932456B2 (en) | 2014-01-06 | 2015-01-06 | Process for recovering polyester from polyester/wool blend |
Country Status (6)
Country | Link |
---|---|
US (2) | US20160311997A1 (zh) |
EP (2) | EP3092335B1 (zh) |
JP (2) | JP2017504694A (zh) |
CN (2) | CN105960489A (zh) |
TW (1) | TW201605939A (zh) |
WO (2) | WO2015111071A2 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160304694A1 (en) * | 2014-01-06 | 2016-10-20 | Reliance Industries Limited | A process for recovering polyester from polyester/wool blend |
KR20200099200A (ko) * | 2018-01-12 | 2020-08-21 | 타이턴 바이오사이언스 엘엘씨 | 폐직물로부터 면 및 폴리에스테르 섬유의 재활용 방법 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016123558A1 (en) | 2015-01-30 | 2016-08-04 | Resinate Materials Group, Inc. | Integrated process for treating recycled streams of pet and ptt |
SE542172C2 (en) | 2018-07-13 | 2020-03-10 | Soedra Skogsaegarna Ekonomisk Foerening | Process for separation |
CN115197467A (zh) * | 2021-04-13 | 2022-10-18 | 香港纺织及成衣研发中心 | 分离混纺织品中涤纶和棉的方法 |
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US2532183A (en) * | 1948-08-18 | 1950-11-28 | Pacific Mills | Treatment of cellulosic textile material to increase its water absorbency |
US5236959A (en) * | 1992-03-12 | 1993-08-17 | Hoechst Celanese Corporation | Process for recycling polyester/cotton blends |
CN102675089A (zh) * | 2012-04-15 | 2012-09-19 | 广东巨洋环保科技有限公司 | 一种废旧涤棉混纺织物回收利用方法 |
WO2012149344A1 (en) * | 2011-04-29 | 2012-11-01 | Novozymes, Inc. | Methods for enhancing the degradation or conversion of cellulosic material |
CN103613784A (zh) * | 2013-11-27 | 2014-03-05 | 青岛福创环境科技有限公司 | 一种从废旧纺织品中回收化学纤维的方法 |
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JP2002173828A (ja) * | 2000-12-04 | 2002-06-21 | Ecolog Recycling Japan:Kk | ポリエステル綿混用繊維製品リサイクル方法 |
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-
2014
- 2014-12-30 US US15/102,053 patent/US20160311997A1/en not_active Abandoned
- 2014-12-30 EP EP14880260.6A patent/EP3092335B1/en not_active Not-in-force
- 2014-12-30 TW TW103146346A patent/TW201605939A/zh unknown
- 2014-12-30 CN CN201480071538.XA patent/CN105960489A/zh active Pending
- 2014-12-30 WO PCT/IN2014/000806 patent/WO2015111071A2/en active Application Filing
- 2014-12-30 JP JP2016543623A patent/JP2017504694A/ja active Pending
-
2015
- 2015-01-06 JP JP2016562080A patent/JP6517235B2/ja not_active Expired - Fee Related
- 2015-01-06 EP EP15733231.3A patent/EP3092270B1/en active Active
- 2015-01-06 CN CN201580003695.1A patent/CN106164150A/zh active Pending
- 2015-01-06 WO PCT/IB2015/050081 patent/WO2015101960A1/en active Application Filing
- 2015-01-06 US US15/102,004 patent/US9932456B2/en not_active Expired - Fee Related
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WO2012149344A1 (en) * | 2011-04-29 | 2012-11-01 | Novozymes, Inc. | Methods for enhancing the degradation or conversion of cellulosic material |
CN102675089A (zh) * | 2012-04-15 | 2012-09-19 | 广东巨洋环保科技有限公司 | 一种废旧涤棉混纺织物回收利用方法 |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160304694A1 (en) * | 2014-01-06 | 2016-10-20 | Reliance Industries Limited | A process for recovering polyester from polyester/wool blend |
US9932456B2 (en) * | 2014-01-06 | 2018-04-03 | Reliance Industries Limited | Process for recovering polyester from polyester/wool blend |
KR20200099200A (ko) * | 2018-01-12 | 2020-08-21 | 타이턴 바이오사이언스 엘엘씨 | 폐직물로부터 면 및 폴리에스테르 섬유의 재활용 방법 |
JP2021510754A (ja) * | 2018-01-12 | 2021-04-30 | サーク,エルエルシー | 廃棄物織物から綿およびポリエステル繊維をリサイクルするための方法 |
EP3737783A4 (en) * | 2018-01-12 | 2021-10-27 | Circ, LLC | METHOD FOR RECYCLING COTTON AND POLYESTER FIBERS FROM WASTE TEXTILES |
US11180629B2 (en) | 2018-01-12 | 2021-11-23 | Circ, LLC | Methods for recycling cotton and polyester fibers from waste textiles |
US11370895B2 (en) | 2018-01-12 | 2022-06-28 | Circ, LLC | Methods for recycling cotton and polyester fibers from waste textiles |
JP7201144B2 (ja) | 2018-01-12 | 2023-01-10 | サーク,インコーポレイテッド | 廃棄物織物から綿およびポリエステル繊維をリサイクルするための方法 |
KR102662467B1 (ko) | 2018-01-12 | 2024-04-30 | 서크, 엘엘씨 | 폐직물로부터 면 및 폴리에스테르 섬유의 재활용 방법 |
US12006403B2 (en) | 2018-01-12 | 2024-06-11 | Circ, LLC | Methods for recycling cotton and polyester fibers from waste textiles |
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EP3092270A4 (en) | 2017-08-16 |
CN105960489A (zh) | 2016-09-21 |
JP2017503067A (ja) | 2017-01-26 |
EP3092270B1 (en) | 2019-05-15 |
US20160304694A1 (en) | 2016-10-20 |
TW201605939A (zh) | 2016-02-16 |
JP6517235B2 (ja) | 2019-05-22 |
WO2015101960A1 (en) | 2015-07-09 |
EP3092270A1 (en) | 2016-11-16 |
CN106164150A (zh) | 2016-11-23 |
US9932456B2 (en) | 2018-04-03 |
WO2015111071A2 (en) | 2015-07-30 |
EP3092335A2 (en) | 2016-11-16 |
EP3092335B1 (en) | 2019-05-15 |
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JP2017504694A (ja) | 2017-02-09 |
WO2015111071A3 (en) | 2015-12-23 |
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