US20070099023A1 - Aluminium alloy strip for brazing - Google Patents
Aluminium alloy strip for brazing Download PDFInfo
- Publication number
- US20070099023A1 US20070099023A1 US10/596,060 US59606004A US2007099023A1 US 20070099023 A1 US20070099023 A1 US 20070099023A1 US 59606004 A US59606004 A US 59606004A US 2007099023 A1 US2007099023 A1 US 2007099023A1
- Authority
- US
- United States
- Prior art keywords
- alloy
- brazing
- strip
- aluminum alloy
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000005219 brazing Methods 0.000 title claims abstract description 52
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 23
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 53
- 239000000956 alloy Substances 0.000 claims abstract description 53
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 14
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 13
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 10
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910001122 Mischmetal Inorganic materials 0.000 claims description 3
- 229910052790 beryllium Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000002952 polymeric resin Substances 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 230000004907 flux Effects 0.000 abstract description 11
- 239000004411 aluminium Substances 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000005253 cladding Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000000151 deposition Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000004320 controlled atmosphere Methods 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910021364 Al-Si alloy Inorganic materials 0.000 description 1
- 229910018137 Al-Zn Inorganic materials 0.000 description 1
- 229910018507 Al—Ni Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- 229910018573 Al—Zn Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000011856 silicon-based particle Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/28—Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
- B23K35/286—Al as the principal constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K1/00—Soldering, e.g. brazing, or unsoldering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B15/00—Arrangements for performing additional metal-working operations specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K1/00—Soldering, e.g. brazing, or unsoldering
- B23K1/0008—Soldering, e.g. brazing, or unsoldering specially adapted for particular articles or work
- B23K1/0012—Brazing heat exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K1/00—Soldering, e.g. brazing, or unsoldering
- B23K1/008—Soldering within a furnace
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/001—Interlayers, transition pieces for metallurgical bonding of workpieces
- B23K35/002—Interlayers, transition pieces for metallurgical bonding of workpieces at least one of the workpieces being of light metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0222—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
- B23K35/0233—Sheets, foils
- B23K35/0238—Sheets, foils layered
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3612—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with organic compounds as principal constituents
- B23K35/3613—Polymers, e.g. resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/016—Layered products comprising a layer of metal all layers being exclusively metallic all layers being formed of aluminium or aluminium alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/04—Tubular or hollow articles
- B23K2101/14—Heat exchangers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/08—Non-ferrous metals or alloys
- B23K2103/10—Aluminium or alloys thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/12764—Next to Al-base component
Definitions
- the invention relates to aluminium alloy strips, possibly cladded on one or two faces with a brazing alloy and intended for the production of brazed parts, particularly heat exchangers for automobiles or buildings, and more particularly parts assembled by fluxless brazing under a controlled atmosphere.
- brazing The most frequently used process for the assembly of automobile heat exchangers is brazing. This is based on the use of a cladded strip composed of a so-called “core” alloy coated on one or two faces with a so-called “brazing” alloy, at least for one of the components to be assembled.
- This so-called “brazing” alloy is characterised by a liquid temperature about 30° C. less than the solidus temperature of the core alloy.
- a third process used more marginally consists of depositing a nickel layer instead of the flux. Brazing is then done under nitrogen. The energy released during the brazing cycle by the creation of Al—Ni phases on the cladding surface is sufficient to break the oxide layer.
- the main problem consists of performing the brazing operation on existing Nocolok® lines, since these are the most widespread and the most economic, without the use of flux or any other complex surface preparation and without causing degradation of the final properties of exchangers that will be assembled using this technique.
- the brazing that contains Mg and Bi is covered with a thin layer formed of an aluminium alloy that will remain solid when it begins to melt; it will only break later during the brazing cycle, releasing liquid cladding that then wets its upper surface. Oxidation of the liquid brazing alloy is avoided by working under an atmosphere for a short period. The oxide present on the thin layer is broken when it is surrounded by liquid.
- the purpose of the invention is to enable production by fluxless brazing of parts made of aluminium alloy under good economic conditions, and particularly using the same equipment as is used for brazing with flux under a controlled atmosphere.
- the purpose of the invention is an aluminium alloy strip or sheet containing 0.01 to 0.5% of yttrium and/or 0.05 to 0.5% of bismuth, coated on at least one face with a brazing alloy.
- the coating may be a layer cladded by co-rolling, for example an aluminium alloy containing 4 to 15% of silicon. It may also be a layer comprising particles of a brazing alloy, particularly particles of Al—Si alloy, possibly coated in a resin.
- Another purpose of the invention is a brazed part, particularly a heat exchanger made using an aluminium alloy strip or sheet containing 0.01 to 0.5% of yttrium and/or 0.05 to 0.5% of bismuth.
- FIGS. 1 a and 1 b show a top and side view respectively of V test pieces used in the examples to evaluate the brazability.
- FIG. 2 shows the definition of the width of the brazed joint used in the brazability test described in the examples.
- the invention is designed to modify the composition of the core alloy, such that brazing can take place without any deposition, under standard controlled atmosphere conditions, and that can be achieved without modifying the brazing installations used at equipment manufacturers.
- the method is applicable to all types of aluminium alloys containing at least 80% by weight of aluminium, and particularly alloys for which the composition satisfies the following conditions (% by weight) before the addition of elements specifically intended to enable fluxless brazing:
- the sheet or strip may be cladded by co-rolling on one or two faces with a brazing aluminium alloy, usually an alloy containing 4 to 15% of silicon.
- the brazing alloy may contain other additives such as copper, magnesium or zinc. It may also contain elements designed to modify the surface tension of the alloy, such as Ag, Be, Bi, Ce, La, Pb, Pd, Sb, Y or mischmetal, in other words a mixture of unseparated rare earth metals.
- the brazing alloy is cladded on a single face, the other face may be coated by a sacrificial alloy, usually of the Al—Zn type, in a manner commonly known and intended to improve the resistance of the core alloy to corrosion.
- the brazing alloy may also be deposited in the form of particles, particularly Al—Si particles, for example as described in patent EP 0565568 (Alcan International).
- the brazing alloy particles are usually associated with flux particles, particularly flux based on fluorides such as potassium fluoro-aluminate, and a binder such as a polymer resin.
- flux particles particularly flux based on fluorides such as potassium fluoro-aluminate
- binder such as a polymer resin
- the alloy sheet with the addition of bismuth and/or yttrium may also be used uncoated when it is associated with another sheet coated with a brazing alloy for the production of the brazed part.
- the test piece illustrated in FIG. 1 was used to evaluate the brazability of these materials.
- the “V” is composed of a 0.3 mm thick bare strip made of a 3003 alloy in the H24 temper. A 15-minute degreasing treatment at 250° C. was applied to the metal to be brazed. No other surface preparation was used and in particular no flux was deposited. Brazing is done in a double-wall glass furnace in which it is possible to view movements of liquid brazing alloy and the formation of joints during the treatment.
- the thermal cycle is composed of a temperature rise phase up to 610° C. at a rate of approximately 20° C./min, holding for 2 minutes at 610° C., and then lowering at a rate of about 30° C./minute. The complete process is done under continuous nitrogen scavenging, at a rate of 8 l/min.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Coating With Molten Metal (AREA)
- Electric Connection Of Electric Components To Printed Circuits (AREA)
- Non-Insulated Conductors (AREA)
- Electroplating Methods And Accessories (AREA)
- Ceramic Products (AREA)
- Details Of Heat-Exchange And Heat-Transfer (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Metal Extraction Processes (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/171,644 US8413876B2 (en) | 2003-11-28 | 2011-06-29 | Aluminium alloy strip for brazing |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0314001 | 2003-11-28 | ||
| FR0314001A FR2862894B1 (fr) | 2003-11-28 | 2003-11-28 | Bande en alliage d'alluminium pour brasage |
| PCT/FR2004/003003 WO2005061165A1 (fr) | 2003-11-28 | 2004-11-24 | Bande en alliage d’aluminium pour brasage |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20070099023A1 true US20070099023A1 (en) | 2007-05-03 |
Family
ID=34566233
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/596,060 Abandoned US20070099023A1 (en) | 2003-11-28 | 2004-11-24 | Aluminium alloy strip for brazing |
| US13/171,644 Expired - Fee Related US8413876B2 (en) | 2003-11-28 | 2011-06-29 | Aluminium alloy strip for brazing |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/171,644 Expired - Fee Related US8413876B2 (en) | 2003-11-28 | 2011-06-29 | Aluminium alloy strip for brazing |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US20070099023A1 (enExample) |
| EP (1) | EP1687115B1 (enExample) |
| JP (1) | JP5701470B2 (enExample) |
| KR (1) | KR101184173B1 (enExample) |
| CN (1) | CN100581700C (enExample) |
| AT (1) | ATE419945T1 (enExample) |
| BR (1) | BRPI0416974A (enExample) |
| CA (1) | CA2547833C (enExample) |
| DE (2) | DE04805532T1 (enExample) |
| FR (1) | FR2862894B1 (enExample) |
| MX (1) | MXPA06005900A (enExample) |
| NO (1) | NO340339B1 (enExample) |
| WO (1) | WO2005061165A1 (enExample) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080118393A1 (en) * | 2006-10-13 | 2008-05-22 | Anders Oskarsson | High strength and sagging resistant fin material |
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| CN113574192A (zh) | 2019-03-13 | 2021-10-29 | 诺维尔里斯公司 | 可时效硬化且可高度成形的铝合金及其制备方法 |
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- 2004-11-24 BR BRPI0416974-3A patent/BRPI0416974A/pt not_active IP Right Cessation
- 2004-11-24 DE DE04805532T patent/DE04805532T1/de active Pending
- 2004-11-24 CN CN200480033570A patent/CN100581700C/zh not_active Expired - Lifetime
- 2004-11-24 EP EP04805532A patent/EP1687115B1/fr not_active Revoked
- 2004-11-24 DE DE602004018970T patent/DE602004018970D1/de not_active Expired - Lifetime
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9493861B2 (en) | 2006-10-13 | 2016-11-15 | Gränges Sweden Ab | High strength and sagging resistant fin material |
| US20080118393A1 (en) * | 2006-10-13 | 2008-05-22 | Anders Oskarsson | High strength and sagging resistant fin material |
| US10131970B2 (en) | 2006-10-13 | 2018-11-20 | Gränges Sweden Ab | High strength and sagging resistant fin material |
| US20100209206A1 (en) * | 2009-02-19 | 2010-08-19 | Kennametal Inc. | Cutting tool components with wear-resistant cladding layer |
| US8123440B2 (en) | 2009-02-19 | 2012-02-28 | Kennametal Inc. | Cutting tool components with wear-resistant cladding layer |
| US20120177947A1 (en) * | 2009-09-17 | 2012-07-12 | Sapa Heat Tranfer Ab | Aluminium brazing sheet |
| US20130306714A1 (en) * | 2011-01-31 | 2013-11-21 | Aleris Rolled Products Germany Gmbh | Aluminium brazing sheet material for fluxless brazing |
| US8763880B2 (en) * | 2011-01-31 | 2014-07-01 | Aleris Rolled Products Germany Gmbh | Aluminium brazing sheet material for fluxless brazing |
| US9377249B2 (en) | 2011-04-20 | 2016-06-28 | Aleris Rolled Products Germany Gmbh | Fin stock material |
| US9885098B2 (en) | 2012-11-15 | 2018-02-06 | Nippon Light Metal Company, Ltd. | Aluminum alloy plate for battery cases, which has excellent moldability and weldability |
| US10661395B2 (en) | 2014-07-30 | 2020-05-26 | Uacj Corporation | Aluminum-alloy brazing sheet |
| CN104711460A (zh) * | 2015-03-23 | 2015-06-17 | 苏州市神龙门窗有限公司 | 一种含钛耐腐蚀铝合金材料及其处理工艺 |
| WO2017080771A1 (en) | 2015-11-10 | 2017-05-18 | Aleris Rolled Products Germany Gmbh | Fluxless brazing method |
| DE112016005165T5 (de) | 2015-11-10 | 2018-07-19 | Aleris Rolled Products Germany Gmbh | Flussmittelfreies Hartlötverfahren |
| WO2017137236A1 (en) | 2016-02-09 | 2017-08-17 | Aleris Rolled Products Germany Gmbh | Aluminium multi-layered brazing sheet product and fluxless brazing method |
| US20190077119A1 (en) * | 2016-02-09 | 2019-03-14 | Aleris Rolled Products Germany Gmbh | Aluminium multi-layered brazing sheet product and fluxless brazing method |
| DE202017100499U1 (de) | 2016-02-09 | 2017-05-10 | Aleris Rolled Products Germany Gmbh | Aluminium Multi-Schicht Hartlötblechprodukt |
| US11225051B2 (en) * | 2016-02-09 | 2022-01-18 | Aleris Rolled Products Germany Gmbh | Aluminium multi-layered brazing sheet product and fluxless brazing method |
| CN109576697A (zh) * | 2018-11-23 | 2019-04-05 | 江苏科技大学 | 一种铝基涂层及制备方法、采用该涂层制备的铝合金复合材料及制备方法 |
| US20220347798A1 (en) * | 2019-10-04 | 2022-11-03 | Mitsubishi Aluminum Co., Ltd. | Aluminum brazing sheet and method for flux-free brazing of aluminum members |
Also Published As
| Publication number | Publication date |
|---|---|
| NO20063022L (no) | 2006-07-28 |
| WO2005061165A1 (fr) | 2005-07-07 |
| US20110315748A1 (en) | 2011-12-29 |
| CN1882407A (zh) | 2006-12-20 |
| JP2007521396A (ja) | 2007-08-02 |
| JP5701470B2 (ja) | 2015-04-15 |
| DE602004018970D1 (de) | 2009-02-26 |
| FR2862894B1 (fr) | 2007-02-16 |
| KR101184173B1 (ko) | 2012-09-19 |
| CA2547833C (fr) | 2014-01-21 |
| EP1687115B1 (fr) | 2009-01-07 |
| CA2547833A1 (fr) | 2005-07-07 |
| BRPI0416974A (pt) | 2007-02-21 |
| KR20060123217A (ko) | 2006-12-01 |
| DE04805532T1 (de) | 2007-01-04 |
| US8413876B2 (en) | 2013-04-09 |
| NO340339B1 (no) | 2017-04-03 |
| CN100581700C (zh) | 2010-01-20 |
| EP1687115A1 (fr) | 2006-08-09 |
| ATE419945T1 (de) | 2009-01-15 |
| MXPA06005900A (es) | 2006-06-27 |
| FR2862894A1 (fr) | 2005-06-03 |
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